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1. 发明授权

US5266670A Selective monohydrosilation of vinyl and ethynyl functional norbornenes and curable products produced thereby 失效
标题翻译：乙烯基和乙炔基功能降冰片烯的选择性单氢化和由此生产的可固化产物
公开(公告)号：US5266670A
公开(公告)日：1993-11-30
申请号：US315737
申请日：1989-02-24
申请人： Steven T. Nakos , Anthony F. Jacobine , David M. Glaser
发明人： Steven T. Nakos , Anthony F. Jacobine , David M. Glaser
IPC分类号： C07F7/14 , C08G75/04 , C08G77/20 , C08G77/38 , C08L83/07 , C07F7/08
CPC分类号： C08G75/045 , C07F7/14 , C08G77/20 , C08G77/38
摘要： A process comprising the steps of:1) reacting a norbornene compound of the formula: ##STR1## where R is H or methyl, R.sup.1 is a direct bond or --C(.dbd.O)O-- and R.sup.2 is vinyl, ethynyl, allyl or propargyl, with a silicon hydride functional compound in the presence of hydrosilation catalyst at a temperature of at least 60 degrees; and2) recovering a product which consists essentially of the addition products of the silicon hydride functional compound to the R.sup.2 group of the norbornene compound and which is substantially free of addition products of the silicon hydride functional compound to the internal ring double bond of the norbornene compound.The products of this process can be used to produce norbornene functional prepolymers which are useful in cureable silicone formulations based on thiolene or hydrosilation cure chemistry.
摘要翻译：一种方法，包括以下步骤：1）使下式的降冰片烯化合物：其中R是H或甲基，R1是直接键或-C（= O）O-，R2是乙烯基，乙炔基，烯丙基或炔丙基与硅氢化物官能化合物在硅氢化催化剂存在下在至少60度的温度下反应; 和2）回收基本上由氢化硅官能化合物的加成产物与降冰片烯化合物的R2基团组成的产物，其基本上不含氢化硅官能化合物与降冰片烯的内环双键的加成产物复合。该方法的产物可用于制备降冰片烯官能预聚物，其可用于基于硫醇或氢化硅烷化固化化学的可固化硅氧烷配方。

2. 发明授权

US07705064B2 Photosensitive compounds, photopolymerizable compositions including the same, and methods of making and using the same 有权
标题翻译：感光性化合物，包含其的光聚合性组合物及其制备和使用方法
公开(公告)号：US07705064B2
公开(公告)日：2010-04-27
申请号：US11781317
申请日：2007-07-23
申请人： Anthony F. Jacobine , John G. Woods , Joel D. Schall , Steven T. Nakos , Andrew D. Messana , David M. Glaser
发明人： Anthony F. Jacobine , John G. Woods , Joel D. Schall , Steven T. Nakos , Andrew D. Messana , David M. Glaser
IPC分类号： C08F2/50 , C08F222/10 , C07C69/587 , C08G16/00
CPC分类号： C08F2/50 , C07C67/347 , C07C255/22 , C08G18/10 , C08G18/672 , C07C69/716 , C08G18/3206 , C08G18/3838 , C08G18/42
摘要： The present invention is directed to reaction products prepared from at least one Michael addition donor material including two or more active methylene hydrogens; and at least one material capable of reacting with a Michael addition donor, the material having one Michael addition acceptor and at least one functional group selected from the group consisting of hydroxy, hydroxyalkyl, vinyl ether, amino, aminoalkyl, carboxy, carboxyalkyl, cyano, and cyanoalkyl groups; or reaction products prepared from (a) at least one Michael addition donor material comprising at least one Michael Addition donor group selected from the group consisting of cyano functional groups and phosphono functional groups; and (b) at least one material capable of reacting with the at least one Michael addition donor group, the material having at least one Michael addition acceptor, wherein the above reaction products are capable of forming free radicals upon exposure to actinic radiation; as well as compositions, and processes for making and using the same.
摘要翻译：本发明涉及由至少一种包含两种或更多种活性亚甲基氢的迈克尔加成供体材料制备的反应产物; 和至少一种能够与迈克尔加成供体反应的材料，所述材料具有一个迈克尔加成受体和至少一种选自羟基，羟基烷基，乙烯基醚，氨基，氨基烷基，羧基，羧基烷基，氰基，和氰基烷基; 或由（a）包含至少一种选自氰基官能团和膦酰基官能团的迈克尔加成供体基团的至少一种迈克尔加成供体材料制备的反应产物; 和（b）至少一种能够与至少一种迈克尔加成供体基团反应的材料，该材料具有至少一种迈克尔加成受体，其中上述反应产物能够在暴露于光化辐射下形成自由基; 以及组合物和制备和使用它们的方法。

3. 发明申请

US20090030106A1 Photosensitive Compounds, Photopolymerizable Compositions Including the Same, and Methods of Making and Using the Same 有权
标题翻译：光敏化合物，包括其的可光聚合组合物及其制备和使用方法
公开(公告)号：US20090030106A1
公开(公告)日：2009-01-29
申请号：US11781317
申请日：2007-07-23
申请人： Anthony F. Jacobine , John G. Woods , Joel D. Schall , Steven T. Nakos , Andrew D. Messana , David M. Glaser
发明人： Anthony F. Jacobine , John G. Woods , Joel D. Schall , Steven T. Nakos , Andrew D. Messana , David M. Glaser
IPC分类号： C08F2/48 , C07C45/00
CPC分类号： C08F2/50 , C07C67/347 , C07C255/22 , C08G18/10 , C08G18/672 , C07C69/716 , C08G18/3206 , C08G18/3838 , C08G18/42
摘要： The present invention is directed to reaction products prepared from at least one Michael addition donor material including two or more active methylene hydrogens; and at least one material capable of reacting with a Michael addition donor, the material having one Michael addition acceptor and at least one functional group selected from the group consisting of hydroxy, hydroxyalkyl, vinyl ether, amino, aminoalkyl, carboxy, carboxyalkyl, cyano, and cyanoalkyl groups; or reaction products prepared from (a) at least one Michael addition donor material comprising at least one Michael Addition donor group selected from the group consisting of cyano functional groups and phosphono functional groups; and (b) at least one material capable of reacting with the at least one Michael addition donor group, the material having at least one Michael addition acceptor, wherein the above reaction products are capable of forming free radicals upon exposure to actinic radiation; as well as compositions, and processes for making and using the same.
摘要翻译：本发明涉及由至少一种包含两种或更多种活性亚甲基氢的迈克尔加成供体材料制备的反应产物; 和至少一种能够与迈克尔加成供体反应的材料，所述材料具有一个迈克尔加成受体和至少一种选自羟基，羟基烷基，乙烯基醚，氨基，氨基烷基，羧基，羧基烷基，氰基，和氰基烷基; 或由（a）包含至少一种选自氰基官能团和膦酰基官能团的迈克尔加成供体基团的至少一种迈克尔加成供体材料制备的反应产物; 和（b）至少一种能够与至少一种迈克尔加成供体基团反应的材料，该材料具有至少一种迈克尔加成受体，其中上述反应产物能够在暴露于光化辐射下形成自由基; 以及组合物和制备和使用它们的方法。

4. 发明申请

US20090012202A1 Acrylated Urethanes, Processes for Making the Same and Curable Compositions Including the Same 审中-公开
标题翻译：丙烯酸聚氨酯，制造相同的方法和包含其的可固化组合物
公开(公告)号：US20090012202A1
公开(公告)日：2009-01-08
申请号：US11772843
申请日：2007-07-03
申请人： Anthony F. Jacobine , John G. Woods , Joel D. Schall , Steven T. Nakos , David M. Glaser
发明人： Anthony F. Jacobine , John G. Woods , Joel D. Schall , Steven T. Nakos , David M. Glaser
IPC分类号： C08G18/04 , C08F2/46 , C08G18/09
CPC分类号： C08F2/48 , C08G18/3212 , C08G18/3275 , C08G18/3281 , C08G18/3876 , C08G18/4277 , C08G18/44 , C08G18/4854 , C08G18/6208 , C08G18/672 , C08G18/755 , C08G18/758 , C08G18/8019 , C08G18/8041 , C08G18/8175 , C09D175/16 , C09J175/16 , C08G18/42 , C08G18/62 , C08G18/48
摘要： The present invention is directed to acrylated urethanes including the reaction product of: (1)(a) at least one urethane having at least two isocyanate groups and at least one acrylate group; and (b) at least one alcohol compound having at least two hydroxyl groups; or (2) (a) at least one isocyanate functional urethane which is the reaction product of at least one alcohol compound selected from the group consisting of amino alcohols, thioether alcohols, phosphino alcohols and mixtures thereof and at least one polyisocyanate; and (b) at least one hydroxy-functional material having at least one acrylate group; curable compositions including the same and processes for making the same.
摘要翻译：本发明涉及丙烯酸酯化的聚氨酯，其包括以下反应产物：（1）（a）至少一种具有至少两个异氰酸酯基团和至少一个丙烯酸酯基团的氨基甲酸酯; 和（b）至少一种具有至少两个羟基的醇化合物; 或（2）（a）至少一种异氰酸酯官能氨基甲酸酯，其是至少一种选自氨基醇，硫醚醇，膦醇及其混合物的醇化合物与至少一种多异氰酸酯的反应产物; 和（b）至少一种具有至少一个丙烯酸酯基团的羟基官能材料; 包括其的可固化组合物及其制备方法。

5. 发明授权

US5171816A Curable norbornenyl functional silicone formulations 失效
标题翻译：可固化的降冰片烯功能硅氧烷配方
公开(公告)号：US5171816A
公开(公告)日：1992-12-15
申请号：US648585
申请日：1991-01-31
申请人： Anthony F. Jacobine , Steven T. Nakos , David M. Glaser
发明人： Anthony F. Jacobine , Steven T. Nakos , David M. Glaser
IPC分类号： C08G75/04 , C08G77/20 , C08G77/38 , C08L83/04 , C08L83/08
CPC分类号： C08L83/04 , C08G75/045 , C08G77/20 , C08G77/38 , C08L83/08 , C08G77/12
摘要： A composition cureable to a solid crosslinked polyorganosiloxane comprises:a) a norbornene functional silicone prepolymer having a plurality of groups of the formula: ##STR1## bound to silicon atoms thereof, where R is H or methyl, R.sup.1 is a direct bond or --C(.dbd.O)O-- and R.sup.4 is ethylene, ethenylene, propylene or propenylene,b) a coreactive silicone prepolymer selected from SiH functional silicones, and alkylthiol functional silicones, said polyorganosiloxanes (a) and (b) being present in an equivalent ratio of between 2:1 and 1:2 norbornene to silicon hydride or alkyl thiol groups, andc) an effective amount of a hydrosilation or thiol-ene cure catalyst, respectively.
摘要翻译：固体交联聚有机硅氧烷可固化的组合物包括：a）降冰片烯官能的硅氧烷预聚物，其具有与下列结合的多个下式的基团：其硅原子，其中R是H或甲基，R 1是直接键或-C （= O）O-和R4是亚乙基，亚乙烯基，丙烯或亚丙烯基，b）选自SiH官能硅氧烷和烷基硫醇官能硅氧烷的共聚活性硅氧烷预聚物，所述聚有机硅氧烷（a）和（b）以 2：1和1：2降冰片烯分别与硅氢化物或烷基硫醇基团，和c）分别有效量的硅氢化或硫醇 - 固化催化剂。

6. 发明授权

US5558937A Optical fiber primary coatings and fibers coated therewith 失效
公开(公告)号：US5558937A
公开(公告)日：1996-09-24
申请号：US433722
申请日：1995-05-03
申请人： John G. Woods , Margaret A. Rakas , Anthony F. Jacobine , Louis M. Alberino , Philip L. Kropp , Donna M. Sutkaitis , David M. Glaser , Steven T. Nakos
发明人： John G. Woods , Margaret A. Rakas , Anthony F. Jacobine , Louis M. Alberino , Philip L. Kropp , Donna M. Sutkaitis , David M. Glaser , Steven T. Nakos
IPC分类号： B29C67/00 , C03C25/10 , C07D263/42 , C08F2/50 , C08F6/02 , C08F8/34 , C08F8/42 , C08G65/332 , C08G73/02 , C08G75/04 , C09D4/00 , G02B6/44 , G03F7/00 , G03F7/027 , G02B6/00 , C08G75/12 , D02G3/00
CPC分类号： G02B6/443 , B29C67/0066 , C03C25/106 , C07D263/42 , C08F6/02 , C08G65/332 , C08G73/028 , C08G75/045 , C09D4/00 , G03F7/0037 , G03F7/0275 , Y10T428/2938
摘要： A curable thiol-ene composition specially adapted for use as a primary coating on optical fibers comprises a polythiol and a compound having a plurality of norbornene groups thereon, are characterized in that one of either the compound having the plurality of norbornene groups or the polythiol has a backbone of a poly(tetramethylene oxide), or is an oligomer thereof, and the poly(tetramethylene oxide) has a molecular weight of between 250 and 5,000. The formulations are relatively low viscosity liquids at practical application temperatures and cure substantially completely with very low irradiation fluence. The formulations cure in ambient air. There is no need to exclude oxygen or to control humidity. The formulations of the invention can be cured using low intensity UV lamps which do not generate significant amounts of heat. The cured products have excellent low temperature flexibility, good humidity and water absorbtion resistance and good thermal oxidative stability. The formulations may be applied to optical fibers using conventional techniques and cured with UV-vis or EB irradiation.

7. 发明授权

US5459175A Optical fiber primary coatings and fibers coated therewith 失效
标题翻译：光纤初级涂层和涂覆的纤维
公开(公告)号：US5459175A
公开(公告)日：1995-10-17
申请号：US80748
申请日：1993-06-22
申请人： John G. Woods , Margaret A. Rakas , Anthony F. Jacobine , Louis M. Alberino , Philip L. Kropp , Donna M. Sutkaitis , David M. Glaser , Steven T. Nakos
发明人： John G. Woods , Margaret A. Rakas , Anthony F. Jacobine , Louis M. Alberino , Philip L. Kropp , Donna M. Sutkaitis , David M. Glaser , Steven T. Nakos
IPC分类号： B29C67/00 , C03C25/10 , C07D263/42 , C08F2/50 , C08F6/02 , C08F8/34 , C08F8/42 , C08G65/332 , C08G73/02 , C08G75/04 , C09D4/00 , G02B6/44 , G03F7/00 , G03F7/027
CPC分类号： G02B6/443 , B29C67/0066 , C03C25/106 , C07D263/42 , C08F6/02 , C08G65/332 , C08G73/028 , C08G75/045 , C09D4/00 , G03F7/0037 , G03F7/0275 , Y10T428/2938
摘要： A curable thiol-ene composition specially adapted for use as a primary coating on optical fibers comprises a polythiol and a compound having a plurality of norbornene groups thereon, are characterized in that one of either the compound having the plurality of norbornene groups or the polythiol has a backbone of a poly(tetramethylene oxide), or is an oligomer thereof, and the poly(tetramethylene oxide) has a molecular weight of between 250 and 5,000. The formulations are relatively low viscosity liquids at practical application temperatures and cure substantially completely with very low irradiation fluence. The formulations cure in ambient air. There is no need to exclude oxygen or to control humidity. The formulations of the invention can be cured using low intensity UV lamps which do not generate significant amounts of heat. The cured products have excellent low temperature flexibility, good humidity and water absorbtion resistance and good thermal oxidative stability. The formulations may be applied to optical fibers using conventional techniques and cured with UV-vis or EB irradiation.
摘要翻译：特别适用于光纤上的初级涂层的可固化硫醇烯组合物包括多硫醇和其上具有多个降冰片烯基团的化合物，其特征在于具有多个降冰片烯基团的化合物或多硫醇中的一种具有聚（四氢呋喃）氧化物的骨架或其低聚物，并且聚（四氢呋喃）的分子量为250-5,000。制剂在实际应用温度下是相对低粘度的液体，并且以非常低的照射能量密度完全固化。配方在环境空气中固化。不需要排除氧气或控制湿度。本发明的配方可以使用不产生大量热量的低强度UV灯来固化。固化产物具有优异的低温柔韧性，良好的湿度和吸水性，良好的热氧化稳定性。可以使用常规技术将制剂施用于光纤并用UV-vis或EB辐照固化。

8. 发明授权

US5034490A Curable norbornenyl functional silicone formulations 失效
标题翻译：可固化的降冰片烯功能硅氧烷配方
公开(公告)号：US5034490A
公开(公告)日：1991-07-23
申请号：US315431
申请日：1989-02-24
申请人： Anthony F. Jacobine , David M. Glaser , Steven T. Nakos
发明人： Anthony F. Jacobine , David M. Glaser , Steven T. Nakos
IPC分类号： C08L83/05 , C08G75/04 , C08G77/20 , C08G77/38 , C08L83/04 , C08L83/06 , C08L83/07 , C08L83/08
CPC分类号： C08L83/04 , C08G75/045 , C08G77/20 , C08G77/38 , C08L83/06 , C08L83/08 , C08G77/12
摘要： A composition cureable to a solid crosslinked polyorganosiloxane comprises:a) a norbornene functional silicone prepolymer having a plurality of groups of the formula: ##STR1## bound to silicone atoms thereof, where R is H or methyl, R.sup.1 is a direct bond of --C(.dbd.O)O-- and R.sup.4 is ethylene, ethenylene, propylene or propenylene,b) a coreactive silicone prepolymer selected from SiH functional silicones, and alkylthiol functional silicones, said polyorganosiloxanes (a) and (b) being present in an equivalent ratio of between 2:1 and 1:2 norbornene to silicon hydride or alkyl thiol groups, andc) an effective amount of a hydrosilation or thiol-ene cure catalyst, respectively.
摘要翻译：可固化至固体交联聚有机硅氧烷的组合物包括：a）降冰片烯官能的硅氧烷预聚物，其具有与下列结合的多个下式的基团：其硅氧烷原子，其中R为H或甲基，R 1为-C （= O）O-和R4是亚乙基，亚乙烯基，丙烯或亚丙烯基，b）选自SiH官能硅氧烷和烷基硫醇官能硅氧烷的共聚活性硅氧烷预聚物，所述聚有机硅氧烷（a）和（b）以 2：1和1：2降冰片烯分别与硅氢化物或烷基硫醇基团，和c）分别有效量的硅氢化或硫醇 - 固化催化剂。

9. 发明授权

US08829136B2 Apparatus and methods for controlled radical polymerization 有权
标题翻译：用于受控自由基聚合的装置和方法
公开(公告)号：US08829136B2
公开(公告)日：2014-09-09
申请号：US12946895
申请日：2010-11-16
申请人： David M. Glaser , Roderick Coffey , John G. Woods, III , Anthony F. Jacobine
发明人： David M. Glaser , Roderick Coffey , John G. Woods, III , Anthony F. Jacobine
IPC分类号： C08F20/10 , B01J19/18 , C08F2/00 , B01J14/00 , C08F293/00 , B01J16/00 , B01J19/00 , C08F220/18
CPC分类号： C08F220/18 , B01J14/005 , B01J16/005 , B01J19/0066 , B01J19/1881 , B01J2219/00063 , B01J2219/00069 , B01J2219/00094 , B01J2219/00162 , B01J2219/002 , B01J2219/00213 , B01J2219/00231 , B01J2219/00238 , C08F2/00 , C08F293/005 , C08F2438/01
摘要： A method of conducting controlled radical polymerization, including: (a) providing a mixture of at least one monomer; at least one monomer solvent; at least one compound metal coordinating capable; and at least one initiator; (b) directing the mixture at a rate over a solid catalyst surface contained in an external chamber to the vessel, the catalyst including a metal or metal compound capable of at least two oxidation states; (c) monitoring the reaction vessel temperature; (d) adjusting the flow rate when the temperature is outside a selected temperature range; and (e) allowing the polymerization to proceed to desired conversion level.
摘要翻译：一种进行受控自由基聚合的方法，包括：（a）提供至少一种单体的混合物; 至少一种单体溶剂; 至少一种配位的复合金属; 和至少一个引发剂; （b）以混合物的速率将包含在外部室中的固体催化剂表面的速率引导至容器，所述催化剂包括能够具有至少两种氧化态的金属或金属化合物; （c）监测反应容器的温度; （d）当温度在选定的温度范围之外时调节流量; 和（e）允许聚合进行到所需的转化水平。

10. 发明授权

US5028661A Adhesion promoters for thiolene adhesive formulations 失效
标题翻译：硫醇粘合剂配方的粘合促进剂
公开(公告)号：US5028661A
公开(公告)日：1991-07-02
申请号：US443046
申请日：1989-11-27
申请人： Paul J. Clark , Anthony F. Jacobine , David M. Glaser
发明人： Paul J. Clark , Anthony F. Jacobine , David M. Glaser
IPC分类号： C08G75/04
CPC分类号： C08G75/045
摘要： Compounds useful as adhesion promoters for thermally cured thiolene adhesives include a) acrylic or norbornene acid phosphate esters such as ##STR1## b) maleic, acrylic, methacrylic, norbornene dicarboxylic, and fumaric acids and half acid esters and peresters of maleic fumaric and norbornene dicarboxylic acids; and c) norbornene, acrylic or methacrylic silanes having two or three hydrolyzable groups bound to the silicon atom thereof, such as 5-(triacetoxysilyl) norbornene.The adhesion promoters may be employed as surface primers for conventional thiolene compositions. Alternatively the thiolene compositions themselves may be modified by addition of 0.1 to 10% by weight of the adhesion promoter. Preferred thiolene compositions employ norbornene functional ene ingredients.
摘要翻译：可用作热固化硫醇粘合剂的粘合促进剂的化合物包括：a）丙烯酸或降冰片烯酸性磷酸酯，例如马来酸，丙烯酸，甲基丙烯酸，降冰片烯二羧酸和富马酸，马来酸的半酸酯和过酸酯富马酸和降冰片烯二羧酸; 和c）具有两个或三个与其硅原子结合的可水解基团的降冰片烯，丙烯酸或甲基丙烯酸硅烷如5-（三乙酰氧基甲硅烷基）降冰片烯。粘合促进剂可用作常规硫羟组合物的表面引物。或者，硫醇组合物本身可以通过加入0.1至10重量％的粘合促进剂来改性。优选的硫醇组合物使用降冰片烯功能烯成分。

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