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1. 发明申请

US20150284604A1 IMINOXYTRIAZINES AS RADICAL GENERATORS 有权
标题翻译：作为辐射发生器的IMINOXYTRIAZINES
公开(公告)号：US20150284604A1
公开(公告)日：2015-10-08
申请号：US14437246
申请日：2013-10-22
申请人： BASF SE
发明人： Peter Nesvadba , Lucienne Bugnon Folger , Antoine Carroy , Marc Faller
IPC分类号： C09J133/14 , C09D11/107
CPC分类号： C09J133/14 , C07D251/30 , C07D251/42 , C07D403/14 , C09D11/107
摘要： Iminoxytriazine compounds of the formula I wherein n is 1 or 2; R1 and R2 independently of each other are hydrogen, NH2, NHR5, NR5R6, COR5, COOR5, CONH2, CONHR5, CONR5R6, CN, SR5, OR5, C1-C18alkyl, C3-C12cycloalkyl, C6-C14aryl or C2-C14heteroaryl, wherein said C3-C12cycloalkyl, C6-C14aryl or C2-C14heteroaryl is unsubstituted or substituted by one or more radicals selected from the group consisting of C1-C12alkyl, C3-C12-cycloalkyl, phenyl, halogen and C1-C12 alkoxy, or R1 and R2 together with the C atom to which they are linked form a 4 to 12 membered carbocyclic or heterocyclic saturated or unsaturated ring which is unsubstituted or substituted by one or more radicals selected from the group consisting of C1-C12alkyl, C3-C12-cycloalkyl, phenyl, halogen and C1-C12 alkoxy; R3 is F, Cl, OH, OR5, SH, SR5, NH2, NHR5, NR5R6 or R1R2C═N—O—; wherein R1 and R2 in all groups R1R2C═N—O— in the compound of the formula I are identical or different; if n is 1, R4 is F, Cl, OH, OR5, SH, SR5, NH2, NHR5, NR5R6 or R1R2C═N—O—; wherein R1 and R2 in all groups R1R2C═N—O— in the compound of the formula I are identical or different; if n is 2, R4 is a difunctional group derived from a diol, diamine, aminoalcohol or mercaptoalcohol; R5 and R6 independently of each other are C1-C18alkyl, C3-C12cycloalkyl, C6-C14aryl or C2-C14heteroaryl; are suitable as radical generating agents.
摘要翻译：式I的亚氨基三嗪化合物，其中n为1或2; R 1和R 2彼此独立地是氢，NH 2，NHR 5，NR 5 R 6，COR 5，COOR 5，CONH 2，CONHR 5，CONR 5 R 6，CN，SR 5，OR 5，C 1 -C 18烷基，C 3 -C 12环烷基，C 6 -C 14芳基或C 2 -C 14杂芳基， C 3 -C 12环烷基，C 6 -C 14芳基或C 2 -C 14杂芳基是未取代的或被一个或多个选自C 1 -C 12烷基，C 3 -C 12环烷基，苯基，卤素和C 1 -C 12烷氧基的基团取代或R 1和R 2一起与其连接的C原子形成4-12元碳环或杂环饱和或不饱和环，其未被取代或被一个或多个选自以下的基团取代：C 1 -C 12烷基，C 3 -C 12环烷基，苯基，卤素和C 1 -C 12烷氧基; R3是F，Cl，OH，OR5，SH，SR5，NH2，NHR5，NR5R6或R1R2C = N-O-; 其中式I化合物中所有基团R1R2C = N-O-中的R1和R2相同或不同; 如果n为1，则R4为F，Cl，OH，OR5，SH，SR5，NH2，NHR5，NR5R6或R1R2C = N-O-; 其中式I化合物中所有基团R1R2C = N-O-中的R1和R2相同或不同; 如果n为2，则R4为衍生自二醇，二胺，氨基醇或巯基醇的双官能团; R 5和R 6彼此独立地是C 1 -C 18烷基，C 3 -C 12环烷基，C 6 -C 14芳基或C 2 -C 14杂芳基; 适合作为自由基产生剂。

2. 发明申请

US20180105719A1 PHOTO-LATENT TITANIUM OXO-CHELATE CATALYSTS 审中-公开
公开(公告)号：US20180105719A1
公开(公告)日：2018-04-19
申请号：US15789548
申请日：2017-10-20
申请人： BASF SE
发明人： Tobias Hintermann , Antoine Carroy , Caroline Lordelot , Didier Bauer , Rachel Kohli Steck , Marc Faller
IPC分类号： C09D175/16 , B01J31/22 , C08G18/22 , C08G18/62 , C09J175/04 , C08G18/68 , B01J31/02 , C08G18/79
CPC分类号： C09D175/16 , B01J31/0208 , B01J31/2234 , B01J2231/14 , B01J2231/48 , B01J2531/46 , C08G18/222 , C08G18/6229 , C08G18/68 , C08G18/792 , C09J175/04 , Y02P20/52
摘要： A titanium-oxo-chelate catalyst formulation, comprising: (i) at least one compound of the formula (I), wherein R1, R2, R3, R4, R5, R6, R7, R8, R9, R10, R11 and R12 independently of each other are for example hydrogen, halogen, C1-C20alkyl, C6-C14aryl which is unsubstituted or substituted; or R1, R2 and R3 and/or R4, R5 and R6 and/or R7, R8 and R9 and/or R10, R11 and R12 together with the C-atom to which they are attached each form a C6-C14aryl group which is unsubstituted or substituted; or R1 and R2 and/or R4 and R5 and/or R7 and R8 and/or R10 and R11 together with the C-atom to which they are attached form a 5- to 7-membered carbocyclic ring; at least one chelate ligand compound of the formula (IIa), (IIb) or (IIc), wherein R1, R2, R3, R4, R5 and R6 are defined as above for formula (I), is suitable as a photolatent catalyst formulation for polymerizing compounds, which are capable to crosslink in the presence of a Lewis acid.

3. 发明授权

US09127098B2 O-imino-iso-urea compounds and polymerizable compositions thereof 有权
标题翻译： O-亚氨基异脲化合物及其可聚合组合物
公开(公告)号：US09127098B2
公开(公告)日：2015-09-08
申请号：US14135788
申请日：2013-12-20
申请人： BASF SE
发明人： Peter Nesvadba , Lucienne Bugnon Folger , Antoine Carroy , Marc Faller , Bruno Spony
IPC分类号： C08F2/46 , C08F2/50 , B29C71/04 , A61L2/08 , A61L24/00 , C08G61/04 , C08F120/18 , C07C275/70 , C08F4/00 , C07C251/58 , C08F8/32 , C09D135/02
CPC分类号： C08F120/18 , C07C251/58 , C07C275/70 , C07C2601/14 , C07C2601/20 , C08F4/00 , C08F8/32 , C09D135/02
摘要： The invention relates to the use of O-imino-iso-urea compounds as source of radicals to polymerizable compositions comprising these O-imino-iso-urea and to new O-imino-iso-urea compounds. The O-Imino-isoureas compounds are compounds of the formula (I) wherein and salts thereof.
摘要翻译：本发明涉及O-亚氨基 - 异脲化合物作为自由基源的用途，其包含这些O-亚氨基 - 异脲和包含新的O-亚氨基 - 异脲化合物的可聚合组合物。 O-亚氨基 - 异脲化合物是式（I）的化合物及其盐。

4. 发明授权

US09255217B2 Iminoxytriazines as radical generators 有权
标题翻译：亚氨基三嗪作为自由基发生剂
公开(公告)号：US09255217B2
公开(公告)日：2016-02-09
申请号：US14437246
申请日：2013-10-22
申请人： BASF SE
发明人： Peter Nesvadba , Lucienne Bugnon Folger , Antoine Carroy , Marc Faller
IPC分类号： C07D251/30 , C07D251/42 , C07D403/14 , C09J133/14 , C09D11/107
CPC分类号： C09J133/14 , C07D251/30 , C07D251/42 , C07D403/14 , C09D11/107
摘要： Iminoxytriazine compounds of the formula I wherein n is 1 or 2; R1 and R2 independently of each other are hydrogen, NH2, NHR5, NR5R6, COR5, COOR5, CONH2, CONHR5, CONR5R6, CN, SR5, OR5, C1-C18alkyl, C3-C12cycloalkyl, C6-C14aryl or C2-C14heteroaryl, wherein said C3-C12cycloalkyl, C6-C14aryl or C2-C14heteroaryl is unsubstituted or substituted by one or more radicals selected from the group consisting of C1-C12alkyl, C3-C12-cycloalkyl, phenyl, halogen and C1-C12 alkoxy, or R1 and R2 together with the C atom to which they are linked form a 4 to 12 membered carbocyclic or heterocyclic saturated or unsaturated ring which is unsubstituted or substituted by one or more radicals selected from the group consisting of C1-C12alkyl, C3-C12-cycloalkyl, phenyl, halogen and C1-C12 alkoxy; R3 is F, Cl, OH, OR5, SH, SR5, NH2, NHR5, NR5R6 or R1R2C═N—O—; wherein R1 and R2 in all groups R1R2C═N—O— in the compound of the formula I are identical or different; if n is 1, R4 is F, Cl, OH, OR5, SH, SR5, NH2, NHR5, NR5R6 or R1R2C═N—O—; wherein R1 and R2 in all groups R1R2C═N—O— in the compound of the formula I are identical or different; if n is 2, R4 is a difunctional group derived from a diol, diamine, aminoalcohol or mercaptoalcohol; R5 and R6 independently of each other are C1-C18alkyl, C3-C12cycloalkyl, C6-C14aryl or C2-C14heteroaryl; are suitable as radical generating agents.
摘要翻译：式I的亚氨基三嗪化合物，其中n为1或2; R 1和R 2彼此独立地是氢，NH 2，NHR 5，NR 5 R 6，COR 5，COOR 5，CONH 2，CONHR 5，CONR 5 R 6，CN，SR 5，OR 5，C 1 -C 18烷基，C 3 -C 12环烷基，C 6 -C 14芳基或C 2 -C 14杂芳基， C 3 -C 12环烷基，C 6 -C 14芳基或C 2 -C 14杂芳基是未取代的或被一个或多个选自C 1 -C 12烷基，C 3 -C 12环烷基，苯基，卤素和C 1 -C 12烷氧基的基团取代或R 1和R 2一起与其连接的C原子形成4-12元碳环或杂环饱和或不饱和环，其未被取代或被一个或多个选自以下的基团取代：C 1 -C 12烷基，C 3 -C 12环烷基，苯基，卤素和C 1 -C 12烷氧基; R3是F，Cl，OH，OR5，SH，SR5，NH2，NHR5，NR5R6或R1R2C = N-O-; 其中式I化合物中所有基团R1R2C = N-O-中的R1和R2相同或不同; 如果n为1，则R4为F，Cl，OH，OR5，SH，SR5，NH2，NHR5，NR5R6或R1R2C = N-O-; 其中式I化合物中所有基团R1R2C = N-O-中的R1和R2相同或不同; 如果n为2，则R4为衍生自二醇，二胺，氨基醇或巯基醇的双官能团; R 5和R 6彼此独立地是C 1 -C 18烷基，C 3 -C 12环烷基，C 6 -C 14芳基或C 2 -C 14杂芳基; 适合作为自由基产生剂。

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