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1. 发明授权

US4454264A Heat curable aqueous lacquer coating composition, its use for electrical deposition, and a process of cathodic deposition onto an electrical conductive substrate 失效
标题翻译：可热固化的水漆涂料组合物，其用于电沉积的方法，以及阴极沉积到导电基材上的过程
公开(公告)号：US4454264A
公开(公告)日：1984-06-12
申请号：US279952
申请日：1981-07-02
申请人： Hans-Peter Patzschke , Armin Gobel
发明人： Hans-Peter Patzschke , Armin Gobel
IPC分类号： C08G18/08 , C08G18/80 , C09D5/44 , C09D175/04 , C08L63/02
CPC分类号： C09D5/4473 , C08G18/0814 , C08G18/8061 , C09D175/04 , C09D5/4488 , Y10S524/901
摘要： Paint coating material capable of cathodic deposition based on a vehicle mixture that has been made water-thinnable with acid and optionally customary additives, wherein said vehicle contains in combination(A) from 50 to 90% by weight of a polymer and/or polycondensate containing tertiary amino-groups and OH groups and having amine and hydroxy numbers of from 30 to 170 and 30 to 300 respectively;(B) from 5 to 40% by weight of a fully blocked polyisocyanate which is stable in the aqueous phase and becomes reactive again under the influence of heat, after dissociation of the blocking group; and(C) from 0 to 30% by weight of polymer and/or polycondensate containing primary and/or secondary OH- and/or amino-groups.
摘要翻译：基于已经用酸稀释的载体混合物和任选的常规添加剂，能够进行阴极沉积的涂料材料，其中所述载体包含（A）50至90重量％的聚合物和/或缩聚物叔氨基和OH基，胺和羟基数分别为30至170和30至300; （B）5〜40重量％的完全封闭的聚异氰酸酯，其在水相中稳定，并且在热阻的作用下，在封闭基团解离之后再次变成反应物; 和（C）0至30重量％的含有伯和/或仲OH-和/或氨基的聚合物和/或缩聚物。

2. 发明授权

US4252703A Cathodically depositable aqueous electro-dipping lacquer coating composition 失效
标题翻译：阴极沉积的水性电镀漆组合物
公开(公告)号：US4252703A
公开(公告)日：1981-02-24
申请号：US18004
申请日：1979-03-07
申请人： Hans-Peter Patzschke , Armin Gobel
发明人： Hans-Peter Patzschke , Armin Gobel
IPC分类号： C08F290/00 , C08F299/00 , C08G18/08 , C08G18/10 , C09D5/44 , C09D163/10 , C08L63/02 , C08L63/10
CPC分类号： C09D5/4496 , C08G18/0814 , C08G18/10 , C09D5/4453 , Y10S524/901
摘要： A cathodically depositable aqueous electro-dipping lacquer coating which contain as binder, which binder can be diluted with water by protonization with acids, 55 to 95% by weight based on the total quantity of binder, of organic synthetic resin binders containing amino groups, having an average molecular weight (Mn) of about 500 to 10,000, a pK.sub.b value of about 3 to 7 and an amine value of about 30 to 150 and 45 to 5% by weight of cross-linking agents having an average molecular weight (Mn) of about 500 to 5,000, which contain esterified terminal carboxyl groups.
摘要翻译：含有作为粘合剂的阴极可沉积的水性电镀漆涂层，该粘合剂可以通过用酸质子化而用水稀释粘合剂，基于粘合剂总量为55-95重量％，含有氨基的有机合成树脂粘合剂，其具有约500至10,000的平均分子量（Mn），约3至7的pKb值和约30至150的胺值和具有平均分子量（Mn）的交联剂的45至5重量％约500至5,000，其含有酯化的末端羧基。

3. 发明授权

US5658617A Aqueous dispersion of polyurethane resins, a method of manufacturing them, coating agents containing them and use thereof 失效
标题翻译：聚氨酯树脂的水分散体，其制造方法，含有它们的涂布剂及其用途
公开(公告)号：US5658617A
公开(公告)日：1997-08-19
申请号：US595454
申请日：1996-02-05
申请人： Armin Gobel , Hans-Peter Patzschke
发明人： Armin Gobel , Hans-Peter Patzschke
IPC分类号： C08G18/00 , C08G18/08 , C08G18/10 , C08G18/12 , C08G18/65 , C08G18/66 , C08G18/80 , C09D175/00 , C09D175/04 , C09D175/06 , B05D3/02 , C08J3/00 , C08K3/20 , C08L75/00
CPC分类号： C09D175/06 , C08G18/0819 , C08G18/0823 , C08G18/10 , C08G18/12 , C08G18/6659 , C08G18/8048 , C08G18/8054
摘要： A method of manufacturing aqueous dipsersion of polyurethane resins free from urea groups and containing ionic groups and suitable for coating agents, with a number average moleculear weight (Mn) of 10,000 to 300,000 and an acid number of 5 to 50, by preparing a polyurethane prepolymer containing OH groups and with an OH number of 5 to 75 and a number average molecular weight (Mn) of 5,000 to 50,000.
摘要翻译：通过制备聚氨酯预聚物，制备数均分子量（Mn）为10,000〜300,000，酸数为5〜50的，不含脲基并含有离子性基团，适合于涂布剂的聚氨酯树脂的水分散性的方法 OH基为5〜75，数均分子量（Mn）为5000〜50,000。

4. 发明授权

US4880867A Aqueous coating compositions, a process for their preparation and method of using the same 失效
标题翻译：水性涂料组合物，其制备方法及其使用方法
公开(公告)号：US4880867A
公开(公告)日：1989-11-14
申请号：US86905
申请日：1987-08-18
申请人： Armin Gobel , Knut Graff , Hans-Ulrich Meier , Hans-Peter Patzschke
发明人： Armin Gobel , Knut Graff , Hans-Ulrich Meier , Hans-Peter Patzschke
IPC分类号： B05D7/24 , C08G18/62 , C08L75/04 , C09D133/14 , C09D175/00 , C09D175/04
CPC分类号： C09D175/04 , C09D133/14 , C08L75/04
摘要： An aqueous coating composition is provided which comprises a film forming material based on water dilutable binders which are comprised of a mixture of (A) 90 to 40% by weight of hydroxyl group-containing polymer resin; (B) 10 to 60% by weight of polyurethane dispersion and (C) pigments; as well as optionally conventional solvents, auxiliary agents, and additives. The process for the preparation of the coating composition and a method for the application of the coating composition are also described.
摘要翻译：提供一种水性涂料组合物，其包含基于水可稀释粘合剂的成膜材料，其由（A）90至40重量％的含羟基聚合物树脂的混合物组成; （B）10〜60重量％的聚氨酯分散体和（C）颜料; 以及任选的常规溶剂，助剂和添加剂。还描述了制备涂料组合物的方法和涂料组合物的应用方法。

5. 发明授权

US4623690A Cathodically precipitable aqueous electro-dipcoating agent 失效
标题翻译：阴极沉淀的水性电泳涂料
公开(公告)号：US4623690A
公开(公告)日：1986-11-18
申请号：US649413
申请日：1984-09-11
申请人： Hans-Peter Patzschke , Armin Gobel , Reiner Bohmert
发明人： Hans-Peter Patzschke , Armin Gobel , Reiner Bohmert
IPC分类号： C08G18/08 , C08G18/83 , C09D5/44 , C09D175/12 , C08L51/00 , C08L77/00
CPC分类号： C09D5/4465 , C08G18/0814 , C08G18/831 , C09D175/12
摘要： A cathodically precipitable aqueous electro-dipcoating agent which includes as Component A, 50 to 99% by mass (relative to the total quantity of Components A and B) of a synthetic resin binder having tertiary amino groups and hydroxyl groups which can be rendered water soluble by protonation with acids, and which(a) has an amine number of 35 to 120,(b) has a hydroxyl number of 50 to 400,(c) has substantially no primary, secondary and quaternary amino groups,(d) has substantially no free isocyanate groups, and(e) has substantially no blocked isocyanate groups which can react at baking temperatures of up to 200.degree. C. with hydroxyl groups present in the reaction components.The agent also includes as Component B, 1 to 50% by mass (relative to the total quantity of Components A and B) of substantially non-acid synthetic resins having at least two terminal esterified carboxyl groups which can react under normal lacquer baking conditions with Component A, accompanied by cross-linkage.
摘要翻译：一种阴极可沉淀的水性电涂布剂，其包含作为组分A的50至99质量％（相对于组分A和B的总量）的具有叔氨基和可以使水溶性的羟基的合成树脂粘合剂（a）具有35至120的胺值，（b）羟基数为50至400，（c）基本上不含伯，仲和季氨基，（d）基本上没有游离的异氰酸酯基团，（e）基本上没有封端的异氰酸酯基，其可以在高达200℃的烘烤温度下与反应组分中存在的羟基反应。该试剂还包括作为组分B的1至50质量％（相对于组分A和B的总量）的基本上非酸性合成树脂，其具有至少两个可在正常漆烘烤条件下反应的末端酯化羧基，组分A，伴有交联。

6. 发明授权

US4865705A Non-auto crosslinking binder combination, aqueous coating compound containing the same and its use 失效
标题翻译：非自动交联粘合剂组合，含有相同含水涂料及其用途
公开(公告)号：US4865705A
公开(公告)日：1989-09-12
申请号：US86719
申请日：1987-08-18
申请人： Georg Hendrikx , Hans-Peter Patzschke , Armin Gobel
发明人： Georg Hendrikx , Hans-Peter Patzschke , Armin Gobel
IPC分类号： C09D5/44 , C09D133/04 , C09D133/14 , C09D133/16 , C09D175/04 , C09D175/14
CPC分类号： C09D133/14 , C09D5/4411 , Y10S524/901
摘要： A non-autocrosslinking binder composition for water dilutable lacquers is described, containing from 95 to 50 parts by weight of a water dilutable poly(meth)acrylate resin containing amino and hydroxyl groups and from 5 to 50% by weight of crosslinking agents is described. An aqueous electrodip lacquer coating composition capable of being deposited at the cathode and its use for coating articles having an electrically conductive surface at the cathode are also described.
摘要翻译：描述了一种用于水可稀释漆的非自交联粘合剂组合物，其含有95至50重量份含有氨基和羟基的水可稀释的聚（甲基）丙烯酸酯树脂和5至50重量％的交联剂。还描述了能够在阴极沉积的水性电涂漆涂料组合物及其用于在阴极处涂覆具有导电表面的制品的用途。

7. 发明授权

US4595717A Aqueous electrodip lacquer coating compound capable of being deposited at the cathode, and its use 失效
标题翻译：能够在阴极沉积的水性电涂漆涂料及其用途
公开(公告)号：US4595717A
公开(公告)日：1986-06-17
申请号：US656356
申请日：1984-10-01
申请人： Hans-Peter Patzschke , Armin Gobel , Klausjorg Klein
发明人： Hans-Peter Patzschke , Armin Gobel , Klausjorg Klein
IPC分类号： C08G59/10 , C09D5/44 , C08G59/14 , C09D3/49 , C25D13/04
CPC分类号： C09D5/4453 , C08G59/10 , C09D5/4434 , Y10S524/901
摘要： Aqueous electrodip lacquer coating compound capable of being deposited cathodically, containing, as synthetic resin binder,(A) 55 to 95% by weight of synthetic resin binder which can be rendered water soluble by protonation with acid and(B) 5 to 45% by weight of a cross-linking agent containing ester groups capable of transesterification and/or transamidation and having terminal ester groups which are substantially stable in a neutral aqueous medium but capable of reacting with synthetic resin binder (A) in an alkaline medium at temperatures above 140.degree. C., component (A) containing in its molecule at least one molecule-enlarging diamine of the formula ##STR1## wherein the symbol Y stands for H or C.sub.m H.sub.2m+1 (m=1 to 8) or an organic group used for defunctionalization, which is formed by the reaction of the primary amino group with monoepoxides, and the symbol X represents a molecular grouping having at least one amide and/or urea group.
摘要翻译：能够阴极沉积的水性电涂漆涂料，含有作为合成树脂粘合剂的（A）55至95重量％的合成树脂粘合剂，其可通过用酸质子化而使水溶性;（B）5-45％含有能够酯交换和/或转酰氨基的酯基并具有在中性水性介质中基本稳定但能够在碱性介质中与合成树脂粘合剂（A）在高于140℃的温度下反应的末端酯基的交联剂的重量在其分子中含有至少一种式（I）的分子扩增二胺的组分（A），其中符号Y代表H或CmH2m + 1（m = 1至8）或有机基团用于通过伯氨基与单环氧化物的反应形成的官能化，符号X表示具有至少一个酰胺和/或脲基团的分子组。

8. 发明授权

US4364860A Cathodically depositable aqueous electro-dipping lacquer coating composition 失效
标题翻译：阴极沉积的水性电镀漆组合物
公开(公告)号：US4364860A
公开(公告)日：1982-12-21
申请号：US164952
申请日：1980-07-01
申请人： Hans-Peter Patzschke , Armin Gobel
发明人： Hans-Peter Patzschke , Armin Gobel
IPC分类号： C08F290/00 , C08F299/00 , C08G18/08 , C08G18/10 , C09D5/44 , C09D163/10 , C08L75/12 , C08L63/02
CPC分类号： C09D5/4496 , C08G18/0814 , C08G18/10 , C09D5/4453 , Y10S524/901
摘要： A cathodically depositable aqueous electro-dipping lacquer coating which contain as binder, which binder can be diluted with water by protonization with acids, 55 to 95% by weight based on the total quantity of binder, of organic synthetic resin binders containing amino groups, having an average molecular weight (Mn) of about 500 to 10,000, a pK.sub.b value of about 3 to 7 and an amine value of about 30 to 150 and 45 to 5% by weight of cross-linking agents having an average molecular weight (Mn) of about 500 to 5,000, which contain esterified terminal carboxyl groups.
摘要翻译：含有作为粘合剂的阴极可沉积的水性电镀漆涂层，该粘合剂可以通过用酸质子化而用水稀释粘合剂，基于粘合剂总量为55-95重量％，含有氨基的有机合成树脂粘合剂，其具有约500至10,000的平均分子量（Mn），约3至7的pKb值和约30至150的胺值和具有平均分子量（Mn）的交联剂的45至5重量％约500至5,000，其含有酯化的末端羧基。

9. 发明授权

US5654391A Aqueous dispersion based on polymer/polyurethane resins, process for the production thereof, coating compositions and use thereof 失效
标题翻译：基于聚合物/聚氨酯树脂的水分散体，其制备方法，涂料组合物及其用途
公开(公告)号：US5654391A
公开(公告)日：1997-08-05
申请号：US425284
申请日：1995-04-20
申请人： Armin Gobel , Hans-Peter Patzschke
发明人： Armin Gobel , Hans-Peter Patzschke
IPC分类号： C08G18/08 , C08G18/10 , C08G18/40
CPC分类号： C08G18/4063 , C08G18/0819 , C08G18/10
摘要： Aqueous binder dispersions for aqueous coating compositions, which are stable in storage and have good applicational properties. The dispersions are obtainable by joint chain extension ofone or more polyurethanes containing no urea groups, bearing ionic groups or groups convertible into ionic groups, having substantially terminal OH groups and having a number average molar mass (M.sub.n) of 1,000 to 10,000, an acid value of 5 to 50 and an OH value of 5 to 50 andII. one or more polymers containing hydroxyl groups based on ethylenically unsaturated monomers, having an acid value of 0 to 20, an OH value of 150 to 400 and a number average molar mass (M.sub.n) of 2,000 to 20,000, wherein the molar ratio of the hydroxyl groups of component I to those of component II is 1:6 to 1.0:0.5, withIII. one or more diisocyanates, in a molar ratio of the OHgroups from components I and II to the NCO groups of component III of 1.05:1 to 10:1, in an anhydrous medium, neutralisation of at least a proportion of the groups present which are convertible into ionic groups and conversion of the resultant product into the aqueous phase.
摘要翻译：用于水性涂料组合物的水性粘合剂分散体，其在储存中稳定并具有良好的应用性能。分散体可以通过一个或多个不含脲基团，带有离子基团或可转化成离子基团的聚氨酯，具有基本上末端的OH基团并且具有1,000至10,000的数均摩尔质量（Mn）的聚氨酯的连接链延伸获得，酸值为5〜50，OH值为5〜50，II。一种或多种含有基于烯属不饱和单体的羟基的聚合物，其酸值为0至20，OH值为150至400，数均摩尔质量（Mn）为2,000至20,000，其中羟基的摩尔比组分I的组分与组分II的组成为1：6至1.0：0.5，与III组成。一种或多种二异氰酸酯，在无水介质中以组分I和II的OH基团与组分III的NCO基团的摩尔比为1.05:1至10:1，中和至少一部分存在的基团可转化成离子基团并将所得产物转化成水相。

10. 发明授权

US5342882A Aqueous coating compound, a process for its preparation and its use in processes for multilayered lacquering 失效
标题翻译：水性涂料化合物，其制备方法及其在多层涂漆工艺中的应用
公开(公告)号：US5342882A
公开(公告)日：1994-08-30
申请号：US95959
申请日：1993-07-22
申请人： Armin Gobel , Hans-Peter Patzschke , Jurgen Doebert
发明人： Armin Gobel , Hans-Peter Patzschke , Jurgen Doebert
IPC分类号： C09D5/02 , B05D7/00 , C08G18/08 , C08G18/66 , C09D5/00 , C09D151/08 , C09D161/00 , C09D161/04 , C09D167/00 , C09D167/08 , C09D175/00 , C09D175/04 , C09D175/14 , C08L75/00
CPC分类号： B05D7/53 , C09D151/08 , C09D175/04
摘要： Aqueous coating compound containing a polyurethane resin-based binder ofI) from 60 to 100% by weight of a mixture ofA) from 5-95% by weight of one or more self-emulsifying polyurethane resins in aqueous dispersion having a number average molar mass (Mn) of from 30000 to 300000 and containing carboxyl groups corresponding to an acid number of from 5 to 50, obtainable from a water dispersible polyurethane prepolymer having more than one free isocyanate group per molecule, by chain lengthening with water andB) from 95 to 5% by weight of one or more acrylated polyesters and/or acrylated polyurethanes having an acid number of from 5 to 50 in aqueous dispersion andII) from 0 to 40% by weight of one or more formaldehyde condensation resins and/or blocked polyisocyanates,the percentages by weight being based in each case on the resin solids content. The coating compounds are suitable in particular as basic lacquers for multi-coat lacquering. Coatings with good weather resistance are produced from them.
摘要翻译：含有I）的聚氨酯树脂基粘合剂的水性涂料化合物为60-100重量％的A）5-95重量％的一种或多种具有数均摩尔数的水分散体中的自乳化聚氨酯树脂的混合物质量（Mn）为30000〜300000，含有相当于酸值为5〜50的羧基，可从每分子多于一个游离异氰酸酯基的水分散性聚氨酯预聚物获得，通过链长度加水，B） 95至5重量％的一种或多种丙烯酸酯化的聚酯和/或丙烯酸酯化聚氨酯，其水分散体中酸值为5至50，和II）0至40重量％的一种或多种甲醛缩合树脂和/或封闭多异氰酸酯，重量百分比基于每种情况下的树脂固体含量。涂料化合物特别适用于多层涂漆的碱性漆。从它们生产具有良好耐候性的涂层。

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