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1. 发明授权

US07038024B2 Fibre-reactive azo dyes, their preparation and their use 失效
标题翻译：纤维反应偶氮染料，其制备及其用途
公开(公告)号：US07038024B2
公开(公告)日：2006-05-02
申请号：US10492181
申请日：2002-10-04
申请人： Athanassios Tzikas , Bernhard Müller
发明人： Athanassios Tzikas , Bernhard Müller
IPC分类号： C09B62/507 , D06P1/38
CPC分类号： C09B62/4415 , C09B62/51 , C09B62/513
摘要： Reactive dyes containing at least one structural unit of formula (I), wherein Y is vinyl or a radical —CH2—CH2—U and U is a group removable under alkaline conditions, are suitable for dyeing cellulosic or amide-group-containing fiber materials.
摘要翻译：含有至少一种式（I）结构单元的反应性染料，其中Y是乙烯基或基团-CH 2 -CH 2 -NU，U是可以在碱性条件适用于染色含纤维素或含酰胺基的纤维材料。

2. 发明授权

US06670457B2 Reactive dyes, their preparation and use 失效
标题翻译：活性染料，其制备和用途
公开(公告)号：US06670457B2
公开(公告)日：2003-12-30
申请号：US10222309
申请日：2002-08-16
申请人： Rolf Deitz , Bernhard Müller , Athanassios Tzikas
发明人： Rolf Deitz , Bernhard Müller , Athanassios Tzikas
IPC分类号： C09B6233
CPC分类号： C09B62/4411
摘要： Compounds of the formula in which the variables are as defined in the claims, which are suitable as fiber-reactive dyes for dyeing widely varying fiber materials, are described.
摘要翻译：描述了变体如权利要求中所定义的适合用作染色广泛变化的纤维材料的纤维活性染料的形式的化合物。

3. 发明授权

US07122667B2 Fibre-reactive dyes, their preparation and their use 失效
标题翻译：纤维活性染料，其制备及其用途
公开(公告)号：US07122667B2
公开(公告)日：2006-10-17
申请号：US10494393
申请日：2002-10-29
申请人： Athanassios Tzikas , Bernhard Müller
发明人： Athanassios Tzikas , Bernhard Müller
IPC分类号： C07D251/70 , C09B44/18 , C09B62/08 , C09B62/16 , C09B62/24 , C09B62/32
CPC分类号： D06P1/382 , C09B62/0061 , C09B62/01 , C09B62/4411 , D06P3/148 , D06P3/66
摘要： Reactive dyes of formula (1) wherein Q1, Q2, Q3 and Q4 are each independently of the others hydrogen or unsubstituted or substituted C1–C4alkyl, A is the radical of a monoazo, polyazo, metal complex azo, anthraquinone, phthalocyanine, formazan or dioxazine chromophore, D is the radical of a diazo component, of the benzene or naphthalene series, X is halogen, 3-carboxpyridin-1-yl, 3-carbamoylpyridin-1-yl, hydroxy, C1–C4alkoxy unsubstituted or substituted in the alkyl moiety, phenoxy unsubstituted or substituted in the phenyl moiety, C1–C4alkylthio unsubstituted or substituted in the alkyl moiety, unsubstituted or substituted amino, or an N-heterocycle which may or may not contain further hetero atoms, and Y is vinyl or a radical —CH2—CH2—U and U is a group removable under alkaline conditions, are suitable for dyeing cellulosic or amide-group-containing fibre materials.
摘要翻译：其中Q 1，Q 2，Q 3和Q 4的式（1）的活性染料各自独立地的另一些氢或未取代或取代的C 1 -C 4烷基，A是单偶氮，多偶氮，金属络合物偶氮，蒽醌，酞菁，甲an或二恶嗪的基团发色团，D是苯或萘系的重氮组分的基团，X是卤素，3-羧基吡啶-1-基，3-氨基甲酰基吡啶-1-基，羟基，C 1 - 在烷基部分中未取代或取代的C 4烷氧基，未取代或在苯基部分取代的苯氧基，未取代或取代的C 1 -C 4烷基硫基在烷基部分，未取代或取代的氨基或可以含有其它杂原子的N-杂环，Y是乙烯基或基团-CH 2 -CH 2，在碱性条件下可以除去基团，适用于染色纤维素或含酰胺基的纤维 e材料。

4. 发明授权

US07087730B2 Fiber-reactive azo dyes, their preparation and their use 失效
标题翻译：纤维反应偶氮染料，其制备及其用途
公开(公告)号：US07087730B2
公开(公告)日：2006-08-08
申请号：US10523241
申请日：2003-07-15
申请人： Athanassios Tzikas , Bernhard Müller , Georg Roentgen
发明人： Athanassios Tzikas , Bernhard Müller , Georg Roentgen
IPC分类号： C09B62/507 , C09B62/08 , D06P1/384 , C09D11/02
CPC分类号： C09B62/4411
摘要： Reactive dyes of formula (I), wherein A is the radical of a monoazo, polyazo, metal complex azo, anthraquinone, phthalocyanine, formazan or dioxazine chromophore, Q1, and Q2 are each independently of the other hydrogen or unsubstituted or substituted C1–C4alkyl, (Q3)n denotes n substituents selected from the group C1–C4alkyl, C1–C4alkoxy, halogen and sulfo, X is halogen, 3-carboxypyridin-1-yl, 3-carbamoylpyridin-1-yl, hydroxy, C1–C4alkoxy unsubstituted or substituted in the alkyl moiety, phenoxy unsubstituted or substituted in the phenyl moiety, C1–C4alkylthio unsubstituted or substituted in the alkyl moiety, unsubstituted or substituted amino, or an N-heterocycle which may or may not contain further hetero atoms, Y is vinyl or a radical —CH2—CH2—U and U is a group removable under alkaline conditions, k is a number 2, 3, 4, 5 or 6, m is a number 0 or 1, and n is a number 0, 1 or 2, with the proviso that when A denotes a monoazo chromophore it is not directly linked to the triazinyl radical through a hydroxynaphthalenesulfonic acid coupling component and does not denote a radical of formula (II), are suitable for dyeing cellulosic or nitrogen-containing fiber materials
摘要翻译：式（I）的活性染料，其中A是单偶氮，多偶氮，金属络合物偶氮，蒽醌，酞菁，甲an或二恶嗪发色团，Q 1和Q 2的基团，（III）各自独立地为另一个氢或未取代或取代的C 1 -C 4烷基，（Q 3 N） / SUB>表示选自C 1 -C 4烷基，C 1 -C 4烷基，C 1 -C 4烷基，烷氧基，卤素和磺基，X是卤素，3-羧基吡啶-1-基，3-氨基甲酰基吡啶-1-基，羟基，未取代的或未取代的C 1 -C 4烷氧基在烷基部分被取代的苯基部分中未取代或取代的苯氧基，未取代或未取代的烷基部分的未取代或取代的未取代或取代的氨基的C 1 -C 4 - 可以含有或可以不含有其它杂原子的N-杂环，Y是乙烯基或基团-CH 2 -CH 2 -O-U，U是在碱性条件下可除去的基团，k是麻木呃2，3，4，5或6，m是数字0或1，n是数字0,1或2，条件是当A表示单偶氮发色团时，它不直接与三嗪基直接连接，羟基萘磺酸偶联组分并不表示式（II）的基团，适用于染色纤维素或含氮纤维材料

5. 发明申请

US20100151134A1 MIXTURES OF REACTIVE DYES AND THEIR USE 审中-公开
标题翻译：反应性染料的混合物及其使用
公开(公告)号：US20100151134A1
公开(公告)日：2010-06-17
申请号：US12711774
申请日：2010-02-24
申请人： Athanassios Tzikas , Georg Roentgen
发明人： Athanassios Tzikas , Georg Roentgen
IPC分类号： C09B62/006 , C09D11/02 , B05D5/00
CPC分类号： D06P3/666 , C09B62/09 , C09B67/0042 , C09B67/0044 , C09B67/0057 , C09B67/0058 , C09D11/328 , D06P1/38 , D06P3/148 , D06P5/30
摘要： Dye mixtures comprisingat least one dye of formula together with at least one dye from the group of formulae wherein the radicals have the definitions given in the claims, are suitable for dyeing or printing cellulose-containing fibre materials, while at the same time exhibiting good build-up behaviour, and yield dyeings of deep shade having good fastness properties.
摘要翻译：包含至少一种下式的染料的染料混合物与至少一种下式的染料组合，其中基团具有权利要求中给出的定义，适用于染色或印刷含纤维素的纤维材料，同时表现出良好的性能积累行为，以及具有良好牢度性质的深色染色产量染色。

6. 发明申请

US20100077555A1 MIXTURES OF REACTIVE DYES AND THEIR USE IN A METHOD FOR TRICHROMATIC DYEING OR PRINTING 有权
标题翻译：反应性染料的混合物及其在三色染色或印刷方法中的应用
公开(公告)号：US20100077555A1
公开(公告)日：2010-04-01
申请号：US12513464
申请日：2007-10-30
申请人： Georg Roentgen , Athanassios Tzikas , Hubert Jean Luc Christnacher
发明人： Georg Roentgen , Athanassios Tzikas , Hubert Jean Luc Christnacher
IPC分类号： C09B62/095 , C09B62/012
CPC分类号： C09B62/4407 , C09B62/4413 , C09B62/4415 , C09B67/005 , C09B67/0059
摘要： Dye mixtures, comprising at least one dye of formula and at least one dye from the group of formulae wherein Q1 is C1-C4alkyl, halogen or a radical —SO2—Z, Q2 and Q3 are each independently of the other C1-C4alkoxy, Q4 is C1-C4alkoxy, C1-C4alkyl, halogen or sulfo, Q5 is C1-C4alkoxy, C1-C4alkyl, C1-C4alkanoylamino, ureido, halogen or sulfo, R1, R2 and R3 are each independently of the others hydrogen or unsubstituted or substituted C1-C4alkyl, k and q are each independently of the other the number 0 or 1, n and p are each independently of the other the number 0, 1 or 2, m is the number 0, 1, 2 or 3, t is the number 1, 2 or 3, X1, X2 and X3 are each independently of the others halogen, 3-carboxypyridin-1-yl, 3-carbamoylpyridin-1-yl or a non-fibre-reactive substituent, and T1, T2 and T3 are each independently of the others a non-fibre-reactive substituent or a fibre-reactive radical of formula wherein (R4)0-2 denotes from 0 to 2 identical or different substituents from the group halogen, C1-C4alkyl, C1-C4alkoxy and sulfo, Z is vinyl or a radical —CH2—CH2—U and U is a group removable under alkaline conditions, Q is a group —CH(Hal)-CH2-Hal or —C(Hal)=CH2, and Hal is halogen, are suitable especially for the dichromatic or trichromatic dyeing or printing of cellulosic fibre materials and yield dyeings or prints having good reproducibility and good all-round fastness properties.
摘要翻译：染料混合物，其包含至少一种下式的染料和至少一种下式基团的染料，其中Q 1是C 1 -C 4烷基，卤素或基团-SO 2 -Z，Q 2和Q 3各自独立地为C 1 -C 4烷氧基，Q 4 C1-C4烷氧基，C1-C4烷基，卤素或磺基，Q5是C1-C4烷氧基，C1-C4烷基，C1-C4烷酰基氨基，脲基，卤素或磺基，R1，R2和R3各自独立地是氢或未取代的或取代的C1 -C 1-4烷基，k和q各自独立于数字0或1中的另一个，n和p各自独立于数字0,1或2中的另一个，m是数字0,1,2或3，t是 1,2或3个，X1，X2和X3各自独立地为卤素，3-羧基吡啶-1-基，3-氨基甲酰基吡啶-1-基或非纤维反应性取代基，T1，T2和T3 各自独立地为非纤维反应性取代基或具有下式的纤维反应性基团其中（R4）0-2表示0至2个相同或不同的取代基，基团卤素，C 1 -C 4烷基，C 1 -C 4烷氧基和磺基，Z是乙烯基或基团-CH 2 -CH 2 -U，U是在碱性条件下可除去的基团，Q是基团-CH（Hal）-CH 2 - Hal或-C（ Hal）= CH2，Hal是卤素，特别适用于纤维素纤维材料的二色或三色染色或印花，并且具有良好的再现性和良好的全面牢固性的产量染色或印花。

7. 发明授权

US07641724B2 Mixtures of reactive dyes and their use 失效
标题翻译：活性染料的混合物及其用途
公开(公告)号：US07641724B2
公开(公告)日：2010-01-05
申请号：US10579364
申请日：2004-11-08
申请人： Athanassios Tzikas , Georg Roentgen
发明人： Athanassios Tzikas , Georg Roentgen
IPC分类号： C09D11/00 , C09B62/006 , C09B62/08
CPC分类号： C09B67/005
摘要： Dye mixtures comprising at least one dye of formula (I) together with at least one dye of formula (II) wherein the radicals are as defined in the claim, are suitable for dyeing or printing cellulosic fiber materials, while having a good build-up behavior, and yield dyeings of a deep shade having good fastness properties.
摘要翻译：包含至少一种式（I）染料与至少一种式（II）染料的染料混合物，其中基团如权利要求中所定义，适用于染色或印刷纤维素纤维材料，同时具有良好的聚集性行为和屈服染色，具有良好的牢度特性。

8. 发明申请

US20080256726A1 Mixtures of Reactive Dyes and Their Use in a Method for Trichromatic Dyeing or Printing 有权
公开(公告)号：US20080256726A1
公开(公告)日：2008-10-23
申请号：US12094429
申请日：2006-11-06
申请人： Jean-Marie Sire , Athanassios Tzikas , Georg Roentgen
发明人： Jean-Marie Sire , Athanassios Tzikas , Georg Roentgen
IPC分类号： C09B62/01 , C09B44/18
CPC分类号： C09B62/4416 , C09B31/057 , C09B62/043 , C09B62/095 , C09B62/4413 , C09B62/4415 , C09B67/0047 , Y10S8/918
摘要： Dye mixtures, comprising at least one dye of formula and at least one dye from the group of formulae wherein B1, B2 and B3 are each independently of the others an organic bridging member, Q1 is C1-C4alkyl, halogen or a radical —SO2-Z, Q2 and Q3 are each independently of the other C1-C4alkoxy, Q4 is C1-C4alkoxy, C1-C4alkyl, halogen or sulfo Q5 is C1-C4alkoxy, C1-C4alkyl, C1-C4alkanoylamino, ureido, halogen or sulfo, R1, R2, R3, R4, R5, R6, R7, R8 and R9 are each independently of the others hydrogen or unsubstituted or substituted C1-C4alkyl, k and q are each independently of the other the number 0 or 1, n and p are each independently of the other the number 0, 1 or 2, m is the number 0, 1, 2 or 3, t is the number 1, 2 or 3, X1, X2, X3, X4, X5 and X6 are each independently of the others halogen, and T1, T2 and T3 are each independently of the others a non-fibre-reactive substituent or a fibre-reactive radical of formula wherein (R10)0-2 denotes from 0 to 2 identical or different substituents from the group halogen, C1-C4alkyl, C1-C4alkoxy and sulfo, Z is vinyl or a radical —CH2—CH2—U and U is a group removable under alkaline conditions, Q is a group —CH(Hal)-CH2-Hal or —C(Hal)=CH2, and Hal is halogen, are suitable especially for the dichromatic or trichromatic dyeing or printing of cellulosic fibre materials and yield dyeings or prints having good reproducibility and good all-round fastness properties.

9. 发明申请

US20080250575A1 Fibre-Reactive Dyes, Their Preparation And Their Use 有权
公开(公告)号：US20080250575A1
公开(公告)日：2008-10-16
申请号：US10592976
申请日：2005-03-09
申请人： Athanassios Tzikas , Georg Roentgen , Hubert Jean Luc Christnacher
发明人： Athanassios Tzikas , Georg Roentgen , Hubert Jean Luc Christnacher
IPC分类号： C09B62/513 , B05D1/02
CPC分类号： C09B62/09 , C09B62/475 , C09B62/513
摘要： Reactive dyes of formula wherein Q1 and Q2 are each independently of the other hydrogen or unsubstituted or substituted C1-C4alkyl, D1 is the radical of a diazo component, which is itself a mono- or dis-azo dye or contains such a dye, D2 has the same definition as D1 or is a radical of formula wherein (Q3)0-3 denotes from 0 to 3 identical or different substituents selected from the group halogen, C1-C4alkyl, C1-C4alkoxy, carboxy and sulfo and Z1 is a radical of formula —SO2—Y , (3a) —NH—CO—(CH2)m—SO2—Y , (3b) —CONH—(CH2)n—SO2—Y , (3c) —NH—CO—CH(Hal)-CH2-Hal or (3d) —NH—CO—C(Hal)=CH2 , (3e) Y is vinyl or a —CH2—CH2—U radical and U is a group that is removable under alkaline conditions, m and n are each independently of the other the number 2, 3 or 4, and Hal is halogen, are suitable for dyeing cellulosic or amide-group-containing fibre materials.

10. 发明申请

US20080010756A1 Cyanopyridine-Based Azo Dyes 审中-公开
标题翻译：氰基吡啶基偶氮染料
公开(公告)号：US20080010756A1
公开(公告)日：2008-01-17
申请号：US11661776
申请日：2005-08-24
申请人： Véronique Hall-Goulle , Athanassios Tzikas
发明人： Véronique Hall-Goulle , Athanassios Tzikas
IPC分类号： C09B29/42 , C09B29/36 , C09B31/153 , C09B67/00 , C09B67/38 , G03F7/00
CPC分类号： G03F7/0007 , C09B29/3639 , C09B31/153 , C09B67/008 , G03F7/105
摘要： A composition containing (A) an alkali-soluble binder and (B) an azo dye of formula (1), wherein D is the radical of a diazo component of the benzene, naphthalene, diphenyl, azobenzene, thiophene, benzothiazole, benzisothiazole, thiadiazole, indazole, benzotriazole, pyrazole, anthraquinone, naphtholic acid imide, chromone, phthalimide or diphenylene oxide series, X and Y are each independently of the other C2-C6alkylene, n is a number from 1 to 10, Z denotes oxygen or sulphur, and R1 is —X[—O—Y]n-ZH, wherein X, Y, Z and n are as defined above, C1-C12alkyl which may be unsubstituted or substituted by one or more halogen atoms, hydroxy groups, amino groups or C1-C8alkoxy groups, C5-C24aryl which may be unsubstituted or substituted by one or more halogen atoms, hydroxy groups, amino groups, C1-C12alkyl groups or C1-C8alkoxy groups, C6-C30aralkyl which may be unsubstituted or substituted by one or more halogen atoms, hydroxy groups, amino groups, C1-C12alkyl groups or C1-C8alkoxy groups, or a C5-C24cycloaliphatic group which may be unsubstituted or substituted by one or more halogen atoms, hydroxy groups, amino groups, C1-C12alkyl groups or C1-C8alkoxy groups, is useful for the production of colour filters for liquid crystal displays, flat-panel displays, colour image pickup tubes, colour-copying machines etc.
摘要翻译：包含（A）碱溶性粘合剂和（B）式（1）的偶氮染料的组合物，其中D是苯，萘，二苯基，偶氮苯，噻吩，苯并噻唑，苯并异噻唑，噻二唑的重氮组分的基团，吲唑，苯并三唑，吡唑，蒽醌，萘甲酰亚胺，色酮，邻苯二甲酰亚胺或二苯醚系列，X和Y各自独立地为C 2 -C 6 -C 6亚烷基，n为1〜10的数，Z为氧或硫，R 1为-X [-OY] n -ZH，其中，X，Y，Z 和n如上所定义，可以是未取代的或被一个或多个卤素原子，羟基，氨基或C 1 -C 12烷基取代的C 1 -C 12烷基， C 1 -C 8烷氧基，C 5 -C 20 -C 24芳基，其可以是未取代的或被一个或多个卤素原子取代，羟基，氨基，C 1 -C 12烷基或C 1 -C 8烷氧基，C

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