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1. 发明授权

US4299992A Process for the selective hydroxymethylation of nitrotoluenes 失效
标题翻译：硝基甲苯选择性羟甲基化方法
公开(公告)号：US4299992A
公开(公告)日：1981-11-10
申请号：US151597
申请日：1980-05-20
申请人： Antal Tungler , Tibor Mathe , Jozsef Petro , Zoltan Bende
发明人： Antal Tungler , Tibor Mathe , Jozsef Petro , Zoltan Bende
IPC分类号： C07C67/00 , C07C201/00 , C07C201/12 , C07C205/19 , C07C205/26 , C07C205/34 , C07C205/37 , C07C29/38 , C07C41/18
CPC分类号： C07C201/12
摘要： The invention relates to a new process for the selective hydroxymethylation of substituted ortho- or paranitrotoluenes of the general formula (I) ##STR1## in order to prepare nitrophenylalkanols of the general formula (II) ##STR2## In the above formulae the nitro group is attached to the benzene ring in ortho or para position related to the methyl group or the hydroxyalkyl side chain, respectively, X stands for hydrogen, fluorine or an alkyl, alkoxy or nitro group, and n is 1, 2 or 3.According to the process of the invention the starting substance is hydroxymethylated with an excess of formaldehyde at a temperature above room temperature in dimethyl formamide and in the presence of a strong base. The reaction is performed in dimethyl formamide containing 0.1 to 1% by weight of water, and the reaction is directed to the formation of the required end-product by properly adjusting the temperature and the amount of formaldehyde and the base with respect to the starting compound of the general formula (I).In this way the required end-products can be prepared selectively also on an industrial scale.
摘要翻译：本发明涉及用于制备通式（I）的取代的邻 - 或对硝基甲苯的选择性羟甲基化的新方法（I），以制备通式（II）的硝基苯基链烷醇。（II）在上述式中，硝基分别在与甲基或羟烷基侧链相关的邻位或对位上与苯环连接，X表示氢，氟或烷基，烷氧基或硝基，n为1,2 或3.根据本发明的方法，在二甲基甲酰胺中和在强碱存在下，在高于室温的温度下，将起始物质用过量的甲醛羟甲基化。反应在含有0.1〜1重量％水的二甲基甲酰胺中进行，通过适当地调节相对于起始化合物的甲醛和碱的温度和量，反应形成所需的最终产物的通式（I）。以这种方式，可以选择性地在工业规模上制备所需的最终产品。

2. 发明授权

US4361500A Process for the preparation of supported metal catalysts 失效
标题翻译：负载金属催化剂的制备方法
公开(公告)号：US4361500A
公开(公告)日：1982-11-30
申请号：US264802
申请日：1981-05-18
申请人： Tibor Mathe , Antal Tungler , Jozsef Petro
发明人： Tibor Mathe , Antal Tungler , Jozsef Petro
IPC分类号： C07B31/00 , B01J23/06 , B01J23/14 , B01J23/18 , B01J23/36 , B01J23/38 , B01J23/40 , B01J23/54 , B01J23/60 , B01J23/62 , B01J23/64 , B01J23/644 , B01J23/70 , B01J23/76 , B01J23/89 , B01J27/24 , B01J37/02 , B01J37/04 , C07C1/22 , C07C5/10 , C07C5/41 , C07C29/141 , C07C29/145 , C07C29/17 , C07C37/00 , C07C45/00 , C07C45/41 , C07C67/00 , C07C209/36 , C07C209/48 , C07D209/08 , B01J31/28 , B01J21/18 , B01J31/26
CPC分类号： C07D209/08 , B01J23/06 , B01J23/14 , B01J23/18 , B01J23/36 , B01J23/54 , B01J23/76 , B01J27/24 , B01J37/0203 , C07C1/22 , C07C209/36 , C07C209/48 , C07C29/141 , C07C29/145 , C07C29/172 , C07C29/175 , C07C37/003 , C07C45/002 , C07C45/006 , C07C45/41 , C07C5/10 , C07C5/417 , C07C2102/10 , C07C2521/04 , C07C2521/08 , C07C2521/18 , C07C2523/42 , C07C2523/44 , C07C2523/656 , C07C2523/755 , Y02P20/52
摘要： The invention relates to a new process for the preparation of a supported metal catalyst containing at least one metal belonging to Group A and optionally at least one metal belonging to Group B, wherein Group A encompasses the metals palladium, rhodium, ruthenium, platinum, iridium, osmium, silver, gold and cadmium and Group B encompasses the metals zinc, mercury, germanium, tin, antimony and lead. According to the invention, the metal(s) is (are) applied onto the support in the presence of at least one compound of the general formula (I), ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 each stands for a straight-chained or branched C.sub.1-20 alkyl group, a C.sub.1-4 hydroxyalkyl group or a phenyl-(C.sub.1-4 alkyl) group optionally having additional substituents, preferably C.sub.1-4 alkyl groups, on the phenyl ring, andX is hydroxy group or the residue of an organic or mineral acid.According to the invention, highly active catalysts can be prepared by an easy and economical process.
摘要翻译：本发明涉及一种制备载体金属催化剂的新方法，该催化剂含有属于A组的至少一种金属和任选的至少一种属于B组的金属，其中A组包括金属钯，铑，钌，铂，铱，镉，银，金，镉和B族包括金属锌，汞，锗，锡，锑和铅。根据本发明，在至少一种通式（I）的化合物，其中R 1，R 2，R 3和R 4各自独立地存在的情况下，将金属（s）施加到载体上对于直链或支链C 1-20烷基，在苯环上任选具有另外的取代基，优选C 1-4烷基的C 1-4羟基烷基或苯基 - （C 1-4烷基），X是羟基或有机或无机酸的残基。根据本发明，可以通过简单和经济的方法制备高活性催化剂。

3. 发明授权

US4021374A Selective hydrogenating catalysts and a process for the preparation thereof 失效
标题翻译：选择性氢化催化剂及其制备方法
公开(公告)号：US4021374A
公开(公告)日：1977-05-03
申请号：US531961
申请日：1974-12-12
申请人： Jozsef Petro , Tibor Mathe , Antal Tungler , Zoltan Csuros
发明人： Jozsef Petro , Tibor Mathe , Antal Tungler , Zoltan Csuros
IPC分类号： B01J23/48 , B01J23/60 , B01J23/89 , C07C45/41 , B01J23/58
CPC分类号： B01J23/48 , B01J23/60 , B01J23/8926 , C07C45/41
摘要： The invention relates to novel selective hydrogenating catalysts comprising at least one platinum group component and at least one of a group IB or group IIB component. These catalysts are prepared by depositing and reducing an ion, complex or hydroxide of at least one metal belonging to the platinum group together with an ion, complex or hydroxide of at least one metal belonging to either of groups IB and IIB of the Periodic System.
摘要翻译：本发明涉及包含至少一种铂族组分和IB族或IIB族组分中的至少一种的新型选择性氢化催化剂。这些催化剂通过将属于铂族的至少一种金属的离子，络合物或氢氧化物与属于周期系统的IB和IIB族中的至少一种金属的离子，络合物或氢氧化物沉积并还原而制备。

4. 发明授权

US4036877A Process for the production of aldehydes 失效
标题翻译：醛的生产工艺
公开(公告)号：US4036877A
公开(公告)日：1977-07-19
申请号：US549143
申请日：1975-02-12
申请人： Jozsef Petro , Tibor Mathe , Antal Tungler
发明人： Jozsef Petro , Tibor Mathe , Antal Tungler
IPC分类号： B01J23/48 , B01J23/60 , B01J23/72 , C07C45/41 , C07C47/00 , C07C47/14 , C07C47/52 , C07D307/46 , C07C63/00 , C07C47/54
CPC分类号： C07D307/46 , B01J23/48 , B01J23/60 , B01J23/72 , C07C201/12 , C07C45/41
摘要： The invention relates to a process for the preparation of aldehydes by hydrogenating carboxylic chlorides of the general formula RCOCl, wherein R stands for alkyl, isoalkyl, substituted alkyl, cycloalkyl, substituted cycloalkyl, aromatic, heterocyclic or substituted heterocyclic group, the substituents being alkyl, halogen, hydroxy, alkoxy, carboxyl, carbonyl and nitro groups wherein the hydrogenation is carried out in the presence of an alloy catalyst comprising at least one element of the platinum group and at least one element of the groups IB and IIB of the periodic system.The invention renders possible the production of aldehydes in a fair yield and at an adequate selectivity.
摘要翻译：本发明涉及通过氢化通式为RCOCl的羧酸氯化物制备醛的方法，其中R代表烷基，异烷基，取代的烷基，环烷基，取代的环烷基，芳族，杂环或取代的杂环基，取代基是烷基，卤素，羟基，烷氧基，羧基，羰基和硝基，其中氢化是在包含铂基团的至少一种元素和周期性体系的IB和IIB族的至少一种元素的合金催化剂的存在下进行的。

5. 发明授权

US4021371A Process for the preparation of metal oxide catalysts and metal oxide supported catalysts 失效
标题翻译：制备金属氧化物催化剂和金属氧化物载体催化剂的方法
公开(公告)号：US4021371A
公开(公告)日：1977-05-03
申请号：US633171
申请日：1975-11-19
申请人： Jozsef Petro , Tibor Mathe , Antal Tungler
发明人： Jozsef Petro , Tibor Mathe , Antal Tungler
IPC分类号： B01J37/00 , B01J29/00 , B01J23/08
CPC分类号： B01J37/00
摘要： The invention relates to a novel method of preparing catalysts containing the oxides and/or oxyhydrates of aluminum, silicon, magnesium or zinc either alone or in combination with each other, or catalysts containing a metal or a metal oxide as active component and an above-identified oxide and/or oxyhydrate or a mixture thereof as support. According to the invention catalysts with excellent activities can be prepared with a simple and economic operation.One proceeds, in accordance with the invention, as follows: powdered metallic aluminum, silicon, magnesium or zinc or a fused mixture thereof, or, when a supported catalyst is to be prepared, a fused mixture also containing one or more catalytically active metals, is admixed with an alkali metal hydroxide or carbonate or an alkaline earth metal hydroxide, said alkaline agent being used in an amount of 0.01 to 2 times the stoichiometric amount with respect to the aluminum, silicon, magnesium and/or zinc component, this mixture is wetted with water, stirred in solid phase, while the evaporated water is supplemented continuously, the resulting crude product is suspended in water, and the suspension is neutralized and/or washed until neutral.
摘要翻译：本发明涉及一种制备含有单独或彼此组合的铝，硅，镁或锌的氧化物和/或氧化合物的催化剂的新方法，或含有金属或金属氧化物作为活性组分的催化剂，鉴定的氧化物和/或氧化水合物或其混合物作为载体。根据本发明，具有优异活性的催化剂可以用简单经济的操作制备。

6. 发明授权

US08052877B2 Chemical process 失效
标题翻译：化学工艺
公开(公告)号：US08052877B2
公开(公告)日：2011-11-08
申请号：US12644418
申请日：2009-12-22
申请人： Antal Tungler , Gabor Bajnoczy , Erzsebet Odor
发明人： Antal Tungler , Gabor Bajnoczy , Erzsebet Odor
IPC分类号： C02F1/70
CPC分类号： C02F1/705 , C02F1/70 , C02F2101/16 , C02F2101/38 , C02F2209/06 , Y10S210/903
摘要： A process for the removal of azide ions from aqueous liquids at alkaline pH by alkali-soluble metals and catalyst or by hydrogen and catalyst.
摘要翻译：通过碱溶性金属和催化剂或氢气和催化剂在碱性pH下从含水液体中除去叠氮离子的方法。

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