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1. 发明授权

US4537901A Insecticidal carbamates 失效
标题翻译：杀虫氨基甲酸酯
公开(公告)号：US4537901A
公开(公告)日：1985-08-27
申请号：US620564
申请日：1984-06-14
申请人： Arno Lange , Franz Merger , Peter Hettinger , Heinrich Adolphi
发明人： Arno Lange , Franz Merger , Peter Hettinger , Heinrich Adolphi
IPC分类号： A01N47/18 , C07C45/75 , C07C47/198 , C07C59/305 , C07D231/20 , C07D231/36 , C07D491/10 , C07D491/107 , A01N43/56 , C07D231/08
CPC分类号： C07D491/10 , A01N47/18 , C07C45/75 , C07C47/198 , C07C59/305 , C07D231/20 , C07D231/36
摘要： Carbamates of the formula ##STR1## where either R.sup.1 is straight-chain or branched alkyl of not more than 4 carbon atoms and R.sup.2 is straight-chain or branched alkyl of not more than 6 carbon atoms, or R.sup.1 and R.sup.2, together with the molecular moiety which they include, form a 5-membered, 6-membered or 7-membered heterocyclic ring, R.sup.3 is straight-chain or branched alkyl of not more than 6 carbon atoms or cycloalkyl of 3 to 6 carbon atoms, R.sup.4 is methyl or methoxy, and n is 1 or 2, their preparation and their use as insecticides.
摘要翻译：式中，R1为直链或支链烷基，不超过4个碳原子，R2为直链或支链烷基，不大于6个碳原子的直链或支链烷基，R1，R2与分子它们包括的部分形成5元，6元或7元杂环，R3是不大于6个碳原子的直链或支链烷基或3至6个碳原子的环烷基，R4是甲基或甲氧基，n为1或2，它们的制备及其作为杀虫剂的用途。

2. 发明授权

US4552985A Preparation of aldols 失效
标题翻译：醛醇的制备
公开(公告)号：US4552985A
公开(公告)日：1985-11-12
申请号：US620558
申请日：1984-06-14
申请人： Franz Merger , Peter Hettinger , Arno Lange
发明人： Franz Merger , Peter Hettinger , Arno Lange
IPC分类号： B01J31/00 , B01J31/02 , C07B61/00 , C07C45/00 , C07C45/75 , C07C47/198 , C07C51/27 , C07C67/00 , C07H15/04 , C07C47/19
CPC分类号： C07H15/04 , C07C45/75 , C07C47/198 , C07C51/27
摘要： Novel ether-aldols of the general formula (I) ##STR1## where R.sup.1 and R.sup.2 are each alkyl, can be prepared by reacting a 2-alkylacrolein (H.sub.2 C.dbd.CHR.sup.2 --CHO), an alcohol (R.sup.1 OH) and formaldehyde, preferably aqueous formaldehyde, in the presence of a tertiary amine.
摘要翻译：通式（I）的新型醚 - 醇，其中R 1和R 2各自为烷基，可以通过使2-烷基丙烯醛（H 2 C = CHR 2 CHO），醇（R 1 OH）和甲醛反应来制备，优选甲醛水溶液，在叔胺的存在下。

3. 发明授权

US4665219A Isolation of neopentyl glycol hydroxypivalate 失效
标题翻译：新戊二醇羟基新戊酸酯的分离
公开(公告)号：US4665219A
公开(公告)日：1987-05-12
申请号：US772841
申请日：1985-09-05
申请人： Franz Merger , Peter Hettinger , Theodor Weber , Guenter Boettger , Wolfgang Koernig
发明人： Franz Merger , Peter Hettinger , Theodor Weber , Guenter Boettger , Wolfgang Koernig
IPC分类号： C07B61/00 , B01J23/02 , C07C67/44 , C07C69/675 , C07C69/66 , B01D3/00
CPC分类号： C07C67/54 , C07C67/58
摘要： Neopentyl glycol hydroxypivalate is isolated from a reaction mixture obtained from a Tishchenko reaction of hydroxypivalaldehyde in the presence of calcium hydroxide, barium hydroxide or strontium hydroxide, by adding acid, removing the salts formed by adjusting the water content in the reaction mixture to 20-60% and extracting the salts at above 50.degree. C. and working up the residual mixture by distillation.
摘要翻译：在氢氧化钙，氢氧化钡或氢氧化锶的存在下，从羟基新戊醛的Tishchenko反应得到的反应混合物中加入新戊二醇羟基新戊酸，加入酸，除去通过将反应混合物中的水分调节至20-60℃形成的盐％，并在50℃以上提取盐，并通过蒸馏处理残留的混合物。

4. 发明授权

US4837357A Preparation of 2,2-disubstituted 3-chloropropionic esters 失效
标题翻译： 2,2-二取代的3-氯丙酸酯的制备
公开(公告)号：US4837357A
公开(公告)日：1989-06-06
申请号：US111624
申请日：1987-10-21
申请人： Franz Merger , Peter Hettinger
发明人： Franz Merger , Peter Hettinger
IPC分类号： C07C67/03 , C07B61/00 , C07C67/307 , C07C67/44 , C07C69/63 , C07C69/65 , C07C69/675 , C07C69/708 , C07C69/732
CPC分类号： C07C67/307 , C07C67/03 , C07C67/44
摘要： 2,2-Disubstituted 3-chloropropionic esters I ##STR1## where R.sup.1 and R.sup.2 are each C.sub.1 -C.sub.6 -alkyl, C.sub.2 -C.sub.6 -oxaalkyl, C.sub.2 -C.sub.6 -alkenyl, C.sub.2 -C.sub.6 -oxaalkenyl, aryl or C.sub.7 -C.sub.12 -aralkyl or R.sup.1 -C-R.sup.2 is 5-, 6- or 7-membered ring, R.sup.3 is C.sub.2 -C.sub.6 -oxaalkyl, C.sub.2 -C.sub.6 -alkenyl, C.sub.2 -C.sub.6 -oxaalkenyl or C.sub.7 -C.sub.12 -aralkyl, are prepared by converting 2,2-disubstituted 3-hydroxypropanals II ##STR2## into the esterdiol III ##STR3## reacting this esterdiol III in the presence of a transesterification catalyst with an alcohol R.sup.3 OH to give the 3-hydroxyester IV ##STR4## reacting the hydroxyester IV with a stoichiometric or greater than stoichiometric amount of the thionyl chloride and thermally decomposing the product to give the chloropropionic ester I.
摘要翻译： 2,2-二取代的3-氯丙酸酯I，其中R 1和R 2各自是C 1 -C 6 - 烷基，C 2 -C 6 - 氧杂烷基，C 2 -C 6 - 烯基，C 2 -C 6 - 氧杂链烯基，芳基或C 7 -C 12 - 芳烷基或R1-C-R2是5-，6-或7-元环，R3是C2-C6-氧杂烷基，C2-C6-烯基，C2-C6-氧杂链烯基或C7-C12-芳烷基，是通过将2 将2-二取代的3-羟基丙醛II转化成酯二醇III在酯交换催化剂与醇R 3 OH的存在下使该酯二醇III反应，得到3-羟基酯IV使羟基酯IV 化学计量或大于化学计量的亚硫酰氯，并热分解产物得到氯丙酸酯I.

5. 发明授权

US4594461A Preparation of trimethylolalkanes from alkanals and formaldehyde 失效
标题翻译：从链烷和甲醛制备三羟甲基烷烃
公开(公告)号：US4594461A
公开(公告)日：1986-06-10
申请号：US668026
申请日：1984-11-05
申请人： Franz Merger , Peter Hettinger , Leopold Hupfer , Juergen Paetsch
发明人： Franz Merger , Peter Hettinger , Leopold Hupfer , Juergen Paetsch
IPC分类号： B01J23/00 , C07B61/00 , C07C27/00 , C07C29/141 , C07C29/38 , C07C31/22 , C07C67/00 , C07C29/14 , C07C29/80
CPC分类号： C07C29/38
摘要： Trimethylolalkanes are prepared by reacting an n-alkanal with formaldehyde and a trialkylamine in aqueous solution and then hydrogenating the product, by a method in which from 2.2 to 4.5 moles of formaldehyde and from 0.6 to 3 moles of trialkylamine are used per mole of the alkanal, and the reaction mixture is worked up by distillation either before or after the hydrogenation.
摘要翻译：通过使正链烷醛与甲醛和三烷基胺在水溶液中反应然后使产物氢化，通过使用每摩尔烷烃使用2.2至4.5摩尔甲醛和0.6至3摩尔三烷基胺的方法制备三羟甲基烷烃，并且在氢化之前或之后通过蒸馏处理反应混合物。

6. 发明授权

US5149861A Recovery of trialkylamines and methyl formate from mixtures obtained in the preparation of trimethylolalkanes 失效
标题翻译：三氯甲烷制备中获得的混合物中的丙烯酰胺和甲基丙烯酸的回收
公开(公告)号：US5149861A
公开(公告)日：1992-09-22
申请号：US664463
申请日：1991-03-01
申请人： Franz Merger , Peter Hettinger , Leopold Hupfer , Juergen Paetsch , Heribert Deck , Heinz Auer , Erwin Brunner
发明人： Franz Merger , Peter Hettinger , Leopold Hupfer , Juergen Paetsch , Heribert Deck , Heinz Auer , Erwin Brunner
IPC分类号： C07C69/06 , C07C27/00 , C07C27/02 , C07C29/38 , C07C29/74 , C07C29/88 , C07C31/22 , C07C67/00 , C07C67/03 , C07C67/08 , C07C209/00 , C07C209/86 , C07C211/03 , C07C211/05
CPC分类号： C07C29/88 , C07C67/03
摘要： Trialkylamines and methyl formate are recovered from reaction mixtures obtained in the preparation of trimethylolalkanes by reaction of n-alkanals with from 2.2 to 4.5 moles of formaldehyde in aqueous solution in the presence of from 0.6 to 3 mole of trialkylamine, each quantity based on 1 mole of alkanal, and subsequent hydrogenation in a process wherein the crude reaction mixturea) is heated to from 100.degree. to 200.degree. C., the water present in the reaction mixture is substantially separated off by distillation, together with any excess free trialkylamine, the trialkylamine present in the form of a trialkylammonium formate is freed to form a trimethylolalkane formate, the trialkylamine is distilled off and the trimethylolalkane formate is transesterified with methanol to trimethylolalkane and methyl formate in the presence or absence of a catalytic amount of an alkali metal alkoxide or alkaline earth metal alkoxide, orb) is substantially dewatered, any excess free trialkylamine being removed at the same time, the trialkylamine present in the form of a trialkylammonium formate is separated off by admixing the remaining mixture with methanol and heating the admixture to from 100.degree. to 200.degree. C. to form methyl formate and trialkylamine.
摘要翻译：三烷基胺和甲酸甲酯从制备三羟甲基烷烃得到的反应混合物中回收，通过在0.6至3摩尔三烷基胺存在的情况下，正链烷与2.2至4.5摩尔甲醛在水溶液中的反应，每个量基于1摩尔然后在将粗反应混合物a）加热至100至200℃的过程中随后进行氢化，反应混合物中存在的水通过蒸馏与任何过量的游离三烷基胺基本上分离出来，以三烷基铵甲酸盐形式存在的三烷基胺可以形成甲酸三羟甲基烷烃，在存在或不存在催化量的碱金属醇盐的条件下，将三烷基胺蒸馏除去，甲醇三甲氧基链烷烃甲酯与甲醇酯交换为三羟甲基烷烃和甲酸甲酯，或碱土金属醇盐或b）基本脱水，任何过量游离的三烷基胺为同时除去以三烷基甲酸铵形式存在的三烷基胺，通过将剩余的混合物与甲醇混合并将混合物加热至100至200℃以分离，形成甲酸甲酯和三烷基胺。

7. 发明授权

US4965362A Joint preparation of 3-dialkylaminopropionitriles, bis-(2-cyanoethyl) ether and, if desired, ethylene-cyanohydrin 失效
标题翻译：联合制备3-二烷基氨基丙腈，双（2-氰基乙基）醚和（如果需要）乙烯 - 氰醇
公开(公告)号：US4965362A
公开(公告)日：1990-10-23
申请号：US376373
申请日：1989-07-06
申请人： Franz Merger , Wolfgang Harder , Peter Hettinger , Claus-Ulrich Priester , Dieter Franz , Dieter Voges
发明人： Franz Merger , Wolfgang Harder , Peter Hettinger , Claus-Ulrich Priester , Dieter Franz , Dieter Voges
IPC分类号： C07C253/18 , C07C255/12 , C07C255/13 , C07C255/24
CPC分类号： C07C255/12 , C07C255/13 , C07C255/24
摘要： 3-Dialkylaminopropionitriles ##STR1## where R.sup.1 and R.sup.2 are each C.sub.1 -C.sub.4 -alkyl which may furthermore be bonded to form a 5-membered or 6-membered ring, bis-(2-cyanoethyl) ether IINC--CH.sub.2 --CH.sub.2 --O--CH.sub.2 --CH.sub.2 --CN IIand, if desired, ethylenecyanohydrin IIIHO--CH.sub.2 --CH.sub.2 --CN IIIare prepared jointly by a process in which(a) acrylonitrile and water are reacted in the presence of a base at from 60.degree. to 150.degree. C. to give a mixture of acrylonitrile, water and bis-(2-cyanoethyl) ether II, the base being a mineral base, a quaternary nitrogen base or a mixture of these,(b) this mixture is reacted at about 0.degree.-50.degree. C. with a dialkylamine of the general formula IV ##STR2## to give a mixture of water, a dialkylaminopropionitrile I and bis-(2-cyanoethyl) ether II, and this mixture is separated into its components and(c) if desired, the ether II obtained in proces stage (b) or an aqueous solution of this ether and/or the reacted mixtures containing this ether and obtained from process stage (a) or (b) is allowed to react at from 50.degree. to 150.degree. C. with the dialkylamine IV to give a mixture of a 3-dialkylaminopropionitrile I and ethylenecyanohydrin III, and, if desired, the said mixture is separated into its components.
摘要翻译： 3-二烷基氨基丙腈其中R 1和R 2各自为可以连接形成5元或6元环的C 1 -C 4 - 烷基，双 - （2-氰基乙基）醚II NC-CH 2 -CH 2 - O-CH 2 -CH 2 -CN II和如果需要，乙烯基氰醇III HO-CH 2 -CH 2 -CN III通过以下方法共同制备，其中（a）丙烯腈和水在碱的存在下在60℃至 150℃，得到丙烯腈，水和双 - （2-氰基乙基）醚II的混合物，碱为矿物碱，季氮碱或它们的混合物，（b）该混合物在约0℃ 与二烷基胺（通式IV IV）反应，得到水，二烷基氨基丙腈I和双 - （2-氰基乙基）醚II的混合物，将该混合物分离成其组分，（c ）如果需要，在步骤阶段（b）中获得的醚II或该醚的水溶液和/或含有该醚的反应混合物从工艺步骤（a）或（b）获得，使其与二烷基胺IV在50-150℃下反应，得到3-二烷基氨基丙腈I和乙基烯丙醇III的混合物，如果需要，将所述混合物分离成其组分。

8. 发明授权

US4709072A Joint preparation of ethylene cyanohydrin and its ethers 失效
标题翻译：联合制备乙烯氰醇及其醚
公开(公告)号：US4709072A
公开(公告)日：1987-11-24
申请号：US872967
申请日：1986-06-11
申请人： Franz Merger , Hans-Martin Hutmacher , Peter Hettinger , Dieter Voges , Wolfgang Lengsfeld
发明人： Franz Merger , Hans-Martin Hutmacher , Peter Hettinger , Dieter Voges , Wolfgang Lengsfeld
IPC分类号： C07C253/00 , C07C67/00 , C07C253/30 , C07C255/12 , C07C255/13 , C07C255/45 , C07C121/34 , C07C121/46 , C07C121/75
CPC分类号： C07C255/00
摘要： Ethylene cyanohydrin (Ia) and its ethersR--O--CH.sub.2 --CH.sub.2 --CN Ib(where R is an organic radical) are prepared jointly by reacting an alcohol R--OH (II) with 2,2'-dicyanodiethyl ether (III) in the presence of a base.
摘要翻译：通过使醇R-OH（II）与2,2'-二氰基二乙醚（III）反应制备乙烯氰醇（Ia）及其醚RO-CH2-CH2-CN Ib（其中R是有机基团）存在基地

9. 发明授权

US08496162B2 Carton and carton blank 有权
标题翻译：纸箱和纸箱空白
公开(公告)号：US08496162B2
公开(公告)日：2013-07-30
申请号：US12743174
申请日：2008-11-14
申请人： Peter Hettinger , Jean Michel Auclair
发明人： Peter Hettinger , Jean Michel Auclair
IPC分类号： B65D5/02 , B65D5/46
CPC分类号： B65D71/14 , B65D2571/00759
摘要： A carton (90) for packaging articles comprises top (14) and bottom (18, 20) panels connected together by spaced side walls (12, 16) to form a tubular structure, and a set of end panels (22a, 22b, 22c, 22d) at each end of the tubular structure. Each set of end panels comprises a pair of lower end closure panels (26a, 26b) connected to the side walls respectively. Each lower end closure panel is hingedly interconnected by gusset panel (34a, 34b) to an anchoring panel (24a, 24b) hinged to an adjacent one of the side wall panels. Each anchoring panel extends into the tubular structure and tucked between the adjacent side wall panel and an adjacent article. One of the gusset panels (34a, 34b) is hinged to the adjacent side wall panel (12, 16) by a hinge line (27a, 27b).
摘要翻译：用于包装制品的纸箱（90）包括通过间隔开的侧壁（12,16）连接在一起的顶部（14）和底部（18,20）面板，以形成管状结构，以及一组端板（22a，22b，22c ，22d）在管状结构的每一端。每组端板包括分别连接到侧壁的一对下端封闭板（26a，26b）。每个下端封闭面板通过角撑板（34a，34b）铰接地互连到铰接到相邻一个侧壁面板的锚定板（24a，24b）。每个锚定板延伸到管状结构中并且折叠在相邻的侧壁板和相邻的物品之间。一个角撑板（34a，34b）通过铰链线（27a，27b）铰接到相邻的侧壁板（12,16）。

10. 发明申请

US20110204128A1 CARTON AND CARTON BLANK 审中-公开
标题翻译：纸盒和纸盒
公开(公告)号：US20110204128A1
公开(公告)日：2011-08-25
申请号：US13059061
申请日：2009-08-13
申请人： Peter Hettinger , Andree Menzel
发明人： Peter Hettinger , Andree Menzel
IPC分类号： B65D5/462 , B65D5/46 , B65D5/54
CPC分类号： B65D71/0055 , B65D2571/0016 , B65D2571/00185 , B65D2571/00265 , B65D2571/00277 , B65D2571/0029 , B65D2571/00475 , B65D2571/00512 , B65D2571/00524 , B65D2571/00574 , B65D2571/0066 , B65D2571/00716 , B65D2571/00839
摘要： A carton (1) comprising a plurality of panels for forming a base panel (12), first and second side walls (14, 24) and first and second top panels (16, 22) coupled to one another by first and second handle panels (18, 20) wherein the first and second handle panels are in substantial face contacting relationship such that the first and second top panels form a top wall of the carton and wherein a reinforcing panel (34a, 34b) is provided in face contacting relationship with both the first and second top panels such that the reinforcing panel forms a bridge connecting between the first and second top panels whereby a portion of each of the first and second top panels is at least two-ply in structure.
摘要翻译：一种纸箱（1），包括用于形成底板（12）的多个板，第一和第二侧壁（14,24）以及通过第一和第二手柄板彼此联接的第一和第二顶板（16,22）（18,20），其中所述第一和第二手柄板具有实质的面接触关系，使得所述第一顶板和所述第二顶板形成所述纸箱的顶壁，并且其中提供加强板（34a，34b）的面接触关系与第一和第二顶板两者使得加强板形成连接在第一和第二顶板之间的桥，由此第一和第二顶板中的每一个的一部分的结构至少是两层。

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