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    • 7. 发明授权
    • Preparation of polymer particles
    • 聚合物颗粒的制备
    • US06559217B1
    • 2003-05-06
    • US09958414
    • 2001-10-09
    • Rolf NordalSvein TøgersenPreben Cato Mørk
    • Rolf NordalSvein TøgersenPreben Cato Mørk
    • C08J300
    • C08J9/18C08F257/02C08J2203/12C08J2351/00C08F212/00
    • The invention provides a process for the preparation of polymer particles having a mode particle size of at least 50 &mgr;m which process comprises (a) obtaining a first particulate polymer seed material having a mode particle diameter of no more than 50 &mgr;m; (b) using said first seed material, performing a suspension polymerization involving the steps: (i) forming an aqueous dispersion comprising a polymer seed material, an organic compound (e.g. a polymerization initiator) which has a molecular weight of less than 5000 Daltons and a water solubility of less than 10−2 g/L at 25° C., a stabilizer and optionally an organic solvent (e.g. acetone or a portion of the monomer mentioned below); (ii) allowing said organic compound to diffuse into the seed material to produce an activated seed material; and (iii) contacting said activated seed material with a monomer (e.g. styrene) and with a polymerization initiator and effecting suspension polymerization thereof and (c) optionally impregnating and/or heat treating and/or surface modifying the particulate product of step (b).
    • 本发明提供了一种制备模粒径至少为50μm的聚合物颗粒的方法,该方法包括(a)获得模式粒径不超过50μm的第一粒状聚合物种子材料; (b)使用所述第一种子材料,进行悬浮聚合,其包括以下步骤:(i)形成包含聚合物种子材料的水性分散体,分子量小于5000道尔顿的有机化合物(例如聚合引发剂)和 在25℃下水溶解度小于10-2g / L,稳定剂和任选的有机溶剂(例如丙酮或下述单体的一部分); (ii)允许所述有机化合物扩散到种子材料中以产生活化的种子材料; 和(iii)使所述活化的种子材料与单体(例如苯乙烯)和聚合引发剂接触并进行其悬浮聚合,和(c)任选地浸渍和/或热处理和/或表面改性步骤(b)的颗粒产物, 。