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1. 发明授权

US07981831B2 Catalysts, methods of making catalysts, and methods of combustion 有权
标题翻译：催化剂，制备催化剂的方法和燃烧方法
公开(公告)号：US07981831B2
公开(公告)日：2011-07-19
申请号：US11959459
申请日：2007-12-18
申请人： Barry Lee-Mean Yang , Ruiqiang Long , Junko M. Watson , Abhishek Gupta
发明人： Barry Lee-Mean Yang , Ruiqiang Long , Junko M. Watson , Abhishek Gupta
IPC分类号： B01J23/00 , B01J19/00 , C22C19/07
CPC分类号： F23C13/00 , B01D53/864 , B01D53/944 , B01J23/894 , B01J23/8993 , B01J35/1009 , B01J37/0226 , B01J37/0242 , B01J37/08 , F23C2900/03001 , Y02C20/20
摘要： Catalysts are described in which an active catalyst is disposed on a low surface area, oxide support. Methods of forming catalysts are described in which a Cr-containing metal is oxidized to form a chromium oxide layer and an active catalyst is applied directly on the chromium oxide layer. Methods of making new catalysts are described in which the surface is sonicated prior to depositing the catalyst. Catalyst systems and methods of oxidation are also described. The inventive systems, catalysts and methods are, in some instances, characterized by surprisingly superior results.
摘要翻译：描述了其中在低表面积上设置活性催化剂的催化剂，氧化物载体。描述了形成催化剂的方法，其中将含Cr金属氧化形成氧化铬层，并将活性催化剂直接施加到氧化铬层上。描述制备新催化剂的方法，其中在沉积催化剂之前将表面进行超声处理。还描述了催化剂体系和氧化方法。在一些情况下，本发明的系统，催化剂和方法的特征在于惊人的优异结果。

2. 发明授权

US07326394B2 Catalysts, methods of making catalysts, and methods of combustion 有权
标题翻译：催化剂，制备催化剂的方法和燃烧方法
公开(公告)号：US07326394B2
公开(公告)日：2008-02-05
申请号：US10384169
申请日：2003-03-07
申请人： Barry Lee-Mean Yang , Ruiqiang Long , Junko M. Watson , Abhishek Gupta
发明人： Barry Lee-Mean Yang , Ruiqiang Long , Junko M. Watson , Abhishek Gupta
IPC分类号： C01B31/20
CPC分类号： F23C13/00 , B01D53/864 , B01D53/944 , B01J23/894 , B01J23/8993 , B01J35/1009 , B01J37/0226 , B01J37/0242 , B01J37/08 , F23C2900/03001 , Y02C20/20
摘要： Catalysts are described in which an active catalyst is disposed on a low surface area, oxide support. Methods of forming catalysts are described in which a Cr-containing metal is oxidized to form a chromium oxide layer and an active catalyst is applied directly on the chromium oxide layer. Methods of making new catalysts are described in which the surface is sonicated prior to depositing the catalyst. Catalyst systems and methods of oxidation are also described. The inventive systems, catalysts and methods are, in some instances, characterized by surprisingly superior results.
摘要翻译：描述了其中在低表面积上设置活性催化剂的催化剂，氧化物载体。描述了形成催化剂的方法，其中将含Cr金属氧化形成氧化铬层，并将活性催化剂直接施加到氧化铬层上。描述制备新催化剂的方法，其中在沉积催化剂之前将表面进行超声处理。还描述了催化剂体系和氧化方法。在一些情况下，本发明的系统，催化剂和方法的特征在于惊人的优异结果。

3. 发明申请

US20100098598A1 Catalysts, Methods of Making Catalysts, and Methods of Combustion 有权
标题翻译：催化剂，制备催化剂的方法和燃烧方法
公开(公告)号：US20100098598A1
公开(公告)日：2010-04-22
申请号：US11959459
申请日：2007-12-18
申请人： Barry Lee-Mean Yang , Ruiqiang Long , Junko M. Waston , Abhishek Gupta
发明人： Barry Lee-Mean Yang , Ruiqiang Long , Junko M. Waston , Abhishek Gupta
IPC分类号： B01J23/00 , B01J23/75 , B01J23/26 , B01J23/755 , B01J23/42 , B01J23/44
CPC分类号： F23C13/00 , B01D53/864 , B01D53/944 , B01J23/894 , B01J23/8993 , B01J35/1009 , B01J37/0226 , B01J37/0242 , B01J37/08 , F23C2900/03001 , Y02C20/20
摘要： Catalysts are described in which an active catalyst is disposed on a low surface area, oxide support. Methods of forming catalysts are described in which a Cr-containing metal is oxidized to form a chromium oxide layer and an active catalyst is applied directly on the chromium oxide layer. Methods of making new catalysts are described in which the surface is sonicated prior to depositing the catalyst. Catalyst systems and methods of oxidation are also described. The inventive systems, catalysts and methods are, in some instances, characterized by surprisingly superior results.
摘要翻译：描述了其中在低表面积上设置活性催化剂的催化剂，氧化物载体。描述了形成催化剂的方法，其中将含Cr金属氧化形成氧化铬层，并将活性催化剂直接施加到氧化铬层上。描述制备新催化剂的方法，其中在沉积催化剂之前将表面进行超声处理。还描述了催化剂体系和氧化方法。在一些情况下，本发明的系统，催化剂和方法的特征在于惊人的优异结果。

4. 发明授权

US06432494B1 Protective coating by high rate arc plasma deposition 有权
标题翻译：高速电弧等离子体沉积保护涂层
公开(公告)号：US06432494B1
公开(公告)日：2002-08-13
申请号：US09560852
申请日：2000-04-28
申请人： Barry Lee-Mean Yang , Steven Marc Gasworth
发明人： Barry Lee-Mean Yang , Steven Marc Gasworth
IPC分类号： C23C1640
CPC分类号： C23C16/405 , C23C16/402 , C23C16/513
摘要： A method for depositing adherent metal oxide-based protective coatings on glass, metal, and plastic substrates by arc plasma deposition.
摘要翻译：通过电弧等离子体沉积在玻璃，金属和塑料基板上沉积粘附的金属氧化物基保护涂层的方法。

5. 发明授权

US06213049B1 Nozzle-injector for arc plasma deposition apparatus 失效
标题翻译：电弧等离子体沉积设备用喷嘴
公开(公告)号：US06213049B1
公开(公告)日：2001-04-10
申请号：US09033862
申请日：1998-03-03
申请人： Barry Lee-Mean Yang
发明人： Barry Lee-Mean Yang
IPC分类号： C23C400
CPC分类号： B05B7/226 , B05B12/12 , C23C4/134 , C23C16/513
摘要： A nozzle-injector was designed and fabricated for plasma deposition of thin-film coatings using a wall-stabilized arc torch as the plasma generator. The design of the nozzle-injector controls the injection, ionization, and reaction of the reagents, and these functions, in turn, determine the coating deposition rate, coating area, coating composition, and coating quality.
摘要翻译：设计和制造喷嘴注射器，用于使用壁稳定电弧焰炬作为等离子体发生器来等离子体沉积薄膜涂层。喷嘴注射器的设计控制了试剂的注入，电离和反应，这些功能又决定了涂层沉积速率，涂层面积，涂层组成和涂层质量。

6. 发明授权

US06872428B2 Apparatus and method for large area chemical vapor deposition using multiple expanding thermal plasma generators 有权
标题翻译：使用多个膨胀热等离子体发生器的大面积化学气相沉积的装置和方法
公开(公告)号：US06872428B2
公开(公告)日：2005-03-29
申请号：US10063094
申请日：2002-03-19
申请人： Barry Lee-Mean Yang , Charles Dominic Iacovangelo , Kenneth Walter Browall , Steven Marc Gasworth , William Arthur Morrison , James Neil Johnson
发明人： Barry Lee-Mean Yang , Charles Dominic Iacovangelo , Kenneth Walter Browall , Steven Marc Gasworth , William Arthur Morrison , James Neil Johnson
IPC分类号： C23C16/40 , C23C16/513 , H01J37/32 , H05H1/44 , C23C16/00
CPC分类号： H01J37/32009 , C23C16/401 , C23C16/513 , H05H1/44
摘要： Chemical vapor deposition is performed using a plurality of expanding thermal plasma generating means to produce a coating on a substrate, such as a thermoplastic and especially a polycarbonate substrate. The substrate is preferably moved past the generating means. Included are methods which coat both sides of the substrate or which employ multiple sets of generating means, either in a single deposition chamber or in a plurality of chambers for deposition of successive coatings. The substrate surfaces spaced from the axes of the generating means are preferably heated to promote coating uniformity.
摘要翻译：使用多个膨胀热等离子体产生装置进行化学气相沉积，以在诸如热塑性材料，特别是聚碳酸酯基材的基底上产生涂层。衬底优选地移动经过发生装置。包括在基板的两面涂覆或者在单个沉积室中或在用于沉积连续涂层的多个室中采用多组发生装置的方法。优选地，与发生装置的轴线间隔开的衬底表面被加热以促进涂层均匀性。

7. 发明授权

US06426125B1 Multilayer article and method of making by ARC plasma deposition 有权
标题翻译：多层制品和ARC等离子体沉积制备方法
公开(公告)号：US06426125B1
公开(公告)日：2002-07-30
申请号：US09271654
申请日：1999-03-17
申请人： Barry Lee-Mean Yang , Charles Dominic Iacovangelo
发明人： Barry Lee-Mean Yang , Charles Dominic Iacovangelo
IPC分类号： C08F252
CPC分类号： C03C17/42 , C03C17/3417 , C03C17/3435 , C03C17/3441 , C03C17/347 , C23C14/22 , C23C14/32 , C23C16/513 , Y10T428/24942 , Y10T428/31663
摘要： According to an exemplary embodiment of the invention, a method of forming a plurality of layers on an article comprises steps of generating a plasma by forming an arc between a cathode and an anode; injecting a first material comprising an organic compound into the plasma to deposit a first layer on the article; injecting a second material comprising an organometallic material into the plasma to form a second layer on the first layer; and injecting a third material comprising a silicon containing organic compound into the plasma to deposit a third layer on the second layer. The invention also relates to an article of manufacture comprising a substrate; an interlayer disposed on the substrate; a second layer disposed on the interlayer, the second layer comprising an inorganic ultraviolet absorbing material; and a third layer disposed on the second layer, the third layer comprising an abrasion resistant material. The interlayer may comprise a polymerized organosilicon material or a polymerized hydrocarbon material, for example. The second layer may comprise a metal oxide or zinc sulfide, for example. The third layer may comprise an oxidized organosilicon material, for example.
摘要翻译：根据本发明的示例性实施例，在制品上形成多个层的方法包括以下步骤：通过在阴极和阳极之间形成电弧来产生等离子体; 将包含有机化合物的第一材料注入到所述等离子体中以将第一层沉积在所述制品上; 将包含有机金属材料的第二材料注入所述等离子体中以在所述第一层上形成第二层; 以及将包含含硅有机化合物的第三材料注射到所述等离子体中以在所述第二层上沉积第三层。本发明还涉及一种包括基底的制品; 设置在基板上的中间层; 设置在所述中间层上的第二层，所述第二层包含无机紫外线吸收材料; 以及设置在所述第二层上的第三层，所述第三层包括耐磨材料。中间层可以包括例如聚合的有机硅材料或聚合烃材料。例如，第二层可以包含金属氧化物或硫化锌。例如，第三层可以包含氧化的有机硅材料。

8. 发明授权

US06641673B2 Fluid injector for and method of prolonged delivery and distribution of reagents into plasma 有权
公开(公告)号：US06641673B2
公开(公告)日：2003-11-04
申请号：US09742837
申请日：2000-12-20
申请人： Barry Lee-Mean Yang
发明人： Barry Lee-Mean Yang
IPC分类号： C23C1600
CPC分类号： C23C16/45563 , C23C16/513 , H01J37/3244 , Y10T428/31663
摘要： A method and apparatus for injecting a fluid into a plasma stream with a uniform distribution and with reduced likelihood of clogging over prolonged use is provided. An injector includes a first channel portion for restricting a flow of the fluid and having a shape such that inner walls of the first channel portion are parallel to a first axis. The injector also includes a second channel portion in fluid communication with the first channel portion. The second channel portion includes a recessed portion such that inner walls of the second channel portion diverge from the first axis at a predetermined angle. The second channel portion reduces a buildup of a clogging layer on the inner walls of the second channel portion over a period of use. In addition, the injector can further include a tip portion that protrudes into the plasma. The injector can be integrated into or interchangeable within an injector system that can be designed for operation within a plasma deposition apparatus.

9. 发明授权

US06365016B1 Method and apparatus for arc plasma deposition with evaporation of reagents 有权
标题翻译：用试剂蒸发电弧等离子体沉积的方法和装置
公开(公告)号：US06365016B1
公开(公告)日：2002-04-02
申请号：US09271655
申请日：1999-03-17
申请人： Charles Dominic Iacovangelo , Keith Milton Borst , Elihu Calvin Jerabek , Patrick Peter Marzano , Barry Lee-Mean Yang
发明人： Charles Dominic Iacovangelo , Keith Milton Borst , Elihu Calvin Jerabek , Patrick Peter Marzano , Barry Lee-Mean Yang
IPC分类号： C23C1408
CPC分类号： C23C14/228 , C23C14/32 , C23C16/513 , H01J37/32422
摘要： A method and apparatus for depositing a coating on a substrate. A method of coating a substrate comprises evaporating a first reactant; introducing the evaporated reactant into a plasma; and depositing the first reactant on a surface of the substrate. This method may be used to deposit an electrically conductive, ultraviolet filter coating at high rate on a glass or polycarbonate substrate, for example. An apparatus for depositing a UV filter coating on a polymeric substrate comprises a plasma generator having an anode and a cathode to form a plasma, and a first inlet for introducing a first reactant into the plasma, the first reactant comprising an evaporated material that is deposited on the substrate by the plasma. Optionally, a nozzle can be utilized to provide a controlled delivery of the first reactant into the plasma.
摘要翻译：一种用于在基底上沉积涂层的方法和装置。涂布基材的方法包括蒸发第一反应物; 将蒸发的反应物引入等离子体; 以及将所述第一反应物沉积在所述衬底的表面上。例如，该方法可用于在玻璃或聚碳酸酯基底上高速沉积导电的紫外线过滤器涂层。用于在聚合物基底上沉积UV过滤器涂层的装置包括具有阳极和阴极以形成等离子体的等离子体发生器，以及用于将第一反应物引入等离子体的第一入口，第一反应物包含沉积的蒸发材料通过等离子体在衬底上。任选地，可以使用喷嘴来提供第一反应物到等离子体的受控输送。

10. 发明授权

US6110544A Protective coating by high rate arc plasma deposition 失效
公开(公告)号：US6110544A
公开(公告)日：2000-08-29
申请号：US36776
申请日：1998-03-09
申请人： Barry Lee-Mean Yang , Steven Marc Gasworth
发明人： Barry Lee-Mean Yang , Steven Marc Gasworth
IPC分类号： C23C16/26 , C23C16/40 , C23C16/42 , C23C16/50 , C23C16/513 , H01L21/205 , H01L21/31
CPC分类号： C23C16/405 , C23C16/402 , C23C16/513
摘要： A method for depositing adherent metal oxide-based protective coatings on glass, metal, and plastic substrates by arc plasma deposition.

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