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    • 4. 发明授权
    • TiB.sub.2 -based materials and process of producing the same
    • 基于TiB2的材料及其制备方法
    • US4673550A
    • 1987-06-16
    • US910859
    • 1986-09-24
    • Serge DallaireBlaise Champagne
    • Serge DallaireBlaise Champagne
    • C01B35/04C04B35/58C04B35/65C22C1/05C22C29/14C23C4/06B22F1/00
    • C04B35/58071C01B35/04C04B35/645C04B35/651C22C1/058C22C29/14C23C4/06
    • There is disclosed a process for synthesizing TiB.sub.2 composite materials containing a metallic phase. The preparation of these composites comprises providing mixtures of titanium alloys which in addition to at least 30 wt. % titanium also contain F, Ni, Al, Mo, Cr, Co, Cu or mixtures thereof, and boron or ferroboron, reacting these mixtures by local igniting and exothermic reaction or by heating or melting, resulting in the synthesis of composite material containing fine TiB.sub.2 crystals dispersed in a fine metallic phase which is derived from the metallic element previously alloyed or combined with the titanium of the titanium alloys or the metallic element or elements contained in the ferroboron. By leaching out the metallic phase, fine TiB.sub.2 powders may be obtained. Parts and coatings can also be obtained. The parts are normally obtained by treating the TiB.sub.2 material by powder metallurgic techniques. Coatings may be obtained by thermo or plasma spray depositing on a substrate. Hard facing techniques may lead to TiB.sub.2 composite overlays.
    • 公开了一种合成含有金属相的TiB 2复合材料的方法。 这些复合材料的制备包括提供钛合金的混合物,该合金除了至少30wt。 %钛还含有F,Ni,Al,Mo,Cr,Co,Cu或其混合物,硼或铁硼,通过局部点燃和放热反应或通过加热或熔融使这些混合物反应,导致合成含有精细的复合材料 分散在细金属相中的TiB 2晶体,其衍生自先前与钛合金的钛合金化或与铁硼中包含的金属元素组合的金属元素。 通过浸出金属相,可以获得细小的TiB 2粉末。 也可以获得零件和涂层。 这些部件通常通过粉末冶金技术处理TiB 2材料来获得。 可以通过在基底上进行热或等离子体喷涂沉积获得涂层。 硬面技术可能导致TiB2复合叠层。
    • 6. 发明授权
    • Process and apparatus for coating particles with fine powder
    • 用细粉末涂覆颗粒的方法和设备
    • US4788080A
    • 1988-11-29
    • US42715
    • 1987-04-27
    • Junichi HojoSerge DallaireBlaise Champagne
    • Junichi HojoSerge DallaireBlaise Champagne
    • B01J2/00B05D1/00B05D7/00B22F1/02C04B41/45C04B41/81B05D7/24
    • C04B41/009B01J2/006B05D1/00B05D7/00B22F1/02C04B41/4584C04B41/81B05D2258/00
    • There is disclosed a process for coating particles, such as ceramic, metallic and organic cores, with fine powder, such as ceramic, metal, organic or carbon powder. The process comprises providing a mixture comprising the particles and a binder which is capable of slowly melting to viscous state. Then the mixture is tumbled while slowly heating it to enable the binder to reach the viscous state while allowing the particles to be substantially covered with the binder. The next step includes cooling the mixture to about room temperature and thereafter breaking up the particles that may have agglomerated during the tumbling and heating to give individual particles covered with the binder. As a final step, the fine powder is added to the individual binder covered particles and the mixture is tumbled and heated again to the viscous state under conditions effective to provide a coating of the fine powder on the particles. Additional heating may be carried out to remove the binder and leave particles exclusively coated with the fine powder. The apparatus includes a rotating cylinder, heating and cooling means. The resulting product has a more uniform microstructure and higher bonding strength than a product resulting from a conventional mixing of ingredients.
    • 公开了用微细粉末如陶瓷,金属,有机或碳粉末涂覆诸如陶瓷,金属和有机芯的颗粒的方法。 该方法包括提供包含颗粒的混合物和能够缓慢熔化成粘性状态的粘合剂。 然后混合物翻滚,同时缓慢加热,使粘合剂达到粘性状态,同时允许颗粒基本上被粘合剂覆盖。 下一步骤包括将混合物冷却至约室温,然后分解在翻滚和加热期间可能发生团聚的颗粒,从而得到用粘合剂覆盖的单个颗粒。 作为最终步骤,将细粉末加入到单个粘合剂覆盖的颗粒中,并且在有效地在颗粒上提供细粉末涂层的条件下,将混合物翻转并再次加热至粘性状态。 可以进行另外的加热以除去粘合剂并且留下仅涂覆有细粉末的颗粒。 该装置包括旋转圆筒,加热和冷却装置。 所得到的产品具有比由常规的成分混合产生的产品更均匀的微观结构和更高的粘结强度。