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1. 发明授权

US07655137B2 Reforming catalysts having a controlled coordination structure and methods for preparing such compositions 失效
标题翻译：具有受控配位结构的重整催化剂和制备这种组合物的方法
公开(公告)号：US07655137B2
公开(公告)日：2010-02-02
申请号：US11435165
申请日：2006-05-16
申请人： Bing Zhou , Horacio Trevino , Zhihua Wu
发明人： Bing Zhou , Horacio Trevino , Zhihua Wu
IPC分类号： C10G35/09 , B01J31/02 , B01J23/42 , B01J23/58 , B01J23/62
CPC分类号： B01J35/0013 , B01J27/13 , B01J27/135 , B01J27/138 , B01J35/002 , B01J35/006 , B01J35/0073 , B01J37/0018 , B01J37/0203 , B01J37/0211 , C10G35/06 , C10G35/085
摘要： The reforming catalysts include a halogen promoter and a plurality of nanocatalyst particles supported on a support material. The nanocatalyst particles have a controlled crystal face exposure of predominately (110). The controlled coordination structure is manufactured by reacting a plurality of catalyst atoms with a control agent such as polyacrylic acid and causing or allowing the catalyst atoms to form nanocatalyst particles. The catalysts are used in a reforming reaction to improve the octane number of gasoline feedstock. The reforming catalysts show improved C5+ hydrocarbon production and improved octane barrel number increases as compared to commercially available reforming catalysts.
摘要翻译：重整催化剂包括卤素促进剂和负载在载体材料上的多个纳米催化剂颗粒。纳米催化剂颗粒主要具有受控的晶面暴露（110）。通过使多个催化剂原子与诸如聚丙烯酸的控制剂反应并使催化剂原子形成纳米催化剂颗粒来制备受控的配位结构。催化剂用于重整反应以改善汽油原料的辛烷值。与市售的重整催化剂相比，重整催化剂显示出改进的C5 +烃生产和改进的辛烷桶数增加。

2. 发明申请

US20060102521A1 Reforming nanocatalysts and method of making and using such catalysts 失效
公开(公告)号：US20060102521A1
公开(公告)日：2006-05-18
申请号：US11101241
申请日：2005-04-07
申请人： Bing Zhou , Horacio Trevino , Zhihua Wu , Zhenhua Zhou , Changkun Liu
发明人： Bing Zhou , Horacio Trevino , Zhihua Wu , Zhenhua Zhou , Changkun Liu
IPC分类号： C10G35/09 , B01J31/00
CPC分类号： C10G35/09 , B01J23/40 , B01J23/42 , B01J23/468 , B01J23/56 , B01J23/626 , B01J23/6567 , B01J23/8906 , B01J35/0013 , B01J35/006 , B01J37/0203 , B01J37/08 , B01J37/16 , B01J37/18 , B82Y30/00 , C10G35/085
摘要： Reforming nanocatalysts are formed using a dispersing agent to increase the activity, selectivity and longevity of the catalyst when used in a reforming process. The nanocatalyst particles are formed using a dispersing agent having at least one functional group selected from the group of a hydroxyl, a carboxyl, a carbonyl, an amide, an amine, a thiol, a sulfonic acid, sulfonyl halide, an acyl halide, an organometallic complex, and combinations of these. The dispersing agent is particularly useful for forming multicomponent catalysts comprising an alloy, combination, mixture, decoration, or interspersion of platinum and one or more of tin, rhenium or iridium. The formation of the nanoparticles may include a heat treating process performed in an inert or oxidative environment to maintain the catalyst atoms in a non-zero oxidation state to thereby maintain a stronger bond between the dispersing agent and the catalyst atoms. Multicomponent reforming catalysts having anchored nanocatalyst particles exhibit particularly good activity, selectivity and longevity when used in the reforming of naphtha and/or formation of BTX.

3. 发明授权

US07449423B2 Heat treatment of anchored nanocatalysts in a non-zero oxidation state and catalysts made by such method 失效
标题翻译：以非零氧化态热处理锚定的纳米催化剂和通过这种方法制备的催化剂
公开(公告)号：US07449423B2
公开(公告)日：2008-11-11
申请号：US11101209
申请日：2005-04-07
申请人： Bing Zhou , Horacio Trevino , Zhihua Wu , Zhenhua Zhou , Changkun Liu
发明人： Bing Zhou , Horacio Trevino , Zhihua Wu , Zhenhua Zhou , Changkun Liu
IPC分类号： B01J30/00 , B01J37/00 , C08F4/02 , C08F4/60
CPC分类号： C10G35/09 , B01J23/40 , B01J23/42 , B01J23/56 , B01J23/626 , B01J23/8906 , B01J35/0013 , B01J35/006 , B01J37/0203 , B01J37/08 , B01J37/18 , B82Y30/00
摘要： A catalyst manufacturing process includes heat treating an intermediate catalyst composition that includes catalyst nanoparticles having catalyst atoms in a non-zero oxidation state bonded to a dispersing/anchoring agent. The catalyst nanoparticles are formed using a dispersing agent having at least one functional group selected from the group of a hydroxyl, a carboxyl, a carbonyl, an amide, an amine, a thiol, a sulfonic acid, sulfonyl halide, an acyl halide, an organometallic complex, and combinations of these. The dispersing agent can be used to form single- or multicomponent supported nanocatalysts. The dispersing agent also acts as an anchoring agent to firmly bond the nanocatalyst to a support. Performing the heat treating process in an inert or oxidative environment to maintain the catalyst atoms in a non-zero oxidation helps maintains a stronger bonding interaction between the dispersing agent and the catalyst atoms. This, in turn, increases the dispersion and/or distribution of catalyst components throughout the supported catalyst.
摘要翻译：催化剂制造方法包括热处理包含催化剂纳米颗粒的中间催化剂组合物，所述催化剂纳米颗粒具有与分散/锚固剂结合的非零氧化态的催化剂原子。催化剂纳米颗粒使用具有至少一个选自羟基，羧基，羰基，酰胺，胺，硫醇，磺酸，磺酰卤，酰基卤，有机金属络合物，以及它们的组合。分散剂可用于形成单组分或多组分负载的纳米催化剂。分散剂也起锚固剂的作用，以将纳米催化剂牢固地粘合到载体上。在惰性或氧化环境中进行热处理工艺以将催化剂原子维持在非零氧化中有助于在分散剂和催化剂原子之间保持更强的粘合相互作用。这反过来又增加催化剂组分在整个负载的催化剂中的分散和/或分布。

4. 发明授权

US07541309B2 Reforming nanocatalysts and methods of making and using such catalysts 失效
标题翻译：纳米催化剂的改性和制备和使用这些催化剂的方法
公开(公告)号：US07541309B2
公开(公告)日：2009-06-02
申请号：US11435580
申请日：2006-05-16
申请人： Horacio Trevino , Zhenhua Zhou , Zhihua Wu , Bing Zhou
发明人： Horacio Trevino , Zhenhua Zhou , Zhihua Wu , Bing Zhou
IPC分类号： B01J31/00 , B01J23/00 , B01J23/58 , B01J23/56 , C10G35/00 , C10G35/04 , C10G35/06
CPC分类号： B01J23/40 , B01J21/04 , B01J23/468 , B01J23/56 , B01J23/626 , B01J23/6567 , B01J31/0201 , B01J31/0215 , B01J31/0217 , B01J31/0225 , B01J31/0229 , B01J31/0235 , B01J31/0237 , B01J31/0247 , B01J31/04 , B01J31/068 , B01J35/0013 , B01J35/002 , B01J35/006 , B01J37/0203 , B01J37/0211 , B01J37/08 , C10G35/09 , C10G35/095
摘要： Catalysts suitable for use in reforming hydrocarbons have a halogen promoter and a plurality of dispersed nanocatalyst particles supported on a solid support. The dispersed nanocatalyst particles are manufactured using a dispersing agent to control the size and/or crystal face exposure of the particles. The controlled size and dispersion of the nanocatalyst particles allows the reforming catalyst to be loaded with significantly less halogen promoter while still maintaining or increasing the catalyst's reforming performance. The catalysts of the present invention have shown improved C5+ production with the significantly reduced levels of halogen promoter.
摘要翻译：适用于重整烃的催化剂具有卤素促进剂和负载在固体载体上的多个分散的纳米催化剂颗粒。使用分散剂制造分散的纳米催化剂颗粒以控制颗粒的尺寸和/或晶面暴露。纳米催化剂颗粒的受控尺寸和分散体允许重整催化剂负载显着更少的卤素促进剂，同时仍保持或提高催化剂的重整性能。本发明的催化剂已显示改进的C5 +产生与显着降低的卤素启动子水平。

5. 发明申请

US20060160695A1 Heat treatment of anchored nanocatalysts in a non-zero oxidation state and catalysts made by such method 失效
标题翻译：以非零氧化态热处理锚定的纳米催化剂和通过这种方法制备的催化剂
公开(公告)号：US20060160695A1
公开(公告)日：2006-07-20
申请号：US11101209
申请日：2005-04-07
申请人： Bing Zhou , Horacio Trevino , Zhihua Wu , Zhenhua Zhou , Changkun Liu
发明人： Bing Zhou , Horacio Trevino , Zhihua Wu , Zhenhua Zhou , Changkun Liu
IPC分类号： B01J29/04 , B01J31/00 , B01J23/40
CPC分类号： C10G35/09 , B01J23/40 , B01J23/42 , B01J23/56 , B01J23/626 , B01J23/8906 , B01J35/0013 , B01J35/006 , B01J37/0203 , B01J37/08 , B01J37/18 , B82Y30/00
摘要： A catalyst manufacturing process includes heat treating an intermediate catalyst composition that includes catalyst nanoparticles having catalyst atoms in a non-zero oxidation state bonded to a dispersing/anchoring agent. The catalyst nanoparticles are formed using a dispersing agent having at least one functional group selected from the group of a hydroxyl, a carboxyl, a carbonyl, an amide, an amine, a thiol, a sulfonic acid, sulfonyl halide, an acyl halide, an organometallic complex, and combinations of these. The dispersing agent can be used to form single- or multicomponent supported nanocatalysts. The dispersing agent also acts as an anchoring agent to firmly bond the nanocatalyst to a support. Performing the heat treating process in an inert or oxidative environment to maintain the catalyst atoms in a non-zero oxidation helps maintains a stronger bonding interaction between the dispersing agent and the catalyst atoms. This, in turn, increases the dispersion and/or distribution of catalyst components throughout the supported catalyst.
摘要翻译：催化剂制造方法包括热处理包含催化剂纳米颗粒的中间催化剂组合物，所述催化剂纳米颗粒具有与分散/锚固剂结合的非零氧化态的催化剂原子。催化剂纳米颗粒使用具有至少一个选自羟基，羧基，羰基，酰胺，胺，硫醇，磺酸，磺酰卤，酰基卤，有机金属络合物，以及它们的组合。分散剂可用于形成单组分或多组分负载的纳米催化剂。分散剂也起锚固剂的作用，以将纳米催化剂牢固地粘合到载体上。在惰性或氧化环境中进行热处理工艺以将催化剂原子维持在非零氧化中有助于在分散剂和催化剂原子之间保持更强的粘合相互作用。这反过来又增加催化剂组分在整个负载的催化剂中的分散和/或分布。

6. 发明申请

US20090114568A1 REFORMING NANOCATALYSTS AND METHODS OF MAKING AND USING SUCH CATALYSTS 失效
标题翻译：重新制备纳米催化剂和制备和使用这种催化剂的方法
公开(公告)号：US20090114568A1
公开(公告)日：2009-05-07
申请号：US11435580
申请日：2006-05-16
申请人： Horacio Trevino , Zhenhua Zhou , Zhihua Wu , Bing Zhou
发明人： Horacio Trevino , Zhenhua Zhou , Zhihua Wu , Bing Zhou
IPC分类号： C10G35/09 , B01J31/28
CPC分类号： B01J23/40 , B01J21/04 , B01J23/468 , B01J23/56 , B01J23/626 , B01J23/6567 , B01J31/0201 , B01J31/0215 , B01J31/0217 , B01J31/0225 , B01J31/0229 , B01J31/0235 , B01J31/0237 , B01J31/0247 , B01J31/04 , B01J31/068 , B01J35/0013 , B01J35/002 , B01J35/006 , B01J37/0203 , B01J37/0211 , B01J37/08 , C10G35/09 , C10G35/095
摘要： Catalysts suitable for use in reforming hydrocarbons have a halogen promoter and a plurality of dispersed nanocatalyst particles supported on a solid support. The dispersed nanocatalyst particles are manufactured using a dispersing agent to control the size and/or crystal face exposure of the particles. The controlled size and dispersion of the nanocatalyst particles allows the reforming catalyst to be loaded with significantly less halogen promoter while still maintaining or increasing the catalyst's reforming performance. The catalysts of the present invention have shown improved C5+ production with the significantly reduced levels of halogen promoter.
摘要翻译：适用于重整烃的催化剂具有卤素促进剂和负载在固体载体上的多个分散的纳米催化剂颗粒。使用分散剂制造分散的纳米催化剂颗粒以控制颗粒的尺寸和/或晶面暴露。纳米催化剂颗粒的受控尺寸和分散体允许重整催化剂负载显着更少的卤素促进剂，同时仍保持或提高催化剂的重整性能。本发明的催化剂已显示改进的C5 +产生与显着降低的卤素启动子水平。

7. 发明申请

US20060243641A1 Reforming catalysts having a controlled coordination structure and methods for preparing such compositions 失效
标题翻译：具有受控配位结构的重整催化剂和制备这种组合物的方法
公开(公告)号：US20060243641A1
公开(公告)日：2006-11-02
申请号：US11435165
申请日：2006-05-16
申请人： Bing Zhou , Horacio Trevino , Zhihua Wu
发明人： Bing Zhou , Horacio Trevino , Zhihua Wu
IPC分类号： C10G35/06 , B01J31/00
CPC分类号： B01J35/0013 , B01J27/13 , B01J27/135 , B01J27/138 , B01J35/002 , B01J35/006 , B01J35/0073 , B01J37/0018 , B01J37/0203 , B01J37/0211 , C10G35/06 , C10G35/085
摘要： The reforming catalysts include a halogen promoter and a plurality of nanocatalyst particles supported on a support material. The nanocatalyst particles have a controlled crystal face exposure of predominately (110). The controlled coordination structure is manufactured by reacting a plurality of catalyst atoms with a control agent such as polyacrylic acid and causing or allowing the catalyst atoms to form nanocatalyst particles. The catalysts are used in a reforming reaction to improve the octane number of gasoline feedstock. The reforming catalysts show improved C5+ hydrocarbon production and improved octane barrel number increases as compared to commercially available reforming catalysts.
摘要翻译：重整催化剂包括卤素促进剂和负载在载体材料上的多个纳米催化剂颗粒。纳米催化剂颗粒主要具有受控的晶面暴露（110）。通过使多个催化剂原子与诸如聚丙烯酸的控制剂反应并使催化剂原子形成纳米催化剂颗粒来制备受控的配位结构。催化剂用于重整反应以改善汽油原料的辛烷值。与市售的重整催化剂相比，重整催化剂显示改进的C 5+烃生产和改进的辛烷桶数增加。

8. 发明授权

US09199224B2 Hydroconversion multi-metallic catalysts and method for making thereof 有权
标题翻译：加氢转化多金属催化剂及其制备方法
公开(公告)号：US09199224B2
公开(公告)日：2015-12-01
申请号：US14019397
申请日：2013-09-05
申请人： Jinyi Han , Alexander E. Kuperman , Theodorus Ludovicus Michael Maesen , Horacio Trevino
发明人： Jinyi Han , Alexander E. Kuperman , Theodorus Ludovicus Michael Maesen , Horacio Trevino
IPC分类号： B01J27/051 , B01J27/049 , B01J27/043 , B01J27/047 , B01J35/00 , B01J35/10
CPC分类号： B01J27/0515 , B01J27/043 , B01J27/047 , B01J27/049 , B01J27/051 , B01J35/002 , B01J35/1014 , B01J35/1038 , C10G45/08
摘要： The invention relates to a self-supported mixed metal sulfide (MMS) catalyst for hydrotreating hydrocarbon feedstock and to a method for preparing the catalyst. The MMS catalyst has molar ratios of metal components Ni:Mo:W in a region defined by five points ABCDE of a ternary phase diagram, and wherein the five points ABCDE are defined as: A (Ni=0.72, Mo=0.00, W=0.25), B (Ni=0.25, Mo=0.00, W=0.75), C (Ni=0.25, Mo=0.25, W=0.50), D (Ni=0.60, Mo=0.25, W=0.15), E (Ni=0.72, Mo=0.13, W=0.15).
摘要翻译：本发明涉及一种用于加氢处理烃原料的自支撑混合金属硫化物（MMS）催化剂及其制备方法。 MMS催化剂在由三元相图的五点ABCDE定义的区域中具有金属成分Ni:Mo:W的摩尔比，其中五点ABCDE定义为：A（Ni = 0.72，Mo = 0.00，W = 0.25），B（Ni = 0.25，Mo = 0.00，W = 0.75），C（Ni = 0.25，Mo = 0.25，W = 0.50），D（Ni = 0.60，Mo = 0.25，W = 0.15） Ni = 0.72，Mo = 0.13，W = 0.15）。

9. 发明申请

US20140135207A1 Hydroconversion Multi-Metallic Catalysts and Method for Making Thereof 有权
标题翻译：加氢转化多金属催化剂及其制备方法
公开(公告)号：US20140135207A1
公开(公告)日：2014-05-15
申请号：US14019444
申请日：2013-09-05
申请人： Jinyi Han , Alexander E. Kuperman , Theodorus Ludovicus Michael Maesen , Horacio Trevino
发明人： Jinyi Han , Alexander E. Kuperman , Theodorus Ludovicus Michael Maesen , Horacio Trevino
IPC分类号： B01J27/051
CPC分类号： B01J27/0515 , B01J27/043 , B01J27/047 , B01J27/049 , B01J27/051 , B01J35/002 , B01J35/1014 , B01J35/1038 , C10G45/08
摘要： The invention relates to a self-supported mixed metal sulfide (MMS) catalyst for hydrotreating hydrocarbon feedstock and to a method for preparing the catalyst. The MMS catalyst is characterized as having a BET surface area of at least 20 m2/g and a pore volume of at least 0.05 cm3/g. In one embodiment, the MMS catalyst is also characterized as having a multi-phased structure comprising five phases: a molybdenum sulfide phase, a tungsten sulfide phase, a molybdenum tungsten sulfide phase, an active nickel phase, and a nickel sulfide phase.
摘要翻译：本发明涉及一种用于加氢处理烃原料的自支撑混合金属硫化物（MMS）催化剂及其制备方法。 MMS催化剂的特征在于具有至少20m 2 / g的BET表面积和至少0.05cm 3 / g的孔体积。在一个实施方案中，MMS催化剂的特征还在于具有包含五相的多相结构：硫化钼相，硫化钨相，硫化钨相，活性镍相和硫化镍相。

10. 发明申请

US20140066295A1 Hydroconversion Multi-Metallic Catalysts and Method for Making Thereof 审中-公开
标题翻译：加氢转化多金属催化剂及其制备方法
公开(公告)号：US20140066295A1
公开(公告)日：2014-03-06
申请号：US14019379
申请日：2013-09-05
申请人： Jinyi Han , Alexander E. Kuperman , Theodorus Ludovicus Michael Maesen , Horacio Trevino
发明人： Jinyi Han , Alexander E. Kuperman , Theodorus Ludovicus Michael Maesen , Horacio Trevino
IPC分类号： B01J27/051 , B01J27/049
CPC分类号： B01J27/0515 , B01J27/043 , B01J27/047 , B01J27/049 , B01J27/051 , B01J35/002 , B01J35/1014 , B01J35/1038 , C10G45/08
摘要： A self-supported mixed metal sulfide (MMS) catalyst for hydrotreating hydrocarbon feedstock is disclosed. The self-supported MMS catalyst is characterized by an HDN reaction rate constant of at least 100 g feed hr−1 g catalyst−1 assuming first order kinetics, and an HDS reaction rate constant of at least 550 g feed hr−1 g catalyst−1 assuming first order kinetics in hydrotreating of a Heavy Coker Gas Oil as a feedstock with properties indicated in Table A and at given process conditions as indicated in Table E. In one embodiment, the catalyst is characterized as having a multi-phased structure comprising five phases: a molybdenum sulfide phase, a tungsten sulfide phase, a molybdenum tungsten sulfide phase, an active nickel phase, and a nickel sulfide phase.
摘要翻译：公开了一种用于加氢处理烃原料的自支撑混合金属硫化物（MMS）催化剂。自支撑的MMS催化剂的特征在于以假定一级动力学为至少100g进料hr-1g催化剂-1的HDN反应速率常数，以及至少550g进料hr-1g催化剂-1的HDS反应速率常数，假设在重型Coker Gas Oil作为原料的加氢处理中的一级动力学作为原料，具有表A所示的性质和表E所示的给定工艺条件。在一个实施方案中，催化剂的特征在于具有多相结构，其包含五相：硫化钼相，硫化钨相，硫化钨相，活性镍相和硫化镍相。

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