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    • 5. 发明申请
    • UV-CURING PROTECTIVE LAYER FOR THERMOPLASTIC SUBSTRATES
    • 用于热塑性基材的UV固化保护层
    • US20120114933A1
    • 2012-05-10
    • US13319628
    • 2010-05-04
    • Birgit Meyer Zu BerstenhorstFrank Buckel
    • Birgit Meyer Zu BerstenhorstFrank Buckel
    • B32B5/16B32B27/00C09D175/14
    • C09D4/00C08F222/1006C08K7/00C09D175/16Y10T428/259Y10T428/31855
    • The invention relates to a multilayer product containing a first layer (S1) and a second layer (S2). The first layer is a lacquer obtained from A) one or more aliphatic polymer precursors selected from among at least one of the groups comprising components A.1 and A.2, wherein A.1) represents aliphatic oligomers that contain urethane or ester bonds and have at least two acrylate functions per molecule, or mixtures of corresponding oligomers, and A.2) represents aliphatic reactive diluents having at least two acrylate groups per molecule, or mixtures of corresponding reactive diluents, B) one or more fine-particle inorganic compounds, C) at least one organic UV absorber selected from among the group of triazine derivatives and diphenyl triazine derivatives, D) 0.1 to 2 wt. %, relative to the experimentally determined solid content of the mixture of components A, B, and F, of a radical interceptor belonging to the class of basic HALS, E) one or more optional self-leveling agents, F) one or more optional solvents, and G) at least one Norrish type II photoinitiator. The second layer is a thermoplastic polymer. The invention also relates to a lacquer made of the aforementioned components.
    • 本发明涉及含有第一层(S1)和第二层(S2)的多层产品。 第一层是由A)一种或多种选自包含组分A.1和A.2的至少一种的脂族聚合物前体得到的漆,其中A.1)表示含有氨基甲酸酯或酯键的脂族低聚物, 每分子具有至少两个丙烯酸酯官能团或相应的低聚物的混合物,A.2)表示每分子具有至少两个丙烯酸酯基团的脂族反应性稀释剂或相应的反应性稀释剂的混合物,B)一种或多种细颗粒无机化合物 C)至少一种选自三嗪衍生物和二苯基三嗪衍生物的有机紫外线吸收剂,D)0.1〜2重量% 相对于属于基本HALS类的自由基拦截器的组分A,B和F的混合物的实验测定的固体含量,E)一种或多种任选的自流平剂,F)一种或多种任选的 溶剂和G)至少一种Norrish II型光引发剂。 第二层是热塑性聚合物。 本发明还涉及由上述组分制成的漆。