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1. 发明授权

US4803238A Polymer composition 失效
标题翻译：聚合物组成
公开(公告)号：US4803238A
公开(公告)日：1989-02-07
申请号：US115548
申请日：1987-10-29
申请人： Atsushi Sato , Keiji Endo , Shigenobu Kawakami , Eiichi Matsuzaka , Satoshi Narui
发明人： Atsushi Sato , Keiji Endo , Shigenobu Kawakami , Eiichi Matsuzaka , Satoshi Narui
IPC分类号： C07C6/12 , B01J27/10 , C07B61/00 , C07C1/00 , C07C7/148 , C07C15/02 , C07C15/12 , C07C67/00 , C08K5/01 , C08C11/22 , C08C13/04
CPC分类号： C08K5/01
摘要： A compounding oil for polymers which can be used as a plasticizer, process oil, thinner, softening agent, extender or the like. The compounding oil of the invention comprises a fraction mainly containing triaryldialkanes and having boiling points in the range of 350.degree. to 450.degree. C., which fraction is prepared by disproportionating a by-product oil fraction at temperatures in the range of 20.degree. to 500.degree. C. in the presence of a disproportionation catalyst, said by-product oil fraction mainly containing diarylalkanes, having boiling points in the range of 260.degree. to 320.degree. C., and being obtained from the process to prepare alkylated monocyclic aromatic hydrocarbons by alkylating monocyclic aromatic hydrocarbons with olefins in the presence of an alkylation catalyst.
摘要翻译：可用作增塑剂，加工油，稀释剂，软化剂，增量剂等的用于聚合物的复合油。本发明的配混油包含主要含有三芳基二烷并且沸点在350-450℃范围内的馏分，该馏分通过在20℃至500℃的温度范围内歧化副产物油馏分在歧化催化剂的存在下，所述副产物油馏分主要含有二芳基烷烃，沸点在260至320℃范围内，并且是从通过烷基化制备烷基化单环芳烃的方法获得的在烷基化催化剂存在下，使烯烃单环芳烃。

2. 发明授权

US4642730A Electrical insulating oil and oil-filled electrical appliances 失效
标题翻译：电绝缘油和充油电器
公开(公告)号：US4642730A
公开(公告)日：1987-02-10
申请号：US760402
申请日：1985-07-30
申请人： Atsushi Sato , Keiji Endo , Shigenobu Kawakami , Eiichi Matsuzaka , Satoshi Narui
发明人： Atsushi Sato , Keiji Endo , Shigenobu Kawakami , Eiichi Matsuzaka , Satoshi Narui
IPC分类号： H01B3/20 , H01B3/22 , H01G4/22
CPC分类号： H01B3/22
摘要： An improved electrical insulating oil and oil-filled electrical appliances impregnated therewith. The electrical insulating oil can be produced inexpensively but has excellent electrical characteristics and it comprises a fraction having boiling points in the range of 350.degree. to 450.degree. C. that is prepared by disproportionating diarylalkane or a hydrocarbon mixture mainly containing the same at temperatures in the range of 20.degree. to 500.degree. C. in the presence of a disproportionation catalyst, said diarylalkane having boiling points in the range of 260.degree. to 320.degree. C.
摘要翻译：改进的电绝缘油和浸油的电油器具。电绝缘油可以廉价地生产，但是具有优异的电特性，并且它包括沸点在350-450℃范围内的馏分，其通过歧化二芳基烷烃或主要含有它们的烃混合物在歧化催化剂存在下，在20〜500℃的范围内，所述二芳基烷烃的沸点在260〜320℃的范围内。

3. 发明授权

US4686548A Pressure-sensitive recording material 失效
标题翻译：压敏记录材料
公开(公告)号：US4686548A
公开(公告)日：1987-08-11
申请号：US745317
申请日：1985-06-14
申请人： Naoya Takahashi , Keiji Endo , Eiichi Matsuzaka , Satoshi Narui , Atsushi Sato
发明人： Naoya Takahashi , Keiji Endo , Eiichi Matsuzaka , Satoshi Narui , Atsushi Sato
IPC分类号： B41M5/165 , B41M5/16 , B41M5/22
CPC分类号： B41M5/1655
摘要： A pressure-sensitive recording material of the type which is prepared by using an electron donating dye-precursor that produces a color when the dye-precursor is brought into contact with an electron accepting color developer. The pressure-sensitive recording material is characterized in that the solvent for said dye-precursor comprises an alkylated fraction which is prepared by alkylating a by-product fraction with at least one alkyl group having 1 to 5 carbon atoms, the by-product fraction containing the components within the boiling range of 255.degree. to 300.degree. C. on the atmospheric pressure basis and being obtained in the process for producing ethylbenzene or ethyltoluene from ethylene and benzene or toluene. The pressure-sensitive recording material of the invention has scarcely offensive odor and can develop a dense color with a higher color developing rate.
摘要翻译：一种压敏记录材料，其是通过使用当染料前体与电子接受显色剂接触时产生颜色的给电子染料前体制备的。压敏记录材料的特征在于，用于所述染料前体的溶剂包括烷基化部分，其通过用至少一个具有1至5个碳原子的烷基烷基化副产物部分制备，副产物部分含有该成分在大气压的基础上在255〜300℃的沸点范围内，并且在从乙烯和苯或甲苯生产乙苯或乙基甲苯的方法中得到。本发明的压敏记录材料几乎没有异味，并且可以产生具有更高显色速率的致密颜色。

4. 发明授权

US4661165A Solvent for the dye of pressure-sensitive recording paper 失效
标题翻译：压敏记录纸染料的溶剂
公开(公告)号：US4661165A
公开(公告)日：1987-04-28
申请号：US745909
申请日：1985-06-18
申请人： Shigenobu Kawakami , Eiichi Matsuzaka , Satoshi Narui , Naoya Takahashi
发明人： Shigenobu Kawakami , Eiichi Matsuzaka , Satoshi Narui , Naoya Takahashi
IPC分类号： B41M5/00 , B41M5/165 , C08K3/00 , C09D11/00
CPC分类号： B41M5/1655
摘要： A solvent for the dye of pressure-sensitive recording paper which solvent has no offensive odor and both the color developing rate and the density of developed color are excellent. The solvent is characterized in that it comprises a fraction having boiling points in the range of 270.degree. to 350.degree. C. which is prepared by distilling the heavier products obtained from the process for producing ethyltoluene by alkylating toluene with ethylene in the presence of synthetic zeolite catalyst.
摘要翻译：用于溶剂没有异味和压力敏感记录纸的染料的溶剂，显色性和显色浓度均优异。溶剂的特征在于其包含沸点在270-350℃范围内的馏分，其通过在合成沸石存在下将乙烯甲苯与甲苯烷基化，从蒸馏生产乙基甲苯的方法中得到的较重产物催化剂。

5. 发明授权

US4879269A Pressure sensitive copy material 失效
标题翻译：压敏复印材料
公开(公告)号：US4879269A
公开(公告)日：1989-11-07
申请号：US333791
申请日：1989-04-03
申请人： Naoya Takahashi , Satoshi Narui , Eiichi Matsuzaka
发明人： Naoya Takahashi , Satoshi Narui , Eiichi Matsuzaka
IPC分类号： C09B11/00 , B41M5/165 , C09B11/02
CPC分类号： B41M5/1655 , Y10S428/914
摘要： The present invention provides a pressure sensitive copy material using an electron accepting developer and an electron donating coupler which develops a color by contacting with the developer, the pressure sensitive copy material being characterized by employing phenyl-sec-butylphenyl-methane as a solvent for the electron donating coupler.
摘要翻译：本发明提供使用电子接受显影剂和给电子偶联剂的压敏复制材料，其通过与显影剂接触而显色，该压敏复制材料的特征在于使用苯基仲丁基苯基甲烷作为溶剂给电耦合器。

6. 发明授权

US4144279A Aralkylation of alkylbenzenes 失效
标题翻译：烷基苯的烷基化
公开(公告)号：US4144279A
公开(公告)日：1979-03-13
申请号：US898328
申请日：1978-04-20
申请人： Atsushi Sato , Isoo Shimizu , Eiichi Matsuzaka
发明人： Atsushi Sato , Isoo Shimizu , Eiichi Matsuzaka
IPC分类号： B01J21/00 , C07B61/00 , C07C1/00 , C07C2/66 , C07C2/70 , C07C15/16 , C07C67/00 , C10G57/00 , H01B3/20 , H01B3/22 , C07C3/10
CPC分类号： C07C2/66 , C10G57/005 , C07C2521/12
摘要： The present invention provides a process for aralkylation of alkylbenzenes wherein an alkylbenzene or alkylbenzenes containing in the substituent alkyl group or groups from 1 to 4 carbon atoms in total is aralkylated with at least one styrene selected from the group consisting of styrene, vinyltoluenes and .alpha.-methylstyrene which comprises carrying out the reaction by continuously feeding to a catalyst layer the above-mentioned alkylbenzene or alkylbenzenes and styrene sources in liquid phase at a temperature from 100.degree. C. to 200.degree. C., said catalyst layer being filled with synthetic silica-alumina containing from 20% by weight to 50% by weight alumina that has been calcined at a temperature in the range from 450.degree. C. to 600.degree. C.
摘要翻译：本发明提供烷基苯的芳烷基化方法，其中在取代烷基中含有的烷基苯或烷基苯或总共1-4个碳原子的烷基苯与至少一种选自苯乙烯，乙烯基甲苯和α-烯烃的苯乙烯芳烷基化，甲基苯乙烯，其包括通过在100℃至200℃的温度下以液相连续地向催化剂层供给上述烷基苯或烷基苯和苯乙烯源进行反应，所述催化剂层填充有合成二氧化硅 - 氧化铝，其含有在450℃至600℃的温度下煅烧的20重量％至50重量％的氧化铝。

7. 发明授权

US4287376A Method for aralkylation 失效
标题翻译：芳烷基化方法
公开(公告)号：US4287376A
公开(公告)日：1981-09-01
申请号：US60662
申请日：1979-07-25
申请人： Isoo Shimizu , Okitsugu Tsuji , Eiichi Matsuzaka , Atsushi Sato
发明人： Isoo Shimizu , Okitsugu Tsuji , Eiichi Matsuzaka , Atsushi Sato
IPC分类号： C07C1/00 , C07C2/70 , C07C2/72 , C07C15/16 , C07C67/00 , C07C2/66
CPC分类号： C07C2/70 , C07C2531/025
摘要： A method for aralkylation of benzene or alkylbenzenes which is characterized in that an aromatic olefin having a double bond or double bonds which are conjugated with the benzene ring is added to the benzene or alkylbenzenes in the presence of at least one member of catalyst selected from the group consisting of the compounds represented by the general formula:C.sub.n F.sub.2n+1-m Cl.sub.m SO.sub.3 Hin which the symbol n is an integer from 1 to 5 and m is 0 or 1. Since the selectivity to the aromatic olefin in the reaction is excellent, the mixture of aromatic olefins and aliphatic olefins can be employed as one of the starting material.
摘要翻译：苯或烷基苯的芳烷基化方法，其特征在于，在至少一种选自以下的催化剂成分存在下，将与苯环共轭的具有双键或双键的芳族烯烃加成到苯或烷基苯中由以下通式表示的化合物：CnF2n + 1-mClmSO3H，其中符号n为1至5的整数，m为0或1.由于反应中芳族烯烃的选择性优异，因此混合物的芳族烯烃和脂肪族烯烃可以用作原料之一。

8. 发明授权

US4254292A Method for preparing polycyclic aromatic hydrocarbons 失效
标题翻译：制备多环芳烃的方法
公开(公告)号：US4254292A
公开(公告)日：1981-03-03
申请号：US85979
申请日：1979-10-18
申请人： Isoo Shimizu , Okitsugu Tsuji , Eiichi Matsuzaka , Atsushi Sato
发明人： Isoo Shimizu , Okitsugu Tsuji , Eiichi Matsuzaka , Atsushi Sato
IPC分类号： C07C2/64 , B01J31/00 , C07B61/00 , C07C1/00 , C07C2/04 , C07C2/66 , C07C2/70 , C07C15/12 , C07C15/16 , C07C67/00 , H01B3/22 , C07C2/20
CPC分类号： H01B3/22 , C07C15/12 , C07C15/16 , C07C2/04 , C07C2/70 , C07C2531/025
摘要： A method for preparing polycyclic aromatic hydrocarbons with excellent yield and selectivity but without the formation of cyclic dimers and other undesirable by-products. In the method of the present invention, styrene, .alpha.-methylstyrene, .beta.-methylstyrene and/or vinyltoluene is dimerized and/or codimerized to produce unsaturated dimer and/or codimer in the first step reaction and said unsaturated dimer and/or codimer is caused to react with an aromatic hydrocarbon or hydrocarbons in the second step reaction, and both the first and second step reactions are carried out in the presence of a catalyst which is represented by the general formula: RCF.sub.2 SO.sub.3 H, in which the symbol R is Cl, F or C.sub.n F.sub.p CL.sub.2n+1-p, wherein n is an integer from 1 to 3 and p is also an integer from 1 to 2n+1.
摘要翻译：制备多环芳烃的方法，其产率和选择性优异但不形成环状二聚体和其它不希望的副产物。在本发明的方法中，在第一步反应中苯乙烯，α-甲基苯乙烯，β-甲基苯乙烯和/或乙烯基甲苯被二聚化和/或同步化以产生不饱和二聚体和/或共二聚体，并引起所述不饱和二聚体和/或同系物在第二步反应中与芳族烃或烃反应，第一步和第二步反应在由以下通式表示的催化剂的存在下进行：RCF2SO3H，其中符号R为Cl，F 或CnFpCL2n + 1-p，其中n是1至3的整数，p也是1至2n + 1的整数。

9. 发明授权

US4208268A Method of processing thermal cracked by-product oil 失效
标题翻译：热裂解副产物油的加工方法
公开(公告)号：US4208268A
公开(公告)日：1980-06-17
申请号：US890302
申请日：1978-03-27
申请人： Atsushi Sato , Isoo Shimizu , Eiichi Matsuzaka
发明人： Atsushi Sato , Isoo Shimizu , Eiichi Matsuzaka
IPC分类号： C10G57/00 , C07C1/00 , C07C2/54 , C07C2/70 , C07C7/148 , C07C15/20 , C07C67/00 , C10G29/12 , C10G29/16 , C10G50/00 , C10G55/04 , H01B3/20 , C10G17/00 , C10G29/00
CPC分类号： C07C7/148 , C10G2400/30
摘要： This invention provides a method of processing thermal cracked by-product oil which comprises reacting a distillate from a thermal cracked by-product oil principally containing components of a boiling range between 75.degree. C. and 198.degree. C. said distillate being one of the distillates from the cracking of petroleum hydrocarbons at a cracking temperature of 700.degree. C. or higher, and containing a ratio of 5-100 molar percent aromatic olefins to non-olefinic aromatic hydrocarbons, in liquid phase in the presence of an acid catalyst under such conditions that the reaction temperature is 0.degree. C.-200.degree. C., the liquid residence time is 0.1 hour-5 hours and wherein the content of aromatic olefins in the reaction system are 5% by weight or less at the end of the reaction, to yield a processed distillate containing non-condensed di- and tricyclic aromatic compounds which are reaction products of aromatic olefins with other aromatic hydrocarbons but no substantial amount of unsaturated components.
摘要翻译：本发明提供了一种处理热裂化的副产物油的方法，该方法包括使主要含有沸点范围在75℃至198℃的组分的热裂解副产物油的馏出物反应。所述馏出物是馏出物之一在70℃以上的裂解温度下，在酸性催化剂的存在下，在这样的条件下，在液相中含有5-100摩尔％的芳香族烯烃与非烯烃芳香烃的比例的石油烃的裂化反应温度为0℃-200℃，液体停留时间为0.1小时-5小时，其中反应体系中芳族烯烃的含量为5重量％以下，得到含有非缩合二环和三环芳族化合物的处理过的馏出物，它们是芳族烯烃与其它芳族烃的反应产物，但没有显着量的不饱和成分 ts。

10. 发明授权

US4175278A Electric insulating oil compositions 失效
标题翻译：电绝缘油组合物
公开(公告)号：US4175278A
公开(公告)日：1979-11-20
申请号：US894117
申请日：1978-04-06
申请人： Atsushi Sato , Isoo Shimizu , Eiichi Matsuzaka
发明人： Atsushi Sato , Isoo Shimizu , Eiichi Matsuzaka
IPC分类号： H01B3/20 , H01B3/22 , H01B13/30 , H01G4/04 , H01G4/22 , C10G37/08 , H01B7/00
CPC分类号： H01B3/22 , H01B13/30 , H01G4/04 , H01G4/221
摘要： The present invention provides novel electric insulating oil compositions and a process for preparing the same. The electric insulating compositions of the invention comprise distillates within a boiling range in terms of normal pressure between 265.degree. C. and 360.degree. C. obtained by processing a hydrocarbon mixture from cracking of petroleum hydrocarbons at a temperature of 700.degree. C. or higher principally composed of components with a boiling range between 75.degree. C. and 198.degree. C., said components mainly containing monocyclic aromatics and comprising aromatic olefins of said boiling range, in liquid phase in the presence of an acid catalyst under such conditions that the reaction temperature is from 0.degree. C. to 200.degree. C., the liquid residence time is from 0.1 hour to 5 hours and the concentration of aromatic olefins in the reaction system is 10% by weight or below.
摘要翻译：本发明提供新型的电绝缘油组合物及其制备方法。本发明的电绝缘组合物包括馏出物在沸点范围内，通常在265℃和360℃之间的常压下，通过在700℃或更高的温度下处理烃混合物从石油烃的裂解中获得由沸点范围在75℃和198℃之间的组分组成，所述组分主要含有单环芳族化合物，并且包含所述沸点范围的芳族烯烃，在酸催化剂存在下，在反应温度为0℃〜200℃，液体停留时间为0.1小时〜5小时，反应体系中芳族烯烃的浓度为10重量％以下。

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