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    • 4. 发明授权
    • Crosslinking of polymers and foams thereof
    • 聚合物和泡沫的交联
    • US06325956B2
    • 2001-12-04
    • US09140004
    • 1998-08-26
    • Bharat I. ChaudharyThoi H. HoSeema V. KarandeChe-I. KaoRobert H. TerbrueggenDavid A. BabbClark H. CumminsMichael J. MullinsH. Craig Silvis
    • Bharat I. ChaudharyThoi H. HoSeema V. KarandeChe-I. KaoRobert H. TerbrueggenDavid A. BabbClark H. CumminsMichael J. MullinsH. Craig Silvis
    • B29C4402
    • The invention includes a process comprising (a) forming a polymeric admixture including at least one polyolefin which has been prepared using a single site catalyst and at least a crosslinking amount of at least one poly(sulfonyl azide) crosslinking agent; (b) shaping the resulting admixture; and (c) heating the resulting shaped admixture to a temperature at least the decomposition temperature of the crosslinking agent. The steps take place in any sequence and optionally include substeps. The single site catalyst is preferably a constrained geometry or metallocene catalyst, but optionally another transition metal catalyst which is not a traditional Ziegler Natta Ti/MgCl2 catalyst such as a vanadium catalyst. The invention further includes all compositions obtainable by the process of the invention as well as all articles formed from these compositions. The articles are preferably thermoformed, compression molded, injection molded, extruded, cast, blow molded, blown, profile extruded, spun, foamed or molded of any composition of the invention. The invention includes a use of any composition of the invention in any process of thermoforming, injection molding, extrusion, casting, blow molding, spinning, blowing, profile extrusion, foaming, compression molding or a combination thereof.
    • 本发明包括一种方法,其包括(a)形成包含至少一种聚烯烃的聚合物混合物,所述聚合物混合物已经使用单中心催化剂和至少交联量的至少一种聚(磺酰基叠氮化物)交联剂制备; (b)成型所得混合物; 和(c)将所得成形的混合物加热至至少交联剂的分解温度的温度。 步骤以任何顺序进行,并且可选地包括子步骤。 单中心催化剂优选为约束几何形状或茂金属催化剂,但可选地为不是传统的齐格勒 - 纳塔Ti / MgCl 2催化剂如钒催化剂的另一种过渡金属催化剂。 本发明还包括通过本发明的方法获得的所有组合物以及由这些组合物形成的所有制品。 制品优选是由本发明的任何组合物进行热成型,压塑,注射成型,挤出,铸造,吹塑,吹塑,型材挤出,纺丝,发泡或模制的。 本发明包括在热成型,注射成型,挤出,铸造,吹塑,纺丝,吹塑,型材挤出,发泡,压缩成型或其组合的任何方法中使用本发明的任何组合物。
    • 5. 发明授权
    • Blends of ethylenic polymers with improved modulus and melt strength and articles fabricated from these blends
    • 具有改进的模量和熔体强度的乙烯类聚合物的共混物和由这些共混物制成的制品
    • US06723793B2
    • 2004-04-20
    • US10350564
    • 2003-01-24
    • Thomas OswaldBharat I. ChaudharyJeffrey Weinhold
    • Thomas OswaldBharat I. ChaudharyJeffrey Weinhold
    • C08L2306
    • C08L23/0815C08L23/02C08L2205/02C08L2207/07C08L2666/04
    • A blend which comprises; A) a heterogeneous or homogenous linear ethylene homopolymer or interpolymer; B) a branched homopolymer or interpolymer; wherein said blend has; 1) a melt index, I2, of about 0.05 to about 20 g/10 min; 2) a flexural modulus of ≧100,000 psi or ≦30,000 psi; 3) a melt strength of ≧2 cN; 4) a melt extensibility of ≧25 mm/sec; and 5) wherein said melt strength of said blend meets the following relationship; Melt strength≧FMS*[(f*A)+((1−f)*B)]; where: A=3.3814*(I2)−06476 and B=16.882*(I2)−06564; where I2 is the measured melt index of the blend; f is the weight fraction of the linear polyethylene in the blend and FMS is ≧1.1. Also included in the present invention are foams, films, fibers, blow molded articles, wire and cable articles and extrusion coatings comprising said blend.
    • 一种共混物,其包含:A)非均相或均匀的线性乙烯均聚物或互聚物; B)支化均聚物或互聚物;其中所述共混物具有:1)约0.05至约20g / 10min的熔体指数I 2; 2 )≥100000psi或<= 30,000PSI的挠曲模量; 3)≥2cN的熔体强度; 4)> 25mm / sec的熔体延展性; 和5)其中所述共混物的熔体强度满足以下关系:其中:A = 3.3814 *(I2)< - 06476>和B = 16.882 *(I2)< - 06564>; 其中I 2是混合物的测量熔体指数; f是共混物中线性聚乙烯的重量分数,FMS = 1.1。本发明还包括泡沫,膜,纤维,吹塑制品,电线和电缆制品以及包含所述共混物的挤出涂层。