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1. 发明授权

US4150245A Hydration of olefins using vaporized phosphoric acid 失效
标题翻译：使用汽化磷酸水合烯烃
公开(公告)号：US4150245A
公开(公告)日：1979-04-17
申请号：US864062
申请日：1977-12-23
申请人： August Sommer , Rainer Brucker , Wilhelm Heitmann
发明人： August Sommer , Rainer Brucker , Wilhelm Heitmann
IPC分类号： C07C29/08 , B01J27/00 , C07B61/00 , C07C27/00 , C07C29/04 , C07C31/02 , C07C67/00
CPC分类号： C07C29/04
摘要： A process for the hydration of olefins to prepare alcohol is disclosed, the hydration being effected in the presence of a phosphorus acid-containing catalyst. There is disclosed a process in which vaporized phosphoric acid is admixed with a gas mixture before the same is added to the reactor, the phosphoric acid being in an amount corresponding to the amount of phosphoric acid discharged during the hydration. In such amount the process can be carried out without further phosphoric acid addition.
摘要翻译：公开了烯烃水合制备醇的方法，水合是在含磷酸催化剂存在下进行的。公开了一种方法，其中将蒸发的磷酸与气体混合物混合，然后将其加入到反应器中，磷酸的量相当于在水合期间排出的磷酸的量。在这样的量下，可以在不进一步加入磷酸的情况下进行该方法。

2. 发明授权

US4351970A Method of preparing alcohols having two to four carbon atoms by catalytic hydration of olefins 失效
标题翻译：通过烯烃的催化水合制备具有2至4个碳原子的醇的方法
公开(公告)号：US4351970A
公开(公告)日：1982-09-28
申请号：US151991
申请日：1980-05-21
申请人： August Sommer , Wilhelm Heitmann , Rainer Brucker
发明人： August Sommer , Wilhelm Heitmann , Rainer Brucker
IPC分类号： B01J27/00 , B01J31/00 , C07B61/00 , C07C27/00 , C07C29/04 , C07C31/02 , C07C67/00
CPC分类号： C07C29/04
摘要： A method is disclosed of preparing alcohols having 2 to 4 carbon atoms by catalytic hydration of the corresponding olefins on acid catalysts at elevated temperature and elevated pressure, characterized in that byproducts of the hydration, namely corresponding ethers and/or low-polymerized hydrocarbons and/or undesired alcohols, which form upon the passage of the input product through catalyst bed, are fed to the input product before entry into the reactor, said method being characterized in that:A. When ethylene is the olefin, the reaction is conducted at a temperature of 200.degree.-300.degree. C.; andB: When propylene is the olefin the reaction is conducted at a temperature of 150.degree. to 220.degree. C.
摘要翻译：公开了一种通过在升高的温度和升高的压力下在酸催化剂上催化水合相应的烯烃来制备具有2至4个碳原子的醇的方法，其特征在于水合的副产物，即相应的醚和/或低聚合烃和/ 或在输入产物通过催化剂床时形成的不期望的醇在进入反应器之前被输入到输入产物中，所述方法的特征在于：A.当乙烯是烯烃时，反应在温度在200〜300℃。和B：当丙烯是烯烃时，反应在150-220℃的温度下进行。

3. 发明授权

US4541897A Distillation process for the production of dehydrated ethanol 失效
标题翻译：用于生产脱水乙醇的蒸馏过程
公开(公告)号：US4541897A
公开(公告)日：1985-09-17
申请号：US436945
申请日：1982-10-27
申请人： August Sommer , Rainer Brucker , Wilhelm Heitmann , Norbert Wozny
发明人： August Sommer , Rainer Brucker , Wilhelm Heitmann , Norbert Wozny
IPC分类号： B01D3/00 , B01D3/14 , B01D3/34
CPC分类号： B01D3/146 , B01D3/005 , Y10S203/14
摘要： A distillation process for the production of dehydrated ethanol from dilute aqueous solutions of ethanol characterized in that the distillation is performed in a two-column system wherein the first column--for rectification--is operated under such a pressure that the second column--for dehydration--is heated exclusively with the vapors of the first column; in the first column the concentration of the dilute aqueous ethanol is effected to an ethanol concentration below the composition of the binary ethanol-water azeotrope; the separation of water is effected from the lower layer of the condensed head product of the second column; the separation of impurities and entrainers, having a lower boiling point than ethanol, is effected at the head of the first column and that of impurities, having a higher boiling point, above the feed point of the dilute aqueous solution in the first column; and, in the second column, the dehydration is effected by means of entrainers, with the addition of a fuel component or fuel, to which the ethanol is to be added, if required, while separating the aqueous phase as a head product.
摘要翻译：用于从稀乙醇水溶液中生产脱水乙醇的蒸馏方法，其特征在于，蒸馏是在双塔系统中进行的，其中第一列用于精馏 - 在第二塔 - 在脱水 - 仅用第一列的蒸气加热; 在第一列中，稀乙醇水溶液的浓度达到低于二元乙醇 - 水共沸物组成的乙醇浓度; 水的分离是从第二塔的冷凝头产物的下层进行的; 具有比乙醇沸点低的杂质和夹带剂的分离在第一塔的头部和高沸点的杂质高于第一塔中的稀水溶液的进料点进行; 并且在第二列中，如果需要，在分离水相作为头部产物的同时，借助于夹带剂进行脱水，同时加入添加有乙醇的燃料成分或燃料。

4. 发明授权

US4380509A Method for producing a catalyst for the hydration of olefins 失效
标题翻译：烯烃水合催化剂的制备方法
公开(公告)号：US4380509A
公开(公告)日：1983-04-19
申请号：US246257
申请日：1981-03-23
申请人： August Sommer , Wilhelm Heitmann , Rainer Brucker
发明人： August Sommer , Wilhelm Heitmann , Rainer Brucker
IPC分类号： C07C29/08 , B01J21/16 , B01J27/18 , B01J27/188 , C07C27/00 , C07C29/04 , C07C31/02 , C07C31/08 , C07C31/10 , C07C67/00 , B01J37/02 , B01J21/12
CPC分类号： C07C29/04 , B01J27/18
摘要： A method for producing a carrier for a catalyst comprising the steps of mixing solutions of a soluble salt of aluminum and a soluble salt of silicic acid in a ratio that gives a precipitate comprising aluminum silicate having a weight ratio of Al.sub.2 O.sub.3 :SiO.sub.2 of 1:5 to 1:7, forming the precipitate into a carrier body, consolidating the carrier body by heating, and contacting the carrier body with an acid to reduce the Al.sub.2 O.sub.3 content to 1-5%. Thus produced carrier bodies are useful for catalyzing the hydration of olefins to alcohols when impregnated with phosphoric acid.
摘要翻译：一种制备催化剂载体的方法，包括以下步骤：将可溶性铝的铝盐和可溶性硅酸盐的溶液混合，其比例为包含Al 2 O 3 :SiO 2的重量比为1:5的含硅酸铝的沉淀物至1:7，将沉淀物形成载体体，通过加热固化载体主体，并使载体与酸接触，将Al 2 O 3含量降低至1-5％。这样制得的载体可用于在用磷酸浸渍时催化烯烃与醇的水合作用。

5. 发明授权

US4329257A Method of producing a catalyst from clay minerals for the hydration of olefins 失效
标题翻译：从粘土矿物生产催化剂用于烯烃水合的方法
公开(公告)号：US4329257A
公开(公告)日：1982-05-11
申请号：US171287
申请日：1980-07-23
申请人： August Sommer , Wilhelm Heitmann , Rainer Brucker
发明人： August Sommer , Wilhelm Heitmann , Rainer Brucker
IPC分类号： B01J21/12 , B01J21/16 , B01J27/16 , C07B61/00 , C07C27/00 , C07C29/04 , C07C29/08 , C07C31/02 , C07C67/00 , C07C231/00 , B01J27/14 , B01J29/00
CPC分类号： C07C29/04 , B01J21/16 , B01J27/16
摘要： A method for producing a catalyst comprising phosphoric acid and a carrier, for the hydration of olefins with 2-3 carbon atoms to the corresponding alcohols, the method comprising:contacting a clay, containing essentially montmorillonite, contaminated by no more than 3% accompanying minerals and containing up to 0.5% by weight K.sub.2 O, or a mineral of the montmorillonite group, containing no potassium, but having the montmorillonite crystalline lattice, with an acid until it has an Al.sub.2 O.sub.3 content of 13-18% by weight and a surface area of 200-400 m.sup.2 /g;admixing the so-treated clay with 5-15% by weight, based on the total dry admixture, of one or more oxides of metals of Group VI of the Periodic System;adjusting the water content of the admixture to 20-35% by weight;pressing the admixture into a desired shape and calcining at 500.degree.-800.degree. C.;treating the so-formed carrier material with an acid until it has an Al.sub.2 O.sub.3 content of 1-5% by weight and a specific surface area of 150-250 m.sup.2 /g; andthen impregnating the resulting carrier with phosphoric acid; and the catalysts so-produced are disclosed.
摘要翻译：一种用于生产包含磷酸和载体的催化剂的方法，用于将具有2-3个碳原子的烯烃水合至相应的醇，该方法包括：使含有不超过3％的伴随矿物质的基本上蒙脱石的粘土并且含有至多0.5重量％的K 2 O或蒙脱石组的矿物，不含钾，但具有蒙脱石晶格的酸，直至其具有13-18重量％的Al 2 O 3含量，并且表面积 200-400 m2 / g; 将经处理的粘土与基于总干混合物的5-15重量％的一种或多种周期系统的第VI族金属氧化物混合; 调整混合物的含水量为20-35重量％; 将混合物压制成所需形状并在500-800℃下煅烧。

6. 发明授权

US4299730A Process for the production of a catalyst for the hydration of olefins into alcohols 失效
标题翻译：制备用于将烯烃水合成醇的催化剂的方法
公开(公告)号：US4299730A
公开(公告)日：1981-11-10
申请号：US124758
申请日：1980-02-26
申请人： August Sommer , Rainer Brucker
发明人： August Sommer , Rainer Brucker
IPC分类号： B01J21/16 , B01J27/16 , C07C27/00 , C07C29/04 , C07C29/08 , C07C31/02 , C07C67/00 , B01J27/14 , B01J29/06
CPC分类号： B01J27/16 , B01J21/16 , C07C29/04
摘要： A process for producing a clay-containing catalyst for the hydration of olefins having 2-3 carbon atoms into alcohols, which comprises: (A) acid-treating a montmorillonite-containing clay which is contaminated by not more than 3% of quartz, feldspar or mica, and which may contain up to 0.5% of K.sub.2 O, until the clay has an Al.sub.2 O.sub.3 content of 13-18% by weight, thereby obtaining a surface area of 200-400 m.sup.2 /g; (B) molding the clay at a total water content of 20-35%; (C) calcining at 500.degree.-800.degree. C.; (D) acid-treating the molded and calcined clay to an Al.sub.2 O.sub.3 content of 1-5% by weight, thereby obtaining a surface area of 150-250 m.sup.2 /g; and (E) impregnating said material with phosphoric acid.
摘要翻译：一种制备用于使具有2-3个碳原子的烯烃水合成醇的含粘土催化剂的方法，其包括：（A）酸性处理被不超过3％的石英，长石污染的含蒙脱石的粘土或云母，并且其可以含有高达0.5％的K 2 O，直到粘土具有13-18重量％的Al 2 O 3含量，从而获得200-400m 2 / g的表面积; （B）以20-35％的总含水量成型粘土; （C）在500〜800℃下煅烧。（D）将成型和煅烧的粘土酸化至1-5重量％的Al 2 O 3含量，从而获得150-250m2 / g的表面积; 和（E）用磷酸浸渍所述材料。

7. 发明授权

US4065506A Continuous process for refining glyoxal 失效
标题翻译：炼制乙二醛的连续工艺
公开(公告)号：US4065506A
公开(公告)日：1977-12-27
申请号：US573197
申请日：1975-04-30
申请人： Richard Wessendorf , August Sommer , Heinrich Birkelbach
发明人： Richard Wessendorf , August Sommer , Heinrich Birkelbach
IPC分类号： C07C47/127 , C07C45/00 , C07C45/28 , C07C45/79 , C07C45/85 , C07C67/00 , C07C47/02
CPC分类号： C07C45/79 , C07C45/28 , C07C45/85
摘要： An improvement in a process for refining crude glyoxal solutions, especially those obtained by the oxidation of acid aldehyde with nitric acid, wherein the crude glyoxal solution, free of volatile acids, is neutralized, the glyoxal is transformed to the glyoxal semiacetal with an alcohol having 1 to 3 carbon atoms and, after separation of the salts and other impurities, is again hydrolized with water at elevated temperatures. The improvement described involves continuously extracting the glyoxal semiacetal formed with an organic solvent which is immiscible with water, hydrolyzing the extracted glyoxal semiacetal and refining the aqueous glyoxal solution obtained with active charcoal.
摘要翻译：精制粗乙二醛溶液的方法的改进，特别是通过用硝酸氧化酸醛获得的方法，其中中和不含挥发性酸的粗乙二醛溶液，乙二醛转化为乙二醛半缩醛，其醇具有在分离盐和其他杂质之后，在高温下再次用水水解1至3个碳原子。所述的改进涉及连续提取与水不混溶的有机溶剂形成的乙二醛半缩醛，水解提取的乙二醛半缩醛并精制用活性炭得到的乙二醛水溶液。

8. 发明授权

US4006189A Process for purifying glyoxal 失效
标题翻译：纯化乙二醛的方法
公开(公告)号：US4006189A
公开(公告)日：1977-02-01
申请号：US478431
申请日：1974-06-11
申请人： August Sommer , Richard Wessendorf
发明人： August Sommer , Richard Wessendorf
IPC分类号： C07C47/127 , C07C45/00 , C07C45/28 , C07C45/85 , C07C67/00 , C07C47/02
CPC分类号： C07C45/28 , C07C45/85
摘要： Crude glyoxal solutions obtained for example by the oxidation of acetaldehyde with nitric acid are purified by removing volatile acids followed by neutralization. Thereafter, the glyoxal is converted into a glyoxal glyoxal-di-(alkylhemiacetal) with an alcohol containing 1 to 3 carbon atoms with water removal during the conversion. After separating salts and other impurities, the glyoxal-di-(alkylhemiacetal) is hydrolyzed with water at elevated temperatures to yield pure glyoxal hydrate.
摘要翻译：通过例如通过用硝酸氧化乙醛获得的粗乙二醛溶液通过除去挥发性酸然后中和来纯化。此后，在转化过程中，乙二醛转化为含有1至3个碳原子的醇，并除去水分子的乙二醛乙二醛 - 二 - （烷基缩醛）。分离盐和其他杂质后，乙二醛 - 二（烷基缩醛）在高温下用水水解，得到纯的乙醛酸水合物。

9. 发明授权

US4808559A Method of manufacturing a catalyst for hydration of olefins to alcohols 失效
标题翻译：制造用于将烯烃水合成醇的催化剂的方法
公开(公告)号：US4808559A
公开(公告)日：1989-02-28
申请号：US151194
申请日：1988-02-01
申请人： August Sommer , Dietrich Schlueter
发明人： August Sommer , Dietrich Schlueter
IPC分类号： B01J21/08 , B01J21/16 , B01J27/16 , C07C27/00 , C07C29/04 , C07C31/08 , C07C31/10 , C07C67/00 , B01J21/04 , B01J21/06
CPC分类号： B01J21/16 , B01J27/16
摘要： A method of manufacturing a catalyst for hydration of olefins to alcohols. A montmorillonite-containing clay is employed as a catalyst support for phosphoric acid, to which a fine-grained silica gel is added after a first acid treatment. The silica gel has a particle size distribution between 30 and 60 micron, a pore volume of 0.9-1.7 ml/g, and a specific surface of 200-500 sq m/g.
摘要翻译：一种制备用于将烯烃水合成醇的催化剂的方法。使用含蒙脱土的粘土作为磷酸的催化剂载体，在第一次酸处理后加入细粒硅胶。硅胶的粒度分布为30至60微米，孔体积为0.9-1.7毫升/克，比表面积为200-500平方米/克。

10. 发明授权

US3955939A Extractive distillation of isopropyl alcohol with an ether solvent recovered from the initial feed 失效
标题翻译：从初始进料中回收异丙醇与醚溶剂的萃取蒸馏
公开(公告)号：US3955939A
公开(公告)日：1976-05-11
申请号：US403688
申请日：1973-10-04
申请人： August Sommer , Martin Urban
发明人： August Sommer , Martin Urban
IPC分类号： C10L1/182 , C07C27/00 , C07C29/04 , C07C31/10 , C07C67/00 , C10L1/18 , C10L1/185 , F02B1/04 , C10L1/02
CPC分类号： C10L1/18 , C10L1/1824 , C10L1/1852 , F02B1/04
摘要： A water-free mixture of isopropyl alcohol, diisopropyl alcohol, diisopropyl ether and by-products is made by the catalytic hydration of propylene in the gaseous phase at temperatures of 140.degree.-170.degree.C under pressures of 25-40 atmospheres gauge. A water-to-propylene molar ratio of 0.1 to 0.25:1 is maintained in the hydration reaction. The crude product from the hydration reaction is dehydrated or dewatered in two columns without using a foreign withdrawing agent. Instead, diiosopropyl ether formed in the process itself is utilized as the withdrawing agent which is subsequently added to the water-free mixture together with additionally formed by-products. The water-free mixture formed according to the process can be used directly as an additive to gasoline fuel for motor vehicles.
摘要翻译：异丙醇，二异丙醇，二异丙基醚和副产物的无水混合物是通过丙烯在气相中在140〜170℃的温度下在25-40大气压的压力下进行催化水合制备的。在水合反应中维持水与丙烯的摩尔比为0.1至0.25：1。来自水化反应的粗产物在不使用异氰酸酯的情况下在两个塔中脱水或脱水。相反，在该方法中形成的二异丙醚本身可用作萃取剂，随后将其与附加形成的副产物一起加入到无水混合物中。根据该方法形成的无水混合物可以直接用作汽车用汽油的添加剂。

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