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1. 发明授权

US08895137B2 Scratch resistant top coats having good adhesion 有权
标题翻译：具有良好附着力的耐刮擦顶层
公开(公告)号：US08895137B2
公开(公告)日：2014-11-25
申请号：US12973079
申请日：2010-12-20
申请人： Birgit Meyer Zu Berstenhorst , Peter Capellen
发明人： Birgit Meyer Zu Berstenhorst , Peter Capellen
IPC分类号： B32B7/02 , B32B9/04 , B32B27/00 , C08K5/544 , C09D5/32 , C09D7/12 , B05D7/02 , B05D7/00 , C08K5/3492
CPC分类号： C08K5/5442 , B05D7/02 , B05D7/57 , B32B7/02 , B32B2307/71 , C08K5/34926 , C09D5/32 , C09D7/48 , C09D7/63 , Y10T428/2495 , Y10T428/31507 , Y10T428/31536 , Y10T428/31663
摘要： The present invention relates to a multilayer system comprising a base layer consisting of a thermoplastic, a primer layer, and a scratch resistant layer consisting of a scratch resistant top coat, the multilayer system being characterized in that the primer layer contains a certain UV absorber and a certain amount of acid, preferably acetic acid, is added to the scratch resistant top coat.
摘要翻译：本发明涉及一种多层体系，其包含由热塑性塑料，底漆层和耐擦伤层组成的基层，所述耐刮层由抗划伤面漆组成，所述多层体系的特征在于底漆层含有一定的紫外线吸收剂和将一定量的酸，优选乙酸加入到耐划伤面漆中。

2. 发明申请

US20110151218A1 SCRATCH RESISTANT TOP COATS HAVING GOOD ADHESION 有权
标题翻译：具有良好粘合性的防滑顶层
公开(公告)号：US20110151218A1
公开(公告)日：2011-06-23
申请号：US12973079
申请日：2010-12-20
申请人： Birgit Meyer Zu Berstenhorst , Peter Capellen
发明人： Birgit Meyer Zu Berstenhorst , Peter Capellen
IPC分类号： B32B7/02 , B32B9/04 , B32B27/00
CPC分类号： C08K5/5442 , B05D7/02 , B05D7/57 , B32B7/02 , B32B2307/71 , C08K5/34926 , C09D5/32 , C09D7/48 , C09D7/63 , Y10T428/2495 , Y10T428/31507 , Y10T428/31536 , Y10T428/31663
摘要： The present invention relates to a multilayer system comprising a base layer consisting of a thermoplastic, a primer layer, and a scratch resistant layer consisting of a scratch resistant top coat, the multilayer system being characterised in that the primer layer contains a certain UV absorber and a certain amount of acid, preferably acetic acid, is added to the scratch resistant top coat.
摘要翻译：本发明涉及一种多层体系，其包含由热塑性塑料，底漆层和耐擦伤层组成的基层，所述耐刮层由抗划伤面漆组成，所述多层体系的特征在于底漆层含有一定的紫外线吸收剂和将一定量的酸，优选乙酸加入到耐划伤面漆中。

3. 发明授权

US07250219B2 Multilayered article and a process for its preparation 有权
标题翻译：多层文章及其准备过程
公开(公告)号：US07250219B2
公开(公告)日：2007-07-31
申请号：US10673906
申请日：2003-09-29
申请人： Peter Bier , Peter Capellen
发明人： Peter Bier , Peter Capellen
IPC分类号： B32B27/06 , B32B7/02 , B32B7/04
CPC分类号： C09D183/04 , B05D3/08 , B05D3/141 , B05D7/546 , B05D7/58 , C08J7/042 , C08J2369/00 , C08J2483/04 , C08J2483/14 , C09D183/14 , Y10T428/31663
摘要： A multilayered article is disclosed, which includes, in sequence: (1) a substrate (S), e.g., of thermoplastic polycarbonate; (2) a scratch-resistant layer (SR); and (3) a top layer (T). The scratch-resistant layer is prepared by curing a scratch-resistant coating composition comprising a polycondensate prepared from at least one silane, said polycondensate being prepared by a sol-gel process. The top layer is prepared by curing a top layer coating composition prepared by hydrolyzing a composition which includes: at lest one compound represented by general formula I, M(R′)m (I) wherein M is an element selected from the group consisting of Si, Ti, Zr, Sn, Ce, Al, B, VO, In and Zn, R′ represents a hydrolysable radical, and m is an integer from 2 to 4; and optionally at least one compound represented by general formula II, RbSiR′a, (II) wherein the radicals R′ and R are the same or different, R′ is as defined for general formula (I), R represents a group selected from an alkyl group, an alkenyl group, an aryl group, a hydrocarbon group with at least one halogen group, an epoxide group, a glycidyloxy group, an amino group, a mercapto group, a methacryloxy group and a cyano group, and a and b independently of one another have a value from 1 to 3, provided that the sum of a and b is four. The multilayered articles are distinguished by possessing outstanding scratch and abrasion resistance.
摘要翻译：公开了一种多层制品，其顺序包括：（1）基底（S），例如热塑性聚碳酸酯; （2）防刮层（SR）; 和（3）顶层（T）。通过固化包含由至少一种硅烷制备的缩聚物的耐刮擦涂料组合物制备耐擦伤层，所述缩聚物通过溶胶 - 凝胶法制备。顶层是通过将通过水解组合物制备的顶层涂料组合物固化而制备的，所述组合物包括：至少一种由通式I表示的化合物，<？在线公式描述=“In-line Formula”end =“lead” α（M'）（I）<βin-line-formula description =“In-line Formulas”end =“tail”？>其中M是选自的Si，Ti，Zr，Sn，Ce，Al，B，VO，In和Zn，R'表示可水解基团，m为2〜4的整数。和任选的至少一种由通式II表示的化合物，<？in-line-formula description =“In-line Formulas”end =“lead”？> R b SiR' 其中基团R'和R相同或不同，R'如通式（ⅰ）所定义，（I）中，R表示选自烷基，烯基，芳基，具有至少一个卤素基团的烃基，环氧基，缩水甘油氧基，氨基，巯基，甲基丙烯酰氧基基团和氰基，a和b彼此独立地具有1至3的值，条件是a和b之和为4。多层制品具有突出的耐刮擦和耐磨性。

4. 发明申请

US20050194721A1 Polycarbonate molded parts having low dust attraction 审中-公开
标题翻译：聚碳酸酯模制件具有低吸尘性
公开(公告)号：US20050194721A1
公开(公告)日：2005-09-08
申请号：US10858677
申请日：2004-06-02
申请人： Peter Bier , Peter Capellen
发明人： Peter Bier , Peter Capellen
IPC分类号： C08J7/06 , B29C71/00
CPC分类号： C08J7/06 , C08J2369/00
摘要： A process for the production of polycarbonate molded article having low dust attraction is disclosed. the process entails treating at least a portion of the surface of a molded article by at least one procedure selected from the group consisting of flame treatment, corona treatment and plasma treatment to obtain a treated surface.
摘要翻译：公开了一种制造具有低吸尘性的聚碳酸酯成型体的方法。该方法需要通过选自火焰处理，电晕处理和等离子体处理的至少一种方法处理模塑制品的至少一部分表面以获得处理过的表面。

5. 发明授权

US08722778B2 UV protective compositions, processes for preparing such compositions, methods of coating substrates therewith and multi-layer articles formed thereby 有权
标题翻译：紫外线防护组合物，制备这种组合物的方法，用其涂覆基材的方法和由此形成的多层制品
公开(公告)号：US08722778B2
公开(公告)日：2014-05-13
申请号：US12254387
申请日：2008-10-20
申请人： Gunther Stollwerck , Robert Maleika , Frank Buckel , Peter Capellen
发明人： Gunther Stollwerck , Robert Maleika , Frank Buckel , Peter Capellen
IPC分类号： C08K5/3492 , C09D5/00 , C09J9/00 , C09J133/08 , C09J133/12 , B05D3/00
CPC分类号： C09D5/002 , C08K5/34926 , C09D7/48
摘要： Compositions, suitable for coating surfaces, methods for their preparation and for coating surfaces therewith, where said compositions comprise: (a) 100,000 parts by weight of a primer composition comprising a binder material (a1), a primer solvent (a2) and a UV absorber (a3), wherein the primer composition is suitable as an adhesion-promoting agent between a thermoplastic substrate and a siloxane-based top coat; (b) 0 to 900,000 parts by weight of a solvent, and (c) 1 to 3000 parts by weight of a compound according to the general formula (I): wherein X represents a moiety selected from the group consisting —OR6, —OCH2CH2OR6, —OCH2CH(OH)CH2OR6 and —OCH(R7)COOR8, wherein R6 represents a branched or unbranched C1-C13 alkyl, C2-C20 alkenyl, C6-C12 aryl or —CO—C1-C18 alkyl, R7 represents H or a branched or unbranched C1-C8 alkyl, and R8 represents a C1-C12 alkyl, a C2-C12 alkenyl or a C5-C6 cycloalkyl, and wherein the composition has a viscosity of 40 s to 140 s measured in accordance with DIN EN ISO 2431 at 23° C. and with a 2 mm cup.
摘要翻译：组合物，适用于涂料表面，其制备方法和用于涂布表面，其中所述组合物包含：（a）100,000重量份的底漆组合物，其包含粘合剂材料（a1），底漆溶剂（a2）和UV 吸收剂（a3），其中底漆组合物适合作为热塑性基材与硅氧烷类面漆之间的粘合促进剂; （b）0〜900,000重量份溶剂，（c）1〜3000重量份根据通式（I）的化合物：其中X表示选自-OR 6，-OCH 2 CH 2 OR 6的部分，-OCH 2 CH（OH）CH 2 OR 6和-OCH（R 7）COOR 8，其中R 6表示支链或非支链C 1 -C 13烷基，C 2 -C 20烯基，C 6 -C 12芳基或-CO-C 1 -C 18烷基，R 7表示H或支链或非支链C 1 -C 8烷基，R 8表示C 1 -C 12烷基，C 2 -C 12烯基或C 5 -C 6环烷基，并且其中所述组合物的粘度为40秒至140秒，根据DIN EN ISO 2431测量在23℃和2mm杯。

6. 发明申请

US20090130489A1 UV PROTECTIVE COMPOSITIONS, PROCESSES FOR PREPARING SUCH COMPOSITIONS, METHODS OF COATING SUBSTRATES THEREWITH AND MULTI-LAYER ARTICLES FORMED THEREBY 有权
标题翻译：紫外线防护组合物，制备这些组合物的方法，涂覆基质的方法和形成的多层制品
公开(公告)号：US20090130489A1
公开(公告)日：2009-05-21
申请号：US12254387
申请日：2008-10-20
申请人： Gunther Stollwerck , Robert Maleika , Frank Buckel , Peter Capellen
发明人： Gunther Stollwerck , Robert Maleika , Frank Buckel , Peter Capellen
IPC分类号： B32B27/06 , C09J9/00 , C09J133/08 , B05D3/00 , C09J133/12
CPC分类号： C09D5/002 , C08K5/34926 , C09D7/48
摘要： Compositions, suitable for coating surfaces, methods for their preparation and for coating surfaces therewith, where said compositions comprise: (a) 100,000 parts by weight of a primer composition comprising a binder material (a1), a primer solvent (a2) and a UV absorber (a3), wherein the primer composition is suitable as an adhesion-promoting agent between a thermoplastic substrate and a siloxane-based top coat; (b) 0 to 900,000 parts by weight of a solvent, and (c) 1 to 3000 parts by weight of a compound according to the general formula (I): wherein X represents a moiety selected from the group consisting —OR6, —OCH2CH2OR6, —OCH2CH(OH)CH2OR6 and —OCH(R7)COOR8, wherein R6 represents a branched or unbranched C1-C13 alkyl, C2-C20 alkenyl, C6-C12 aryl or —CO—C1-C18 alkyl, R7 represents H or a branched or unbranched C1-C8 alkyl, and R8 represents a C1-C12 alkyl, a C2-C12 alkenyl or a C5-C6 cycloalkyl, and wherein the composition has a viscosity of 40 s to 140 s measured in accordance with DIN EN ISO 2431 at 23° C. and with a 2 mm cup.
摘要翻译：组合物，适用于涂料表面，其制备方法和用于涂布表面，其中所述组合物包含：（a）100,000重量份的底漆组合物，其包含粘合剂材料（a1），底漆溶剂（a2）和UV 吸收剂（a3），其中底漆组合物适合作为热塑性基材与硅氧烷类面漆之间的粘合促进剂; （b）0〜900,000重量份溶剂，（c）1〜3000重量份根据通式（I）的化合物：其中X表示选自-OR 6，-OCH 2 CH 2 OR 6的部分，-OCH 2 CH（OH）CH 2 OR 6和-OCH（R 7）COOR 8，其中R 6表示支链或非支链C 1 -C 13烷基，C 2 -C 20烯基，C 6 -C 12芳基或-CO-C 1 -C 18烷基，R 7表示H或支链或非支链C 1 -C 8烷基，R 8表示C 1 -C 12烷基，C 2 -C 12烯基或C 5 -C 6环烷基，并且其中所述组合物的粘度为40秒至140秒，根据DIN EN ISO 2431测量在23℃和2mm杯。

7. 发明授权

US06548146B1 Composite consisting of a coated polycarbonate and a polymer 失效
标题翻译：复合材料由涂覆的聚碳酸酯和聚合物组成
公开(公告)号：US06548146B1
公开(公告)日：2003-04-15
申请号：US09700327
申请日：2000-11-09
申请人： Peter Bier , Peter Capellen
发明人： Peter Bier , Peter Capellen
IPC分类号： B32B300
CPC分类号： B29C37/0082 , B29C39/00 , B29C45/14311 , B29C2045/14327 , B29K2069/00 , B29L2031/778 , B29L2031/7782 , Y10T428/24628 , Y10T428/24653 , Y10T428/24777 , Y10T428/2495 , Y10T428/24967 , Y10T428/31507
摘要： A composite plastic structure is described. The composite structure includes: (a) a shaped polycarbonate article having an edge region, the edge region having an adhesion-promoting geometric feature therein; (b) a coating applied to the surface of the shaped polycarbonate article; and (c) a polymer that is injection-molded or cast over the edge region of the shaped polycarbonate article. The polymer (c) envelopes the adhesion-promoting geometric feature of the shaped polycarbonate article (a). The envelopment of the adhesion-promoting geometric feature by the polymer (c) provides a structurally firm connection between the shaped polycarbonate article (a) and the polymer (c). Also described is a method of preparing the composite structure, and composite structures according to the present invention, such as picture frames, slide frames, windows having a seal or frame, and a glazing for a motor vehicle.
摘要翻译：描述复合塑料结构。所述复合结构包括：（a）具有边缘区域的成形聚碳酸酯制品，所述边缘区域在其中具有粘合促进几何特征; （b）施加到成型的聚碳酸酯制品的表面上的涂层; 和（c）在成型的聚碳酸酯制品的边缘区域上注塑或铸造的聚合物。聚合物（c）包围成型聚碳酸酯制品（a）的粘附促进几何特征。通过聚合物（c）的粘附促进几何特征的包封提供了成型的聚碳酸酯制品（a）和聚合物（c）之间的结构牢固的连接。还描述了制备复合结构的方法，以及根据本发明的复合结构，例如相框，滑动框架，具有密封件或框架的窗户以及用于机动车辆的玻璃窗。

8. 发明申请

US20150344370A1 MATTE FLAME-RETARDANT ARTICLE WITH HIGH TRANSMISSION 审中-公开
标题翻译：具有高传动性的MATTE阻燃物品
公开(公告)号：US20150344370A1
公开(公告)日：2015-12-03
申请号：US14130968
申请日：2012-07-04
申请人： Karlheinz Hildenbrand , Helmut Krülls , Hans Franssen , Peter Capellen , Rüdiger Hahn , Andreas Müller , Constantin Schwecke
发明人： Karlheinz Hildenbrand , Helmut Krülls , Hans Franssen , Peter Capellen , Rüdiger Hahn , Andreas Müller , Constantin Schwecke
IPC分类号： C04B35/14 , C04B35/622
CPC分类号： C04B35/14 , C04B35/62222 , C08J7/045 , C08J2369/00 , C08J2483/04 , C08K5/42 , C08K5/43 , C08K5/523 , C09D5/18 , C09D7/69 , H04N5/64 , Y10T29/49002 , Y10T428/259 , Y10T428/31507 , C08L69/00
摘要： The invention relates to a coated article containing a) a substrate (S) with a transmission of at least 88% (measured according to ASTM E 1348 with 3 mm layer thickness and a wavelength of 550 nm), comprising a substrate layer consisting of a thermoplastic polymer containing a flame-retardant agent, and b) a scratch-resistant coating (K) containing silica micro-particles on the substrate, said coating (K) containing 0.2 to 1.8 wt. %. silica micro-particles relative to the solids content thereof. The invention further relates to the production of such coated articles and the use thereof, especially for producing flat screens.
摘要翻译：本发明涉及一种涂覆制品，其包含a）具有至少88％的透射率的基底（S）（根据ASTM E 1348测量，其厚度为3mm，波长为550nm），包括由含有阻燃剂的热塑性聚合物，和b）在基材上含有二氧化硅微粒的抗刮涂层（K），所述涂层（K）含有0.2-1.8wt。％。二氧化硅微粒相对于其固体含量。本发明还涉及这种涂覆制品的生产及其用途，特别是用于生产平面筛网。

9. 发明授权

US08101673B2 Silica-containing UV-crosslinkable hardcoat coatings comprising urethane acrylates 有权
标题翻译：含二氧化硅的UV交联硬涂层包含聚氨酯丙烯酸酯
公开(公告)号：US08101673B2
公开(公告)日：2012-01-24
申请号：US12354226
申请日：2009-01-15
申请人： Karlheinz Hildenbrand , Peter Capellen , Eberhard Koch
发明人： Karlheinz Hildenbrand , Peter Capellen , Eberhard Koch
IPC分类号： C08F2/50 , C08J3/28 , B29C35/08
CPC分类号： C09D4/00
摘要： The present invention relates to a UV-crosslinkable composition comprising a) unmodified, protonated silica nanoparticles; b) urethane acrylate; c) polar solvent; and d) UV initiator system, wherein the amount by weight of unmodified, protonated silica nanoparticles exceeds the content of urethane acrylate and is at least 50.1 wt. %, based on the dry weight of the coating, to the use of the composition in the coating of substrates, and to substrates coated with such formulations.
摘要翻译：本发明涉及一种紫外线交联组合物，其包含a）未改性的质子化二氧化硅纳米颗粒; b）氨基甲酸酯丙烯酸酯; c）极性溶剂; 和d）UV引发剂体系，其中未改性的质子化二氧化硅纳米颗粒的重量超过氨基甲酸酯丙烯酸酯的含量，并且至少为50.1wt。％，基于涂层的干重，使用基材涂层中的组合物，以及涂覆有这些配方的基材。

10. 发明申请

US20110318567A1 ANTI-REFLECTION/ANTI-FOG COATINGS 审中-公开
标题翻译：抗反射/防雾涂料
公开(公告)号：US20110318567A1
公开(公告)日：2011-12-29
申请号：US13148975
申请日：2010-02-02
申请人： Karlheinz Hildenbrand , Peter Capellen , Friedrich-Kark Bruder
发明人： Karlheinz Hildenbrand , Peter Capellen , Friedrich-Kark Bruder
IPC分类号： B32B5/18 , B05D7/24 , B05D3/06 , G02B5/22 , C09K3/18
CPC分类号： C09D133/12 , C08K7/26 , C08L33/12 , C08L2205/02 , C09D5/00 , C09D7/67 , C09D7/70 , Y10T428/249974 , C08L2666/04
摘要： The invention relates to a composition, comprising a) porous silica nanoparticles, b) one or more organic soluble polymer resins, c) one or more UV-cross linkable reactive diluents, d) solvents and e) a UV-initiator system. The invention further relates to the use of the composition for coating transparent substrates, and to substrates that are coated with formulations of said kind.
摘要翻译：本发明涉及一种组合物，其包含a）多孔二氧化硅纳米颗粒，b）一种或多种有机可溶性聚合物树脂，c）一种或多种可紫外交联的反应性稀释剂，d）溶剂和e）UV引发剂体系。本发明还涉及用于涂覆透明基材的组合物的用途以及用所述种类的制剂涂覆的基材。

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