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1. 发明申请

US20120283372A1 Rubber Composition Including a Phenolic Resin 有权
标题翻译：包含酚醛树脂的橡胶组合物
公开(公告)号：US20120283372A1
公开(公告)日：2012-11-08
申请号：US13496148
申请日：2010-09-13
申请人： Anne Veyland , José Carlos Araujo Silva , Vincent Hunault
发明人： Anne Veyland , José Carlos Araujo Silva , Vincent Hunault
IPC分类号： C08L7/00 , C08K5/13 , C08K3/04
CPC分类号： C08L21/00 , B60C1/0016 , C08K5/07 , C08L61/06 , Y02T10/862 , C08L2666/16
摘要： A rubber composition which can be used in particular in tires, based on at least one diene elastomer, one reinforcing filler, one crosslinking system, one phenolic resin and one polyaldehyde. The use of a polyaldehyde makes it possible to advantageously replace conventional methylene donors while preventing the production of formaldehyde during the vulcanization of the rubber compositions and thus to limit the environmental impact of these compounds. Furthermore, these polyaldehyde compounds make it possible not only to obtain rubber compositions exhibiting the same low-strain stiffness as conventional rubber compositions using HMT or H3M methylene donors but also, surprisingly, to greatly improve the fatigue strength of the rubber compositions and thus the endurance of the tires.
摘要翻译：基于至少一种二烯弹性体，一种增强填料，一种交联体系，一种酚醛树脂和一种多醛，可特别用于轮胎的橡胶组合物。使用聚醛可以有利地代替常规的亚甲基供体，同时防止在橡胶组合物硫化期间产生甲醛，从而限制这些化合物的环境影响。此外，这些多醛化合物使得不仅可以获得表现出与使用HMT或H3M亚甲基供体的常规橡胶组合物相同的低应变刚度的橡胶组合物，而且令人惊奇的是，大大提高橡胶组合物的疲劳强度，从而耐久性的轮胎。

2. 发明申请

US20120196976A1 USE OF ARYL DINITRILE OXIDES IN ADHESIVE COMPOSITION 审中-公开
标题翻译：在胶粘组合物中使用ARYL DINITRILE氧化物
公开(公告)号：US20120196976A1
公开(公告)日：2012-08-02
申请号：US13258560
申请日：2010-03-30
申请人： José Carlos Araujo Da Silva , Vincent Hunault , Pierre Robert , Anne Veyland
发明人： José Carlos Araujo Da Silva , Vincent Hunault , Pierre Robert , Anne Veyland
IPC分类号： C08L7/00 , C08L9/06 , B60C19/00 , B29D30/06 , B32B37/12 , C08L9/00 , B32B37/14
CPC分类号： B29C73/10 , B29L2030/00 , C08K5/32 , C09J7/29 , Y10T152/10882 , C08L21/00
摘要： The invention relates to the use of an adhesive composition between a vulcanized rubber part and an uncured or prevulcanized or vulcanized rubber part, based on at least one highly unsaturated elastomer chosen from the group formed by natural rubber, polyisoprene, polybutadiene, styrene-butadiene, styrene-isoprene and butadiene-isoprene copolymers and styrene-butadiene-isoprene terpolymers, an aliphatic solvent and a “curing” system comprising at least one stable aryl dinitrile oxide compound.
摘要翻译：本发明涉及在硫化橡胶部分与未固化或预硫化或硫化的橡胶部分之间的粘合剂组合物的用途，所述粘合剂组合物基于至少一种选自天然橡胶，聚异戊二烯，聚丁二烯，苯乙烯 - 丁二烯，苯乙烯 - 异戊二烯和丁二烯 - 异戊二烯共聚物和苯乙烯 - 丁二烯 - 异戊二烯三元共聚物，脂族溶剂和包含至少一种稳定的芳基二腈氧化物化合物的“固化”体系。

3. 发明授权

US09145494B2 Rubber composition including a phenolic resin 有权
标题翻译：包含酚醛树脂的橡胶组合物
公开(公告)号：US09145494B2
公开(公告)日：2015-09-29
申请号：US13496148
申请日：2010-09-13
申请人： Anne Veyland , José Carlos Araujo Da Silva , Vincent Hunault
发明人： Anne Veyland , José Carlos Araujo Da Silva , Vincent Hunault
IPC分类号： C08L61/06 , C08L21/00 , B60C1/00 , C08K5/07
CPC分类号： C08L21/00 , B60C1/0016 , C08K5/07 , C08L61/06 , Y02T10/862 , C08L2666/16
摘要： A rubber composition which can be used in particular in tires, based on at least one diene elastomer, one reinforcing filler, one crosslinking system, one phenolic resin and one polyaldehyde. The use of a polyaldehyde makes it possible to advantageously replace conventional methylene donors while preventing the production of formaldehyde during the vulcanization of the rubber compositions and thus to limit the environmental impact of these compounds. Furthermore, these polyaldehyde compounds make it possible not only to obtain rubber compositions exhibiting the same low-strain stiffness as conventional rubber compositions using HMT or H3M methylene donors but also, surprisingly, to greatly improve the fatigue strength of the rubber compositions and thus the endurance of the tires.
摘要翻译：基于至少一种二烯弹性体，一种增强填料，一种交联体系，一种酚醛树脂和一种多醛，可特别用于轮胎的橡胶组合物。使用聚醛可以有利地代替常规的亚甲基供体，同时防止在橡胶组合物硫化期间产生甲醛，从而限制这些化合物的环境影响。此外，这些多醛化合物使得不仅可以获得表现出与使用HMT或H3M亚甲基供体的常规橡胶组合物相同的低应变刚度的橡胶组合物，而且令人惊奇的是，大大提高橡胶组合物的疲劳强度，从而耐久性的轮胎。

4. 发明授权

US08877839B2 Rubber composition including an expoxide resin 有权
标题翻译：包含过氧化物树脂的橡胶组合物
公开(公告)号：US08877839B2
公开(公告)日：2014-11-04
申请号：US13502341
申请日：2010-10-13
申请人： Anne Veyland , Vincent Hunault , Jose Carlos Araujo Da Silva
发明人： Anne Veyland , Vincent Hunault , Jose Carlos Araujo Da Silva
IPC分类号： C08L63/00 , C08L7/00 , C08L9/00 , C08L21/00 , C08L61/04 , C08K5/17
CPC分类号： C08L9/00 , C08K5/17 , C08L7/00 , C08L21/00 , C08L61/04 , C08L63/00 , Y02T10/862 , C08L2666/16 , C08L2666/22 , C08L2666/14
摘要： A rubber composition which can be used in particular in tires, based on at least one diene elastomer, one reinforcing filler, one crosslinking system, between 1 and 20 phr of an epoxide resin and between 1 and 15 phr of an amine-comprising curing agent. The pair formed of epoxide resin with an amine-comprising curing agent advantageously replaces the pair formed of phenollformaldehyde resin, which is a methylene acceptor, with the curing agent(s) HMT or H3M, which are conventional methylene donors. The use of this pair of reactants, epoxide resin and amine-comprising curing agent, makes it possible to obtain rubber compositions exhibiting a greater low-strain stiffness in comparison with conventional rubber compositions, without significantly damaging the hysteresis. Moreover, the combination of a phenolic resin, which is a methylene acceptor, with HMT or H3M, which is a methylene donor, produces formaldehyde during the vulcanization of the rubber composition. In point of fact, it is desirable to reduce, indeed even in the long run to eliminate, the formaldehyde of rubber compositions due to the environmental impact of this compound.
摘要翻译：基于至少一种二烯弹性体，一种增强填料，一种交联体系，1至20phr的环氧树脂和1至15phr的含胺固化剂之间可以特别用于轮胎的橡胶组合物。由环氧树脂与含胺固化剂形成的一对有利地用作为常规亚甲基供体的固化剂HMT或H3M替代由亚甲基受体的苯甲醛树脂形成的一对。使用这对反应物，环氧树脂和含胺固化剂，可以获得与常规橡胶组合物相比具有更高的低应变刚度的橡胶组合物，而不会显着损伤滞后。此外，作为亚甲基受体的酚醛树脂与作为亚甲基供体的HMT或H3M的组合在橡胶组合物硫化期间产生甲醛。实际上，由于这种化合物的环境影响，希望减少甚至长期消除橡胶组合物的甲醛。

5. 发明申请

US20120283360A1 Rubber Composition Including an Expoxide Resin 有权
标题翻译：含有过氧化物树脂的橡胶组合物
公开(公告)号：US20120283360A1
公开(公告)日：2012-11-08
申请号：US13502341
申请日：2010-10-13
申请人： Anne Veyland , Vincent Hunault , Jose Carlos Araujo Da Silva
发明人： Anne Veyland , Vincent Hunault , Jose Carlos Araujo Da Silva
IPC分类号： C08L63/00
CPC分类号： C08L9/00 , C08K5/17 , C08L7/00 , C08L21/00 , C08L61/04 , C08L63/00 , Y02T10/862 , C08L2666/16 , C08L2666/22 , C08L2666/14
摘要： A rubber composition which can be used in particular in tires, based on at least one diene elastomer, one reinforcing filler, one crosslinking system, between 1 and 20 phr of an epoxide resin and between 1 and 15 phr of an amine-comprising curing agent. The pair formed of epoxide resin with an amine-comprising curing agent advantageously replaces the pair formed of phenol/formaldehyde resin, which is a methylene acceptor, with the curing agent(s) HMT or H3M, which are conventional methylene donors. The use of this pair of reactants, epoxide resin and amine-comprising curing agent, makes it possible to obtain rubber compositions exhibiting a greater low-strain stiffness in comparison with conventional rubber compositions, without significantly damaging the hysteresis. Moreover, the combination of a phenolic resin, which is a methylene acceptor, with HMT or H3M, which is a methylene donor, produces formaldehyde during the vulcanization of the rubber composition. In point of fact, it is desirable to reduce, indeed even in the long run to eliminate, the formaldehyde of rubber compositions due to the environmental impact of this compound.
摘要翻译：基于至少一种二烯弹性体，一种增强填料，一种交联体系，1至20phr的环氧树脂和1至15phr的含胺固化剂之间可以特别用于轮胎的橡胶组合物。由环氧树脂与含胺固化剂形成的一对有利地将作为亚甲基受体的苯酚/甲醛树脂形成的对与作为常规亚甲基供体的固化剂HMT或H3M取代。使用这对反应物，环氧树脂和含胺固化剂，可以获得与常规橡胶组合物相比具有更高的低应变刚度的橡胶组合物，而不会显着损伤滞后。此外，作为亚甲基受体的酚醛树脂与作为亚甲基供体的HMT或H3M的组合在橡胶组合物硫化期间产生甲醛。事实上，由于该化合物的环境影响，希望减少，甚至长期以消除橡胶组合物的甲醛。

6. 发明授权

US09487049B2 Rubber composition for magnesium hydroxide wafer-reinforced tire 有权
标题翻译：氢氧化镁晶片加固轮胎橡胶组合物
公开(公告)号：US09487049B2
公开(公告)日：2016-11-08
申请号：US11988217
申请日：2006-07-04
申请人： Arnaud Lapra , Franck Varagniat , Anne Veyland
发明人： Arnaud Lapra , Franck Varagniat , Anne Veyland
IPC分类号： B60C1/00 , C08K3/22 , C08K9/02 , C08K5/548 , C08K7/00
CPC分类号： B60C1/0016 , C08K3/22 , C08K5/548 , C08K7/00 , C08K9/02 , Y10T428/25 , Y10T428/266 , C08L21/00
摘要： The invention relates to a rubber composition having improved vulcanization kinetics, which can be used in particular for manufacturing tires or semi-finished products for tires, based on at least one diene elastomer, a reinforcing filler and a coupling agent providing the bond between filler and elastomer, characterized in that said reinforcing filler comprises synthetic magnesium hydroxide Mg(OH)2 wafers, covered with silica. The invention also relates to the use of such a composition for manufacturing rubber articles, in particular tires or semi-finished products made of rubber intended for these tires, especially treads. The invention also relates, per se, to this synthetic magnesium hydroxide in the form of silica-covered wafers, and also to its use as a reinforcing filler, especially in a diene elastomer matrix.
摘要翻译：本发明涉及一种具有改进的硫化动力学的橡胶组合物，其可以特别用于制造用于轮胎的轮胎或半成品，基于至少一种二烯弹性体，增强填料和提供填料与弹性体，其特征在于，所述增强填料包括用二氧化硅覆盖的合成氢氧化镁Mg（OH）2晶片。本发明还涉及这种组合物用于制造橡胶制品，特别是用于这些轮胎的橡胶制成的轮胎或半成品，特别是胎面的用途。本发明本身还涉及以二氧化硅覆盖的晶片的形式的这种合成氢氧化镁，并且还涉及其用作增强填料，特别是在二烯弹性体基质中的用途。

7. 发明授权

US09187620B2 Rubber composition comprising a thiadiazole 有权
标题翻译：包含噻二唑的橡胶组合物
公开(公告)号：US09187620B2
公开(公告)日：2015-11-17
申请号：US13501090
申请日：2010-10-08
申请人： Anne Veyland , Nicolas Seeboth , Jose Carlos Araujo Da Silva
发明人： Anne Veyland , Nicolas Seeboth , Jose Carlos Araujo Da Silva
IPC分类号： C08L7/00 , C08K5/46 , B60C1/00 , C07D285/125 , C08K5/00 , C08K5/47 , C08L9/06
CPC分类号： C08K5/46 , B60C1/00 , C07D285/125 , C08K5/0025 , C08K5/47 , C08L9/06 , C08L21/00
摘要： A rubber composition for the manufacture of tires, based on one or more diene elastomers, on one or more reinforcing fillers and on a vulcanization system, characterized in that the said vulcanization system comprises one or more thiadiazole compounds of formula:
摘要翻译：一种用于在一种或多种增强填料上和硫化体系上制造基于一种或多种二烯弹性体的轮胎的橡胶组合物，其特征在于所述硫化体系包含一种或多种下式的噻二唑化合物：

8. 发明申请

US20140371345A1 RUBBER TIRE COMPOSITION COMPRISING AN AZO-SILANE COUPLING AGENT 审中-公开
标题翻译：包含AZO-硅烷偶联剂的橡胶轮胎组合物
公开(公告)号：US20140371345A1
公开(公告)日：2014-12-18
申请号：US14008832
申请日：2012-03-28
申请人： Christelle Darnaud , José Carlos Araujo Da Silva , Karine Longchambon , Anne Veyland
发明人： Christelle Darnaud , José Carlos Araujo Da Silva , Karine Longchambon , Anne Veyland
IPC分类号： C08K5/5455 , C08K13/02 , C08K3/36 , C08L7/00 , C08K3/04
CPC分类号： C08K5/5455 , C08K3/04 , C08K3/36 , C08K13/02 , C08L7/00 , C08L21/00
摘要： A tire rubber composition based on at least one diene elastomer, an inorganic filler as reinforcing filler, a coupling agent providing the bonding between the inorganic filler and the diene elastomer, wherein the coupling agent is an azosilane compound of formula (I): (G1)3-a(G2)aSi—Z—NH—C(O)—N═N—C(O)—NH—Z—Si(G1)3-a(G2)a (I) wherein: G1, identical to or different, each represent a monovalent hydrocarbon group chosen from branched or unbranched, substituted or unsubstituted alkyls having from 1 to 18 carbon atoms, substituted or unsubstituted cycloalkyls or aryls having from 5 to 18 carbon atoms, G2, identical to or different, each represent a hydroxyl group or a monovalent group chosen from branched or unbranched, substituted or unsubstituted alkoxyls having from 1 to 18 carbon atoms, substituted or unsubstituted cycloalkoxyls having from 5 to 18 carbon atoms, Z represents a divalent linking group having from 1 to 18 carbon atoms, a is equal to 1, 2 or 3.
摘要翻译：一种基于至少一种二烯弹性体，无机填料作为增强填料的轮胎橡胶组合物，提供无机填料和二烯弹性体之间的结合的偶联剂，其中偶联剂是式（I）的偶氮硅烷化合物：（G1 ）3-a（G2）aSi-Z-NH-C（O）-N = N-C（O）-NH-Z-Si（G1）3-a（G2）a（I）其中：G1，各自表示选自具有1至18个碳原子的支链或非支链，取代或未取代的烷基，取代或未取代的环烷基或具有5至18个碳原子的芳基，G 2，各自相同或不同的一价烃基表示选自具有1至18个碳原子的支链或非支链，取代或未取代烷氧基的羟基或一价基团，具有5至18个碳原子的取代或未取代的环烷氧基，Z表示具有1至18个碳原子的二价连接基团原子a等于1,2或3。

9. 发明申请

US20090297827A1 Rubber Composition for Magnesium Hydroxide Wafer-Reinforced Tire 有权
标题翻译：氢氧化镁晶片加强轮胎的橡胶组合物
公开(公告)号：US20090297827A1
公开(公告)日：2009-12-03
申请号：US11988217
申请日：2006-07-04
申请人： Arnaud Lapra , Franck Varagniat , Anne Veyland
发明人： Arnaud Lapra , Franck Varagniat , Anne Veyland
IPC分类号： B32B5/16 , C08K11/00 , B32B17/06 , B32B5/00
CPC分类号： B60C1/0016 , C08K3/22 , C08K5/548 , C08K7/00 , C08K9/02 , Y10T428/25 , Y10T428/266 , C08L21/00
摘要： The invention relates to a rubber composition having improved vulcanisation kinetics, which can be used in particular for manufacturing tyres or semi-finished products for tyres, based on at least one diene elastomer, a reinforcing filler and a coupling agent providing the bond between filler and elastomer, characterized in that said reinforcing filler comprises synthetic magnesium hydroxide Mg(OH)2 wafers, covered with silica. The invention also relates to the use of such a composition for manufacturing rubber articles, in particular tyres or semi-finished products made of rubber intended for these tyres, especially treads. The invention also relates, per se, to this synthetic magnesium hydroxide in the form of silica-covered wafers, and also to its use as a reinforcing filler, especially in a diene elastomer matrix.
摘要翻译：本发明涉及一种具有改进的硫化动力学的橡胶组合物，其特别可用于制造用于轮胎的轮胎或半成品，基于至少一种二烯弹性体，增强填料和提供填料与弹性体，其特征在于，所述增强填料包括用二氧化硅覆盖的合成氢氧化镁Mg（OH）2晶片。本发明还涉及这种组合物用于制造橡胶制品，特别是用于这些轮胎的橡胶制成的轮胎或半成品，特别是胎面的用途。本发明本身还涉及以二氧化硅覆盖的晶片的形式的这种合成氢氧化镁，并且还涉及其用作增强填料，特别是在二烯弹性体基质中的用途。

10. 发明授权

US09624358B2 Rubber tire composition comprising an azo-silane coupling agent 有权
公开(公告)号：US09624358B2
公开(公告)日：2017-04-18
申请号：US14008620
申请日：2012-03-28
申请人： Christelle Darnaud , José Carlos Araujo Da Silva , Karine Longchambon , Anne Veyland
发明人： Christelle Darnaud , José Carlos Araujo Da Silva , Karine Longchambon , Anne Veyland
IPC分类号： C08K3/36 , C08K5/5455 , C08L7/00 , C08L21/00 , C08F136/08
CPC分类号： C08K5/5455 , C08F136/08 , C08K3/36 , C08L7/00 , C08L21/00
摘要： The invention relates to a tire rubber composition based on at least one diene elastomer, an inorganic filler as reinforcing filler, a coupling agent providing the bonding between the inorganic filler and the diene elastomer, characterized in that the coupling agent is an azosilane compound of following formula (I): (G1)3-a(G2)aSi—Z—NH—C(O)—N═N—C(O)—NH—Z—Si(G1)3-a(G2)a (I) in which: G1, identical to or different from one another, each represent a monovalent hydrocarbon-based group chosen from branched or unbranched, substituted or unsubstituted alkyls, having from 1 to 18 carbon atoms, substituted or unsubstituted cycloalkyls or aryls, having from 5 to 18 carbon atoms, G2, identical to or different from one another, each represent a hydroxyl group or a monovalent group in the form (G3)n-OG1 in which G3 is a divalent linking group having from 1 to 18 carbon atoms and comprising one or more heteroatoms chosen from O, S, Si and N, n being a number equal to or higher than 0 and less than or equal to 18, Z represents a divalent linking group having from 1 to 18 carbon atoms, a is equal to 1, 2 or 3.

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