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1. 发明授权

US4134935A Dental varnishes 失效
标题翻译：牙科清漆
公开(公告)号：US4134935A
公开(公告)日：1979-01-16
申请号：US702904
申请日：1976-07-06
申请人： Bernd Quiring , Kuno Wagner , Joachim Konig
发明人： Bernd Quiring , Kuno Wagner , Joachim Konig
IPC分类号： A61K6/09 , C08G18/04 , C08G18/72 , C08L75/00
CPC分类号： A61K6/0017 , C08G18/04 , C08G18/728
摘要： Graft copolymers or telomerisates made of polyisocyanates and a copolymer of methylmethacrylate bearing isocyanategroups or groups reactive with isocyanates can be employed as dental varnishes. They demonstrate high abrasion resistance, are quick drying and hardening, and possess excellent adhesion properties.
摘要翻译：可以使用由多异氰酸酯制成的接枝共聚物或调聚物和甲基丙烯酸甲酯带有异氰酸酯基团或与异氰酸酯反应的基团的共聚物作为牙科清漆。它们表现出高耐磨性，快速干燥和硬化，并且具有优异的粘合性能。

2. 发明授权

US4254176A Novel transparent polyurethane polyurea films for lamination of glazing materials and their method of production 失效
标题翻译：用于层压玻璃材料的新型透明聚氨酯聚脲膜及其生产方法
公开(公告)号：US4254176A
公开(公告)日：1981-03-03
申请号：US947121
申请日：1978-09-29
申请人： Hanns P. Muller , Wolfgang Oberkirch , Kuno Wagner , Bernd Quiring
发明人： Hanns P. Muller , Wolfgang Oberkirch , Kuno Wagner , Bernd Quiring
IPC分类号： C03C27/12 , B32B7/12 , B32B17/10 , C08G18/00 , C08G18/08 , C08G18/12 , C08G18/28 , C08G18/65 , C08G18/71 , C08G18/75 , C09J175/00 , B29D7/02 , C08G18/32
CPC分类号： B32B17/10018 , B32B17/10036 , B32B17/1077 , B32B17/10825 , C08G18/0823 , C08G18/12 , C08G18/2805 , C08G18/71 , C08G18/75 , F41H5/0407 , Y10T428/269 , Y10T428/31551 , Y10T428/31601
摘要： The present disclosure is concerned with a novel transparent polyurethane polyurea which is particularly suitable for lamination to glass and glasslike transparent plastics. The polymer is the reaction product of high molecular weight diols, optionally low molecular weight diols, dihydroxy carboxylic acids, diisocyanates with only aliphatically and cycloaliphatically bound isocyanates and organic diamines having aliphatically and cycloaliphatically bound primary amino groups. It has specified contents of carboxyl groups and urea groups, and it has a minimum shear modulus at both 20.degree. and 60.degree. C.The present disclosure is also concerned with a process for synthesizing such polymers. A preferred method is to react the diisocyanate and hydroxyl bearing compounds to prepare an isocyanate terminated prepolymer and chain extend with the diamine.Also discussed are the production of film from these polymers by extrusion and solution casting, the production of laminates with glass and glasslike plastics and the laminates so produced. The solution cast or extruded films can be laminated to these substrates by the application of heat and pressure.
摘要翻译：本公开涉及一种新型的透明聚氨酯聚脲，其特别适用于层压至玻璃和玻璃状透明塑料。聚合物是高分子量二醇，任选的低分子量二醇，二羟基羧酸，仅具有脂肪和环状结合的异氰酸酯的二异氰酸酯和具有脂族和环烯键合的伯氨基的有机二胺的反应产物。具体规定了羧基和脲基的含量，在20℃〜60℃都具有最小的剪切弹性模量。本发明还涉及合成这些聚合物的方法。优选的方法是使二异氰酸酯和含羟基的化合物反应以制备异氰酸酯封端的预聚物，并且链与二胺延伸。还讨论了通过挤出和溶液流延从这些聚合物生产膜，生产具有玻璃和玻璃状塑料的层压材料以及如此生产的层压材料。可以通过施加热和压力将溶液流延或挤出的膜层压到这些基底上。

3. 发明授权

US4174240A Novel transparent polyurethane polyureas for lamination of glazing materials 失效
标题翻译：用于层压玻璃材料的新型透明聚氨酯聚脲
公开(公告)号：US4174240A
公开(公告)日：1979-11-13
申请号：US947222
申请日：1978-09-29
申请人： Hanns P. Muller , Wolfgang Oberkirch , Kuno Wagner , Bernd Quiring
发明人： Hanns P. Muller , Wolfgang Oberkirch , Kuno Wagner , Bernd Quiring
IPC分类号： B32B17/10 , C08G18/08 , C08G18/12 , C08G18/75 , C03C27/04 , B32B27/40 , C08G18/32 , C09J5/04
CPC分类号： C08G18/75 , B32B17/10036 , B32B17/1077 , B32B17/10825 , C08G18/0823 , C08G18/12 , F41H5/0407 , Y10T428/26 , Y10T428/263 , Y10T428/269 , Y10T428/31576 , Y10T428/31601
摘要： The present disclosure is concerned with a novel transparent polyurethane polyurea which is particularly suitable for lamination to glass and glasslike transparent plastics. The polymer is the reaction product of high molecular weight diols, optionally low molecular weight diols, dihydroxy carboxylic acids, diisocyanates with only aliphatically and cycloaliphatically bound isocyanates and organic diamines having aliphatically and cycloaliphatically bound primary amino groups. It has specified contents of carboxyl groups and urea groups, and it has a minimum shear modulus at both 20.degree. and 60.degree. C.The present disclosure is also concerned with a process for synthesizing such polymers. A preferred method is to react the diisocyanate and hydroxyl bearing compounds to prepare an isocyanate terminated prepolymer and chain extend with the diamine.Also discussed are the production of film from these polymers by extrusion and solution casting, the production of laminates with glass and glasslike plastics and the laminates so produced. The solution cast or extruded films can be laminated to these substrates by the application of heat and pressure.
摘要翻译：本公开涉及一种新型的透明聚氨酯聚脲，其特别适用于层压至玻璃和玻璃状透明塑料。聚合物是高分子量二醇，任选的低分子量二醇，二羟基羧酸，仅具有脂肪和环状结合的异氰酸酯的二异氰酸酯和具有脂族和环烯键合的伯氨基的有机二胺的反应产物。具体规定了羧基和脲基的含量，在20℃〜60℃都具有最小的剪切弹性模量。本发明还涉及合成这些聚合物的方法。优选的方法是使二异氰酸酯和含羟基的化合物反应以制备异氰酸酯封端的预聚物，并且链与二胺延伸。还讨论了通过挤出和溶液流延从这些聚合物生产膜，生产具有玻璃和玻璃状塑料的层压材料以及如此生产的层压材料。可以通过施加热和压力将溶液流延或挤出的膜层压到这些基底上。

4. 发明授权

US4139674A Novel transparent polyurethane polyureas for lamination of glazing materials 失效
标题翻译：用于层压玻璃材料的新型透明聚氨酯聚脲
公开(公告)号：US4139674A
公开(公告)日：1979-02-13
申请号：US833311
申请日：1977-09-14
申请人： Hanns P. Muller , Wolfgang Oberkirch , Kuno Wagner , Bernd Quiring
发明人： Hanns P. Muller , Wolfgang Oberkirch , Kuno Wagner , Bernd Quiring
IPC分类号： C03C27/12 , B32B7/12 , B32B17/10 , C08G18/00 , C08G18/08 , C08G18/12 , C08G18/28 , C08G18/65 , C08G18/71 , C08G18/75 , C09J175/00 , B32B27/40 , B29D7/02 , C08G18/32 , C09J5/04
CPC分类号： B32B17/10018 , B32B17/10036 , B32B17/1077 , B32B17/10825 , C08G18/0823 , C08G18/12 , C08G18/2805 , C08G18/71 , C08G18/75 , F41H5/0407 , Y10T428/269 , Y10T428/31551 , Y10T428/31601
摘要： The present disclosure is concerned with a novel transparent polyurethane polyurea which is particularly suitable for lamination to glass and glasslike transparent plastics. The polymer is the reaction product of high molecular weight diols, optionally low molecular weight diols, dihydroxy carboxylic acids, diisocyanates with only aliphatically and cycloaliphatically bound isocyanates and organic diamines having aliphatically and cycloaliphatically bound primary amino groups. It has specified contents of carboxyl groups and urea groups, and it has a minimum shear modulus at both 20 and 60.degree. C.The present disclosure is also concerned with a process for synthesizing such polymers. A preferred method is to react the diisocyanate and hydroxyl bearing compounds to prepare an isocyanate terminated prepolymer and chain extend with the diamine.Also discussed are the production of film from these polymers by extrusion and solution casting, the production of laminates with glass and glasslike plastics and the laminates so produced. The solution cast or extruded films can be laminated to these substrates by the application of heat and pressure.
摘要翻译：本公开涉及一种新型的透明聚氨酯聚脲，其特别适用于层压至玻璃和玻璃状透明塑料。聚合物是高分子量二醇，任选的低分子量二醇，二羟基羧酸，仅具有脂肪和环状结合的异氰酸酯的二异氰酸酯和具有脂族和环烯键合的伯氨基的有机二胺的反应产物。具体规定了羧基和脲基的含量，在20和60℃下均具有最小的剪切模量。

5. 发明授权

US3943159A Process for the production of telomers containing isocyanate groups 失效
标题翻译：生产含有异氰酸酯基团的调聚物的方法
公开(公告)号：US3943159A
公开(公告)日：1976-03-09
申请号：US414575
申请日：1973-11-09
申请人： Bernd Quiring , Kuno Wagner
发明人： Bernd Quiring , Kuno Wagner
IPC分类号： C07C323/12 , C07C67/00 , C07C313/00 , C08F2/38 , C08G18/04 , C07C118/00
CPC分类号： C08G18/04
摘要： An improved process for the preparation of isocyanate group containing telomers of reduced viscosity by conducting the telomerization of an ethylenically unsaturated monomer with an organic isocyanate in the presence of an organic compound containing at least one sulfhydryl group.
摘要翻译：一种通过在含有至少一个巯基的有机化合物存在下，通过使有机异氰酸酯进行调节烯键式不饱和单体来制备具有降低的粘度的含异氰酸酯基的调聚物的改进方法。

6. 发明授权

US4166149A Novel transparent polyurethane polyureas for lamination of glazing materials 失效
标题翻译：用于玻璃复合材料层压的新型透明聚氨酯聚合物
公开(公告)号：US4166149A
公开(公告)日：1979-08-28
申请号：US947221
申请日：1978-09-29
申请人： Hanns P. Muller , Wolfgang Oberkirch , Kuno Wagner , Bernd Quiring
发明人： Hanns P. Muller , Wolfgang Oberkirch , Kuno Wagner , Bernd Quiring
IPC分类号： B32B17/10 , C08G18/08 , C08G18/12 , C08G18/75 , B32B27/40 , B29D7/02 , C08G18/32 , C09J5/04
CPC分类号： C08G18/75 , B32B17/10036 , B32B17/1077 , B32B17/10825 , C08G18/0823 , C08G18/12 , F41H5/0407 , Y10T428/26 , Y10T428/263 , Y10T428/269 , Y10T428/31507 , Y10T428/31576 , Y10T428/31591 , Y10T428/31601 , Y10T428/31935 , Y10T428/31971
摘要： The present disclosure is concerned with a novel transparent polyurethane polyurea which is particularly suitable for lamination to glass and glasslike transparent plastics. The polymer is the reaction product of high molecular weight diols, optionally low molecular weight diols, dihydroxy carboxylic acids, diisocyanates with only aliphatically and cycloaliphatically bound isocyanates and organic diamines having aliphatically and cycloaliphatically bound primary amino groups. It has specified contents of carboxyl groups and urea groups, and it has a minimum shear modulus at both 20.degree. and 60.degree. C.The present disclosure is also concerned with a process for synthesizing such polymers. A preferred method is to react the diisocyanate and hydroxyl bearing compounds to prepare an isocyanate terminated prepolymer and chain extend with the diamine.Also discussed are the production of film from these polymers by extrusion and solution casting, the production of laminates with glass and glasslike plastics and the laminates so produced. The solution cast or extruded films can be laminated to these substrates by the application of heat and pressure.

7. 发明授权

US4143060A Process for the preparation of silyl substituted urea derivatives 失效
标题翻译：制备SILYL替代尿素衍生物的方法
公开(公告)号：US4143060A
公开(公告)日：1979-03-06
申请号：US535537
申请日：1974-12-23
申请人： Kuno Wagner , Gunter Oertel , Hans D. Golitz, deceased , Bernd Quiring
发明人： Kuno Wagner , Gunter Oertel , Hans D. Golitz, deceased , Bernd Quiring
IPC分类号： C07F7/10 , C07F7/18 , C08G18/71 , C08G18/80 , C07F7/02 , C07F7/07
CPC分类号： C08G18/718 , C07F7/10 , C07F7/1804 , C08G18/809
摘要： The instant invention is directed to a process of preparing a silyl substituted urea derivative comprising reacting an isocyanate of the formula ##STR1## wherein R represents a C.sub.1 -C.sub.18 alkyl group, a C.sub.4 -C.sub.14 cycloalkyl group or a phenyl group,R' represents an optionally halogenated or cyano-substituted C.sub.1 -C.sub.10 alkyl, C.sub.4 -C.sub.10 cycloalkyl or C.sub.6 -C.sub.10 aryl group,R" represents a hydrogen atom, a methyl group or a phenyl group,R'" represents a hydrogen atom or an optionally halogenated or cyano-substituted C.sub.1 -C.sub.18 alkyl, C.sub.4 -C.sub.14 cycloalkyl or C.sub.6 -C.sub.14 aryl group,Q' represents a divalent alkyl group containing 4 to 12 carbon atoms or a divalent C.sub.4 -C.sub.14 cycloalkyl, C.sub.7 -C.sub.15 aralkyl, C.sub.6 -C.sub.14 aryl or C.sub.8 alkylaryl group,A = 0 or 1,With a compound of the formula: Q (XH).sub.c, whereinQ represents a c-valent radical derived by the removal of c-XH groups from compounds with a molecular weight of 4000 to 80,000 which contains urea and urethane groups and in addition thereto, contains groups selected from the group consisting of ester groups, ether groups, and carbonate groups,C = 1 to 8 andX represents NH or NY, where Y is a C.sub.1 -C.sub.8 alkyl group, at a temperature of between -20.degree. to 150.degree. C in the presence of a stabilizing amount of a secondary or tertiary alcohol.The products so obtained have excellent storage stability, controlled reactivity and improved properties of cross-linked end products.

8. 发明授权

US4676234A Moisture-hardenable bandaging materials 失效
标题翻译：水分硬化包扎材料
公开(公告)号：US4676234A
公开(公告)日：1987-06-30
申请号：US829893
申请日：1986-02-18
申请人： Christian Wegner , Gottfried Schneider , Hans-Uwe Lanzke , Wolfram Mayer , Kuno Wagner , Wulf von Bonin , Ulrich von Gizycki , Dietmar Schaepel
发明人： Christian Wegner , Gottfried Schneider , Hans-Uwe Lanzke , Wolfram Mayer , Kuno Wagner , Wulf von Bonin , Ulrich von Gizycki , Dietmar Schaepel
IPC分类号： A61F13/04 , A61L15/12 , C08G18/08 , C08G18/10 , C08G18/30 , A61F5/04
CPC分类号： C08G18/307 , A61F13/04 , A61L15/12 , C08G18/08 , C08G18/10
摘要： The invention relates to a self-hardening material for supporting bandages which is packaged with exclusion of moisture and consists of an air-permeable, flexible carrier material which is impregnated and/or coated with a compound possessing at least 2 NCO groups. The self-hardening material has a greatly improved shelf life by being stored substantially oxygen-free in an air-tight pack.
摘要翻译：本发明涉及一种用于支撑绷带的自硬化材料，该绷带被包装，排除了水分，并且由透气的柔性载体材料组成，该载体材料用具有至少2个NCO基团的化合物浸渍和/或涂覆。通过在气密性包装中基本上无氧地储存，自硬化材料具有大大提高的保质期。

9. 发明授权

US4639502A Substantially colorless organic polyisocyanates, processes for their production and their use in the production of polyurethane plastics 失效
标题翻译：基本无色有机多异氰酸酯，其生产工艺及其在聚氨酯塑料生产中的应用
公开(公告)号：US4639502A
公开(公告)日：1987-01-27
申请号：US730134
申请日：1985-05-03
申请人： Hanns P. Muller , Werner Clarenz , Ulrich von Gizycki , Kuno Wagner
发明人： Hanns P. Muller , Werner Clarenz , Ulrich von Gizycki , Kuno Wagner
IPC分类号： C08G18/00 , C07C67/00 , C07C239/00 , C07C269/02 , C08G18/70 , C08G18/78 , C08G18/79 , C08K5/00 , C09D175/00 , C08G18/80
CPC分类号： C08G18/792 , C08G18/70 , C08G18/7831 , C08G18/791 , C08K5/0041
摘要： The present invention relates to substantially colorless organic polyisocyanates, optionally in solution in an inert solvent, having a Hazen color index according to DIN 53 409 of at most 60 and a yellow value according to DIN 6167 of at most 3.0, characterized by a content of about 0.01 to 1 ppm (by weight), based on polyisocyanate, of an organic dye soluble in the polyisocyanate and having an absorption maximum of about 560 to 590 nm or a mixture of such dyes.The present invention also relates to two processes for preparing the substantially colorless organic polyisocyanates. In the first process, the organic dye is added to the prepared polyisocyanate while in the second process the organic dye is added to the starting materials used to prepare the polyisocyanate. Finally, the present invention is directed to the production of polyisocyanate polyaddition products from the substantially colorless organic polyisocyanates and isocyanate-reactive compounds.
摘要翻译：本发明涉及基本上无色的有机多异氰酸酯，任选在惰性溶剂中的溶液中，根据DIN 53 409的Hazen颜色指数最多为60，根据DIN 6167的黄色值至多为3.0，其特征在于含量约0.01至1ppm（重量），基于多异氰酸酯，可溶于多异氰酸酯的有机染料并且具有约560至590nm的吸收最大值或这些染料的混合物。本发明还涉及制备基本上无色的有机多异氰酸酯的两种方法。在第一种方法中，将有机染料加入到制备的多异氰酸酯中，而在第二种方法中，将有机染料加入到用于制备多异氰酸酯的原料中。最后，本发明涉及从基本上无色的有机多异氰酸酯和异氰酸酯反应性化合物制备多异氰酸酯加聚产物。

10. 发明授权

US4400331A Dialkoxy-phosphonyl-N-alkyl-formic acid amides 失效
标题翻译：二烷氧基 - 膦酰基-N-烷基 - 甲酸酰胺
公开(公告)号：US4400331A
公开(公告)日：1983-08-23
申请号：US342544
申请日：1982-01-25
申请人： Peter Haas , Heinz Muller , Peter Seifert , Kuno Wagner , Kurt Findeisen , Klaus Konig
发明人： Peter Haas , Heinz Muller , Peter Seifert , Kuno Wagner , Kurt Findeisen , Klaus Konig
IPC分类号： C08G18/00 , C07F9/40 , C08J9/00 , C08L75/00 , C08L75/04
CPC分类号： C08J9/0038 , C07F9/4065 , C08J2375/04
摘要： The present invention relates to a process for the preparation of polyurethane foams capable of being flame laminated and high frequency welded, comprising reacting:(a) polyisocyanate,(b) a compound having a molecular weight of from 400 to 10,000 containing at least two isocyanate-reactive hydrogen atoms and(c) a dialkoxy-phosphonyl-N-alkyl-formic acid amide of the formula: ##STR1## wherein m represents an integer of from 1 to 3,n represents an integer of from 0 to 8,X represents halogen, hydrogen, C.sub.1 to C.sub.6 alkyl, -OR, or ##STR2## R represents C.sub.1 to C.sub.6 alkyl, R.sub.1 represents hydrogen, C.sub.1 to C.sub.10 alkyl, C.sub.1 to C.sub.10 alkylene, C.sub.6 to C.sub.10 aryl or C.sub.6 to C.sub.10 arylene, andR.sub.2 and R.sub.3, which may be the same or different, represent C.sub.1 to C.sub.10 alkyl in the presence of water and/or blowing agent.The present invention also relates to dialkoxy-phosphonyl-N-formic acid amides.
摘要翻译：本发明涉及一种制备能够进行火焰层压和高频焊接的聚氨酯泡沫体的方法，包括使（a）多异氰酸酯，（b）分子量为400至10,000的含有至少两种异氰酸酯的化合物 - 反应性氢原子和（c）下式的二烷氧基膦酰基-N-烷基 - 甲酸酰胺其中m表示1至3的整数，n表示0至8的整数，X表示卤素，氢，C1至C6烷基，-OR或R表示C1至C6烷基，R1表示氢，C1至C10烷基，C1至C10亚烷基，C6至C10芳基或C6至C10亚芳基，R2和 R 3可以相同或不同，在水和/或发泡剂的存在下表示C1至C10烷基。本发明还涉及二烷氧基 - 膦酰基-N-甲酸酰胺。

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