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1. 发明授权

US5955159A Conforming shoe construction using gels and method of making the same 失效
公开(公告)号：US5955159A
公开(公告)日：1999-09-21
申请号：US549299
申请日：1995-10-27
申请人： Bernie Allen , Zoran Petrovic , Ivan Javni , Neil M. Goldman
发明人： Bernie Allen , Zoran Petrovic , Ivan Javni , Neil M. Goldman
IPC分类号： A41C3/10 , A42B1/22 , A42B3/12 , A43B7/02 , A43B7/14 , A43B7/16 , A43B7/18 , A43B7/28 , A43B13/18 , A43B17/16 , A43B19/00 , A43B23/02 , A43B23/26 , A47C27/08 , A63B71/08 , A63B71/14 , B29D35/12 , B29D35/14 , B32B27/06 , A61G7/00
CPC分类号： A42B3/121 , A43B13/187 , A43B13/189 , A43B17/16 , A43B19/00 , A43B23/0235 , A43B23/0285 , A43B23/26 , A43B7/02 , A43B7/14 , A43B7/142 , A43B7/144 , A43B7/1495 , A43B7/16 , A43B7/18 , A43B7/28 , A47C27/085 , A63B71/143 , B29D35/126 , B29D35/14 , B29D35/142 , B29D35/146 , B32B27/06 , A41C3/146 , A63B71/081 , Y10T428/13
摘要： A shoe that conforms to foot contours and provides cushioning is comprised of a shoe sole and a shoe upper attached to the shoe sole. The shoe upper is comprised of an outer layer, an inner layer and a conforming layer therebetween, wherein a first portion of the conforming layer is comprised of environmentally-responsive gel. The environmentally-responsive gel is a temperature-responsive gel that will react to the heat emanating from a foot inserted into the shoe to express a liquid.

2. 发明授权

US5985383A Conforming shoe construction and gel compositions therefor 失效
标题翻译：符合鞋结构及其凝胶成分
公开(公告)号：US5985383A
公开(公告)日：1999-11-16
申请号：US616130
申请日：1996-03-14
申请人： Bernie Allen , Zoran Petrovic , Ivan Javni , Neil M. Goldman
发明人： Bernie Allen , Zoran Petrovic , Ivan Javni , Neil M. Goldman
IPC分类号： A42B1/22 , A42B3/12 , A43B7/02 , A43B7/14 , A43B7/18 , A43B13/18 , A43B17/16 , A43B19/00 , A43B23/02 , A43B23/26 , A47C27/08 , A63B71/08 , A63B71/14 , B29D35/12 , B29D35/14 , B32B27/06 , A61G7/04
CPC分类号： B32B27/06 , A42B3/121 , A43B1/0072 , A43B13/187 , A43B13/189 , A43B17/16 , A43B19/00 , A43B23/0255 , A43B23/0285 , A43B23/26 , A43B7/02 , A43B7/14 , A43B7/142 , A43B7/144 , A43B7/1495 , A43B7/18 , A47C27/085 , A63B71/143 , B29D35/126 , B29D35/14 , B29D35/142 , B29D35/146 , A63B71/081 , Y10T428/13
摘要： The invention provides a conforming medium containing gels for customized fitting components, such as those used in a shoe. The invention further includes environmentally-responsive gels that are temperature-responsive so that they will react to body heat to transition from a liquid to a gel state or a gel state to a liquid state. Furthermore, the invention is directed to an article for conforming to the contours of an object having isolation means, such as a ladder of a flexible member, to contain the environmentally-responsive gel therein.
摘要翻译：本发明提供了一种含有用于定制装配部件的凝胶的合适介质，例如在鞋中使用的那些。本发明还包括温度敏感的环境响应性凝胶，使得它们将与体热反应从液体转变为凝胶状态或凝胶状态至液体状态。此外，本发明涉及一种用于符合具有隔离装置（例如柔性构件的梯子）的物体的轮廓以在其中容纳环境响应性凝胶的物品。

3. 发明授权

US5766704A Conforming shoe construction and gel compositions therefor 失效
标题翻译：符合鞋结构及其凝胶成分
公开(公告)号：US5766704A
公开(公告)日：1998-06-16
申请号：US614758
申请日：1996-03-13
申请人： Bernie Allen , Zoran Petrovic , Ivan Javni
发明人： Bernie Allen , Zoran Petrovic , Ivan Javni
IPC分类号： A43B7/02 , A43B7/14 , A43B7/16 , A43B7/18 , A43B17/16 , B29D35/12 , B29D35/14 , C08L71/02 , C08L33/24
CPC分类号： B29D35/126 , A43B17/16 , A43B7/02 , A43B7/142 , A43B7/144 , A43B7/1495 , A43B7/16 , A43B7/18 , B29D35/146 , C08L71/02 , Y10T428/13
摘要： The invention provides a conforming medium containing gels for customized fitting components, such as those used in a shoe. The invention further includes environmentally-responsive gels that are temperature-responsive so that they will react to body heat to transition from a liquid to a gel state or a gel state to a liquid state. The invention optionally includes thermally-sensitive dyes and other colorants in the environmentally-responsive gels. Furthermore, the invention is directed to an article for conforming to the contours of an object having isolation means, such as a bladder of a flexible member, to contain the environmentally-responsive gel therein.
摘要翻译：本发明提供了一种含有用于定制装配部件的凝胶的合适介质，例如在鞋中使用的那些。本发明还包括温度敏感的环境响应性凝胶，使得它们将与体热反应从液体转变为凝胶状态或凝胶状态至液体状态。本发明任选地包括在环境敏感性凝胶中的热敏染料和其它着色剂。此外，本发明涉及一种用于符合具有隔离装置（例如柔性构件的囊）的物体的轮廓以在其中容纳环境响应性凝胶的物品。

4. 发明授权

US06573354B1 Process for the preparation of vegetable oil-based polyols and electroinsulating casting compounds created from vegetable oil-based polyols 有权
标题翻译：植物油基多元醇的制备方法和由植物油基多元醇制成的电铸电铸化合物的方法
公开(公告)号：US06573354B1
公开(公告)日：2003-06-03
申请号：US09567997
申请日：2000-05-10
申请人： Zoran Petrovic , Andrew Guo , Ivan Javni
发明人： Zoran Petrovic , Andrew Guo , Ivan Javni
IPC分类号： C08J300
CPC分类号： C08G18/36 , C07D303/42 , C08G2190/00
摘要： A vegetable oil-based polyol is made by adding a peroxyacid to vegetable oil wherein said peroxyacid reacts with said vegetable oil to form epoxidized vegetable oil and adding said epoxidized vegetable oil to a mixture of an alcohol, water, and a catalytic amount of fluoboric acid so as to form a vegetable oil-based polyol. A further embodiment of the present invention involves making a vegetable oil-based polyol using an epoxidized vegetable oil as the starting material. The epoxidized vegetable oil undergoes hydroxylation by the same process as outlined above. According to another aspect of the present invention, the vegetable oil-based polyol formed by the novel methods of this invention may be reacted with an isocyanate to form a polyurethane. Alternatively, a filler such as silica may be combined with the vegetable oil-based polyol before it is reacted with the isocyanate. These polyurethanes made from vegetable oil-based polyols may be used to form electroinsulating casting resins.
摘要翻译：通过向植物油中加入过氧酸而制备植物油性多元醇，其中所述过氧酸与所述植物油反应形成环氧化植物油，并将所述环氧化植物油加入到醇，水和催化量的氟硼酸的混合物中以形成植物油基多元醇。本发明的另一个实施方案涉及使用环氧化植物油作为原料制备植物油基多元醇。环氧化植物油通过与上述相同的方法进行羟基化。根据本发明的另一方面，通过本发明的新方法形成的植物油基多元醇可以与异氰酸酯反应形成聚氨酯。或者，诸如二氧化硅的填料可以在与异氰酸酯反应之前与植物油基多元醇组合。这些由植物油基多元醇制成的聚氨酯可用于形成电绝缘铸塑树脂。

5. 发明申请

US20060041157A1 Modified vegetable oil-based polyols 有权
标题翻译：改性植物油基多元醇
公开(公告)号：US20060041157A1
公开(公告)日：2006-02-23
申请号：US11165962
申请日：2005-06-24
申请人： Zoran Petrovic , Ivan Javni , Alisa Zlatanic , Andrew Guo
发明人： Zoran Petrovic , Ivan Javni , Alisa Zlatanic , Andrew Guo
IPC分类号： C07C67/31
CPC分类号： C08G18/36 , C07D303/42
摘要： Methods of making unsaturated modified vegetable oil-based polyols are described. Also described are methods of making oligomeric modified vegetable oil-based polyols. An oligomeric composition having a modified fatty acid triglyceride structure is also described. Also, methods of making a polyol including hydroformylation and hydrogenation of oils in the presence of a catalyst and support are described.
摘要翻译：描述了制备不饱和改性植物油基多元醇的方法。还描述了制备低聚改性植物油基多元醇的方法。还描述了具有改性脂肪酸甘油三酯结构的低聚组合物。另外，描述了在催化剂和载体的存在下制备包括加氢甲酰基化和油化氢化的多元醇的方法。

6. 发明授权

US06433121B1 Method of making natural oil-based polyols and polyurethanes therefrom 有权
标题翻译：从其制备天然油基多元醇和聚氨酯的方法
公开(公告)号：US06433121B1
公开(公告)日：2002-08-13
申请号：US09612716
申请日：2000-07-10
申请人： Zoran Petrovic , Ivan Javni , Andrew Guo , Wei Zhang
发明人： Zoran Petrovic , Ivan Javni , Andrew Guo , Wei Zhang
IPC分类号： C08J300
CPC分类号： C07D303/42 , C08G18/36 , C08G2190/00
摘要： A method for making natural oil-based polyols directly from vegetable or animal oil using a consecutive two-step process involving epoxidation and hydroxylation is provided. Specifically, this process comprises adding a peroxyacid to a natural oil wherein said natural oil and said peroxyacid react to form an epoxidized natural oil and adding said epoxidized natural oil to a mixture of an alcohol, water, and a fluoboric acid catalyst. The catalytic amount of fluoboric acid is less than about 0.5% by weight of the entire reaction mixture, and the amount of water is about 10 to 30% by weight of the entire mixture. The epoxidized natural oil undergoes hydroxylation and forms a natural oil-based polyol. The present invention further includes a method for making natural oil-based polyols from epoxidized oil by hydroylating the epoxidized oil in the presence of fluoboric acid, alcohol and water in the amounts discussed above. The natural oil-based polyols created by this method may be reacted with isocyanates so as to form polyurethanes, which is another embodiment of the present invention. Alternatively, fillers such as silica may be combined with these natural oil-based polyols before they are reacted with isocyanates to form polyurethanes. In still another embodiment of the present invention, polyurethanes made from natural oil-based polyols may be used to form electroinsulating casting resins for use in electrical applications.
摘要翻译：提供了一种使用直接由植物油或动物油直接制备天然油基多元醇的方法，该方法使用涉及环氧化和羟基化的连续两步法。具体地，该方法包括向天然油中加入过氧酸，其中所述天然油和所述过氧酸反应形成环氧化天然油，并将所述环氧化天然油加入到醇，水和氟硼酸催化剂的混合物中。氟硼酸的催化量小于整个反应混合物的约0.5重量％，水的量为整个混合物的约10至30重量％。环氧化天然油经历羟基化，形成天然油基多元醇。本发明还包括通过在上述量的氟硼酸，醇和水的存在下对环氧化油进行水解来制备环氧化油的天然油基多元醇的方法。通过该方法制备的天然油基多元醇可以是与异氰酸酯反应以形成聚氨酯，这是本发明的另一个实施方案。或者，诸如二氧化硅的填料可以在与异氰酸酯反应形成聚氨酯之前与这些天然油基多元醇组合。在本发明的另一个实施方案中，由天然油基多元醇制成的聚氨酯可用于形成用于电气应用的电绝缘铸塑树脂。

7. 发明授权

US07977424B2 Polymer concrete and method for preparation thereof 有权
标题翻译：聚合物混凝土及其制备方法
公开(公告)号：US07977424B2
公开(公告)日：2011-07-12
申请号：US09928579
申请日：2001-08-13
申请人： Zoran Petrovic , Wei Zhang , Ivan Javni , X. Andrew Guo
发明人： Zoran Petrovic , Wei Zhang , Ivan Javni , X. Andrew Guo
IPC分类号： C04B24/26 , C04B28/02 , C08J3/00 , C08K3/00 , C08L75/00 , C08G18/08 , C08G18/28
CPC分类号： C08G18/36 , C04B26/16 , C04B2111/20 , C08G18/3206 , C08K3/22 , C08K3/34 , Y02W30/92 , C04B14/06 , C04B14/42 , C04B14/48 , C04B18/08 , C04B24/02
摘要： A soy-based polyol is mixed with an isocyanate and aggregate to produce a soy-based polyurethane having superior mechanical properties. The aggregate composition may be varied to obtain different mechanical properties, as can the amount of resin. The resin may be crosslinked using a low molecular weight polyol, such as glycerine, to also improve structural performance. A catalyst may be added to accelerate curing time without reducing structural performance.
摘要翻译：将大豆基多元醇与异氰酸酯和聚集体混合以制备具有优异机械性能的大豆基聚氨酯。聚集体组合物可以改变以获得不同的机械性能，以及树脂的量。树脂可以使用低分子量多元醇如甘油进行交联，以提高结构性能。可以加入催化剂以加速固化时间而不降低结构性能。

8. 发明授权

US6107433A Process for the preparation of vegetable oil-based polyols and electroninsulating casting compounds created from vegetable oil-based polyols 有权
标题翻译：由植物油基多元醇制备的植物油基多元醇和电子注射铸造化合物的制备方法
公开(公告)号：US6107433A
公开(公告)日：2000-08-22
申请号：US187992
申请日：1998-11-06
申请人： Zoran Petrovic , Andrew Guo , Ivan Javni
发明人： Zoran Petrovic , Andrew Guo , Ivan Javni
IPC分类号： C07D303/42 , C08G18/36 , C08G83/00 , C07D301/00 , C07D301/14 , C07D301/19 , C07D303/00
CPC分类号： C08G18/36 , C07D303/42 , C08G2190/00
摘要： A vegetable oil-based polyol is made by adding a peroxyacid to vegetable oil wherein said peroxyacid reacts with said vegetable oil to form epoxidized vegetable oil and adding said epoxidized vegetable oil to a mixture of an alcohol, water, and a catalytic amount of fluoboric acid so as to form a vegetable oil-based polyol. A further embodiment of the present invention involves making a vegetable oil-based polyol using an epoxidized vegetable oil as the starting material. The epoxidized vegetable oil undergoes hydroxylation by the same process as outlined above. According to another aspect of the present invention, the vegetable oil-based polyol formed by the novel methods of this invention may be reacted with an isocyanate to form a polyurethane. Alternatively, a filler such as silica may be combined with the vegetable oil-based polyol before it is reacted with the isocyanate. These polyurethanes made from vegetable oil-based polyols may be used to form electroinsulating casting resins.
摘要翻译：通过向植物油中加入过氧酸而制备植物油性多元醇，其中所述过氧酸与所述植物油反应形成环氧化植物油，并将所述环氧化植物油加入到醇，水和催化量的氟硼酸的混合物中以形成植物油基多元醇。本发明的另一个实施方案涉及使用环氧化植物油作为原料制备植物油基多元醇。环氧化植物油通过与上述相同的方法进行羟基化。根据本发明的另一方面，通过本发明的新方法形成的植物油基多元醇可以与异氰酸酯反应形成聚氨酯。或者，诸如二氧化硅的填料可以在与异氰酸酯反应之前与植物油基多元醇组合。这些由植物油基多元醇制成的聚氨酯可用于形成电绝缘铸塑树脂。

9. 发明授权

US06686435B1 Method of making natural oil-based polyols and polyurethanes therefrom 有权
标题翻译：从其制备天然油基多元醇和聚氨酯的方法
公开(公告)号：US06686435B1
公开(公告)日：2004-02-03
申请号：US10176214
申请日：2002-06-20
申请人： Zoran Petrovic , Ivan Javni , Andrew Guo , Wei Zhang
发明人： Zoran Petrovic , Ivan Javni , Andrew Guo , Wei Zhang
IPC分类号： C08J300
CPC分类号： C07D303/42 , C08G18/36 , C08G2190/00
摘要： A method for making natural oil-based polyols directly from vegetable or animal oil using a consecutive two-step process involving epoxidation and hydroxylation is provided. Specifically, this process comprises adding a peroxyacid to a natural oil wherein said natural oil and said peroxyacid react to form an epoxidized natural oil and adding said epoxidized natural oil to a mixture of an alcohol, water, and a fluoboric acid catalyst. The catalytic amount of fluoboric acid is less than about 0.5% by weight of the entire reaction mixture, and the amount of water is about 10 to 30% by weight of the entire mixture. The epoxidized natural oil undergoes hydroxylation and forms a natural oil-based polyol. The present invention further includes a method for making natural oil-based polyols from epoxidized oil by hydroylating the epoxidized oil in the presence of fluoboric acid, alcohol and water in the amounts discussed above. The natural oil-based polyols created by this method may be reacted with isocyanates so as to form polyurethanes, which is another embodiment of the present invention. Alternatively, fillers such as silica may be combined with these natural oil-based polyols before they are reacted with isocyanates to form polyurethanes. In still another embodiment of the present invention, polyurethanes made from natural oil-based polyols may be used to form electroinsulating casting resins for use in electrical applications.
摘要翻译：提供了一种使用直接由植物油或动物油直接制备天然油基多元醇的方法，该方法使用涉及环氧化和羟基化的连续两步法。具体地，该方法包括向天然油中加入过氧酸，其中所述天然油和所述过氧酸反应形成环氧化天然油，并将所述环氧化天然油加入到醇，水和氟硼酸催化剂的混合物中。氟硼酸的催化量小于整个反应混合物的约0.5重量％，水的量为整个混合物的约10至30重量％。环氧化天然油经历羟基化，形成天然油基多元醇。本发明还包括通过在上述量的氟硼酸，醇和水的存在下对环氧化油进行水解来制备环氧化油的天然油基多元醇的方法。通过该方法制备的天然油基多元醇可以是与异氰酸酯反应以形成聚氨酯，这是本发明的另一个实施方案。或者，诸如二氧化硅的填料可以在与异氰酸酯反应形成聚氨酯之前与这些天然油基多元醇组合。在本发明的另一个实施方案中，由天然油基多元醇制成的聚氨酯可用于形成用于电气应用的电绝缘铸塑树脂。

10. 发明授权

US07786239B2 Modified vegetable oil-based polyols 有权
标题翻译：改性植物油基多元醇
公开(公告)号：US07786239B2
公开(公告)日：2010-08-31
申请号：US11165962
申请日：2005-06-24
申请人： Zoran S. Petrovic , Ivan Javni , Alisa Zlatanic , Andrew Guo
发明人： Zoran S. Petrovic , Ivan Javni , Alisa Zlatanic , Andrew Guo
IPC分类号： C08G83/00 , C07D303/00
CPC分类号： C08G18/36 , C07D303/42
摘要： Methods of making unsaturated modified vegetable oil-based polyols are described. Also described are methods of making oligomeric modified vegetable oil-based polyols. An oligomeric composition having a modified fatty acid triglyceride structure is also described. Also, methods of making a polyol including hydroformylation and hydrogenation of oils in the presence of a catalyst and support are described.
摘要翻译：描述了制备不饱和改性植物油基多元醇的方法。还描述了制备低聚改性植物油基多元醇的方法。还描述了具有改性脂肪酸甘油三酯结构的低聚组合物。另外，描述了在催化剂和载体的存在下制备包括加氢甲酰基化和油化氢化的多元醇的方法。

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