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1. 发明授权

US10315975B2 Method for the hydroformylation of 2-substituted butadienes and the production of secondary products thereof, especially ambrox 有权
公开(公告)号：US10315975B2
公开(公告)日：2019-06-11
申请号：US15743153
申请日：2016-07-08
申请人： BASF SE , Ruprecht-Karls-Universität Heidelberg , Christa Johanna Hofmann , Stefanie Hoffman
发明人： Julia Strautmann , Stefan Rüdenauer , Christian Rein , Melanie Weingarten , Rocco Paciello , Wolfgang Siegel , Michael Breuer , Peter Hofmann , Sebastian Schmidt
IPC分类号： C07C45/50 , B01J31/00 , C07C47/21 , C07D307/92 , C07C29/141 , C07C29/56 , B01J31/18 , C07C33/025
摘要： The present invention relates to a method for the regioselective hydroformylation of polyunsaturated acyclic hydrocarbons, which are 1, 3 butadienes, which, in the 2 position, bear a saturated or monounsaturated or polyunsaturated acyclic hydrocarbon radical. The present invention also relates to the production of secondary products of these hydroformylation products, especially of ambrox.

2. 发明申请

US20140288265A1 ALKOXYLATED POLYALKYLENEPOLYAMINES 有权
标题翻译：烷氧基聚亚烷基硅氧烷
公开(公告)号：US20140288265A1
公开(公告)日：2014-09-25
申请号：US14356281
申请日：2012-11-19
申请人： BASF SE
发明人： Sophia Ebert , Thomas Schaub , Julia Strautmann , Stephan Hueffer
IPC分类号： C08G73/02
CPC分类号： C08G73/0213 , C08G65/2609 , C08G65/2621 , C08G65/2624 , C08G65/2672 , C08G73/0206 , C08G73/024 , C08G2650/50
摘要： Process for the preparation of alkoxylated polyalkylenepolyamines, comprising the following steps (a) homogeneously catalyzed alcohol amination, where aliphatic amino alcohols are reacted with one another or aliphatic diamines or polyamines are reacted with aliphatic diols or polyols with the elimination of water in the presence of a homogeneous catalyst to give polyalkylenepolyamines, (b) reaction of these polyalkylenepolyamines with alkylene oxides to give alkoxylated polyalkylenepolyamines. Specific alkoxylated polyalkylenepolyamines obtainable by such processes and alkoxylated polyalkylenepolyamines and processes for their preparation. Uses of alkoxylated polyalkylenepolyamines as detergent additives, dispersants, textile auxiliaries, wood protectants, corrosion inhibitors.
摘要翻译：制备烷氧基化聚亚烷基多胺的方法，包括以下步骤（a）均匀催化的醇胺化，其中脂族氨基醇彼此反应或脂族二胺或多胺与脂族二元醇或多元醇反应，在存在得到聚亚烷基多胺的均相催化剂，（b）这些聚亚烷基多胺与烯化氧反应得到烷氧基化聚亚烷基多胺。通过这些方法获得的特定烷氧基化聚亚烷基多胺和烷氧基化聚亚烷基多胺及其制备方法。使用烷氧基化聚亚烷基多胺作为洗涤剂添加剂，分散剂，纺织助剂，木材保护剂，腐蚀抑制剂。

3. 发明授权

US10344381B2 Process for the generation of thin inorganic films 有权
公开(公告)号：US10344381B2
公开(公告)日：2019-07-09
申请号：US15325840
申请日：2015-07-22
申请人： BASF SE
发明人： Julia Strautmann , Rocco Paciello , Thomas Schaub , Felix Eickemeyer , Daniel Loeffler , Hagen Wilmer , Udo Radius , Johannes Berthel , Florian Hering
IPC分类号： C23C16/455 , C23C16/18 , C07F15/04 , C07F15/06 , C30B25/10 , C30B25/08
摘要： The present invention is in the field of processes for the generation of thin inorganic films on substrates, in particular atomic layer deposition processes. In detail the present invention relates a process comprising bringing a compound of general formula (I) into the gaseous or aerosol state (Fig.) and depositing the compound of general formula (I) from the gaseous or aerosol state onto a solid substrate, wherein R1 and R4 are independent of each other an alkyl group, an aryl group or a trialkylsilyl group, R2, R3, R5 and R6 are independent of each other hydrogen, an alkyl group, an aryl group or a trialkylsilyl group, n is an integer from 1 to 3, M is Ni or Co, X is a ligand which coordinates M, and m is an integer from 0 to 4.

4. 发明授权

US10106888B2 Process for the generation of thin inorganic films 有权
公开(公告)号：US10106888B2
公开(公告)日：2018-10-23
申请号：US15501631
申请日：2015-07-24
申请人： BASF SE
发明人： Julia Strautmann , Rocco Paciello , Thomas Schaub , Kerstin Schierle-Arndt , Daniel Loeffler , Hagen Wilmer , Felix Eickemeyer , Florian Blasberg , Carolin Limburg
IPC分类号： C23C16/06 , C23C16/18 , C23C16/455
摘要： A process of bringing a compound of general formula (I) into the gaseous or aerosol state and depositing the compound of general formula (I) from the gaseous or aerosol state onto a solid substrate, wherein R11, R12, R13, R14, R15, R16, R17, R18 are independent of each other hydrogen, an alkyl group, an aryl group, or a trialkylsilyl group, R21, R22, R23, R24 are independent of each other an alkyl group, an aryl group, or a trialkylsilyl group, n is 1 or 2, M is a metal or semimetal, X is a ligand which coordinates M, and m is an integer from 0 to 3.

5. 发明授权

US09328201B2 Alkoxylated polyalkylenepolyamines 有权
标题翻译：烷氧基化聚亚烷基多胺
公开(公告)号：US09328201B2
公开(公告)日：2016-05-03
申请号：US14356281
申请日：2012-11-19
申请人： BASF SE
发明人： Sophia Ebert , Thomas Schaub , Julia Strautmann , Stephan Hueffer
IPC分类号： C08G73/02 , C08G59/64 , C08G59/68 , C08G65/26 , C08G65/30
CPC分类号： C08G73/0213 , C08G65/2609 , C08G65/2621 , C08G65/2624 , C08G65/2672 , C08G73/0206 , C08G73/024 , C08G2650/50
摘要： Process for the preparation of alkoxylated polyalkylenepolyamines, comprising the following steps (a) homogeneously catalyzed alcohol amination, where aliphatic amino alcohols are reacted with one another or aliphatic diamines or polyamines are reacted with aliphatic diols or polyols with the elimination of water in the presence of a homogeneous catalyst to give polyalkylenepolyamines, (b) reaction of these polyalkylenepolyamines with alkylene oxides to give alkoxylated polyalkylenepolyamines. Specific alkoxylated polyalkylenepolyamines obtainable by such processes and alkoxylated polyalkylenepolyamines and processes for their preparation. Uses of alkoxylated polyalkylenepolyamines as detergent additives, dispersants, textile auxiliaries, wood protectants, corrosion inhibitors.
摘要翻译：制备烷氧基化聚亚烷基多胺的方法，包括以下步骤（a）均匀催化的醇胺化，其中脂族氨基醇彼此反应或脂族二胺或多胺与脂族二元醇或多元醇反应，在存在得到聚亚烷基多胺的均相催化剂，（b）这些聚亚烷基多胺与烯化氧反应得到烷氧基化聚亚烷基多胺。通过这些方法获得的特定烷氧基化聚亚烷基多胺和烷氧基化聚亚烷基多胺及其制备方法。使用烷氧基化聚亚烷基多胺作为洗涤剂添加剂，分散剂，纺织助剂，木材保护剂，腐蚀抑制剂。

6. 发明授权

US09550725B2 Lipophilic polyalkylenepolyamines by homogeneously catalyzed alcohol amination 有权
标题翻译：亲油性聚亚烷基多胺通过均相催化醇胺化
公开(公告)号：US09550725B2
公开(公告)日：2017-01-24
申请号：US14359134
申请日：2012-11-19
申请人： BASF SE
发明人： Julia Strautmann , Thomas Schaub , Stephan Hueffer , Steffen Maas , Claudia Wood
IPC分类号： C07C209/14 , C08G73/02 , C09J179/02
CPC分类号： C07C209/14 , C08G73/0213 , C09J179/02
摘要： Process for the preparation of lipophilic polyalkylenepolyamines by homogeneously catalyzed alcohol amination, where aliphatic amino alcohols are reacted with one another or aliphatic diamines or polyamines are reacted with aliphatic diols or polyols with the elimination of water in the presence of a homogeneous catalyst, at least one of the reactants comprising an alkyl or alkylene group having five or more carbon atoms, and after the reaction a phase separation into at least one apolar phase and at least one polar phase being present, the lipophilic polyalkylenepolyamines being present in enriched form in the apolar phase. Polyalkylenepolyamines obtainable by such processes, and polyalkylenepolyamines comprising hydroxyl groups, secondary amines or tertiary amines. Uses of such polyalkylenepolyamines as adhesion promoters for printing inks, adhesion promoters in composite films, cohesion promoters for adhesives, crosslinkers/curing agents for resins, primers in paints, wet-adhesion promoters for emulsion paints, complexing agents and flocculating agents, penetration assistants in wood preservation, corrosion inhibitors, immobilizing agents for proteins and enzymes.
摘要翻译：通过均相催化的醇胺化制备亲脂性聚亚烷基多胺的方法，其中脂肪族氨基醇彼此反应或脂族二胺或多胺与脂肪族二元醇或多元醇反应，在均相催化剂存在下，除去水，至少一种的反应物，其包含具有五个或更多个碳原子的烷基或亚烷基，并且在反应之后，相分离成至少一个非极性相和至少一个极性相存在，亲油性聚亚烷基多胺以非极性相存在于富集形式。可通过这些方法得到的聚亚烷基多胺，以及包含羟基，仲胺或叔胺的聚亚烷基多胺。使用这种聚亚烷基多胺作为印刷油墨的粘合促进剂，复合膜中的粘合促进剂，粘合剂的粘合促进剂，树脂的交联剂/固化剂，油漆中的底漆，乳液涂料的湿粘合促进剂，络合剂和絮凝剂，渗透助剂木材保存，腐蚀抑制剂，蛋白质和酶的固定剂。

7. 发明申请

US20140309460A1 INCREASING THE MOLAR MASS OF POLYALKYLENEPOLYAMINES BY HOMOGENEOUSLY CATALYZED ALCOHOL AMINATION 审中-公开
标题翻译：通过均相催化的醇醇胺化增加聚烯丙基胺的摩尔质量
公开(公告)号：US20140309460A1
公开(公告)日：2014-10-16
申请号：US14357822
申请日：2012-11-19
申请人： BASF SE
发明人： Julia Strautmann , Thomas Schaub , Stephan Hueffer , Rocco Paciello
IPC分类号： C07C209/16 , C07C211/02
CPC分类号： C07C209/16 , C07C211/02 , C08G73/0213
摘要： Process for increasing the molar mass of polyalkylenepolyamines by homogeneously catalyzed alcohol amination, which comprises carrying out a reaction of the polyalkylenepolyamines in a reactor with elimination of water in the presence of a homogeneous catalyst and removing the water of reaction from the reaction system. Polyalkylenepolyamines obtainable by such processes, and polyalkylenepolyamines comprising hydroxyl groups, secondary amines or tertiary amines. Uses of such polyalkylenepolyamines as adhesion promoters for printing inks, adhesion promoters in composite films, cohesion promoters for adhesives, crosslinkers/curing agents for resins, primers for paints, wet-adhesion promoters for emulsion paints, complexing agents and flocculating agents, penetration assistants in wood preservation, corrosion inhibitors, immobilizing agents for proteins and enzymes.
摘要翻译：通过均相催化醇胺化来提高聚亚烷基多胺的摩尔质量的方法，其包括在均相催化剂存在下进行反应中的聚亚烷基多胺与反应器中的水反应，并从反应体系中除去反应水。可通过这些方法得到的聚亚烷基多胺，以及包含羟基，仲胺或叔胺的聚亚烷基多胺。使用这种聚亚烷基多胺作为印刷油墨的粘合促进剂，复合膜中的粘合促进剂，粘合剂的内聚力促进剂，树脂的交联剂/固化剂，油漆的底漆，乳液漆的湿粘合促进剂，络合剂和絮凝剂，渗透助剂木材保存，腐蚀抑制剂，蛋白质和酶的固定剂。

8. 发明申请

US20140305339A1 LIPOPHILIC POLYALKYLENEPOLYAMINES BY HOMOGENEOUSLY CATALYZED ALCOHOL AMINATION 有权
标题翻译：通过均相催化的醇醇胺化得到的聚丙烯酰胺（LIPOPHILIC POLYALKYLENEPOLYAMINES）
公开(公告)号：US20140305339A1
公开(公告)日：2014-10-16
申请号：US14359134
申请日：2012-11-19
申请人： BASF SE
发明人： Julia Strautmann , Thomas Schaub , Stephan Hueffer , Steffen Maas , Claudia Wood
IPC分类号： C07C209/14 , C09J179/02
CPC分类号： C07C209/14 , C08G73/0213 , C09J179/02
摘要： Process for the preparation of lipophilic polyalkylenepolyamines by homogeneously catalyzed alcohol amination, where aliphatic amino alcohols are reacted with one another or aliphatic diamines or polyamines are reacted with aliphatic diols or polyols with the elimination of water in the presence of a homogeneous catalyst, at least one of the reactants comprising an alkyl or alkylene group having five or more carbon atoms, and after the reaction a phase separation into at least one apolar phase and at least one polar phase being present, the lipophilic polyalkylenepolyamines being present in enriched form in the apolar phase. Polyalkylenepolyamines obtainable by such processes, and polyalkylenepolyamines comprising hydroxyl groups, secondary amines or tertiary amines. Uses of such polyalkylenepolyamines as adhesion promoters for printing inks, adhesion promoters in composite films, cohesion promoters for adhesives, crosslinkers/curing agents for resins, primers in paints, wet-adhesion promoters for emulsion paints, complexing agents and flocculating agents, penetration assistants in wood preservation, corrosion inhibitors, immobilizing agents for proteins and enzymes.
摘要翻译：通过均相催化的醇胺化制备亲脂性聚亚烷基多胺的方法，其中脂肪族氨基醇彼此反应或脂族二胺或多胺与脂肪族二元醇或多元醇反应，在均相催化剂存在下，除去水，至少一种的反应物，其包含具有五个或更多个碳原子的烷基或亚烷基，并且在反应之后，相分离成至少一个非极性相和至少一个极性相存在，亲油性聚亚烷基多胺以非极性相存在于富集形式。可通过这些方法得到的聚亚烷基多胺，以及包含羟基，仲胺或叔胺的聚亚烷基多胺。使用这种聚亚烷基多胺作为印刷油墨的粘合促进剂，复合膜中的粘合促进剂，粘合剂的粘合促进剂，树脂的交联剂/固化剂，油漆中的底漆，乳液涂料的湿粘合促进剂，络合剂和絮凝剂，渗透助剂木材保存，腐蚀抑制剂，蛋白质和酶的固定剂。

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