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    • 4. 发明授权
    • Anisotropic membranes for gas separation
    • 用于气体分离的各向异性膜
    • US4681605A
    • 1987-07-21
    • US749574
    • 1985-06-27
    • Arye Z. Gollan
    • Arye Z. Gollan
    • B01D53/22B01D67/00B01D69/12B01D71/12B01D71/22C08J9/28D01D5/24
    • D01D5/24B01D67/0009B01D69/02B01D69/08B01D69/12B01D71/22B01D2323/08B01D2323/12B01D2325/022Y10S264/14
    • A gas separation membrane has a dense separating layer about 10,000 Angstroms or less thick and a porous support layer 10 to 400 microns thick that is an integral unit with gradually and continuously decreasing pore size from the base of the support layer to the surface of the thin separating layer and is made from a casting solution comprising ethyl cellulose and ethyl cellulose-based blends, typically greater than 47.5 ethoxyl content ethyl cellulose blended with compatible second polymers, such as nitrocellulose. The polymer content of the casting solution is from about 10% to about 35% by weight of the total solution with up to about 50% of this polymer weight a compatible second polymer to the ethyl cellulose in a volatile solvent such as isopropanol, methylacetate, methanol, ethanol, and acetone. Typical nonsolvents for the casting solutions include water and formamide. The casting solution is cast in air from about zero to 10 seconds to allow the volatile solvent to evaporate and then quenched in a coagulation bath, typically water, at a temperature of 7.degree.-25.degree. C. and then air dried at ambient temperature, typically 10.degree.-30.degree. C.
    • 气体分离膜具有大约10,000埃或更小厚度的致密分离层和10至400微米厚的多孔支撑层,其是整体单元,其具有从支撑层的底部到薄壁的表面逐渐且连续减小的孔径 并且由包含乙基纤维素和乙基纤维素基共混物的浇铸溶液制成,通常大于47.5乙氧基含量的乙基纤维素与相容的第二聚合物如硝化纤维素混合。 浇铸溶液的聚合物含量为总溶液的约10重量%至约35重量%,高达该聚合物重量的约50%,在挥发性溶剂如异丙醇,乙酸甲酯中与乙基纤维素相容的第二聚合物, 甲醇,乙醇和丙酮。 铸造溶液的典型非溶剂包括水和甲酰胺。 浇铸溶液在空气中从大约零到10秒铸造,使挥发性溶剂蒸发,然后在凝固浴(通常为水)中在7〜25℃的温度下骤冷,然后在环境温度下空气干燥, 通常为10°-30℃