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1. 发明授权

US5376150A Use of pyridine dyes in the textile sector, dye mixtures with pyridine dyes, and triazolopyridine dyes having a thienyl radical 失效
标题翻译：在纺织部门中使用吡啶染料，用吡啶染料染料混合物和具有噻吩基的三唑并吡啶染料
公开(公告)号：US5376150A
公开(公告)日：1994-12-27
申请号：US116958
申请日：1993-09-07
申请人： Arno Lange , Volker Bach , Ruediger Sens , Karl-Heinz Etzbach , Helmut Reichelt , Sabine Gruettner-Merten
发明人： Arno Lange , Volker Bach , Ruediger Sens , Karl-Heinz Etzbach , Helmut Reichelt , Sabine Gruettner-Merten
IPC分类号： C09B57/00 , B41M5/385 , B41M5/39 , C07D471/04 , C09B53/00 , C09B55/00 , C09B67/22 , C09B67/38 , D06P1/16 , D06P3/42 , D06P3/48 , C07D471/02
CPC分类号： B41M5/3856 , C09B55/009 , C09B67/0033 , B41M5/3854 , B41M5/39
摘要： There are described the use of pyridine dyes of the formula ##STR1## where R.sup.1 is substituted or unsubstituted C.sub.1 -C.sub.20 -alkyl, substituted or unsubstituted phenyl or hydroxyl,R.sup.2 is a carbocyclic or heterocyclic radical,R.sup.3 is cyano, carbamoyl, carboxyl or C.sub.1 -C.sub.4 -alkoxy carbonyl,R.sup.4 is oxygen or the radical of an acidic CH compound,R.sup.5 is hydrogen or C.sub.1 -C.sub.4 -alkyl,R.sup.6 is substituted or unsubstituted C.sub.1 -C.sub.20 -alkyl, substituted or unsubstituted phenyl, hydroxyl or substituted or unsubstituted amino, andX is nitrogen or optionally CH,for dyeing or printing synthetic fibers, cellulose esters or blends thereof, dye mixtures comprising pyridine dyes of the above formulae and blue disperse dyes, the use thereof for dyeing and printing synthetic fibers, cellulose esters or blends thereof, and triazolopyridine dyes having a thienyl radical.
摘要翻译：描述了使用式“IMAGE”或“IMAGE”的吡啶染料，其中R 1是取代或未取代的C 1 -C 20 - 烷基，取代或未取代的苯基或羟基，R 2是碳环或杂环基，R 3是氰基，氨基甲酰基，羧基或C 1 -C 4 - 烷氧基羰基，R 4是氧或酸性CH化合物的基团，R 5是氢或C 1 -C 4 - 烷基，R 6是取代或未取代的C 1 -C 20 - 烷基，取代或未取代的苯基，羟基或取代或未取代的氨基，X是氮或任选的CH，用于染色或印刷合成纤维，纤维素酯或其混合物，包含上述吡啶染料的染料混合物和蓝色分散染料，其用于染色和印刷合成纤维的用途，纤维素酯或其共混物，以及具有噻吩基的三氮代吡啶染料。

2. 发明授权

US5382263A Blue dye mixtures of high brilliance 失效
标题翻译：蓝色染料混合色泽高
公开(公告)号：US5382263A
公开(公告)日：1995-01-17
申请号：US946652
申请日：1992-09-18
申请人： Helmut Degen , Arno Lange , Sabine Gruettner-Merten , Helmut Reichelt
发明人： Helmut Degen , Arno Lange , Sabine Gruettner-Merten , Helmut Reichelt
IPC分类号： C09B5/24 , C09B29/00 , C09B67/22 , D06P3/54 , C09B29/03
CPC分类号： C09B67/0041 , C09B29/0059 , C09B5/2463 , D06P3/54
摘要： Blue dye mixtures useful for dyeing or printing polyester fabrics contain from 30 to 95% by weight, based on the total weight of the dyes, of one or more dyes based on 1,4-diaminoanthraquinone-2,3-dicarboximides and also from 5 to 70% by weight based on the total weight of the dyes, of one or more thiopheneazo dyes having a coupling component of the aniline series.
摘要翻译：用于染色或印花聚酯织物的蓝色染料混合物含有基于染料总重量的30至95重量％的一种或多种基于1,4-二氨基蒽醌-2,3-二甲酰亚胺的染料以及5 相对于染料的总重量为70重量％的一种或多种具有苯胺系列的偶联成分的噻吩偶氮染料。

3. 发明授权

US5502170A Azo dyes with an acetalized diazo component of the thiophene or thiazole series 失效
标题翻译：偶氮染料与噻吩或噻唑系列的缩醛重氮组分
公开(公告)号：US5502170A
公开(公告)日：1996-03-26
申请号：US443165
申请日：1995-05-17
申请人： Sabine Gruettner-Merten , Helmut Reichelt , Arno Lange , Helmut Degen
发明人： Sabine Gruettner-Merten , Helmut Reichelt , Arno Lange , Helmut Degen
IPC分类号： C09B29/033 , C09B29/00 , C09B29/042 , C09B29/09 , C09B43/00 , C09B67/48 , D06P1/18
CPC分类号： C09B43/00 , C09B29/0059 , C09B29/0085
摘要： Azo dyes of the formula ##STR1## where L.sup.1, L.sup.2, L.sup.3, L.sup.4, X and K are as defined in the specification, and crystal forms of thienylazobenzene dyes are useful for dyeing or printing textile materials such as polyesters, fibers or fabrics made of cellulose esters or polyamides or blend fabrics from polyester and cellulose fibers with high color strength, good fastness properties and brilliant hues.
摘要翻译：其中L1，L2，L3，L4，X和K如说明书中所定义的式“IMAGE”的偶氮染料和噻吩基偶氮染料的晶体形式可用于染色或印刷纺织材料，例如聚酯，纤维或由纤维素酯或聚酰胺或来自聚酯和纤维素纤维的混合织物，具有高着色强度，良好的牢度性能和辉煌的色调。

4. 发明授权

US5466790A Azo dyes with an acetalized diazo component of the thiophene or thiazole series 失效
标题翻译：偶氮染料与噻吩或噻唑系列的缩醛重氮组分
公开(公告)号：US5466790A
公开(公告)日：1995-11-14
申请号：US307794
申请日：1994-09-30
申请人： Sabine Gruettner-Merten , Helmut Reichelt , Arno Lange , Helmut Degen
发明人： Sabine Gruettner-Merten , Helmut Reichelt , Arno Lange , Helmut Degen
IPC分类号： C09B29/033 , C09B29/00 , C09B29/042 , C09B29/09 , C09B43/00 , C09B67/48 , D06P1/18
CPC分类号： C09B43/00 , C09B29/0059 , C09B29/0085
摘要： Azo dyes of the formula ##STR1## where L.sup.1 is hydrogen, C.sub.1 -C.sub.8 -alkyl or phenyl,L.sup.2 and L.sup.3 are each substituted or unsubstituted C.sub.1 -C.sub.8 -alkyl, or together a radical of the formula ##STR2## where n is 0, 1 or 2, Y.sup.1 and Y.sup.4 are hydrogen, hydroxymethyl, 1,2-dihydroxyethyl or a radical of the formula COO.sym.M.sup..crclbar. or SO.sub.3.sup..crclbar. M.sup..sym., Y.sup.2 and Y.sup.3 are halogen or hydroxymethyl, and M.sup..sym. is the equivalent of a cation,L.sup.4 is hydrogen, substituted or unsubstituted C.sub.1 -C.sub.8 -alkyl, substituted or unsubstituted phenyl, halogen, C.sub.1 -C.sub.8 -alkoxy, substituted or unsubstituted phenoxy, C.sub.1 -C.sub.8 -alkylthio, C.sub.1 -C.sub.8 -alkylsulfonyl, substituted or unsubstituted phenylthio, substituted or unsubstituted phenylsulfonyl, C.sub.1 -C.sub.8 -alkoxycarbonyl, C.sub.3 -C.sub.6 -alkenyloxycarbonyl or phenoxycarbonyl,X is nitrogen or the radical C--L.sup.5, where L.sup.5 is as defined in the specification,K is the radical of a coupling component, andnovel crystal forms of thienylazobenzene dyes are useful for dyeing or printing textile materials.
摘要翻译： PCT No.PCT / EP93 / 01043 Sec。 371日期1994年9月30日 102（e）1994年9月30日PCT 1993年4月30日PCT公布。第WO93 / 23479号公报日本公开说明书，其中L1是氢，C1-C8-烷基或苯基，L2和L3各自是取代或未取代的C1-C8-烷基，或者一起是式其中n为0,1或2，Y 1和Y 4为氢，羟甲基，1,2-二羟乙基或式COO（+）M（ - ）或SO 3（ - ）M（+），Y 2和 Y 3为卤素或羟甲基，M（+）为阳离子，L4为氢，取代或未取代的C1-C8-烷基，取代或未取代的苯基，卤素，C1-C8-烷氧基，取代或未取代的苯氧基，C1 C 1 -C 8 - 烷硫基，C 1 -C 8 - 烷基磺酰基，取代或未取代的苯硫基，取代或未取代的苯基磺酰基，C 1 -C 8 - 烷氧基羰基，C 3 -C 6 - 烯氧基羰基或苯氧基羰基，X是氮或基团C-L 5，其中L 5如在说明书中，K是偶联组分的基团，噻吩并氮苯染料的新型晶体形式可用于染色或印刷纺织材料。

5. 发明授权

US5484460A Dye mixtures containing azo dyes having a coupling component from the diaminopyridine series 失效
标题翻译：包含偶氮染料的染料混合物，其具有来自二氨基吡啶系列的偶联组分
公开(公告)号：US5484460A
公开(公告)日：1996-01-16
申请号：US338208
申请日：1994-11-09
申请人： Hermann Loeffler , Gunther Lamm , Volker Bach , Arno Lange , Helmut Reichelt , Herbert Rothmaier
发明人： Hermann Loeffler , Gunther Lamm , Volker Bach , Arno Lange , Helmut Reichelt , Herbert Rothmaier
IPC分类号： C09B67/22 , C09B67/38 , D06P1/16 , D06P3/54
CPC分类号： C09B67/0051 , Y10S8/922
摘要： Dye mixtures comprising at least six isochromatic dyes of the formula ##STR1## where D is the radical of a diazo component of the aniline, aminothiophene, aminothiazole, aminoisothiazole or aminobenzisothiazole series andone of the radicals X.sup.1 and X.sup.2 is amino and the other is a radical of the formula ##STR2## where L is unsubstituted or substituted C.sub.2 -C.sub.8 -alkyleneR.sup.1 is hydrogen or unsubstituted or substituted C.sub.1 -C.sub.4 -alkyl andR.sup.2 is hydrogen, C.sub.1 -C.sub.4 -alkyl, benzyl, phenyl, or C.sub.1 -C.sub.8 -alkanoyl,and the use thereof for dyeing or printing textile materials, and dye mixtures comprising thienylazopyridine dyes and anthraquinone dyes and the use thereof for dyeing or printing textile materials.
摘要翻译：染料混合物包含至少六种通式为“IMAGE”的同色染料，其中D是苯胺，氨基噻吩，氨基噻唑，氨基异噻唑或氨基苯并异噻唑系列的重氮组分的基团，基团X1和X2之一是氨基，另一个是其中L为未取代的或取代的C 2 -C 8 - 亚烷基R 1为氢或未取代或取代的C 1 -C 4 - 烷基且R 2为氢，C 1 -C 4 - 烷基，苄基，苯基或C 1 -C 8 - 烷酰基及其用于染色或印刷纺织材料的用途，以及包含噻吩基偶氮基吡啶染料和蒽醌染料的染料混合物及其用于染色或印刷纺织材料的用途。

6. 发明授权

US5403363A Dye mixtures containing azo dyes having a coupling component from the diaminopyridine series 失效
标题翻译：包含偶氮染料的染料混合物，其具有来自二氨基吡啶系列的偶联组分
公开(公告)号：US5403363A
公开(公告)日：1995-04-04
申请号：US159301
申请日：1993-11-30
申请人： Hermann Loeffler , Gunther Lamm , Volker Bach , Arno Lange , Helmut Reichelt , Herbert Rothmaier
发明人： Hermann Loeffler , Gunther Lamm , Volker Bach , Arno Lange , Helmut Reichelt , Herbert Rothmaier
IPC分类号： C09B67/22 , C09B29/00 , D06P3/54
CPC分类号： C09B67/0051 , Y10S8/922
摘要： Dye mixtures comprising at least six isochromatic dyes of the formula ##STR1## where D is the radical of a diazo component of the aniline, aminothiophene, aminothiazole, aminoisothiazole or aminobenzisothiazole series andone of the radicals X.sup.1 and X.sup.2 is amino and the other is a radical of the formula ##STR2## where L is unsubstituted or substituted C.sub.2 -C.sub.8 -alkyleneR.sup.1 is hydrogen or unsubstituted or substituted C.sub.1 -C.sub.4 -alkyl andR.sup.2 is hydrogen, C.sub.1 -C.sub.4 -alkyl, benzyl, phenyl, or C.sub.1 -C.sub.8 -alkanoyl,and the use thereof for dyeing or printing textile materials, and dye mixtures comprising thienylazopyridine dyes and anthraquinone dyes and the use thereof for dyeing or printing textile materials.
摘要翻译：染料混合物包含至少六种通式为“IMAGE”的同色染料，其中D是苯胺，氨基噻吩，氨基噻唑，氨基异噻唑或氨基苯并异噻唑系列的重氮组分的基团，基团X1和X2之一是氨基，另一个是其中L为未取代的或取代的C 2 -C 8 - 亚烷基R 1为氢或未取代或取代的C 1 -C 4 - 烷基且R 2为氢，C 1 -C 4 - 烷基，苄基，苯基或C 1 -C 8 - 烷酰基及其用于染色或印刷纺织材料的用途，以及包含噻吩基偶氮基吡啶染料和蒽醌染料的染料混合物及其用于染色或印刷纺织材料的用途。

7. 发明授权

US5393308A Mixtures of azo dyes for navy to black shades 失效
标题翻译：用于海军至黑色阴影的偶氮染料的混合物
公开(公告)号：US5393308A
公开(公告)日：1995-02-28
申请号：US125826
申请日：1993-09-24
申请人： Arno Lange , Volker Bach , Clemens Grund , Helmut Reichelt , Paul Richter
发明人： Arno Lange , Volker Bach , Clemens Grund , Helmut Reichelt , Paul Richter
IPC分类号： C09B67/22 , C09B29/00 , D06P3/54
CPC分类号： C09B67/0046 , Y10S8/922
摘要： There are described dye mixtures containinga) an azo dye of the formula I ##STR1## where Hal is chlorine or bromine, b) the azo dye of the formula II ##STR2## where L is allyl or optionally hydrogen, and c) an azo dye of the formula III and/or IV ##STR3## where R.sup.1 is nitro or substituted or unsubstituted C.sub.1 -C.sub.4 -alkylsulfonyl,R.sup.2 and R.sup.3 are each hydrogen, chlorine or bromine,R.sup.4 and R.sup.5 are each hydrogen or chlorine,R.sup.6 and R.sup.7 are each hydrogen, phenyl or substituted or unsubstituted C.sub.1 -C.sub.4 -alkyl,X.sup.1 is hydrogen, hydroxyl, methoxy, acetylamino or nitro,X.sup.2, X.sup.3, X.sup.4 and X.sup.5 are each hydrogen, methyl or methoxy, andX.sup.6 is hydroxyl, 2-hydroxyethoxy, formyl or methoxycarbonylamino,dye preparations containing the novel dye mixtures, and the use of the novel dye mixtures for dyeing or printing polyesters in textile form.
摘要翻译：描述了染料混合物，其包含a）式I的偶氮染料，其中Hal是氯或溴，b）式II的偶氮染料（II），其中L是烯丙基或任选的氢，和c）式III和/或IV的偶氮染料（III）其中R 1是硝基或取代或未取代的C 1 -C 4 - 烷基磺酰基，R 2和R 3各自是氢，氯或溴，R 4和R 5各自为氢或氯，R 6和R 7各自为氢，苯基或取代或未取代的C 1 -C 4 - 烷基，X 1为氢，羟基，甲氧基，乙酰氨基或硝基，X 2，X 3，X 4和X 5为氢，甲基或甲氧基，X6是羟基，2-羟基乙氧基，甲酰基或甲氧基羰基氨基，含有新染料混合物的染料制剂，以及使用新型染料混合物以纺织形式染色或印刷聚酯。

8. 发明授权

US5554782A Preparation of dicyanobenzenes by ammonoxidation 失效
标题翻译：通过氨氧化制备二氰基苯
公开(公告)号：US5554782A
公开(公告)日：1996-09-10
申请号：US194461
申请日：1994-02-08
申请人： Clemens Grund , Guenther Glas , Paul Guenthert , Helmut Reichelt , Rainer Becker , Arno Lange , Klaus Friedrich
发明人： Clemens Grund , Guenther Glas , Paul Guenthert , Helmut Reichelt , Rainer Becker , Arno Lange , Klaus Friedrich
IPC分类号： B01J23/22 , C07B61/00 , C07C253/28 , C07C255/51 , C07C255/53 , C07C255/54 , C07C255/58 , C07D209/48 , C07D295/14
CPC分类号： C07D209/48 , B01J23/22 , C07C253/28 , C07C255/51 , C07C255/53 , C07C255/54 , C07C255/58
摘要： A process for the preparation of dicyanobenzenes of the formula ##STR1## in which x denotes hydroxy, C.sub.1 -C.sub.4 alkoxy, nitro, amino, mono- or di-(C.sub.1 -C.sub.4 alkyl)amino, phthalimido or a nitrogenous saturated 5-membered or 6-membered heterocyclic radical, which is attached to the phenyl ring via a nitrogen atomin which a xylene of the formula ##STR2## in which x has the meaning stated above,is oxidized at a temperature of from 400.degree. to 500.degree. C. with oxygen in the presence of ammonia and a catalyst.
摘要翻译：制备式“IMAGE”的二氰基苯的方法，其中x表示羟基，C 1 -C 4烷氧基，硝基，氨基，单 - 或二 - （C 1 -C 4烷基）氨基，邻苯二甲酰亚氨基或含氮饱和5元或通过氮原子连接到苯环上的6元杂环基，其中x具有上述含义的式“IMAGE”的二甲苯在400℃至500℃的温度下被氧化。在氨和催化剂存在下用氧气。

9. 发明授权

US5330543A Thiopheneazo dyes with a coupling component of the diaminopyridine series 失效
标题翻译：噻吩偶氮染料与二氨基吡啶系列的偶联组分
公开(公告)号：US5330543A
公开(公告)日：1994-07-19
申请号：US141705
申请日：1993-10-27
申请人： Guenter Hansen , Gunther Lamm , Hermann Loeffler , Helmut Reichelt , Helmut Degen , Arno Lange , Clemens Grund
发明人： Guenter Hansen , Gunther Lamm , Hermann Loeffler , Helmut Reichelt , Helmut Degen , Arno Lange , Clemens Grund
IPC分类号： C09B29/00 , C09B29/42 , D06P1/18 , C09B29/042 , C09B29/40 , D06P3/54
CPC分类号： C09B29/0059 , C09B29/3639 , Y10S8/922
摘要： Azo dyes having the formula ##STR1## wherein the substituents are as defined in the specification and are useful for dyeing or printing textile materials.
摘要翻译：具有式“IMAGE”的偶氮染料，其中取代基如说明书中所定义，并且可用于染色或印刷纺织材料。

10. 发明授权

US5364972A Preparation of nitrobenzophenones, and a color-stable modification of a benzophenone-azopyridone dye 失效
标题翻译：硝基二苯甲酮的制备和二苯甲酮 - 叠氮吡啶染料的颜色稳定的改性
公开(公告)号：US5364972A
公开(公告)日：1994-11-15
申请号：US948579
申请日：1992-09-23
申请人： Helmut Degen , Norbert Zimmerman , Ralf Brueckmann , Gunther Lamm , Arno Lange , Helmut Reichelt
发明人： Helmut Degen , Norbert Zimmerman , Ralf Brueckmann , Gunther Lamm , Arno Lange , Helmut Reichelt
IPC分类号： B01J27/125 , B01J27/128 , C07B61/00 , C07C201/12 , C07C205/45 , C09B29/01 , C09B29/42 , C09B67/00 , C07C45/45
CPC分类号： C07C201/12 , C07C221/00 , C09B29/3626 , C09B67/0029
摘要： A process for preparing nitrobenzophenones by reaction of benzene or its derivatives with nitrobenzoyl chloride in the presence of a Lewis acid, a color-stable modification of 1,4-dimethyl-5-cyano-3-[4-(2,4-dimethylbenzoyl)phenylazo]-2-hydroxy-6-pyridone and its use for dyeing or printing synthetic fiber material are described.
摘要翻译：在路易斯酸存在下，苯或其衍生物与硝基苯甲酰氯反应制备硝基二苯甲酮的方法，1,4-二甲基-5-氰基-3- [4-（2,4-二甲基苯甲酰基））苯偶氮] -2-羟基-6-吡啶酮及其用于染色或印刷合成纤维材料的用途。

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