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1. 发明授权

US06268456B1 Coating composition containing silane functionality 失效
标题翻译：含有硅烷官能团的涂料组合物
公开(公告)号：US06268456B1
公开(公告)日：2001-07-31
申请号：US08973383
申请日：1997-12-03
申请人： Basil V. Gregorovich , Isidor Hazan , Robert Rudolph Matheson , Lech Wilczek
发明人： Basil V. Gregorovich , Isidor Hazan , Robert Rudolph Matheson , Lech Wilczek
IPC分类号： C08G7760
CPC分类号： C09D4/00 , C09D201/10 , C08F230/00 , C08G77/04 , C08G77/00 , C08L2666/02
摘要： A sprayable coating composition that contains at least one soluble film-forming silicon-containing compound having, on average, more than one fuctionalized silicon group, a volatile organic carrier, a polymer microparticle component, and a catalyst; a substrate coated with the composition; a process for coating the substrate to provide a protective finish; the finish-protected substrate; certain oligomeric compounds and a process therefor.
摘要翻译：一种可喷涂的涂料组合物，其含有至少一种平均具有多于一个功能硅基团的可溶性成膜含硅化合物，挥发性有机载体，聚合物微粒组分和催化剂; 涂有组合物的基材; 用于涂覆基材以提供保护性整理剂的方法; 保护底材; 某些寡聚化合物及其制备方法。

2. 发明授权

US6080816A Coatings that contain reactive silicon oligomers 失效
标题翻译：含有反应性硅低聚物的涂料
公开(公告)号：US6080816A
公开(公告)日：2000-06-27
申请号：US969198
申请日：1997-11-10
申请人： Basil V. Gregorovich , Isidor Hazan , Lech Wilczek
发明人： Basil V. Gregorovich , Isidor Hazan , Lech Wilczek
IPC分类号： C08F8/42 , C08G18/38 , C08G18/67 , C08G18/71 , C08G65/336 , C08G77/60 , C08K5/5465 , C08L61/20 , C09D133/00 , C09D133/06 , C09D143/04 , C09D151/00 , C09D161/28 , C09D171/02 , C09D175/04 , C09D183/04 , C09D183/10 , C09D201/02 , C09D201/10 , C08G77/00 , C08G77/16 , C08G77/48
CPC分类号： C09D201/025 , C08F8/42 , C08G18/3893 , C08G18/677 , C08G18/718 , C08G65/336 , C09D133/066 , C09D151/003 , C09D171/02 , C09D183/10 , C09D201/10 , C08K5/5465 , C08L61/20
摘要： A coating comprising the silated reaction product of R.sup.1 (OH).sub.m and OCN(CH.sub.2).sub.t SiR.sup.4 (OR.sup.5).sub.2 and/or R.sup.2 --(SiYX.sub.2).sub.n ; a graft copolymer having an acrylic polymer based backbone and stabilizing arms comprising ethylenically unsaturated monomer, the backbone being insoluble and the arms being soluble in the composition; a melamine crosslinker; and an acrylic polyol; m, n, t, R.sup.1, R.sup.2 R.sup.4, R.sup.5, X and Y being defined in the text.
摘要翻译：包含R1（OH）m和OCN（CH2）tSiR4（OR5）2和/或R2-（SiYX2）n的硅烷化反应产物的涂层; 具有基于丙烯酸聚合物的主链和包含烯键式不饱和单体的稳定臂的接枝共聚物，所述骨架是不溶的，并且所述臂可溶于所述组合物中; 三聚氰胺交联剂; 和丙烯酸多元醇; m，n，t，R1，R2 R4，R5，X和Y在文中定义。

3. 发明授权

US06329489B1 Process for producing reactive silane oligomers 失效
标题翻译：反应性硅烷低聚物的制备方法
公开(公告)号：US06329489B1
公开(公告)日：2001-12-11
申请号：US09467158
申请日：1999-12-20
申请人： Basil V. Gregorovich , Isidor Hazan , Robert R. Matheson , Lech Wilczek
发明人： Basil V. Gregorovich , Isidor Hazan , Robert R. Matheson , Lech Wilczek
IPC分类号： C08G7718
CPC分类号： C08G77/50 , C07F7/1804 , C07F7/188 , C09D183/10 , C09D183/14
摘要： The invention is directed to a process for making a reactive silane oligomer having low polydispersity, viscosity and volatility. The process utilizes reacting unsymmetrical difunctional silane monomers with water, diol monomers, or a combination thereof to make the reactive silane oligomer. The unsymmetrical difunctional silane monomers are with silane reactive groups having significantly different reactivities. Use of such reactive silane oligomers results in multi-component coating compositions having high miscibility, low VOC, low viscosity and high percentage of solids.
摘要翻译：本发明涉及制备具有低多分散性，粘度和挥发性的反应性硅烷低聚物的方法。该方法利用不对称双官能硅烷单体与水，二醇单体或其组合反应制备反应性硅烷低聚物。非对称双官能硅烷单体具有显着不同的反应性的硅烷反应性基团。使用这种反应性硅烷低聚物导致具有高混溶性，低VOC，低粘度和高百分比固体的多组分涂料组合物。

4. 发明授权

US5719251A Reactive organosilicon compounds 失效
标题翻译：活性有机硅化合物
公开(公告)号：US5719251A
公开(公告)日：1998-02-17
申请号：US703285
申请日：1996-08-26
申请人： Lech Wilczek , Idisor Hazan , Basil V. Gregorovich
发明人： Lech Wilczek , Idisor Hazan , Basil V. Gregorovich
IPC分类号： C07F7/12 , C07F7/18 , C09D7/12 , C09D183/14 , C09D201/00 , C08G77/04
CPC分类号： C09D183/14 , C07F7/12 , C07F7/1836
摘要： Organosilicon compounds are described which contain a cyclic organic moiety between at least two reactive silane groups. The compounds are useful in coatings, adhesives, and sealants, and the like.
摘要翻译：描述了在至少两个反应性硅烷基团之间含有环状有机部分的有机硅化合物。这些化合物可用于涂料，粘合剂和密封剂等。

5. 发明授权

US5932667A Reactive adducts of vinyldioxo compounds 失效
标题翻译：乙烯基二氧化合物的活性加合物
公开(公告)号：US5932667A
公开(公告)日：1999-08-03
申请号：US670956
申请日：1996-06-26
申请人： Basil V. Gregorovich , Isidor Hazan , Hisanori Omura
发明人： Basil V. Gregorovich , Isidor Hazan , Hisanori Omura
IPC分类号： C07F7/04 , C07F7/18 , C08F283/00 , C08G77/06 , C07D319/06 , C07D305/00
CPC分类号： C07F7/1836 , C07F7/04 , C07F7/182
摘要： Adducts of vinyldioxo compounds comprising a crosslinkable silyl-functional terminal group are disclosed. Such adducts are useful for preparing curable coating compositions.
摘要翻译：公开了包含可交联甲硅烷基官能端基的乙烯基二氧代化合物的加合物。这种加合物可用于制备可固化涂料组合物。

6. 发明授权

US6020034A Process for producing corrosion- and creep resistant coatings 失效
标题翻译：生产耐腐蚀和抗蠕变涂层的工艺
公开(公告)号：US6020034A
公开(公告)日：2000-02-01
申请号：US970513
申请日：1997-11-14
申请人： Rashi Akki , Basil V. Gregorovich , George K. Kodokian , George W. Prejean
发明人： Rashi Akki , Basil V. Gregorovich , George K. Kodokian , George W. Prejean
IPC分类号： C09D201/02 , C09D5/03 , C09D5/08 , C09D5/46 , C09D123/08 , B05D1/04 , B05D1/22
CPC分类号： C09D5/084 , C09D123/08
摘要： This invention concerns a process for imparting corrosion and creep resistance to a coating prepared from a particulate polymer composition and applied from a fluidized bed or by electrostatic spraying over metal substrates. The process of the present invention provides for maintaining the content of acid functionality of an acid-functionalized semicrystalline or acid-functionalized amorphous particulate polymer of the particulate polymer composition within a desired range. The acid functionality on the particulate polymer can be maintained, by crosslinking and/or neutralizing, within a desired range of the acid content which results in imparting corrosion and creep resistance to the coating applied over the metal substrates. Neutralizing the acid functionality of the polymer component results in hardening the coatings resulting therefrom. The process further provides for adding anticorrosive pigments to the composition for further improving corrosion resistance of the resultant coatings.
摘要翻译：本发明涉及一种赋予由颗粒聚合物组合物制备的涂层和从流化床施加或通过静电喷涂在金属基底上的涂层的腐蚀和抗蠕变性的方法。本发明的方法提供将颗粒状聚合物组合物的酸官能化半结晶或酸官能化无定形颗粒聚合物的酸官能度含量保持在所需范围内。粒状聚合物上的酸官能度可以通过交联和/或中和在所需的酸含量范围内保持，这导致对施加在金属基底上的涂层赋予腐蚀和抗蠕变性。中和聚合物组分的酸官能团导致硬化由此产生的涂层。该方法进一步提供了将抗腐蚀颜料添加到组合物中，以进一步提高所得涂层的耐腐蚀性。

7. 发明授权

US4476270A Process for making high solids acrylic dispersion lacquer 失效
标题翻译：制备高固体丙烯酸分散漆的方法
公开(公告)号：US4476270A
公开(公告)日：1984-10-09
申请号：US485752
申请日：1983-04-18
申请人： Wallace R. Brasen , Glenn E. Gerhardt , Basil V. Gregorovich
发明人： Wallace R. Brasen , Glenn E. Gerhardt , Basil V. Gregorovich
IPC分类号： C09D133/12 , C08F285/00
CPC分类号： C09D133/12
摘要： A process for making high solids acrylic dispersion lacquer coating composition having an acrylic polymer binder content of about 25-45% by weight in a nonaqueous medium; wherein the acrylic polymer is a blend of(1) Polymer A of methyl methacrylate and a polymerized monomer of allyl methacrylate, alkyl amino alkyl methacrylate or mixtures thereof;(2) Copolymer B of methyl methacrylate and an alkyl acrylate having 6-12 carbon atoms in the alkyl group; and(3) A graft copolymer of Polymer A which forms a backbone of the graft copolymer and Copolymer B attached to the backbone which forms side chains of the graft copolymer; andwherein the nonaqueous medium is a blend of(a) an aliphatic solvent which at 25.degree. C. is a nonsolvent for Polymer A and a solvent for Copolymer B; and(b) a coalescing solvent for the binder;the composition is useful as an exterior finish for automobiles and trucks.
摘要翻译：一种在非水介质中制备具有约25-45重量％的丙烯酸聚合物粘合剂含量的高固体丙烯酸分散漆涂料组合物的方法; 其中所述丙烯酸类聚合物是（1）甲基丙烯酸甲酯的聚合物A和甲基丙烯酸烯丙酯的烷基氨基烷基酯或其混合物的共聚物; （2）甲基丙烯酸甲酯的共聚物B和烷基中具有6-12个碳原子的丙烯酸烷基酯; 和（3）聚合物A的接枝共聚物，其形成接枝共聚物的主链和连接到骨架的共聚物B，共聚物B形成接枝共聚物的侧链; 并且其中所述非水介质是（a）在25℃是聚合物A的非溶剂和共聚物B的溶剂的脂族溶剂的共混物; 和（b）粘合剂的聚结溶剂; 该组合物可用作汽车和卡车的外观。

8. 发明授权

US5806957A Sealed automotive emblem lighting assembly and method 失效
标题翻译：密封汽车徽标照明组装及方法
公开(公告)号：US5806957A
公开(公告)日：1998-09-15
申请号：US605361
申请日：1996-02-22
申请人： Donald R. Prior , Michael T. Sweeney , Basil V. Gregorovich
发明人： Donald R. Prior , Michael T. Sweeney , Basil V. Gregorovich
IPC分类号： B60R13/00 , B60R13/10 , G09F13/04 , G09F13/14 , G09F21/04 , F21N31/02 , B60Q1/00
CPC分类号： G09F21/04 , B60R13/005 , B60R13/10 , G09F13/04 , G09F13/14 , G09F2013/0422 , G09F2013/0472 , G09F2013/0481 , G09F2013/145
摘要： Automotive emblem lighting assemblies, and methods of making. One embodiment comprises a bezel mounted to a transparent/translucent lens, with junction therebetween which can be sealed. Viscous curable material is dispensed upon the lens rear and bezel. Bubbles within the viscous material are removed. A housing is bonded with the viscous material and bezel/lens. The curable material is cured and seals the assembly. A light source shines through the lens. The lens can have an emblem shaped recess or recesses. Part of the lens rear can be coated with substantially opaque material. A reflective-transmissive material coats at least part of the lens rear for light transmission/reflection. Diffusion can be by a diffusing agent in the viscous material, reflective surface on the light source, or diffusing material on the lens. Modifications: lens with no substantially opaque coating, an emblem shaped lens, reflective-transmissive material on the lens rear, and no bezel. The lens and housing can interfit, with the cured material sealing their junction. The lens rear can be curved or even. Another modification: lens and housing do not interfit. Sealer dispensed over the lens perimeter, housing placed thereagainst and viscous curable material dispensed through housing to cover lens to bond to housing. Another embodiment: lens with sealer dispensed about perimeter, viscous curable material dispensed therein, with bonded light source, e.g., LED or electro luminescent pad. The cured material seals to impede contaminants and moisture from the interior, protect lens coatings and enhance visual effects while bonding components.
摘要翻译：汽车会徽照明组件及制作方法。一个实施例包括安装到透明/半透明透镜的边框，其间可以密封有接合部。粘性可固化材料分配在透镜后部和边框上。去除粘性物质内的气泡。外壳与粘性材料和表圈/镜片粘合。可固化材料固化并密封组件。光源照射透镜。透镜可以具有标志形状的凹部或凹部。透镜后部的一部分可涂覆有基本上不透明的材料。反射透射材料涂覆透镜后部的至少一部分用于透光/反射。可以通过粘性材料中的扩散剂，光源上的反射表面或透镜上的扩散材料进行扩散。修改：镜头没有实质上不透明的涂层，会徽形透镜，反射透镜材料在镜头后面，没有挡板。透镜和外壳可以互相配合，固化的材料密封它们的连接处。镜头后部可以弯曲或均匀。另一个修改：镜头和房屋不配合。封口机分配在镜片周边，外壳放置在其上，粘性固化材料通过外壳分配以覆盖透镜以结合到外壳。另一个实施例：具有密封剂的透镜，其围绕周边分配，其中分配有粘性可固化材料，具有粘合光源，例如LED或电发光垫。固化的材料密封以阻止内部的污染物和水分，保护透镜涂层并在粘合部件时增强视觉效果。

9. 发明授权

US5571931A Process for the synthesis of vinyldioxo compounds 失效
标题翻译：乙烯基二氧化合物的合成方法
公开(公告)号：US5571931A
公开(公告)日：1996-11-05
申请号：US435251
申请日：1995-05-05
申请人： Basil V. Gregorovich
发明人： Basil V. Gregorovich
IPC分类号： C07D319/06
CPC分类号： C07D319/06
摘要： An improved process for preparing a vinyl-substituted dioxo compound, in which process a vinyl aldehyde is reacted with a compound having three or more hydroxyl groups. In particular, the reaction is carried out, using an acid catalyst, in an organic solvent comprising an aliphatic solvent which forms a binary azeotrope with water as the reaction is driven to completion.
摘要翻译：一种制备乙烯基取代的二氧化合物的改进方法，其中乙烯基醛与具有三个或更多个羟基的化合物反应。特别地，使用酸催化剂在包含与水形成二元共沸物的脂肪族溶剂的有机溶剂中进行反应，从而使反应完成。

10. 发明授权

US5447998A Clear coat resins by continuous polymerization 失效
标题翻译：透明涂层树脂通过连续聚合
公开(公告)号：US5447998A
公开(公告)日：1995-09-05
申请号：US224418
申请日：1994-04-08
申请人： Michael C. Grady , Basil V. Gregorovich
发明人： Michael C. Grady , Basil V. Gregorovich
IPC分类号： C08F2/04 , B01J19/18 , C08F2/00 , C08F2/02 , C08F20/00 , C08F20/12 , C08F18/02
CPC分类号： B01J19/1862 , C08F20/12 , B01J2219/00083 , B01J2219/00094 , B01J2219/0013 , B01J2219/00166
摘要： A process for preparing acrylic polymers having good crater resistance by continuous polymerization in vessels having agitating means tip speed from 500 to 1200 rpm. Placement of the feed valve for charging the monomer and/or the initiator is located beneath the surface of the agitating mass.
摘要翻译：一种制备丙烯酸聚合物的方法，该聚合物具有通过连续聚合在具有搅拌装置的搅拌装置的尖端速度为500至1200rpm的连续聚合物中具有用于装入单体和/或引发剂的进料阀的放置位于搅拌物质表面下方。

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