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    • 7. 发明授权
    • Stabilizer combination for the rotomolding process
    • 稳定剂组合用于滚塑过程
    • US06902695B2
    • 2005-06-07
    • US10762601
    • 2004-01-22
    • Urs Leo Stadler
    • Urs Leo Stadler
    • C08J5/00B29C41/06C08K5/32C08K5/3435C08K5/3492C08K5/51C08L23/00D01D5/24
    • C08K5/34926B29C41/06C08K5/32C08K5/3435C08K5/51C08L23/02
    • A process for the production of polyolefin hollow articles comprises charging the polyolefin with a stabilizer combination comprising (a) at least one compound from the group of the organic phosphites or phosphonites, (b) one or more compounds selected from the group consisting of i.) hydroxylamine derivatives and ii.) amine oxide derivatives and (c) at least one compound from the group of the hindered amine stabilizers, filling this mixture into a mold, heating this mold in an oven to above 280° C., such that the stabilized polyolefin fuses, rotating the mold around at least 2 axes, the plastic spreading to the walls, and cooling the mold while still rotating, opening it and taking the resultant hollow article out.
    • 制备聚烯烃中空制品的方法包括用稳定剂组合物填充聚烯烃,所述稳定剂组合包含(a)至少一种来自有机亚磷酸酯或亚膦酸酯的化合物,(b)一种或多种选自以下的化合物: )羟胺衍生物和ii。)氧化胺衍生物和(c)至少一种来自受阻胺稳定剂的化合物,将该混合物填充到模具中,将该模具在烘箱中加热至280℃以上,使得 稳定的聚烯烃保险丝,将模具绕至少2个轴线旋转,塑料扩展到墙壁,并在仍然旋转的同时冷却模具,将其打开并取出所得的空心制品。
    • 10. 发明授权
    • Stabilizer combination for the rotomolding process
    • 稳定剂组合用于滚塑过程
    • US06444733B1
    • 2002-09-03
    • US09455143
    • 1999-12-06
    • Urs Leo Stadler
    • Urs Leo Stadler
    • C08K534
    • C08K5/34926B29C41/06C08K5/32C08K5/3435C08K5/51C08L23/02
    • A process for the production of polyolefin hollow articles comprises charging the polyolefin with a stabilizer combination comprising (a) at least one compound from the group of the organic phosphites or phosphonites, (b) one or more compounds selected from the group consisting of i.) hydroxylamine derivatives and ii.) amine oxide derivatives and (c) at least one compound from the group of the hindered amine stabilizers, filling this mixture into a mold, heating this mold in an oven to above 280° C., such that the stabilized polyolefin fuses, rotating the mold around at least 2 axes, the plastic spreading to the walls, and cooling the mold while still rotating, opening it and taking the resultant hollow article out.
    • 制备聚烯烃中空制品的方法包括用稳定剂组合物填充聚烯烃,所述稳定剂组合包含(a)至少一种来自有机亚磷酸酯或亚膦酸酯的化合物,(b)一种或多种选自以下的化合物: )羟胺衍生物和ii。)氧化胺衍生物和(c)至少一种来自受阻胺稳定剂的化合物,将该混合物填充到模具中,将该模具在烘箱中加热至280℃以上,使得 稳定的聚烯烃保险丝,将模具绕至少2个轴线旋转,塑料扩展到墙壁,并在仍然旋转的同时冷却模具,将其打开并取出所得的空心制品。