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1. 发明授权

US07329779B2 Process for preparing optionally substituted arylsulphonic anhydrides 失效
标题翻译：制备任选取代的芳基磺酸酐的方法
公开(公告)号：US07329779B2
公开(公告)日：2008-02-12
申请号：US11392009
申请日：2006-03-29
申请人： Björn Schlummer , Florian Rampf , Paul Naab , Guido Giffels , Matthias Gotta
发明人： Björn Schlummer , Florian Rampf , Paul Naab , Guido Giffels , Matthias Gotta
IPC分类号： C07C303/00
CPC分类号： C07C303/22 , C07C303/00 , C07C309/00
摘要： The present invention relates to a process for preparing optionally substituted arylsulphonic anhydrides of the general formula (I)
摘要翻译：本发明涉及制备通式（I）的任选取代的芳基磺酸酐的方法，

2. 发明申请

US20060229468A1 Process for preparing optionally substituted arylsulphonic anhydrides 失效
标题翻译：制备任选取代的芳基磺酸酐的方法
公开(公告)号：US20060229468A1
公开(公告)日：2006-10-12
申请号：US11392009
申请日：2006-03-29
申请人： Bjorn Schlummer , Florian Rampf , Paul Naab , Guido Giffels , Matthias Gotta
发明人： Bjorn Schlummer , Florian Rampf , Paul Naab , Guido Giffels , Matthias Gotta
IPC分类号： C07C309/00
CPC分类号： C07C303/22 , C07C303/00 , C07C309/00
摘要： The present invention relates to a process for preparing optionally substituted arylsulphonic anhydrides of the general formula (I)
摘要翻译：本发明涉及制备通式（I）的任选取代的芳基磺酸酐的方法，

3. 发明授权

US08227641B2 Process for the preparation of aminoalkylamines 失效
标题翻译：制备氨基烷基胺的方法
公开(公告)号：US08227641B2
公开(公告)日：2012-07-24
申请号：US12520877
申请日：2007-12-12
申请人： Florian Rampf , Guido Giffels
发明人： Florian Rampf , Guido Giffels
IPC分类号： C07C209/48
CPC分类号： C07C209/48 , C07C211/14
摘要： Process for the preparation of polyfunctional amines of the formulae by hydrogenation of the associated nitriles of the formulae with hydrogen, where A is an aromatic or aliphatic compound from the group of unsubstituted or substituted phenylene or naphthylene, methylene, unsubstituted or substituted ethylene, propylene, unsubstituted or substituted straight-chain or branched butylene, pentylene, hexylene, heptylene, octylene, nonylene, decylene and B is a straight-chain or branched aliphatic carbon chain having 1 to 10 carbon atoms, and X can be missing or is a straight-chain or branched aliphatic carbon chain having 1 to 10 carbon atoms, wherein a melt, solution or suspension of the nitrile of formula (III) or (IV) is added over the course of the reaction time to a suspension or solution of a catalyst in a solvent which comprises ammonia and is stirred at a temperature range from 60 to 150° C. under hydrogen pressure.
摘要翻译：通过用氢氢化式的相关腈，制备下式的多官能胺的方法，其中A是未取代或取代的亚苯基或亚萘基的芳族或脂族化合物，亚甲基，未取代或取代的亚乙基，亚丙基，未取代或取代的直链或支链亚丁基，亚戊基，亚己基，亚庚基，亚辛基，亚壬基，亚癸基，B是具有1-10个碳原子的直链或支链脂族碳链，X可以缺失，具有1至10个碳原子的链或支链脂族碳链，其中在反应时间内将式（III）或（IV）腈的熔体，溶液或悬浮液加入催化剂的悬浮液或溶液中包含氨的溶剂，并在氢压力下在60至150℃的温度范围内搅拌。

4. 发明申请

US20100145102A1 PROCESS FOR THE PREPARATION OF AMINOALKYLAMINES 失效
标题翻译：制备氨基甲酰胺的方法
公开(公告)号：US20100145102A1
公开(公告)日：2010-06-10
申请号：US12520877
申请日：2007-12-12
申请人： Florian Rampf , Guido Giffels
发明人： Florian Rampf , Guido Giffels
IPC分类号： C07C209/48
CPC分类号： C07C209/48 , C07C211/14
摘要： A process for the preparation of polyfunctional amines of the formulae by hydrogenation of the associated nitriles of the formulae with hydrogen, where A is an aromatic or aliphatic compound from the group of unsubstituted or substituted phenylene or naphthylene, methylene, unsubstituted or substituted ethylene, propylene, unsubstituted or substituted straight-chain or branched butylene, pentylene, hexylene, heptylene, octylene, nonylene, decylene and B is a straight-chain or branched aliphatic carbon chain having 1 to 10 carbon atoms, such as methylene, unsubstituted or substituted ethylene, propylene, unsubstituted or substituted straight-chain or branched butylene, pentylene, hexylene, heptylene, octylene, nonylene, decylene, where at least one CH2 unit must be in direct vicinity to the amino group, and X can be missing or is a straight-chain or branched aliphatic carbon chain having 1 to 10 carbon atoms, such as methylene, unsubstituted or substituted ethylene, propylene, unsubstituted or substituted straight-chain or branched butylene, pentylene, hexylene, heptylene, octylene, nonylene, decylene, characterized in that a melt, solution or suspension of the nitrile of the formula (I) or (II) is added over the course of the reaction time to a suspension or solution of a catalyst in a solvent which comprises ammonia and optionally other additives and is stirred at a temperature in the range from 60 to 150° C. under hydrogen pressure, is described.
摘要翻译：一种制备下式的多官能胺的方法，其通过用氢氢化下式的相关腈，其中A是未取代或取代的亚苯基或亚萘基的芳族或脂族化合物，亚甲基，未取代或取代的亚乙基，亚丙基未取代或取代的直链或支链亚丁基，亚戊基，亚己基，亚庚基，亚辛基，亚丁基，亚芳基，B是具有1-10个碳原子的直链或支链脂族碳链，如亚甲基，未取代或取代的亚乙基，丙烯，未取代或取代的直链或支链亚丁基，亚戊基，亚己基，亚庚基，亚辛基，亚壬基，亚芳基，其中至少一个CH2单元必须直接与氨基相邻，并且X可以缺失或是直链，具有1-10个碳原子的链或支链脂族碳链，例如亚甲基，未取代或取代的亚乙基，亚丙基，未取代的烷基带有或取代的直链或支链亚丁基，亚戊基，亚己基，亚庚基，亚辛基，亚壬基，亚癸基，其特征在于在式（I）或（II）的腈的熔体，溶液或悬浮液中加入式描述了在氢气压力下在60至150℃的温度下搅拌到催化剂在包含氨和任选的其它添加剂的溶剂中的悬浮液或溶液的反应时间。

5. 发明申请

US20140031564A1 PROCESS FOR PREPARING (S)-3-N-METHYLAMINO-1-(2-THIENYL)-1-PROPANOL 审中-公开
标题翻译：制备（S）-3-N-甲基氨基-1-（2-噻吩基）-1-丙醇的方法
公开(公告)号：US20140031564A1
公开(公告)日：2014-01-30
申请号：US13819447
申请日：2011-08-26
申请人： Michael Kreis , Antje Steinhaus , Guido Giffels , Oliver Krebs
发明人： Michael Kreis , Antje Steinhaus , Guido Giffels , Oliver Krebs
IPC分类号： C07D333/20
CPC分类号： C07D333/20
摘要： The present invention relates to a method for preparing (S)-3-N-methylamino-1-(2-thienyl)-1-propanol and salts thereof.
摘要翻译：本发明涉及制备（S）-3-N-甲基氨基-1-（2-噻吩基）-1-丙醇及其盐的方法。

6. 发明授权

US06844462B2 Biphenydiols 有权
标题翻译：联苯二醇
公开(公告)号：US06844462B2
公开(公告)日：2005-01-18
申请号：US10408493
申请日：2003-04-07
申请人： Birgit Drieben-Hölscher , Joachim Kralik , Inga Ritzkopf , Christian Steffens , Guido Giffels , Claus Dreisbach , Thomas Prinz
发明人： Birgit Drieben-Hölscher , Joachim Kralik , Inga Ritzkopf , Christian Steffens , Guido Giffels , Claus Dreisbach , Thomas Prinz
IPC分类号： B01J23/46 , B01J31/24 , C07B53/00 , C07B57/00 , C07B61/00 , C07C43/23 , C07C67/303 , C07C69/34 , C07C303/28 , C07C309/65 , C07D321/10 , C07F9/50 , C07F9/572 , C07F9/655 , C07F15/00 , C07C309/04 , C07C309/06 , C07C43/205
CPC分类号： B01J31/2409 , B01J2231/641 , B01J2231/645 , B01J2531/0266 , B01J2531/80 , B01J2531/821 , B01J2531/822 , B01J2531/827 , C07C303/28 , C07D321/10 , C07F9/5027 , C07F9/5072 , C07F9/572 , C07F9/65515 , C07F15/0013 , C07F15/004 , C07F15/0053 , C07F15/008 , C07C309/65
摘要： The invention relates to the biphenyldiols of the formula (V) The corresponding racemic and enantiomerically pure triflate compounds thereof, where R1 and R2 are H, R3 is chlorine, and R4 is methoxy.In an alternate embodiment, R1 and R2 are hydrogen and R3 and R4 are C1-C4-alkoxy, fluorine, or chlorine.
摘要翻译：本发明涉及式（Ⅴ）的联苯二醇其相应的外消旋和对映体纯的三氟甲磺酸酯化合物，其中R 1和R 2为H，R 3为氯，R 4为甲氧基。在另一个实施方案中，R 1和R 2是氢，R 3和R 4是C 1 -C 4 - 烷氧基，氟或氯。

7. 发明授权

US06180837B2 Process for the catalytic enantioselective reduction of ketones 失效
标题翻译：催化对映选择性还原酮的方法
公开(公告)号：US06180837B2
公开(公告)日：2001-01-30
申请号：US09308211
申请日：1999-07-13
申请人： Guido Giffels , Marcel Felder , Udo Kragl , Christian Wandrey , Andreas Bommarius , Carsten Bolm , Nadine Derrien , Karlheinz Drauz
发明人： Guido Giffels , Marcel Felder , Udo Kragl , Christian Wandrey , Andreas Bommarius , Carsten Bolm , Nadine Derrien , Karlheinz Drauz
IPC分类号： C07C29143
CPC分类号： C07C29/143 , C07B2200/07 , C07C33/22
摘要： The invention involves a procedure for the catalytic enantioselective reduction of ketones to chiral alcohols. Heretofore, this reaction was carried out batch-wise. Because, in this procedure, one utilizes a catalyst increased in size with polymer, it is possible to carry out the reaction in a quasi-continuous manner in a membrane reactor. In contrast to the state of the art, one thus dramatically increases the operative life of the catalyst.
摘要翻译：本发明涉及用于将酮催化对映选择性还原成手性醇的方法。迄今为止，该反应是间歇进行的。因为在该方法中，使用聚合物尺寸增加的催化剂，可以在膜反应器中以准连续的方式进行反应。与现有技术相反，因此大大增加了催化剂的使用寿命。

8. 发明授权

US07119237B2 Process and catalyst for preparing alcohols 有权
公开(公告)号：US07119237B2
公开(公告)日：2006-10-10
申请号：US10368767
申请日：2003-02-19
申请人： Thomas Prinz , Jürgen Kintrup , Andreas Schulze Tilling , Jörg-Dietrich Jentsch , Gerald John , Hans-Jürgen Grob , Guido Giffels
发明人： Thomas Prinz , Jürgen Kintrup , Andreas Schulze Tilling , Jörg-Dietrich Jentsch , Gerald John , Hans-Jürgen Grob , Guido Giffels
IPC分类号： B01J23/02 , B01J23/06 , C07C27/04 , C07C29/149
CPC分类号： B01J37/035 , B01J23/80 , B01J35/023 , B01J35/10 , B01J35/1014 , B01J35/1038 , B01J35/108 , B01J37/0018 , B01J37/03 , C07C29/149 , C07C31/20
摘要： Alcohols prepared by reacting carboxylic acids and/or carboxylic esters with hydrogen in the presence of a special catalyst.

9. 发明授权

US06462200B2 Diphosphines 失效
标题翻译：二膦
公开(公告)号：US06462200B2
公开(公告)日：2002-10-08
申请号：US09948826
申请日：2001-09-07
申请人： Birgit Driessen-Hölscher , Joachim Kralik , Inga Ritzkopf , Christian Steffens , Guido Giffels , Claus Dreisbach , Thomas Prinz , Walter Lange
发明人： Birgit Driessen-Hölscher , Joachim Kralik , Inga Ritzkopf , Christian Steffens , Guido Giffels , Claus Dreisbach , Thomas Prinz , Walter Lange
IPC分类号： C07F9572
CPC分类号： B01J31/2409 , B01J2231/641 , B01J2231/645 , B01J2531/0266 , B01J2531/80 , B01J2531/821 , B01J2531/822 , B01J2531/827 , C07C303/28 , C07D321/10 , C07F9/5027 , C07F9/5072 , C07F9/572 , C07F9/65515 , C07F15/0013 , C07F15/004 , C07F15/0053 , C07F15/008 , C07C309/65
摘要： The invention relates to the preparation and use as catalysts of diphosphines of the formula (I) in which R is C6-C14-aryl or C4-C13-heteroaryl containing 1 to 3 heteroatoms selected from the group consisting of nitrogen, oxygen, and sulfur, wherein the aryl and heteroaryl radicals may optionally be substituted by halogen, C1-C6-alkyl, C1-C6-alkoxy, and/or trimethylsilyl, and R1 to R4, independently of one another, are each hydrogen, C1-C10-alkyl, C1-C10-alkoxy, F, Cl, or Br.
摘要翻译：本发明涉及制备和用作式（I）的二膦的催化剂，其中R是含有1至3个选自氮，氧和硫的杂原子的C 6 -C 14 - 芳基或C 4 -C 13 - 杂芳基，其中芳基和杂芳基可以任选被卤素，C 1 -C 6 - 烷基，C 1 -C 6 - 烷氧基和/或三甲基甲硅烷基取代，R 1 -R 4各自独立地为氢，C 1 -C 10 - 烷基，C 1 -C 10 - 烷氧基，F，Cl或Br。

10. 发明授权

US06566298B2 Diphosphines 有权
公开(公告)号：US06566298B2
公开(公告)日：2003-05-20
申请号：US10219750
申请日：2002-08-15
申请人： Birgit Driessen-Hölscher , Joachim Kralik , Inga Ritzkopf , Christian Steffens , Guido Giffels , Claus Dreisbach , Thomas Prinz , Walter Lange
发明人： Birgit Driessen-Hölscher , Joachim Kralik , Inga Ritzkopf , Christian Steffens , Guido Giffels , Claus Dreisbach , Thomas Prinz , Walter Lange
IPC分类号： B01J3124
CPC分类号： B01J31/2409 , B01J2231/641 , B01J2231/645 , B01J2531/0266 , B01J2531/80 , B01J2531/821 , B01J2531/822 , B01J2531/827 , C07C303/28 , C07D321/10 , C07F9/5027 , C07F9/5072 , C07F9/572 , C07F9/65515 , C07F15/0013 , C07F15/004 , C07F15/0053 , C07F15/008 , C07C309/65
摘要： The invention relates to the preparation and use as catalysts of diphosphines of the formula (I) in which R is C6-C14-aryl or C4-C13-heteroaryl containing 1 to 3 heteroatoms selected from the group consisting of nitrogen, oxygen, and sulfur, wherein the aryl and heteroaryl radicals may optionally be substituted by halogen, C1-C6-alkyl, C1-C6-alkoxy, and/or trimethylsilyl, and R1 to R4, independently of one another, are each hydrogen, C1-C10-alkyl, C1-C10-alkoxy, F, Cl, or Br.

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