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1. 发明授权

US4980477A Sterically hindered 4-oxy-methylene[2-(norborn-5-enyl)]-2,2,6,6-tetramethyl N-substituted-piperidine derivatives 失效
标题翻译：受阻4-氧基 - 亚甲基[2-（降冰片烯-5-烯基）] - 2,2,6,6-四甲基N-取代哌啶衍生物
公开(公告)号：US4980477A
公开(公告)日：1990-12-25
申请号：US517527
申请日：1990-04-27
申请人： Arnaldo Roggero , Guglielmo Bertolini
发明人： Arnaldo Roggero , Guglielmo Bertolini
IPC分类号： C07D211/46 , C08K5/3435 , C07D211/06 , C07D211/08 , C07D211/44
CPC分类号： C07D211/46 , C08K5/3435
摘要： Sterically hindered amino compounds definable by the general formula (I): ##STR1## where R represents a hydrogen atom, a C.sub.1 -C.sub.18 alkyl radical or a C.sub.7 -C.sub.18 alkaryl radical, are useful as organic polymer stabilizers. Processes for preparing these compounds are described.

2. 发明授权

US4853440A Polymeric stabilizer compounds and process for their preparation 失效
标题翻译：聚合物稳定剂化合物及其制备方法
公开(公告)号：US4853440A
公开(公告)日：1989-08-01
申请号：US57092
申请日：1987-06-02
申请人： Arnaldo Roggero , Guglielmo Bertolini
发明人： Arnaldo Roggero , Guglielmo Bertolini
IPC分类号： C08C19/02 , C08C19/22 , C08C19/44 , C08F8/04 , C08F8/32 , C08L9/00 , C08L23/10 , C08L23/12 , C08L101/00
CPC分类号： C08C19/44 , C08C19/02 , C08L23/10 , C08L9/00
摘要： Polymeric stabilizer compounds are formed by an organic polymeric matrix, of paraffinic character, deriving from a hydrogenated polydiene and bearing bonded at at least one chain end a sterically hindered aminic function.Such polymeric stabilizer compounds are obtained by means of a process, which provides:(a) the polymerization of a diene, by the technique of the living polymers, under the influence of alkyl metal-alkyl or alkyl metal-aryl catalysts, to yield a polydiene bearing on its chain end a terminal metal atom;(b) the reaction of said metal-bearing polydiene with a sterically hindered aminic compound, bearing in its molecule an electrophilic group, in particular a carbonyl group, reactive towards said metal of the metal-bearing polydiene;(c) the catalytic hydrogenation of the polydiene bearing said sterically hindered aminic function at its chain end.The so-obtained compounds are particularly useful in the stabilization of polypropylene towards the U.V. light degrading action.
摘要翻译：聚合稳定剂化合物由具有链烷属性的有机聚合物基质形成，衍生自氢化聚二烯并且在至少一个链端承载空间位阻胺官能团。这种聚合稳定剂化合物是通过一种方法获得的，该方法提供：（a）在烷基金属 - 烷基或烷基金属 - 芳基催化剂的影响下，通过活性聚合物的技术聚合二烯，得到在其末端具有末端金属原子的聚二烯; （b）所述含金属聚二烯与空间位阻胺化合物在其分子中具有对所述含金属聚二烯的所述金属具有反应性的亲电基团，特别是羰基的反应; （c）在其末端具有所述空间位阻胺官能团的聚二烯的催化氢化。如此获得的化合物特别可用于将聚丙烯稳定化为U.V. 轻微的退化行为。

3. 发明授权

US4833211A Process for the preparation of solid polymeric stabilizer compounds 失效
标题翻译：固体高分子稳定剂化合物的制备方法
公开(公告)号：US4833211A
公开(公告)日：1989-05-23
申请号：US19881
申请日：1987-02-27
申请人： Arnaldo Roggero , Mario Clerici , Guglielmo Bertolini
发明人： Arnaldo Roggero , Mario Clerici , Guglielmo Bertolini
IPC分类号： C08L101/00 , C08F8/10 , C08F212/08 , C09K3/00
CPC分类号： C08F8/10
摘要： Solid polymeric stabilizer compound containing the hydroxybenzophenone function, having the general formula (I): ##STR1## wherein: m=from 0.01 to 0.99 (preferably from 0.1 to 0.6);l=from 0.99 to 0.01 (preferably from 0.9 to 0.4):m+l=1;R=H, --OH, --OR" (R"+(C.sub.1 -C.sub.20)-alkyl; aryl, alkylaryl cycloalkyl). halogen, (C.sub.1 -C.sub.20)-alkyl, cycloalkyl;R'=H, (C.sub.1 -C.sub.20)-alkyl, cycloalkyl.Also the process for preparing said solid polymeric stabilizers and the stabilized polymeric compositions comprising at least an organic polymer and a stabilizing amount of said solid polymeric stabilizers are disclosed.
摘要翻译：具有通式（I）的羟基二苯甲酮功能的固体高分子稳定剂化合物：其中：m = 0.01〜0.99（优选为0.1〜0.6）。 l = 0.99至0.01（优选0.9至0.4）：m + 1 = 1; R = H，-OH，-OR“（R”+（C 1 -C 20） - 烷基;芳基，烷基芳基环烷基）。卤素，（C 1 -C 20） - 烷基，环烷基; R'= H，（C 1 -C 20） - 烷基，环烷基。还公开了制备所述固体聚合物稳定剂和包含至少一种有机聚合物和稳定量的所述固体聚合物稳定剂的稳定化聚合物组合物的方法。

4. 发明授权

US4797451A Solid polymeric stabilizer compounds and process for their manufacture 失效
标题翻译：固体聚合物稳定剂化合物及其制备方法
公开(公告)号：US4797451A
公开(公告)日：1989-01-10
申请号：US910885
申请日：1986-09-24
申请人： Arnaldo Roggero , Guglielmo Bertolini , Carlo Busetto
发明人： Arnaldo Roggero , Guglielmo Bertolini , Carlo Busetto
IPC分类号： C08K5/34 , C08C19/22 , C08F8/30 , C08L101/00 , C08F8/42
CPC分类号： C08F8/30 , C08C19/22
摘要： Solid polymeric stabilizer compounds are disclosed comprising an organic polymeric matrix, to which are linked groups containing a sterically hindered aminic function, the organic polymeric matrix being a polymeric matrix of a vinyl-aromatic, aromatic with heteroatoms, dienic or olefinic polymer, containing hydrogen atoms replaceable by metal atoms, the groups containing the sterically hindered aminic function replacing, at least partially, said replaceable-by-metal hydrogen atoms of the matrix.Also disclosed are processes for the preparation of said solid polymeric stabilizers and stabilized polymeric compositions comprising an organic polymer and a stabilizing amount of said solid polymeric stabilizers.
摘要翻译：公开了包含有机聚合物基质的固体聚合物稳定剂化合物，其中是含有空间位阻胺官能团的连接基团，有机聚合物基质是具有杂原子的芳香族芳族化合物，含有氢原子的二烯或烯烃聚合物的聚合物基体由金属原子替代，含有空间位阻氨基官能团的基团至少部分替代了基质的所述可替换的金属氢原子。还公开了制备所述固体聚合物稳定剂和包含有机聚合物和稳定量的所述固体聚合物稳定剂的稳定化聚合物组合物的方法。

5. 发明授权

US5264307A Solid, polymeric, polyether based electrolyte 失效
标题翻译：固体，聚合物，聚醚基电解质
公开(公告)号：US5264307A
公开(公告)日：1993-11-23
申请号：US21199
申请日：1993-02-23
申请人： Maria Andrei , Luca Marchese , Arnaldo Roggero , Marco Ferrari
发明人： Maria Andrei , Luca Marchese , Arnaldo Roggero , Marco Ferrari
IPC分类号： C07C43/16 , C07C69/54 , C08G65/331 , C08L71/02 , H01B1/12 , H01M6/18
CPC分类号： H01M6/181 , C07C43/16 , C07C69/54 , C08G65/331 , C08L71/02 , H01B1/122
摘要： A solid, polymeric electrolyte is prepared by:1) blending:(a) a macromer of formula (I) ##STR1## wherein R =methyl, ethyl, n is an integer comprised within the range of from 2 to 20, x is an integer comprised within the range of from 2 to 5;(b) a difunctional comonomer of formula (II) CH.sub.2 .dbd.C(CH.sub.3)COO(CH.sub.2 CH.sub.2 O).sub.m --CO--(CH.sub.3)C.dbd.CH.sub.2 wherein m is an integer comprised within the range of from 2 to 5; with a molar ratio of the macromer (I) to the difunctional comonomer (II) comprised within the range of from 98:2 to 60:40;(c) an ionic compound in an amount comprised within the range of from 1 to 30% by weight;(d) an oligomer or a dipolar aprotic liquid in an amount comprised within the range of from 0 to 80% by weight;(e) a photoinitiator in an amount comprised within the range of from 0 to 10% by weight; 2) applying the above mixture on an inert support and exposing it to a source of ultraviolet light, thermal radiations, or electron beam.
摘要翻译：固体高分子电解质是通过以下方法制备的：1）共混：（a）式（I）的大分子单体，其中R =甲基，乙基，n是包含在2至20范围内的整数，x是整数在2至5的范围内; （b）式（II）的二官能共聚单体CH 2 = C（CH 3）COO（CH 2 CH 2 O）m -CO-（CH 3）C = CH 2其中m是包含在2至5范围内的整数; 大分子单体（I）与双官能共聚单体（II）的摩尔比在98:2至60:40的范围内; （c）以1至30重量％范围内的量的离子化合物; （d）低聚物或偶极非质子液体，其量为0-80％（重量）; （e）光引发剂，其量为0至10重量％; 2）将上述混合物施加到惰性载体上并将其暴露于紫外光，热辐射或电子束的源。

6. 发明授权

US5219953A Catalytic preparation of semi-aromatic copolyamides and copolyester-amides 失效
标题翻译：催化制备半芳族共聚酰胺和共聚酯酰胺
公开(公告)号：US5219953A
公开(公告)日：1993-06-15
申请号：US605342
申请日：1990-10-30
申请人： Ming-de Liu , Bruno Bresci , Pier L. Magagnini , Nicoletta Maurizi , Ugo Pedretti , Arnaldo Roggero
发明人： Ming-de Liu , Bruno Bresci , Pier L. Magagnini , Nicoletta Maurizi , Ugo Pedretti , Arnaldo Roggero
IPC分类号： C08G69/36 , C08G69/44
CPC分类号： C08G69/36 , C08G69/44
摘要： Semi-aromatic copolyamides and copolyester-amides are obtained by placing an aliphatic polyamide into contact with an aromatic hydroxyacid or aminoacid, by operating at high temperature, under melting conditions, possibly in the presence of a catalyst, with a ratio of the monomer units of aliphatic polyamide to the mols of aromatic hydroxyacid or aminoacid comprised within the range of from 20:1 to 1:1.The semiaromatic copolyamides and copolyester-amides so obtained can display a thermotropic liquid-crystal behavior as a function of their content of aromatic units linked inside the molecular chain. Their elastic modulus results to be improved relatively to the alifatic polyamides used as the starting product, and the elongation at break results to be decreased.Such semiaromatic polyamides and copolyester-amides can find application in the production of high-stiffness articles, by means of moulding or extrusion processes. They can also be used as blends with the usual thermoplastic polymers, in which they act as reinforcer or compatibilizer agents.
摘要翻译：半芳族共聚酰胺和共聚酯酰胺通过将脂族聚酰胺与芳族羟基酸或氨基酸接触，通过在熔融条件下，可能在催化剂存在下在高温下操作而获得，单体单元的比例脂族聚酰胺与芳族羟基酸或氨基酸的摩尔比在20:1至1:1的范围内。如此获得的半芳族共聚酰胺和共聚酯酰胺可以显示出热分散性液晶的性质，作为其分子链内连接的芳族单元的含量的函数。它们的弹性模量相对于用作起始产物的聚酰胺酰胺相对改善，断裂伸长率降低。这种半芳族聚酰胺和共聚酯酰胺可以通过模塑或挤出方法应用于高刚度制品的生产中。它们也可以用作与通常的热塑性聚合物的共混物，其中它们用作增强剂或增容剂。

7. 发明授权

US5169416A Process for preparing modified poly-(2,6-dimethyl-p-oxyphenylene) 失效
标题翻译：制备改性聚（2,6-二甲基-P-氧苯）的方法
公开(公告)号：US5169416A
公开(公告)日：1992-12-08
申请号：US623100
申请日：1990-12-06
申请人： Ugo Pedretti , Alberto Gandini , Arnaldo Roggero , Raffaello Sisto , Claudio Valentini , Amalia Assogna , Alessandro Stopponi
发明人： Ugo Pedretti , Alberto Gandini , Arnaldo Roggero , Raffaello Sisto , Claudio Valentini , Amalia Assogna , Alessandro Stopponi
IPC分类号： B01D71/52 , C08G65/48
CPC分类号： C08G65/485
摘要： A process for preparing a modified, amorphous poly-(2,6-dimethyl-p-oxyphenylene) (PPO) comprises:(a) metalating PPO with a metalating agent, and(b) functionalizing such a metalated PPO by reacting the PPO with a trialkylsilyl halide and/or ethylene oxide; and is characterized in that the reaction of metalation is carried out in an inert liquid vehicle which contains PPO in an at least partially suspended solid form, by operating under metalating conditions of gradually adding metalating agent to such a suspension, either continuously or as discrete portions. Depending on the functionalizing agents used, and on the sequence of addition thereof, the process makes it possible to obtain PPO polymers which are modified with trialkyl-silyl, hydroxyethylene and/or ethyleneoxytrialkyl-silyl functional groups. The modified PPO polymers are particularly suitable for preparing flat membranes, including asymmetrical membranes, for the separation of gas mixtures.

8. 发明授权

US4728702A Method for the termination of living polymers and compounds suitable to that purpose 失效
标题翻译：终止适用于该目的的活性聚合物和化合物的方法
公开(公告)号：US4728702A
公开(公告)日：1988-03-01
申请号：US939304
申请日：1986-12-05
申请人： Arnaldo Roggero , Tito Salvatori
发明人： Arnaldo Roggero , Tito Salvatori
IPC分类号： C08F236/00 , C07C1/00 , C07C2/02 , C07C13/267 , C07C15/44 , C07C67/00 , C08C19/44 , C08F2/38 , C08F8/00 , C08F236/10 , C08F297/00 , C08F297/04 , C08F12/08 , C08F36/06 , C08F36/08
CPC分类号： C08F8/00 , C08C19/44
摘要： Coupling agents suitable to be synthetized by cyclo-oligomerization of 3-methylbutyn-1-ol-3 with subsequent dehydration of the alcohol compounds, and their use in a method for the termination of living polymers obtained by means of the anionic polymerization of diene and/or vinylaromatic monomers.
摘要翻译：适合于通过3-甲基丁-1-醇-3的环低聚合成的偶联剂，随后醇化合物的脱水，以及它们用于终止通过二烯的阴离子聚合获得的活性聚合物的方法和 /或乙烯基芳族单体。

9. 发明授权

US5501920A Solid polymeric electrolyte including a cross-linked polyether encompassing an ion compound and a liquid plasticizer 失效
标题翻译：包括包含离子化合物和液体增塑剂的交联聚醚的固体高分子电解质
公开(公告)号：US5501920A
公开(公告)日：1996-03-26
申请号：US267521
申请日：1994-06-29
申请人： Maria Andrei , Arnaldo Roggero , Massimo Soprani , Alberto Gandini
发明人： Maria Andrei , Arnaldo Roggero , Massimo Soprani , Alberto Gandini
IPC分类号： C08L71/00 , C08F8/00 , C08F8/42 , G01N27/49 , H01B1/06 , H01B1/12 , H01M6/18 , H01M8/02
CPC分类号： G01N27/4045 , C08F8/00 , C08F8/42 , H01B1/122 , H01M6/181 , C08F2800/10 , C08F2810/20 , C08F2810/50
摘要： A solid polymeric electrolytic membrane comprising a solution of an ion compound in a cross-linked polyether including a liquid plasticizer obtained by:a) copolymerizing a vinyl ether of the formula:R--(O--CH.sub.2 --CH.sub.2 --).sub.n --O--CH=CH.sub.2 (I)with an allyl vinyl ether of the formula:CH.sub.2 =CH--CH.sub.2 --(O--CH.sub.2 --CH.sub.2 --).sub.m --O--CH=CH.sub.2 (II)where R is a methyl or ethyl radical, n is an integer ranging from 1 to 16, m is an integer ranging from 1 to 10 and the molar ratio of (I) to (II) is between 70/30 and 95/5, forming an allyl copolymer; b) hydrosilating the allyl double bonds of the allyl copolymer by reaction with trimethoxy or triethoxy silane to form a hydrosilated copolymer; c) cross-linking the hydrosilated copolymer by means of a diprotic cross-linking agent in a plasticizer solution of an oligomer or a dipolar aprotic solvent present in a quantity of 20 to 80% by weight and in the presence of an ion compound, and evaporating the low-boiling compounds formed in step c) to obtain a membrane capable of retaining the liquid plasticizer.
摘要翻译：一种固体聚合物电解质膜，其包含离子化合物在包含液体增塑剂的交联聚醚中的溶液，其通过以下步骤获得：a）使下式的乙烯基醚共聚：R-（O-CH 2 -CH 2 - ）n O-CH = CH 2 （I）与下式的烯丙基乙烯基醚：CH 2 = CH-CH 2 - （O-CH 2 -CH 2 - ）m O-CH = CH 2（II）其中R是甲基或乙基，n是1 至16，m为1〜10的整数，（I）〜（II）的摩尔比为70/30〜95/5，形成烯丙基共聚物; b）通过与三甲氧基或三乙氧基硅烷反应来氢化烯丙基共聚物的烯丙基双键以形成氢化硅烷化共聚物; c）通过二价交联剂在20至80重量％存在的低聚物或偶极非质子溶剂的增塑剂溶液中和在离子化合物的存在下交联氢化硅烷化共聚物，以及蒸发步骤c）中形成的低沸点化合物以获得能够保持液体增塑剂的膜。

10. 发明授权

US5417870A Solid, polyether-bases polymeric electrolyte 失效
标题翻译：固体聚醚基聚合物电解质
公开(公告)号：US5417870A
公开(公告)日：1995-05-23
申请号：US194561
申请日：1994-02-10
申请人： Maria Andrei , Arnaldo Roggero , Massimo Soprani
发明人： Maria Andrei , Arnaldo Roggero , Massimo Soprani
IPC分类号： H01M6/18 , H01G9/025
CPC分类号： H01M6/181
摘要： The instant invention provides a solid, polymeric electrolyte in membrane form, constituted by a solid solution of an ionic compound in a crosslinked polyether, characterized in that said polymeric electrolyte is obtained by (1) blending a prepolymer, an ionic compound, a plasticizer, and a free-radical-generating activator; and (2) applying the resulting blend on an inert carrier and exposing said blend to a source of ultraviolet light, thermal radiation or electron beam, until the blend is completely crosslinked. The instant invention also provides an electrolyte separator for use in electrochemical devices, optical and electrochemical displays and sensors, which comprises the polymeric electrolyte of the instant invention.
摘要翻译：本发明提供一种膜形式的固体聚合物电解质，其由离子化合物在交联聚醚中的固溶体构成，其特征在于，所述聚合物电解质通过以下步骤获得：（1）将预聚物，离子化合物，增塑剂，和自由基产生活化剂; 和（2）将所得共混物施加到惰性载体上，并将所述共混物暴露于紫外线，热辐射或电子束源，直到共混物完全交联。本发明还提供了用于电化学装置的电解质分离器，包括本发明的聚合物电解质的光学和电化学显示器和传感器。

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