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1. 发明申请

US20080287596A1 Aqueous Dispersions of Water-Soluble Polymers with Comblike Stabilizers 失效
标题翻译：具有梳状稳定剂的水溶性聚合物的水性分散体
公开(公告)号：US20080287596A1
公开(公告)日：2008-11-20
申请号：US12091527
申请日：2006-10-25
申请人： Bettina Wester , Volker Braig , Werner Gauweiler , Marc Leduc , Stefan Becker , Robert Feuerhake
发明人： Bettina Wester , Volker Braig , Werner Gauweiler , Marc Leduc , Stefan Becker , Robert Feuerhake
IPC分类号： C08L33/24 , C08L61/00 , C08L33/06 , C08L33/10
CPC分类号： C08F226/02 , C08F8/12 , C08F8/44 , D21H21/10 , D21H21/14 , C08F283/06 , C08F220/06
摘要： The invention relates to aqueous dispersions of water-soluble polymers of N-vinyl-carboxamides, which are substantially salt-free and comprise anionic polymeric stabilizers having a comb-like molecular structure, processes for the preparation of the dispersions in the presence of anionic polymeric stabilizers having a comb-like molecular structure and the use of the dispersions as retention aids or fixing agents in papermaking.
摘要翻译：本发明涉及N-乙烯基 - 甲酰胺的水溶性聚合物的水性分散体，其基本上不含盐，并且包含具有梳状分子结构的阴离子聚合物稳定剂，在阴离子聚合物存在下制备分散体的方法具有梳状分子结构的稳定剂和在造纸中使用分散体作为助留剂或固定剂。

2. 发明授权

US07795340B2 Aqueous dispersions of water-soluble polymers with comblike stabilizers 失效
标题翻译：具有梳状稳定剂的水溶性聚合物的水分散体
公开(公告)号：US07795340B2
公开(公告)日：2010-09-14
申请号：US12091527
申请日：2006-10-25
申请人： Bettina Wester , Volker Braig , Werner Gauweiler , Marc Leduc , Stefan Becker , Robert Feuerhake
发明人： Bettina Wester , Volker Braig , Werner Gauweiler , Marc Leduc , Stefan Becker , Robert Feuerhake
IPC分类号： C08L51/00 , C09D5/02
CPC分类号： C08F226/02 , C08F8/12 , C08F8/44 , D21H21/10 , D21H21/14 , C08F283/06 , C08F220/06
摘要： The invention relates to aqueous dispersions of water-soluble polymers of N-vinyl-carboxamides, which are substantially salt-free and comprise anionic polymeric stabilizers having a comb-like molecular structure, processes for the preparation of the dispersions in the presence of anionic polymeric stabilizers having a comb-like molecular structure and the use of the dispersions as retention aids or fixing agents in papermaking.
摘要翻译：本发明涉及N-乙烯基 - 甲酰胺的水溶性聚合物的水性分散体，其基本上不含盐，并且包含具有梳状分子结构的阴离子聚合物稳定剂，在阴离子聚合物存在下制备分散体的方法具有梳状分子结构的稳定剂和在造纸中使用分散体作为助留剂或固定剂。

3. 发明授权

US07754804B2 Aqueous dispersions of hydrosoluble polymerisates of ethylenically unsaturated anionic monomers, method for the production and use thereof 失效
标题翻译：烯键式不饱和阴离子单体的水溶性聚合物的水分散体，其制备方法和用途
公开(公告)号：US07754804B2
公开(公告)日：2010-07-13
申请号：US10565772
申请日：2004-07-17
申请人： Pulakesh Mukherjee , Marc Leduc , Peter Claassen , Werner Gauweiler , Roland Nowack
发明人： Pulakesh Mukherjee , Marc Leduc , Peter Claassen , Werner Gauweiler , Roland Nowack
IPC分类号： C08F2/16
CPC分类号： C08F283/06 , C08F251/00 , C08F265/00 , C08F291/06 , C08F2/20
摘要： An aqueous dispersion of water-soluble polymers obtained by free radical polymerization of ethylenically unsaturated anionic monomers in an aqueous medium in the presence of a stabilizer, wherein the stabilizer comprises: (a) at least one water-soluble polymer selected from the group consisting of a graft polymer of vinyl acetate and/or vinyl propionate on polyethylene glycol, a polyethylene glycol blocked at one or both terminal groups with an alkyl, a carboxyl or an amino group, and a copolymer of alkyl polyalkylene glycol methacrylate and methacrylic acid; and (b) at least one water-soluble polymer selected from the group consisting of a hydrolyzed copolymer of vinyl alkyl ether and maleic anhydride in the form of free carboxyl groups or in the form of salts at least partially neutralized with one or more alkali metal hydroxides or one or more ammonium bases, a cationically modified potato starch, an anionically modified potato starch, a degraded potato starch and maltodextrin.
摘要翻译：通过烯属不饱和阴离子单体在水性介质中在稳定剂存在下自由基聚合获得的水溶性聚合物的水分散体，其中所述稳定剂包括：（a）至少一种选自以下的水溶性聚合物：乙酸乙烯酯和/或丙酸乙烯酯在聚乙二醇上的接枝聚合物，在一个或两个端基被烷基，羧基或氨基封端的聚乙二醇和烷基聚亚烷基二醇甲基丙烯酸酯和甲基丙烯酸的共聚物; 和（b）至少一种选自游离羧基形式的乙烯基烷基醚和马来酸酐的水解共聚物的水溶性聚合物或至少部分用一种或多种碱金属中和的盐形式氢氧化物或一种或多种铵碱，阳离子改性马铃薯淀粉，阴离子改性马铃薯淀粉，降解马铃薯淀粉和麦芽糖糊精。

4. 发明申请

US20070117903A1 Aqueous dispersions of hydrosoluble polymerisates of ethylenically unsaturated anionic monomers, method for the production and use thereof 失效
标题翻译：烯键式不饱和阴离子单体的水溶性聚合物的水分散体，其制备方法和用途
公开(公告)号：US20070117903A1
公开(公告)日：2007-05-24
申请号：US10565772
申请日：2004-07-17
申请人： Pulakesh Mukherjee , Marc Leduc , Peter Claassen , Werner Gauweiler , Roland Nowack
发明人： Pulakesh Mukherjee , Marc Leduc , Peter Claassen , Werner Gauweiler , Roland Nowack
IPC分类号： C08L9/00
CPC分类号： C08F283/06 , C08F251/00 , C08F265/00 , C08F291/06 , C08F2/20
摘要： Aqueous dispersions of water-soluble polymers of ethylenically unsaturated anionic monomers are obtainable by free radical polymerization of the monomers in an aqueous medium in the presence of at least one stabilizer, the polymerization being carried out in the presence of at least one water-soluble polymer of the groups consisting of (a) graft polymers of vinyl acetate and/or vinyl propionate on polyethylene glycols, polyethylene glycols blocked at one or both terminal groups with alkyl, carboxyl or amino groups, copolymers of alkyl polyalkylene glycol acrylates or alkyl polyalkylene glycol methacrylates and acrylic acid and/or methacrylic acid, polyalkylene glycols, polyalkylene glycols blocked at one or both terminal groups with alkyl, carboxyl or amino groups, and (b) hydrolyzed copolymers of vinyl alkyl ethers and maleic anhydride in the form of the free carboxyl groups and in the form of the salts at least partly neutralized with alkali metal hydroxides or ammonium bases, and/or of water-soluble starch from the group consisting of cationically modified potato starch, anionically modified potato starch, degraded potato starch and maltodextrin as a stabilizer, said aqueous dispersions are prepared by free radical polymerization of the monomers in an aqueous medium in the presence of the abovementioned water-soluble polymers of the groups (a) and (b) and said aqueous dispersions are used as thickeners for aqueous systems.
摘要翻译：烯键式不饱和阴离子单体的水溶性聚合物的水分散体可通过在至少一种稳定剂存在下在水性介质中单体自由基聚合而获得，聚合在至少一种水溶性聚合物存在下进行由（a）乙酸乙烯酯和/或丙酸乙烯酯在聚乙二醇上的接枝聚合物，在一个或两个末端用烷基，羧基或氨基封端的聚乙二醇，烷基聚亚烷基二醇丙烯酸酯或烷基聚亚烷基二醇甲基丙烯酸酯的共聚物和丙烯酸和/或甲基丙烯酸，聚亚烷基二醇，在一个或两个端基用烷基，羧基或氨基封闭的聚亚烷基二醇，和（b）游离羧基形式的乙烯基烷基醚和马来酸酐的水解共聚物和至少部分用碱金属氢氧化物或铵碱中和的盐的形式，和/或由阳离子改性马铃薯淀粉，阴离子改性马铃薯淀粉，降解马铃薯淀粉和麦芽糖糊精作为稳定剂组成的组中的水溶性淀粉，所述水性分散体是通过单体在含水介质中的存在下的自由基聚合制备的上述（a）和（b）组的水溶性聚合物和所述水分散体用作含水体系的增稠剂。

5. 发明申请

US20060122322A1 Aqueous polymer dispersions 审中-公开
标题翻译：聚合物水分散体
公开(公告)号：US20060122322A1
公开(公告)日：2006-06-08
申请号：US10540097
申请日：2003-12-16
申请人： Lysander Chrisstoffels , Peter Hossel , Marc Leduc , Claudia Wood , Maximillian Angel , Klemens Mathauer , Pulakesh Mukherjee , Werner Gauweiler , Henning Bolter
发明人： Lysander Chrisstoffels , Peter Hossel , Marc Leduc , Claudia Wood , Maximillian Angel , Klemens Mathauer , Pulakesh Mukherjee , Werner Gauweiler , Henning Bolter
IPC分类号： C08F2/22
CPC分类号： C08F26/02 , A61K8/0212 , A61K8/8158 , A61Q1/02 , A61Q1/06 , A61Q1/10 , A61Q5/00 , A61Q5/006 , A61Q5/02 , A61Q5/04 , A61Q5/06 , A61Q5/065 , A61Q5/10 , A61Q5/12 , A61Q9/02 , A61Q11/00 , A61Q15/00 , A61Q17/04 , A61Q19/00 , A61Q19/001 , A61Q19/002 , A61Q19/005 , A61Q19/007 , A61Q19/10 , C08F20/54
摘要： Aqueous dispersion obtainable by free-radical polymerization of a) at least one N-vinyl-containing monomer b) at least one polymeric dispersant c) at least one polymeric precipitation agent d) at least one crosslinker e) optionally further monomers f) optionally at least one regulator g) optionally a buffer substance where the weight ratio of b) to c) is in the range from 1:50 to 1:0.02.
摘要翻译： b）至少一种聚合物分散剂c）至少一种聚合物分散剂d）至少一种交联剂e）任选地其它单体f）任选地在（a）至少一种含N-乙烯基单体的自由基聚合至少一个调节剂g）任选的缓冲物质，其中b）至c）的重量比在1:50至1:0.02的范围内。

6. 发明申请

US20060165639A1 Use of cross-linked cationic polymers in cosmetics 审中-公开
标题翻译：在化妆品中使用交联的阳离子聚合物
公开(公告)号：US20060165639A1
公开(公告)日：2006-07-27
申请号：US10525232
申请日：2003-08-29
申请人： Werner Gauweiler , Ludger Wegmann , Marc Leduc , Lysander Chrisstoffels , Michael Gotsche , Claudia Wood
发明人： Werner Gauweiler , Ludger Wegmann , Marc Leduc , Lysander Chrisstoffels , Michael Gotsche , Claudia Wood
IPC分类号： A61K8/81
CPC分类号： C08F226/10 , A61K8/8182 , A61K2800/48 , A61K2800/5426 , A61Q5/02 , A61Q5/12 , A61Q19/10 , C08F8/44 , C08F220/34 , C08F220/60 , C08F226/04 , C08F226/06
摘要： The invention relates to the use of a cationic crosslinked polymer which is preparable by free-radical polymerization in the presence of salts and of protective colloids in cosmetics.
摘要翻译：本发明涉及一种阳离子交联聚合物的用途，该聚合物可以在化合物中存在盐和保护胶体的情况下通过自由基聚合制备。

7. 发明申请

US20060116470A1 Production of aqueous dispersions of cationic homo-and copolymers using amphoteric protective colloids 审中-公开
标题翻译：使用两性保护胶体生产阳离子均聚物和共聚物的水分散体
公开(公告)号：US20060116470A1
公开(公告)日：2006-06-01
申请号：US10525587
申请日：2003-08-29
申请人： Werner Gauweiler , Marc Leduc , Lysander Chrisstoffels , Michael Gotsche , Claudia Wood
发明人： Werner Gauweiler , Marc Leduc , Lysander Chrisstoffels , Michael Gotsche , Claudia Wood
IPC分类号： C08G73/02
CPC分类号： C08F220/34 , C08F220/04 , C08F226/10 , C08F226/04
摘要： A process for the production of water-soluble or water-swellable cationic polymers by (i) free-radically initiated copolymerization of monomer mixtures in water comprising (a) from 1 to 99% by weight of a cationic monomer or quaternizable monomer, (b) from 1 to 99% by weight of a water-soluble monomer, (c) from 0 to 10% by weight of a bi- or polyfunctional, free-radically copolymerizable monomer, adjusting the amounts (a) to (c) in such a way that the resulting polymer has an overall positive charge, in the presence of 1 to 100% of the amount of a salt which is necessary to saturate the reaction medium with said salt and in the presence of 0.1 to 20% by weight referred to the weight of the dispersion, of an amphoteric dispersant having an overall negative charge, and (ii) subsequent quaternization of the polymer if the monomer (a) employed is a non-quaternized monomer is disclosed.
摘要翻译：（i）自由基引发的单体混合物在水中的共聚合产生水溶性或水溶胀性阳离子聚合物的方法，其包含（a）1至99重量％的阳离子单体或季铵化单体，（b ）1至99重量％的水溶性单体，（c）0至10重量％的双官能或多官能的可自由基共聚单体，调节其量（a）至（c）在所述聚合物具有总体正电荷的方法中，在存在1至100％量的使所述盐饱和反应介质所需的盐和在0.1-20重量％的存在下，所述盐称为分散体的重量，具有总负电荷的两性分散剂的重量，和（ii）如果使用的单体（a）是非季铵化单体，则聚合物随后的季铵化。

8. 发明授权

US08486227B2 Method for producing paper, paperboard and cardboard 有权
标题翻译：生产纸张，纸板和纸板的方法
公开(公告)号：US08486227B2
公开(公告)日：2013-07-16
申请号：US13609356
申请日：2012-09-11
申请人： Anton Esser , Rainer Blum , Joachim Kuhn , Marc Leduc , Ralf Hemel
发明人： Anton Esser , Rainer Blum , Joachim Kuhn , Marc Leduc , Ralf Hemel
IPC分类号： D21H17/34 , D21H17/37 , D21H17/55 , D21H17/56 , D21H21/02 , D21H21/10
CPC分类号： D21H21/02 , D21H17/37
摘要： A process for the production of paper, board and cardboard by draining a paper stock containing interfering substances in the presence of polymers which contain vinylamine units and which have an average molar mass Mw of at least 1 million, a high-consistency stock first being prepared, at least one polymer containing vinylamine units and having an average molar mass Mw of at least 1 million and a degree of hydrolysis of from 1 to 20 mol % being metered into the high-consistency stock, the high-consistency stock being diluted to a low-consistency stock by adding water, and the low-consistency stock being drained, the polymers being hydrolyzed homo- or copolymers of N-vinylcarboxamides additives for reducing deposits in the wire part, press section and drying section of paper machines.
摘要翻译：一种制备纸，纸板和纸板的方法，该方法是在含有乙烯胺单元的聚合物存在下含有干扰物质的纸料，并且其平均摩尔质量Mw至少为100万，首先制备高稠度原料至少一种含有乙烯胺单元并且具有至少100万的平均摩尔质量Mw和1至20摩尔％的水解度的聚合物被计量加入高浓度原料中，将高稠度原料稀释至低浓度原料通过加水，低浓度原料被排出，聚合物被水解为N-乙烯基甲酰胺添加剂的均聚物或共聚物，用于还原造纸机的丝线部分，压榨部分和干燥部分中的沉积物。

9. 发明申请

US20080196852A1 Method For the Production of Paper, Cardboard and Card 有权
标题翻译：生产纸张，纸板和卡片的方法
公开(公告)号：US20080196852A1
公开(公告)日：2008-08-21
申请号：US12065688
申请日：2006-09-05
申请人： Marc Leduc , Oliver Koch , Simon Champ , Rainer Blum , Andreas Merkel , Knut Menke
发明人： Marc Leduc , Oliver Koch , Simon Champ , Rainer Blum , Andreas Merkel , Knut Menke
IPC分类号： D21H17/45
CPC分类号： D21H21/10 , D21H17/37 , D21H17/55 , D21H17/56 , D21H17/68
摘要： Process for the production of paper, board and cardboard by draining a paper stock with sheet formation in the presence of a retention aid system comprising (i) at least one polymer comprising vinylamine units, in the form of the free bases, of the salts and/or in quaternized form, as the sole cationic polymer, (ii) at least one linear, anionic polymer having a molar mass Mw of at least 1 million and/or at least one branched, anionic, water-soluble polymer and/or bentonite and/or silica gel and (iii) at least one particulate, anionic, crosslinked, organic polymer having a mean particle diameter of at least 1 μm and an intrinsic viscosity of less than 3 dl/g, and use of the retention aid system comprising the components (i), (ii) and (iii) as an additive in the production of paper, board and cardboard.
摘要翻译：用于在存在助留剂系统的情况下通过排出具有片材形成的纸料的纸，纸板和纸板的生产方法，包括（i）至少一种包含游离碱形式的乙烯胺单元的聚合物盐，和 /或以季铵化形式，作为唯一的阳离子聚合物，（ii）至少一种线性阴离子聚合物，其具有至少100万摩尔质量百分比和/或至少一种支链，阴离子，水溶性聚合物和/或膨润土和/或硅胶和（iii）至少一种平均粒径至少为1μm，特性粘度小于3dl / g的颗粒状，阴离子交联的有机聚合物，以及包含组分（i），（ii）和（iii））的助留剂体系在纸，纸板和纸板的生产中作为添加剂的使用。

10. 发明申请

US20130014908A1 METHOD FOR PRODUCING PAPER, PAPERBOARD AND CARDBOARD 有权
标题翻译：生产纸张，纸板和卡片的方法
公开(公告)号：US20130014908A1
公开(公告)日：2013-01-17
申请号：US13609356
申请日：2012-09-11
申请人： Anton Esser , Ranier Blum , Joachim Kuhn , Marc Leduc , Ralf Hemel
发明人： Anton Esser , Ranier Blum , Joachim Kuhn , Marc Leduc , Ralf Hemel
IPC分类号： D21H23/00
CPC分类号： D21H21/02 , D21H17/37
摘要： A process for the production of paper, board and cardboard by draining a paper stock containing interfering substances in the presence of polymers which contain vinylamine units and which have an average molar mass Mw of at least 1 million, a high-consistency stock first being prepared, at least one polymer containing vinylamine units and having an average molar mass Mw of at least 1 million and a degree of hydrolysis of from 1 to 20 mol % being metered into the high-consistency stock, the high-consistency stock being diluted to a low-consistency stock by adding water, and the low-consistency stock being drained, the polymers being hydrolyzed homo- or copolymers of N-vinylcarboxamides additives for reducing deposits in the wire part, press section and drying section of paper machines.
摘要翻译：一种制备纸，纸板和纸板的方法，该方法是在含有乙烯胺单元的聚合物存在下含有干扰物质的纸料，并且其平均摩尔质量Mw至少为100万，首先制备高稠度原料至少一种含有乙烯胺单元并且具有至少100万的平均摩尔质量Mw和1至20摩尔％的水解度的聚合物被计量加入高浓度原料中，将高浓度原料稀释至低浓度原料通过加水，低浓度原料被排出，聚合物被水解为N-乙烯基甲酰胺添加剂的均聚物或共聚物，用于还原造纸机的丝线部分，压榨部分和干燥部分中的沉积物。

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