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1. 发明申请

US20130209790A1 PVD-Metallic Effect Pigments with Diffractive Structure and Metal Nanoparticles, Process for Preparing Them and Use Thereof 有权
$PVD-Metallic Effect Pigments with Diffractive Structure and Metal Nanoparticles, Process for Preparing Them and Use Thereof$
标题翻译：具有衍射结构和金属纳米颗粒的PVD金属效应颜料，其制备方法及其用途
公开(公告)号：US20130209790A1
公开(公告)日：2013-08-15
申请号：US13812284
申请日：2011-07-21
申请人： Bernhard Geissler , Martin Fischer , Frank Henglein , Ralph Schneider , Wolfgang Herzing , Klaus Greiwe
发明人： Bernhard Geissler , Martin Fischer , Frank Henglein , Ralph Schneider , Wolfgang Herzing , Klaus Greiwe
IPC分类号： C09C1/62
CPC分类号： C09C1/62 , B82Y30/00 , C01P2002/85 , C01P2004/03 , C01P2004/04 , C01P2004/64 , C01P2006/62 , C01P2006/65 , C01P2006/66 , C09C1/0015 , C09C1/0018 , C09C2200/1004 , C09C2200/30 , C09C2200/405 , C09C2200/407 , C09C2200/502 , C09C2210/30 , C09C2210/40 , C09C2220/20 , C09D5/36 , C09D7/62 , C09D7/67 , C09D7/68 , Y10T428/256 , Y10T428/257 , Y10T428/258
摘要： The invention relates to metallic effect pigment, the metallic effect pigment having at least one diffractive structure and at least one layer which comprises metal nanoparticles and metal oxide phase, the metal of the metal oxide phase and the metal of the metal nanoparticles in this at least one layer being identical. The invention further relates to a process for preparing these metallic effect pigments, to a coating composition, and to a coated article.
摘要翻译：本发明涉及金属效应颜料，金属效应颜料具有至少一种衍射结构，并且至少一层包含金属纳米颗粒和金属氧化物相，金属氧化物相的金属和金属纳米颗粒在该至少一层相同。本发明还涉及制备这些金属效应颜料，涂料组合物和涂覆制品的方法。

2. 发明授权

US09453131B2 PVD-metallic effect pigments with diffractive structure and metal nanoparticles, process for preparing them and use thereof 有权
$PVD-metallic effect pigments with diffractive structure and metal nanoparticles, process for preparing them and use thereof$
标题翻译：具有衍射结构的PVD金属效应颜料和金属纳米颗粒，其制备方法和用途
公开(公告)号：US09453131B2
公开(公告)日：2016-09-27
申请号：US13812284
申请日：2011-07-21
申请人： Bernhard Geissler , Martin Fischer , Frank Henglein , Ralph Schneider , Wolfgang Herzing , Klaus Greiwe
发明人： Bernhard Geissler , Martin Fischer , Frank Henglein , Ralph Schneider , Wolfgang Herzing , Klaus Greiwe
IPC分类号： C09C1/62 , B82Y30/00 , C09C1/00 , C09D5/36 , C09D7/12
CPC分类号： C09C1/62 , B82Y30/00 , C01P2002/85 , C01P2004/03 , C01P2004/04 , C01P2004/64 , C01P2006/62 , C01P2006/65 , C01P2006/66 , C09C1/0015 , C09C1/0018 , C09C2200/1004 , C09C2200/30 , C09C2200/405 , C09C2200/407 , C09C2200/502 , C09C2210/30 , C09C2210/40 , C09C2220/20 , C09D5/36 , C09D7/62 , C09D7/67 , C09D7/68 , Y10T428/256 , Y10T428/257 , Y10T428/258
摘要： The invention relates to metallic effect pigment, the metallic effect pigment having at least one diffractive structure and at least one layer which comprises metal nanoparticles and metal oxide phase, the metal of the metal oxide phase and the metal of the metal nanoparticles in this at least one layer being identical. The invention further relates to a process for preparing these metallic effect pigments, to a coating composition, and to a coated article.
摘要翻译：本发明涉及金属效应颜料，金属效应颜料具有至少一种衍射结构，并且至少一层包含金属纳米颗粒和金属氧化物相，该金属氧化物相的金属和该金属纳米颗粒的金属在该至少一层相同。本发明还涉及制备这些金属效应颜料，涂料组合物和涂覆制品的方法。

3. 发明授权

US08864899B2 PVD metal effect pigment having gradient on nanoscale metal particles, method for the production thereof and use thereof 有权
标题翻译：具有在纳米级金属颗粒上具有梯度的PVD金属效应颜料，其制备方法及其用途
公开(公告)号：US08864899B2
公开(公告)日：2014-10-21
申请号：US13146254
申请日：2010-01-28
申请人： Bernhard Geissler , Wolfgang Herzing , Frank Henglein , Ralph Schneider , Martin Fischer
发明人： Bernhard Geissler , Wolfgang Herzing , Frank Henglein , Ralph Schneider , Martin Fischer
IPC分类号： C09C1/62 , C09C1/00 , C09C1/64
CPC分类号： C09C1/0015 , C01P2002/70 , C01P2004/04 , C01P2004/54 , C09C1/0018 , C09C1/0078 , C09C1/62 , C09C1/64 , C09C2200/20 , C09C2200/24 , C09C2200/307 , C09C2200/40 , C09C2200/401 , C09C2200/402 , C09C2200/50 , C09C2200/502 , C09C2200/505 , C09C2220/20
摘要： A platelet-shaped PVD metallic effect pigment having first and second outer faces, the platelet-shaped PVD metallic effect pigment having at least one PVD layer, the at least one PVD layer including elemental metal with clusters of elemental metal and metal oxide. The amounts of elemental metal in the first outer face and in the second outer face of the PVD metallic effect pigment are different from one another and they differ by at least 10 atom %. The disclosure further relates to a method for producing these platelet-shaped PVD metallic effect pigments, and to their use.
摘要翻译：一种具有第一和第二外表面的片状PVD金属效应颜料，所述片状PVD金属效应颜料具有至少一个PVD层，所述至少一个PVD层包括具有元素金属和金属氧化物簇的元素金属。 PVD金属效应颜料的第一外表面和第二外表面中的元素金属的量彼此不同，它们相差至少为10原子％。本发明还涉及一种制备这些片状PVD金属效应颜料的方法及其应用。

4. 发明申请

US20110293547A1 PVD METAL EFFECT PIGMENT HAVING GRADIENT ON NANOSCALE METAL PARTICLES, METHOD FOR THE PRODUCTION THEREOF AND USE THEREOF 有权
标题翻译：具有纳米金属颗粒上的梯度的PVD金属效应颜料，其生产方法及其用途
公开(公告)号：US20110293547A1
公开(公告)日：2011-12-01
申请号：US13146254
申请日：2010-01-28
申请人： Bernhard Geissler , Wolfgang Herzing , Frank Henglein , Ralph Schneider , Martin Fischer
发明人： Bernhard Geissler , Wolfgang Herzing , Frank Henglein , Ralph Schneider , Martin Fischer
IPC分类号： C09D11/02 , C08K3/22 , A61K8/26 , C09C1/62 , A61K8/29 , A61Q1/02 , B32B5/16 , C09D1/00 , A61K8/27
CPC分类号： C09C1/0015 , C01P2002/70 , C01P2004/04 , C01P2004/54 , C09C1/0018 , C09C1/0078 , C09C1/62 , C09C1/64 , C09C2200/20 , C09C2200/24 , C09C2200/307 , C09C2200/40 , C09C2200/401 , C09C2200/402 , C09C2200/50 , C09C2200/502 , C09C2200/505 , C09C2220/20
摘要： A platelet-shaped PVD metallic effect pigment having first and second outer faces, the platelet-shaped PVD metallic effect pigment having at least one PVD layer, the at least one PVD layer including elemental metal with clusters of elemental metal and metal oxide. The amounts of elemental metal in the first outer face and in the second outer face of the PVD metallic effect pigment are different from one another and they differ by at least 10 atom %. The disclosure further relates to a method for producing these platelet-shaped PVD metallic effect pigments, and to their use.
摘要翻译：一种具有第一和第二外表面的片状PVD金属效应颜料，所述片状PVD金属效应颜料具有至少一个PVD层，所述至少一个PVD层包括具有元素金属和金属氧化物簇的元素金属。 PVD金属效应颜料的第一外表面和第二外表面中的元素金属的量彼此不同，它们相差至少为10原子％。本发明还涉及一种制备这些片状PVD金属效应颜料的方法及其应用。

5. 发明授权

US06645286B2 Iron effect pigments 有权
公开(公告)号：US06645286B2
公开(公告)日：2003-11-11
申请号：US10103762
申请日：2002-03-25
申请人： Werner Ostertag , Stefan Trummer , Frank Henglein , Klaus Greiwe
发明人： Werner Ostertag , Stefan Trummer , Frank Henglein , Klaus Greiwe
IPC分类号： C09C122
CPC分类号： B22F1/0055 , B22F1/0007 , B22F1/02 , B22F2998/00 , B22F2998/10 , B41M3/14 , C01P2004/20 , C01P2004/61 , C09C1/0018 , C09C1/62 , C09C1/622 , C09D5/36 , B22F9/305 , B22F9/04
摘要： The present invention is concerned with soft-magnetic iron effect pigments with metallic luster, which are produced by grinding reductively treated carbonyl iron powder, and which are passivated either during grinding or subsequent to the grinding. The products find application in the decorative and functional fields in paint and lacquer coatings, coloring of plastics, in printing, cosmetics, and glass and ceramics.

6. 发明授权

US06589331B2 Soft iron pigments 有权
公开(公告)号：US06589331B2
公开(公告)日：2003-07-08
申请号：US10103839
申请日：2002-03-25
申请人： Werner Ostertag , Stefan Trummer , Frank Henglein , Klaus Greiwe
发明人： Werner Ostertag , Stefan Trummer , Frank Henglein , Klaus Greiwe
IPC分类号： C09C122
CPC分类号： B22F1/0055 , A61K8/0266 , A61K2800/412 , A61K2800/43 , A61K2800/621 , A61K2800/651 , A61Q1/02 , B22F1/0007 , B22F1/02 , B22F2998/00 , B22F2998/10 , C01P2004/03 , C01P2004/61 , C01P2004/84 , C01P2006/40 , C01P2006/42 , C01P2006/60 , C01P2006/66 , C08K9/02 , C09C1/0015 , C09C1/0021 , C09C1/0039 , C09C1/622 , C09C2200/1054 , C09C2200/1058 , C09C2200/306 , C09C2220/106 , C09C2220/20 , C09D5/36 , C22B5/20 , B22F9/305 , B22F9/04
摘要： The present invention deals with metal oxide coated, flake shaped soft iron pigments. The characteristic feature is a reflector substrate, which is produced by deformation of reduced carbonyl iron powder. The pigments are colorful, display metallic luster and a high magnetic permeability. They can be oriented in the medium by means of an external magnetic field. The novel pigments find use in the decorative and/or functional field, particularly in lacquers, paints, plastics, in printing, in glass, ceramics and in cosmetics.

7. 发明申请

US20110064779A1 PEARLESCENT PIGMENTS BASED ON FINE AND THIN SUBSTRATES 审中-公开
标题翻译：基于精细和薄基材的珍珠粉
公开(公告)号：US20110064779A1
公开(公告)日：2011-03-17
申请号：US12937818
申请日：2009-04-15
申请人： Michael Gruener , Ulrich Schmidt , Günter Kaupp , Peter Krueger , Jens Depner , Katrin Steinbach , Ralph Schneider , Frank Henglein
发明人： Michael Gruener , Ulrich Schmidt , Günter Kaupp , Peter Krueger , Jens Depner , Katrin Steinbach , Ralph Schneider , Frank Henglein
IPC分类号： A61K8/11 , C04B16/00 , C04B14/20 , C09D11/02 , C09D5/29 , C03C14/00 , C04B35/00 , A61Q1/02 , A61Q1/04 , A61Q5/06 , A61Q5/00 , A61Q3/02 , G01B21/08
CPC分类号： C09C1/0015 , C01P2004/61 , C01P2006/60 , C09C1/0021 , C09C2200/1004 , C09C2200/102 , C09C2200/301 , C09C2200/401 , C09C2200/405
摘要： Pearlescent pigments including a largely transparent platelet-shaped substrate having a density ρS and at least one optically active coating having a density ρM, the substrate having an average size d50 of 3 to 8 μm and an average height hS of 40 to 110 nm. The disclosure further relates to a method for producing the pearlescent pigments, and also to the use thereof.
摘要翻译：珠光颜料，其包括具有密度的大部分透明的片状基材和至少一种具有密度的光学活性涂层，所述基材的平均尺寸d50为3至8μm，平均高度hS为40至 110nm。本公开进一步涉及珠光颜料的制造方法，以及其用途。

8. 发明申请

US20070199478A1 Thin Covering Aluminum Pigments, Process For The Production Thereof, And Use Of Said Aluminum Pigments 审中-公开
标题翻译：薄覆盖铝颜料，其制造方法和所述铝颜料的使用
公开(公告)号：US20070199478A1
公开(公告)日：2007-08-30
申请号：US10552116
申请日：2004-04-02
申请人： Thomas Schlegl , Stefan Trummer , Frank Henglein , Ralph Schneider , Thomas Schuster
发明人： Thomas Schlegl , Stefan Trummer , Frank Henglein , Ralph Schneider , Thomas Schuster
IPC分类号： C09D11/00 , A61K8/00 , C09C1/62
CPC分类号： C09D11/50 , A61K8/26 , A61K2800/43 , A61Q3/02 , B22F1/0011 , C01P2004/54 , C01P2006/12 , C09C1/64 , C09C1/644 , C09D5/028 , C09D5/032 , C09D5/36 , C09D11/037
摘要： The invention relates to aluminum pigments which are at least partially coated with lubricants, wherein said aluminum pigment have a) a water coverage between 40,000 and 130,000 cm2/g, b) a mean thickness h of less than 100 to 30 nm, as calculated from the water coverage as well as the h50 value determined from the cumulative breakthrough curve of a scanning electron microscope thickness count, c) as determined by a scanning electron microscope thickness count, a relative width of the distribution of thicknesses Δh between 70% and 140%, which is calculated on the basis of the corresponding cumulative breakthrough curve of the relative frequencies according to the formula Δ ⁢ ⁢ h = 100 × h 90 - h 10 h 50 , , d) an aspect ratio d50/h of more than 200, e) a roughness value of from 0.30 to 0.9, calculated from the specific surface area, as determined by the BET test method, and the water coverage according to the following formula BET value/2×water coverage. The invention also relates to a process for the manufacture of said aluminum pigments and to the use thereof.
摘要翻译：本发明涉及至少部分涂覆有润滑剂的铝颜料，其中所述铝颜料具有a）水覆盖在40,000和130,000cm 2 / g之间，b）平均厚度h小于根据扫描电子显微镜厚度计数的累积穿透曲线确定的从水覆盖率计算的100至30nm，以及由扫描电子显微镜厚度计数确定的c）根据公式 $Delta>，d）宽高比d <50> / h 大于200，e）通过BET测试方法测定的比表面积计算的粗糙度为0.30至0.9，根据下式BET值/ 2x水覆盖率的水覆盖率。本发明还涉及制造所述铝颜料的方法及其用途。$

9. 发明授权

US11230643B2 Pearlescent pigments based on fine and thin substrates 有权
公开(公告)号：US11230643B2
公开(公告)日：2022-01-25
申请号：US12937818
申请日：2009-04-15
申请人： Michael Gruener , Ulrich Schmidt , Günter Kaupp , Peter Krueger , Jens Depner , Katrin Steinbach , Ralph Schneider , Frank Henglein
发明人： Michael Gruener , Ulrich Schmidt , Günter Kaupp , Peter Krueger , Jens Depner , Katrin Steinbach , Ralph Schneider , Frank Henglein
IPC分类号： A61K8/11 , C09C1/00
摘要： Pearlescent pigments including a largely transparent platelet-shaped substrate having a density ρS and at least one optically active coating having a density ρM, the substrate having an average size d50 of 3 to 8 μm and an average height hS of 40 to 110 nm. The disclosure further relates to a method for producing the pearlescent pigments, and also to the use thereof.

10. 发明授权

US08980976B2 Pearlescent pigments coated with mixed inorganic/organic layers and method for the production thereof 有权
标题翻译：涂有混合无机/有机层的珠光颜料及其制备方法
公开(公告)号：US08980976B2
公开(公告)日：2015-03-17
申请号：US12280398
申请日：2007-02-22
申请人： Frank Henglein , Stefan Trummer , Ulrich Schmidt , Günter Kaupp , Peter Krüger
发明人： Frank Henglein , Stefan Trummer , Ulrich Schmidt , Günter Kaupp , Peter Krüger
IPC分类号： C08K9/00 , C08K3/08 , C09B67/00 , C09C1/00
CPC分类号： C09C1/0021 , C01P2006/66 , C09B67/0098 , C09C1/0015 , C09C1/0024 , C09C2200/1004 , C09C2200/102 , C09C2200/301 , C09C2200/307 , C09C2200/409 , C09C2220/10
摘要： The invention relates to platelet-shaped pearlescent pigments that are coated with at least one mixed inorganic/organic layer for improving their application properties, and of these, particularly their mechanical properties, and to methods for the production thereof and to the use thereof. The said mixed inorganic/organic layer comprises at least one at least partially crosslinked inorganic metal-oxide component and an organic component. The organic component is at least one organic oligomer and/or polymer, which is covalently bonded, at least in part, to the inorganic network via network formers, wherein the coating comprises at least one mixed inorganic/organic layer, which mixed layer comprises, at least in part, an inorganic network having one or more inorganic oxide component(s) and at least one organic component, the organic component being, at least in part, an organic oligomer and/or polymer covalently bonded, at least in part, to the inorganic network via one or more organic network formers.The invention also relates to a method for the production of such pearlescent pigments.
摘要翻译：本发明涉及涂覆有至少一种混合无机/有机层以提高它们的应用性能，特别是其机械性能的片状珠光颜料及其生产方法及其应用。所述混合无机/有机层包含至少一种至少部分交联的无机金属氧化物组分和有机组分。有机组分是至少一种有机低聚物和/或聚合物，其至少部分地通过网络成型体与无机网络共价键合，其中涂层包含至少一种混合的无机/有机层，该混合层包含，至少部分是具有一种或多种无机氧化物组分和至少一种有机组分的无机网络，所述有机组分至少部分是至少部分共价键合的有机低聚物和/或聚合物，通过一个或多个有机网络建立者到无机网络。本发明还涉及一种生产这种珠光颜料的方法。

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