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    • 9. 发明授权
    • Plasma process for etching multicomponent alloys
    • 用于蚀刻多组分合金的等离子体工艺
    • US5779926A
    • 1998-07-14
    • US596960
    • 1996-02-05
    • Diana Xiaobing MaDaisuke TajimaAllen ZhaoPeter K. LoewenhardtTimothy R. Webb
    • Diana Xiaobing MaDaisuke TajimaAllen ZhaoPeter K. LoewenhardtTimothy R. Webb
    • C23F4/00H01J37/32H01L21/302H01L21/3065H01L21/3213B44C1/22C23F1/00H01L21/00
    • H01J37/321C23F4/00H01L21/32136
    • A method of etching a multicomponent alloy on a substrate, without forming etchant residue on the substrate, is described. In the method, the substrate is placed in a process chamber comprising a plasma generator and plasma electrodes. A process gas comprising a volumetric flow ratio V.sub.r of (i) a chlorine-containing gas capable of ionizing to form dissociated Cl.sup.+ plasma ions and non-dissociated Cl.sub.2.sup.+ plasma ions, and (ii) an inert gas capable of enhancing dissociation of the chlorine-containing gas, in introduced into the process chamber. The process gas is ionized to form plasma ions that energetically impinge on the substrate by (i) applying RF current at a first power level to the plasma generator, and (ii) applying RF current at a second power level to the plasma electrodes. The combination of (i) the volumetric flow ratio V.sub.r of the process gas and (ii) the power ratio P.sub.r of the first power level to the second power level, is selected so that the chlorine-containing etchant gas ionizes to form dissociated Cl.sup.+ plasma ions and non-dissociated Cl.sub.2.sup.+ plasma ions in a number ratio of at least about 0.6:1. The increased amount of dissociated Cl.sup.+ ions relative to non-dissociated Cl.sub.2.sup.+ ions etches the multicomponent alloy on the substrate at an etch rate of at least about 500 nm/min, without forming etchant residue on the substrate.
    • 描述了在衬底上蚀刻多组分合金而不在衬底上形成蚀刻剂残留物的方法。 在该方法中,将基板放置在包括等离子体发生器和等离子体电极的处理室中。 一种工艺气体,其包括(i)能够电离以形成离解的Cl +等离子体离子和非离解的Cl 2 +等离子体离子的含氯气体的体积流量比Vr,和(ii)能够增强氯 - 含有气体,被引入处理室。 通过(i)以等离子体发生器施加第一功率电平的RF电流,并且(ii)将第二功率电平的RF电流施加到等离子体电极,将工艺气体电离以形成能量地撞击衬底的等离子体离子。 选择(i)处理气体的体积流量比Vr和(ii)第一功率水平与第二功率水平的功率比Pr的组合,使得含氯蚀刻剂气体电离以形成离解的Cl +等离子体 离子和非离解的Cl2 +等离子体离子的数量比至少为约0.6:1。 解离的Cl +离子相对于未离解的Cl 2 +离子的量的增加量以至少约500nm / min的蚀刻速率蚀刻衬底上的多组分合金,而不在衬底上形成蚀刻剂残留物。