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1. 发明授权

US6069218A Aqueous coatings, the production thereof and the use thereof in the production of multi-layer paint coatings 失效
标题翻译：水性涂料，其制备方法及其在多层涂料涂料生产中的应用
公开(公告)号：US6069218A
公开(公告)日：2000-05-30
申请号：US254416
申请日：1999-03-08
申请人： Bettina Vogt-Birnbrich , Armin Gobel , Jurgen Dobert , Marcus Brunner
发明人： Bettina Vogt-Birnbrich , Armin Gobel , Jurgen Dobert , Marcus Brunner
IPC分类号： B05D1/36 , C08G18/12 , C08G18/67 , C09D175/04 , C08G18/04
CPC分类号： C08G18/672 , C08G18/12 , C09D175/04 , C08L2205/04
摘要： Aqueous coatings for the multi-layer painting of motor vehicles based on one or more binders and optionally crosslinking agents, pigments and/or fillers, paint industry additives and/or solvents, which contain as binder an aqueous dispersion based on polyurethane/polymer hybrid polymers having a numerical average of the molar mass (Mn) of 8000 to 1500000, a ratio by weight of polyurethane to polymer content of 0.05:1 to 50:1, a hydroxyl number of 0 to 150 mg KOH/g, based on solid resin, hydroxyl groups bound to silicon not being included when calculating the OH number, and an acid number of 1.5 to 40 mg KOH/g, based on solid resin, and a content of 0.5 to 150 mmole of silicon per 100 g of solid resin in the form of siloxane bridges (--Si--O--Si--) bound into the polyurethane content and/or in the form of silanol groups bound to the polyurethane content.
摘要翻译： PCT No.PCT / EP97 / 04821 Sec。 371日期1999年3月8日 102（e）1999年3月8日PCT 1997年9月5日PCT公布。公开号WO98 / 日期1998年3月12日基于一种或多种粘合剂和任选的交联剂，颜料和/或填料，涂料工业添加剂和/或溶剂的机动车辆多层涂料的水性涂料，其包含作为粘合剂的基于数均摩尔质量（Mn）为8000〜1500000的聚氨酯/聚合物混合聚合物，聚氨酯与聚合物含量的重量比为0.05:1〜50:1，羟值为0〜150mgKOH / g ，基于固体树脂，当计算OH值时不包括与硅结合的羟基，并且基于固体树脂的酸值为1.5至40mg KOH / g，并且每100个含量为0.5至150mmol的硅 g的结合到聚氨酯含量的硅氧烷桥（-Si-O-Si-）形式的固体树脂和/或与聚氨酯含量结合的硅烷醇基的形式。

2. 发明授权

US5908895A Aqueous dispersion of silane-functional polyurethane resins, coating compositions and use thereof 失效
标题翻译：硅烷官能聚氨酯树脂的水分散体，涂料组合物及其用途
公开(公告)号：US5908895A
公开(公告)日：1999-06-01
申请号：US879971
申请日：1997-06-20
申请人： Bettina Vogt-Birnbrich , Armin Gobel , Wilfried Collong , Birgit Kleuser
发明人： Bettina Vogt-Birnbrich , Armin Gobel , Wilfried Collong , Birgit Kleuser
IPC分类号： C08G18/77 , C08G18/08 , C08G18/42 , C08G18/80 , C08G18/83 , C09D5/00 , C09D175/06 , C08J3/00 , C08K3/20 , C08L75/00 , C08L83/00
CPC分类号： C08G18/8096 , C08G18/0823 , C08G18/4288 , C08G18/8064 , C08G18/809 , C09D175/06
摘要： Aqueous dispersion of silane-functional polyurethane resins having a number average molecular weight of 10000 to 500000 and a silicon content of 1 to 30 mmol per 100 g of resin solids obtainable by reacting(A) adducts containing NCO groups, which adducts are obtainable by reactinga) one or more compounds having at least one ionic or ionisable and/or hydrophilic nonionic group, and more than one isocyanate-reactive group withb) one or more organic diisocyanates,(B) with polyesters having an OH value of 150 to 300 mg of KOH/g and more than three OH groups per molecule, which are obtainable by reactingc) polyalcohols withd) polycarboxylic acids ande) monofatty acids(C) optionally with linear polyesters having an OH value of 40 to less than 150 mg of KOH/g, which contain no monofatty acids, and(D) with organic polyisocyanates, wherein at least a proportion of the polyisocyanates has at least one functional group R.sup.1 OSi.tbd. in whichR.sup.1 means C.sub.1 to C.sub.8 alkyl or --C(O)R.sup.2 and R.sup.2 means C.sub.1 to C.sub.10 alkyl,and converting the reaction product into an aqueous dispersion.
摘要翻译：数均分子量为10000〜500000，硅含量为1〜30mmol的硅烷官能聚氨酯树脂的水分散体，每100克树脂固体可通过使（A）含有NCO基团的加合物反应得到，该加合物可通过使 a）一种或多种具有至少一种离子或可离子和/或亲水性非离子基团的化合物，以及多于一种异氰酸酯反应性基团，其中b）一种或多种有机二异氰酸酯，（B）与OH值为150至300的聚酯 mg / g和每个分子多于三个OH基团，它们可通过使c）多元醇与d）多元羧酸和e）单糖（C）任选地具有OH值为40至小于150mg的线性聚酯不含单糖的KOH / g，和（D）有机多异氰酸酯，其中至少一部分多异氰酸酯具有至少一个官能团R1OSi 3BOND，其中R1表示C1至C8烷基或-C（O）R2 而R2意味着 C1-C10烷基，并将反应产物转化成水分散体。

3. 发明授权

US5854329A Water-thinnable dispersion, a process for producing it, and coating media 失效
标题翻译：水稀释分散体，其制备方法和涂布介质
公开(公告)号：US5854329A
公开(公告)日：1998-12-29
申请号：US818922
申请日：1997-03-17
申请人： Bettina Vogt-Birnbrich , Armin Gobel
发明人： Bettina Vogt-Birnbrich , Armin Gobel
IPC分类号： B05D7/14 , B01J13/00 , C08F8/44 , C08F290/06 , C08F290/14 , C08G18/67 , C09D5/00 , C09D155/00 , C09D175/14 , C09D175/16 , C08J3/02
CPC分类号： C09D175/14 , C08G18/67 , C08G18/672 , C09D175/16
摘要： This invention relates to a water-thinnable dispersion of one or more cationically modified and urethane-modified (meth)acrylic copolymers, which are produced by the solution polymerisation of unsaturated monomers which are polymerisable by a radical mechanism, or of a mixture of such monomers. Coating media based on this dispersion are particularly suitable for the production of base coats in multi-layer coatings, particularly in the coating of vehicles and vehicle parts.
摘要翻译：本发明涉及一种或多种阳离子改性和氨基甲酸酯改性（甲基）丙烯酸共聚物的水稀释分散体，其通过可通过自由基机理聚合的不饱和单体的溶液聚合或这些单体的混合物。基于该分散体的涂布介质特别适用于多层涂料中的底涂层的生产，特别是在车辆和车辆部件的涂覆中。

4. 发明授权

US6001924A Aqueous polymer/polyurethane resin binder vehicle dispersion and the production thereof, and coating media and the use thereof 失效
标题翻译：水性聚合物/聚氨酯树脂粘合剂载体分散体及其制备，以及涂布介质及其用途
公开(公告)号：US6001924A
公开(公告)日：1999-12-14
申请号：US101849
申请日：1998-07-20
申请人： Jurgen Dobert , Bettina Vogt-Birnbrich , Armin Gobel , Marcus Brunner
发明人： Jurgen Dobert , Bettina Vogt-Birnbrich , Armin Gobel , Marcus Brunner
IPC分类号： C08L75/02 , C08F283/00 , C08G18/08 , C08G18/10 , C08G18/40 , C08G18/63 , C08G18/83 , C08L75/04 , C09D5/00 , C09D133/00 , C09D167/00 , C09D175/04 , C08J3/00 , B05D3/02 , C08F8/30 , C08K3/20 , C08L75/00
CPC分类号： C08G18/832 , C08F283/006 , C08G18/0804 , C08G18/10 , C08G18/637
摘要： An aqueous binder vehicle dispersion and coating media, which can be used for multi-layer coating, wherein the dispersion is obtainable by the reaction ofI. 20 to 97% by weight of a polyurethane(-urea) resin containing groups which are reactive towards a chain extender IV), having a number average molecular weight (Mn) of 1000 to 10,000, and 8 to 80 milliequivalents per 100 g of ionic groups, groups which can be converted into ionic groups and/or hydrophilic groups,II. 0 to 30% by weight of a polyester resin having a number average molecular weight (Mn) of 500 to 5000, and having the same groups as in I) which are reactive towards IV), andIII. 3 to 80% by weight of a (meth)acrylic copolymer containing 0 to 40 milliequivalents per 100 g of ionic groups, groups which can be converted into ionic groups with the same charge as in I) and/or hydrophilic groups, having the same groups as in I) and II) which are reactive towards IV), wherein at least 50% by weight of III) has been produced in the presence of at least part of components I) and/or II), withIV. one or more chain extenders,and conversion into the aqueous phase.
摘要翻译： PCT No.PCT / EP97 / 00150 Sec。 371日期：1998年7月20日 102（e）1998年7月20日PCT PCT 1997年1月15日PCT公布。公开号WO97 / 26289 日期1997年7月24日可以用于多层涂布的水性粘合剂载体分散体和涂布介质，其中所述分散体可通过将I-20-97重量％的含有对扩链剂IV具有反应性的基团），数均分子量（Mn）为1000至10,000，每100g离子基团为8至80毫当量，可转化为离子基团和/或亲水基团的基团，II。 0〜30重量％的对IV具有反应性的数均分子量（Mn）为500〜5000的聚酯树脂，并且具有与I相同的基团），以及III。 3至80重量％的每100克离子基团含有0至40毫当量的（甲基）丙烯酸共聚物，可以转化为与I相同的电荷的离子基团）和/或具有相同电荷的亲水基团在I）和/或II）至少部分I）和/或II）的存在下，其中至少50重量％的III）已经在IV中产生。一种或多种扩链剂，并转化成水相。

5. 发明授权

US4623690A Cathodically precipitable aqueous electro-dipcoating agent 失效
标题翻译：阴极沉淀的水性电泳涂料
公开(公告)号：US4623690A
公开(公告)日：1986-11-18
申请号：US649413
申请日：1984-09-11
申请人： Hans-Peter Patzschke , Armin Gobel , Reiner Bohmert
发明人： Hans-Peter Patzschke , Armin Gobel , Reiner Bohmert
IPC分类号： C08G18/08 , C08G18/83 , C09D5/44 , C09D175/12 , C08L51/00 , C08L77/00
CPC分类号： C09D5/4465 , C08G18/0814 , C08G18/831 , C09D175/12
摘要： A cathodically precipitable aqueous electro-dipcoating agent which includes as Component A, 50 to 99% by mass (relative to the total quantity of Components A and B) of a synthetic resin binder having tertiary amino groups and hydroxyl groups which can be rendered water soluble by protonation with acids, and which(a) has an amine number of 35 to 120,(b) has a hydroxyl number of 50 to 400,(c) has substantially no primary, secondary and quaternary amino groups,(d) has substantially no free isocyanate groups, and(e) has substantially no blocked isocyanate groups which can react at baking temperatures of up to 200.degree. C. with hydroxyl groups present in the reaction components.The agent also includes as Component B, 1 to 50% by mass (relative to the total quantity of Components A and B) of substantially non-acid synthetic resins having at least two terminal esterified carboxyl groups which can react under normal lacquer baking conditions with Component A, accompanied by cross-linkage.
摘要翻译：一种阴极可沉淀的水性电涂布剂，其包含作为组分A的50至99质量％（相对于组分A和B的总量）的具有叔氨基和可以使水溶性的羟基的合成树脂粘合剂（a）具有35至120的胺值，（b）羟基数为50至400，（c）基本上不含伯，仲和季氨基，（d）基本上没有游离的异氰酸酯基团，（e）基本上没有封端的异氰酸酯基，其可以在高达200℃的烘烤温度下与反应组分中存在的羟基反应。该试剂还包括作为组分B的1至50质量％（相对于组分A和B的总量）的基本上非酸性合成树脂，其具有至少两个可在正常漆烘烤条件下反应的末端酯化羧基，组分A，伴有交联。

6. 发明授权

US5658617A Aqueous dispersion of polyurethane resins, a method of manufacturing them, coating agents containing them and use thereof 失效
标题翻译：聚氨酯树脂的水分散体，其制造方法，含有它们的涂布剂及其用途
公开(公告)号：US5658617A
公开(公告)日：1997-08-19
申请号：US595454
申请日：1996-02-05
申请人： Armin Gobel , Hans-Peter Patzschke
发明人： Armin Gobel , Hans-Peter Patzschke
IPC分类号： C08G18/00 , C08G18/08 , C08G18/10 , C08G18/12 , C08G18/65 , C08G18/66 , C08G18/80 , C09D175/00 , C09D175/04 , C09D175/06 , B05D3/02 , C08J3/00 , C08K3/20 , C08L75/00
CPC分类号： C09D175/06 , C08G18/0819 , C08G18/0823 , C08G18/10 , C08G18/12 , C08G18/6659 , C08G18/8048 , C08G18/8054
摘要： A method of manufacturing aqueous dipsersion of polyurethane resins free from urea groups and containing ionic groups and suitable for coating agents, with a number average moleculear weight (Mn) of 10,000 to 300,000 and an acid number of 5 to 50, by preparing a polyurethane prepolymer containing OH groups and with an OH number of 5 to 75 and a number average molecular weight (Mn) of 5,000 to 50,000.
摘要翻译：通过制备聚氨酯预聚物，制备数均分子量（Mn）为10,000〜300,000，酸数为5〜50的，不含脲基并含有离子性基团，适合于涂布剂的聚氨酯树脂的水分散性的方法 OH基为5〜75，数均分子量（Mn）为5000〜50,000。

7. 发明授权

US4880867A Aqueous coating compositions, a process for their preparation and method of using the same 失效
标题翻译：水性涂料组合物，其制备方法及其使用方法
公开(公告)号：US4880867A
公开(公告)日：1989-11-14
申请号：US86905
申请日：1987-08-18
申请人： Armin Gobel , Knut Graff , Hans-Ulrich Meier , Hans-Peter Patzschke
发明人： Armin Gobel , Knut Graff , Hans-Ulrich Meier , Hans-Peter Patzschke
IPC分类号： B05D7/24 , C08G18/62 , C08L75/04 , C09D133/14 , C09D175/00 , C09D175/04
CPC分类号： C09D175/04 , C09D133/14 , C08L75/04
摘要： An aqueous coating composition is provided which comprises a film forming material based on water dilutable binders which are comprised of a mixture of (A) 90 to 40% by weight of hydroxyl group-containing polymer resin; (B) 10 to 60% by weight of polyurethane dispersion and (C) pigments; as well as optionally conventional solvents, auxiliary agents, and additives. The process for the preparation of the coating composition and a method for the application of the coating composition are also described.
摘要翻译：提供一种水性涂料组合物，其包含基于水可稀释粘合剂的成膜材料，其由（A）90至40重量％的含羟基聚合物树脂的混合物组成; （B）10〜60重量％的聚氨酯分散体和（C）颜料; 以及任选的常规溶剂，助剂和添加剂。还描述了制备涂料组合物的方法和涂料组合物的应用方法。

8. 发明授权

US4454264A Heat curable aqueous lacquer coating composition, its use for electrical deposition, and a process of cathodic deposition onto an electrical conductive substrate 失效
标题翻译：可热固化的水漆涂料组合物，其用于电沉积的方法，以及阴极沉积到导电基材上的过程
公开(公告)号：US4454264A
公开(公告)日：1984-06-12
申请号：US279952
申请日：1981-07-02
申请人： Hans-Peter Patzschke , Armin Gobel
发明人： Hans-Peter Patzschke , Armin Gobel
IPC分类号： C08G18/08 , C08G18/80 , C09D5/44 , C09D175/04 , C08L63/02
CPC分类号： C09D5/4473 , C08G18/0814 , C08G18/8061 , C09D175/04 , C09D5/4488 , Y10S524/901
摘要： Paint coating material capable of cathodic deposition based on a vehicle mixture that has been made water-thinnable with acid and optionally customary additives, wherein said vehicle contains in combination(A) from 50 to 90% by weight of a polymer and/or polycondensate containing tertiary amino-groups and OH groups and having amine and hydroxy numbers of from 30 to 170 and 30 to 300 respectively;(B) from 5 to 40% by weight of a fully blocked polyisocyanate which is stable in the aqueous phase and becomes reactive again under the influence of heat, after dissociation of the blocking group; and(C) from 0 to 30% by weight of polymer and/or polycondensate containing primary and/or secondary OH- and/or amino-groups.
摘要翻译：基于已经用酸稀释的载体混合物和任选的常规添加剂，能够进行阴极沉积的涂料材料，其中所述载体包含（A）50至90重量％的聚合物和/或缩聚物叔氨基和OH基，胺和羟基数分别为30至170和30至300; （B）5〜40重量％的完全封闭的聚异氰酸酯，其在水相中稳定，并且在热阻的作用下，在封闭基团解离之后再次变成反应物; 和（C）0至30重量％的含有伯和/或仲OH-和/或氨基的聚合物和/或缩聚物。

9. 发明授权

US4252703A Cathodically depositable aqueous electro-dipping lacquer coating composition 失效
标题翻译：阴极沉积的水性电镀漆组合物
公开(公告)号：US4252703A
公开(公告)日：1981-02-24
申请号：US18004
申请日：1979-03-07
申请人： Hans-Peter Patzschke , Armin Gobel
发明人： Hans-Peter Patzschke , Armin Gobel
IPC分类号： C08F290/00 , C08F299/00 , C08G18/08 , C08G18/10 , C09D5/44 , C09D163/10 , C08L63/02 , C08L63/10
CPC分类号： C09D5/4496 , C08G18/0814 , C08G18/10 , C09D5/4453 , Y10S524/901
摘要： A cathodically depositable aqueous electro-dipping lacquer coating which contain as binder, which binder can be diluted with water by protonization with acids, 55 to 95% by weight based on the total quantity of binder, of organic synthetic resin binders containing amino groups, having an average molecular weight (Mn) of about 500 to 10,000, a pK.sub.b value of about 3 to 7 and an amine value of about 30 to 150 and 45 to 5% by weight of cross-linking agents having an average molecular weight (Mn) of about 500 to 5,000, which contain esterified terminal carboxyl groups.
摘要翻译：含有作为粘合剂的阴极可沉积的水性电镀漆涂层，该粘合剂可以通过用酸质子化而用水稀释粘合剂，基于粘合剂总量为55-95重量％，含有氨基的有机合成树脂粘合剂，其具有约500至10,000的平均分子量（Mn），约3至7的pKb值和约30至150的胺值和具有平均分子量（Mn）的交联剂的45至5重量％约500至5,000，其含有酯化的末端羧基。

10. 发明授权

US4865705A Non-auto crosslinking binder combination, aqueous coating compound containing the same and its use 失效
标题翻译：非自动交联粘合剂组合，含有相同含水涂料及其用途
公开(公告)号：US4865705A
公开(公告)日：1989-09-12
申请号：US86719
申请日：1987-08-18
申请人： Georg Hendrikx , Hans-Peter Patzschke , Armin Gobel
发明人： Georg Hendrikx , Hans-Peter Patzschke , Armin Gobel
IPC分类号： C09D5/44 , C09D133/04 , C09D133/14 , C09D133/16 , C09D175/04 , C09D175/14
CPC分类号： C09D133/14 , C09D5/4411 , Y10S524/901
摘要： A non-autocrosslinking binder composition for water dilutable lacquers is described, containing from 95 to 50 parts by weight of a water dilutable poly(meth)acrylate resin containing amino and hydroxyl groups and from 5 to 50% by weight of crosslinking agents is described. An aqueous electrodip lacquer coating composition capable of being deposited at the cathode and its use for coating articles having an electrically conductive surface at the cathode are also described.
摘要翻译：描述了一种用于水可稀释漆的非自交联粘合剂组合物，其含有95至50重量份含有氨基和羟基的水可稀释的聚（甲基）丙烯酸酯树脂和5至50重量％的交联剂。还描述了能够在阴极沉积的水性电涂漆涂料组合物及其用于在阴极处涂覆具有导电表面的制品的用途。

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