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    • 4. 发明授权
    • Preparation of branched siloxane
    • 支链硅氧烷的制备
    • US06943264B2
    • 2005-09-13
    • US10926081
    • 2004-08-26
    • Yasufumi KubotaTohru Kubota
    • Yasufumi KubotaTohru Kubota
    • C07F7/08C07F7/20C07F7/04
    • C07F7/20C07F7/0874
    • By reacting a branched siloxane compound of formula (2) containing compounds of formula (1) as an impurity with a disiloxane compound of formula (3) in the presence of an acid compound, there is prepared a branched siloxane of formula (2) containing a reduced level of compounds of formula (1). R1nSi(OSiR23)3-n(OR3)  (1) R1nSi(OSiR23)4-n  (2) R23SiOSiR23  (3) R1 is a monovalent hydrocarbon group, R2 and R3 are H or monovalent hydrocarbon groups, and n is 0 or 1.
    • 通过使含有式(1)的化合物作为杂质的式(2)的支链硅氧烷化合物在酸化合物存在下与式(3)的二硅氧烷化合物反应,制备式(2)的支链硅氧烷,其含有 降低水平的式(1)化合物。 <?in-line-formula description =“In-line Formulas”end =“lead”?> R&lt; 1&lt; n&gt;&lt; 3-n(或<3>)(1)<?in-line-formula description =“In-line Formulas”end = “tail”?> <?in-line-formula description =“In-line Formulas”end =“lead”?> R&lt; 1&lt; 2-n(2)<?in-line-formula description =“In-line Formulas”end =“tail”?> < ?in-line-formula description =“In-line Formulas”end =“lead”?> R&lt; 2&lt; 3&gt; SiOSiR&lt; 2&gt; 3(3)<?in-line-formula description =“In-line formula”end =“tail”?> R 1是单价烃基,R 2 R 3和R 3是H或一价烃基,n是0或1。