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1. 发明授权

US09487049B2 Rubber composition for magnesium hydroxide wafer-reinforced tire 有权
标题翻译：氢氧化镁晶片加固轮胎橡胶组合物
公开(公告)号：US09487049B2
公开(公告)日：2016-11-08
申请号：US11988217
申请日：2006-07-04
申请人： Arnaud Lapra , Franck Varagniat , Anne Veyland
发明人： Arnaud Lapra , Franck Varagniat , Anne Veyland
IPC分类号： B60C1/00 , C08K3/22 , C08K9/02 , C08K5/548 , C08K7/00
CPC分类号： B60C1/0016 , C08K3/22 , C08K5/548 , C08K7/00 , C08K9/02 , Y10T428/25 , Y10T428/266 , C08L21/00
摘要： The invention relates to a rubber composition having improved vulcanization kinetics, which can be used in particular for manufacturing tires or semi-finished products for tires, based on at least one diene elastomer, a reinforcing filler and a coupling agent providing the bond between filler and elastomer, characterized in that said reinforcing filler comprises synthetic magnesium hydroxide Mg(OH)2 wafers, covered with silica. The invention also relates to the use of such a composition for manufacturing rubber articles, in particular tires or semi-finished products made of rubber intended for these tires, especially treads. The invention also relates, per se, to this synthetic magnesium hydroxide in the form of silica-covered wafers, and also to its use as a reinforcing filler, especially in a diene elastomer matrix.
摘要翻译：本发明涉及一种具有改进的硫化动力学的橡胶组合物，其可以特别用于制造用于轮胎的轮胎或半成品，基于至少一种二烯弹性体，增强填料和提供填料与弹性体，其特征在于，所述增强填料包括用二氧化硅覆盖的合成氢氧化镁Mg（OH）2晶片。本发明还涉及这种组合物用于制造橡胶制品，特别是用于这些轮胎的橡胶制成的轮胎或半成品，特别是胎面的用途。本发明本身还涉及以二氧化硅覆盖的晶片的形式的这种合成氢氧化镁，并且还涉及其用作增强填料，特别是在二烯弹性体基质中的用途。

2. 发明申请

US20090297827A1 Rubber Composition for Magnesium Hydroxide Wafer-Reinforced Tire 有权
标题翻译：氢氧化镁晶片加强轮胎的橡胶组合物
公开(公告)号：US20090297827A1
公开(公告)日：2009-12-03
申请号：US11988217
申请日：2006-07-04
申请人： Arnaud Lapra , Franck Varagniat , Anne Veyland
发明人： Arnaud Lapra , Franck Varagniat , Anne Veyland
IPC分类号： B32B5/16 , C08K11/00 , B32B17/06 , B32B5/00
CPC分类号： B60C1/0016 , C08K3/22 , C08K5/548 , C08K7/00 , C08K9/02 , Y10T428/25 , Y10T428/266 , C08L21/00
摘要： The invention relates to a rubber composition having improved vulcanisation kinetics, which can be used in particular for manufacturing tyres or semi-finished products for tyres, based on at least one diene elastomer, a reinforcing filler and a coupling agent providing the bond between filler and elastomer, characterized in that said reinforcing filler comprises synthetic magnesium hydroxide Mg(OH)2 wafers, covered with silica. The invention also relates to the use of such a composition for manufacturing rubber articles, in particular tyres or semi-finished products made of rubber intended for these tyres, especially treads. The invention also relates, per se, to this synthetic magnesium hydroxide in the form of silica-covered wafers, and also to its use as a reinforcing filler, especially in a diene elastomer matrix.
摘要翻译：本发明涉及一种具有改进的硫化动力学的橡胶组合物，其特别可用于制造用于轮胎的轮胎或半成品，基于至少一种二烯弹性体，增强填料和提供填料与弹性体，其特征在于，所述增强填料包括用二氧化硅覆盖的合成氢氧化镁Mg（OH）2晶片。本发明还涉及这种组合物用于制造橡胶制品，特别是用于这些轮胎的橡胶制成的轮胎或半成品，特别是胎面的用途。本发明本身还涉及以二氧化硅覆盖的晶片的形式的这种合成氢氧化镁，并且还涉及其用作增强填料，特别是在二烯弹性体基质中的用途。

3. 发明授权

US07718717B2 Tyre rubber composition based on a reinforcing metal hydroxide 有权
标题翻译：基于增强金属氢氧化物的轮胎橡胶组合物
公开(公告)号：US07718717B2
公开(公告)日：2010-05-18
申请号：US11631820
申请日：2005-07-06
申请人： Arnaud Lapra , Franck Varagniat , Anne Veyland
发明人： Arnaud Lapra , Franck Varagniat , Anne Veyland
IPC分类号： C08K9/02
CPC分类号： C08K9/02 , C08K3/22 , C08L21/00
摘要： A rubber composition usable for the manufacture of tyres, based on at least a diene elastomer, a reinforcing filler and a coupling agent, characterised in that said filler comprises a synthetic metal hydroxide covered with silica, the metal of the hydroxide being selected from the group consisting of Al, Fe, Mg and mixtures of these metals. Use as reinforcing filler, in a diene rubber composition, of such a metal hydroxide. The metal hydroxide is preferably constituted of aggregates (secondary particles) of anisometric form, the primary particles possibly themselves being of anisometric form, for example in the form of rods, which imparts to the compositions of the invention anisotropic properties which are advantageous for separating their mechanical properties. Use of such a rubber composition for the manufacture of rubber articles, in particular of tyres or semi-finished products made of rubber intended for these tyres, in particular of treads.
摘要翻译：一种可用于制造基于至少二烯弹性体，增强填料和偶联剂的轮胎的橡胶组合物，其特征在于所述填料包括用二氧化硅覆盖的合成金属氢氧化物，所述氢氧化物的金属选自由Al，Fe，Mg和这些金属的混合物组成。在二烯橡胶组合物中用作这种金属氢氧化物的增强填料。金属氢氧化物优选由不等角度形式的聚集体（二次颗粒）构成，主要颗粒本身可以是不规则形式，例如以棒的形式，赋予本发明组合物各向异性特性，这有利于分离它们机械性能。使用这种橡胶组合物来制造橡胶制品，特别是用于这些轮胎的橡胶制成的轮胎或半成品，特别是胎面。

4. 发明授权

US07820771B2 Elastomeric composition reinforced with a functionalized polyvinylaromatic filler 有权
标题翻译：用官能化聚乙烯基芳族填料增强的弹性组合物
公开(公告)号：US07820771B2
公开(公告)日：2010-10-26
申请号：US11794451
申请日：2005-12-30
申请人： Arnaud Lapra , Sylvie Gandon-Pain , Franck Varagniat
发明人： Arnaud Lapra , Sylvie Gandon-Pain , Franck Varagniat
IPC分类号： C08F283/12 , C08L27/10 , C08L25/00 , C08L21/00 , B60C1/00
CPC分类号： B60C9/08 , C08L9/00 , C08L21/00 , C08L25/04 , C08L25/16 , Y10S526/909 , C08L2666/06 , C08L2666/08
摘要： Rubber composition based on at least one diene elastomer, a polymeric filler as reinforcing filler and a coupling agent for bonding between the polymeric filler and the elastomer. The polymeric filler includes nanoparticles of a polyvinylaromatic (PVAr) carrying a functional group denoted by Z of formula a ≡Si—X, X representing a hydroxyl or hydrolyzable group. The PVAr is especially a copolymer of styrene, ethylvinylbenzene, divinylbenzene and trimethoxysilylpropylacrylate or trimethoxysilylpropylmethacrylate, being in the form of nanobeads, the diameter of which is between 10 and 100 nm. Also described is a method of obtaining such a composition, and use of such a rubber composition for the manufacture of rubber articles, in particular tires or rubber semi-finished products intended for these tires, as well as a masterbatch including at least one diene elastomer and such a polymeric filler, and a method of obtaining such a masterbatch.
摘要翻译：基于至少一种二烯弹性体的橡胶组合物，作为增强填料的聚合物填料和用于在聚合物填料和弹性体之间粘合的偶联剂。聚合物填料包括携带由式a≡Si-X的Z表示的官能团的聚乙烯基芳族化合物（PVAr）的纳米颗粒，X表示羟基或可水解基团。 PVAr特别是苯乙烯，乙基乙烯基苯，二乙烯基苯和丙烯酸三甲氧基甲硅烷基丙酯或三甲氧基甲硅烷基丙基甲基丙烯酸酯的共聚物，其形式为纳米棒，直径为10至100nm。还描述了获得这种组合物的方法，以及使用这种橡胶组合物来制造橡胶制品，特别是用于这些轮胎的轮胎或橡胶半成品，以及包含至少一种二烯弹性体和这种聚合物填料，以及获得这种母料的方法。

5. 发明申请

US20100022714A1 ELASTOMERIC COMPOSITION REINFORCED WITH A FUNTIONALIZED NON-AROMATIC VINYL POLYMER FILLER 有权
标题翻译：用非官能化的非芳香族聚合物填料填充的弹性体组合物
公开(公告)号：US20100022714A1
公开(公告)日：2010-01-28
申请号：US12309076
申请日：2007-06-29
申请人： Franck Varagniat , Sylvie Gandon-Pain , Arnaud Lapra
发明人： Franck Varagniat , Sylvie Gandon-Pain , Arnaud Lapra
IPC分类号： C08L43/04
CPC分类号： B60C1/00 , B60C1/0016 , C08L21/00 , C08L33/068 , C08L33/08 , C08L33/10 , C08L2666/14 , C08L83/04
摘要： Rubber composition based on at least one diene elastomer, a polymer filler as reinforcing filler, a coupling agent providing the bond between the polymer filler and the elastomer. The polymer filler comprises nanoparticles of non-aromatic vinnyl polymer (“NAVP”) bearing a function Z of formula ≡Si—X, X representing a hydroxyl or hydrolysable group. The NAVP is in particular a copolymer of methyl methacrylate, trimethoxysilylpropyl methacrylate and ethylene glycol dimethacrylate, in the form of nanobeads the diameter of which is between 10 and 100 nm.
摘要翻译：基于至少一种二烯弹性体的橡胶组合物，作为增强填料的聚合物填料，提供聚合物填料和弹性体之间的键的偶联剂。聚合物填料包括具有式≡Si-X的官能团Z，表示羟基或可水解基团的非芳香族乙烯基聚合物（“NAVP”）的纳米颗粒。 NAVP特别是甲基丙烯酸甲酯，甲基丙烯酸三甲氧基甲硅烷基丙酯和二甲基丙烯酸乙二醇酯的共聚物，其直径为10至100nm的纳米棒形式。

6. 发明授权

US08461269B2 Elastomeric composition reinforced with a funtionalized non-aromatic vinyl polymer filler 有权
标题翻译：用功能化的非芳族乙烯基聚合物填料增强的弹性组合物
公开(公告)号：US08461269B2
公开(公告)日：2013-06-11
申请号：US12309076
申请日：2007-06-29
申请人： Franck Varagniat , Sylvie Gandon-Pain , Arnaud Lapra
发明人： Franck Varagniat , Sylvie Gandon-Pain , Arnaud Lapra
IPC分类号： C08L21/00 , C08L33/08 , B60C1/00
CPC分类号： B60C1/00 , B60C1/0016 , C08L21/00 , C08L33/068 , C08L33/08 , C08L33/10 , C08L2666/14 , C08L83/04
摘要： Rubber composition based on at least one diene elastomer, a polymer filler as reinforcing filler, a coupling agent providing the bond between the polymer filler and the elastomer. The polymer filler comprises nanoparticles of non-aromatic vinnyl polymer (“NAVP”) bearing a function Z of formula ≡Si—X, X representing a hydroxyl or hydrolysable group. The NAVP is in particular a copolymer of methyl methacrylate, trimethoxysilylpropyl methacrylate and ethylene glycol dimethacrylate, in the form of nanobeads the diameter of which is between 10 and 100 nm.
摘要翻译：基于至少一种二烯弹性体的橡胶组合物，作为增强填料的聚合物填料，提供聚合物填料和弹性体之间的键的偶联剂。聚合物填料包括具有式= Si-X的官能团Z的非芳香族乙烯基聚合物（“NAVP”）的纳米颗粒，X表示羟基或可水解基团。 NAVP特别是甲基丙烯酸甲酯，甲基丙烯酸三甲氧基甲硅烷基丙酯和二甲基丙烯酸乙二醇酯的共聚物，其直径为10至100nm的纳米棒形式。

7. 发明申请

US20080132644A1 Elastomeric Composition Reinforced with a Functionalized Polyvinylaromatic Filler 有权
标题翻译：用功能化聚乙烯基芳香填料加强的弹性组合物
公开(公告)号：US20080132644A1
公开(公告)日：2008-06-05
申请号：US11794451
申请日：2005-12-30
申请人： Arnaud Lapra , Sylvie Gandon-Pain , Franck Varagniat
发明人： Arnaud Lapra , Sylvie Gandon-Pain , Franck Varagniat
IPC分类号： C08L47/00 , B60C1/00
CPC分类号： B60C9/08 , C08L9/00 , C08L21/00 , C08L25/04 , C08L25/16 , Y10S526/909 , C08L2666/06 , C08L2666/08
摘要： Rubber composition based on at least one diene elastomer, a polymeric filler as reinforcing filler and a coupling agent for bonding between the polymeric filler and the elastomer, characterized in that said polymeric filler comprises nanoparticles of a polyvinylaromatic (PVAr) carrying a functional group denoted by Z of formula ≡Si—X, X representing a hydroxyl or hydrolyzable group. The PVAr is especially a copolymer of styrene, ethylvinylbenzene, divinylbenzene and trimethoxysilylpropyl(meth)acrylate, being in the form of nanobeads, the diameter of which is between 10 and 100 nm. This polymeric filler, thanks to a very low density, allows the weight of the compositions of the invention to be reduced without degrading the reinforcement, and with an appreciable reduction in hysteresis.The method of obtaining such a composition, masterbatch comprising at least one diene elastomer and such a polymeric filler, and method of obtaining such a masterbatch, use of such a rubber composition for the manufacture of rubber articles, in particular tires or rubber semi-finished products intended for these tires.
摘要翻译：基于至少一种二烯弹性体的橡胶组合物，作为增强填料的聚合物填料和用于在聚合物填料和弹性体之间结合的偶联剂，其特征在于，所述聚合物填料包含携带官能团的聚乙烯基芳族化合物（PVAr）的纳米颗粒， Z =式≡Si-X，X表示羟基或可水解基团。 PVAr特别是苯乙烯，乙基乙烯基苯，二乙烯基苯和三甲氧基甲硅烷基丙基（甲基）丙烯酸酯的共聚物，其为直径为10至100nm的纳米棒形式。由于非常低的密度，这种聚合物填料允许本发明组合物的重量减少而不降低增强材料，并显着减小滞后。获得这种组合物的方法，包含至少一种二烯弹性体的母料和这种聚合物填料，以及获得这种母料的方法，使用这种橡胶组合物用于制造橡胶制品，特别是轮胎或橡胶半成品用于这些轮胎的产品。

8. 发明授权

US09080041B2 Rubber composition including a polar thermoplastic elastomer including an alkylacrylate unit 有权
标题翻译：包括含有丙烯酸烷基酯单元的极性热塑性弹性体的橡胶组合物
公开(公告)号：US09080041B2
公开(公告)日：2015-07-14
申请号：US13520401
申请日：2011-01-13
申请人： Garance Lopitaux , Didier Vasseur , Franck Varagniat
发明人： Garance Lopitaux , Didier Vasseur , Franck Varagniat
IPC分类号： C08L53/00 , C08L7/00 , B60C1/00 , C08L9/06 , C08L21/00 , C08F212/08 , C08L53/02
CPC分类号： C08L7/00 , B60C1/0016 , C08F212/08 , C08L9/06 , C08L21/00 , C08L53/02 , C08L2666/24 , C08F220/18 , C08F236/04 , C08L53/00
摘要： A rubber composition used for forming a tread of a tire includes an elastomer matrix, a reinforcing filler, and a coupling agent. The elastomer matrix includes from 60 to 95 phr of at least one diene elastomer and from 5 to 40 phr of a polar thermoplastic elastomer (TPE). The polar TPE includes at least one elastomer block and one polar thermoplastic block selected from a homopolymer or copolymers of an alkylacrylic acid ester, with an alkyl radical containing 1 to 4 carbon atoms. The reinforcing filler includes a reinforcing inorganic filler. The presence of the polar TPE makes it possible to improve a compromise of wet grip and dry grip performances of the tread.
摘要翻译：用于形成轮胎胎面的橡胶组合物包括弹性体基质，增强填料和偶联剂。弹性体基体包括60至95phr的至少一种二烯弹性体和5至40phr的极性热塑性弹性体（TPE）。极性TPE包括至少一种弹性体嵌段和一种选自烷基丙烯酸酯的均聚物或共聚物与含有1至4个碳原子的烷基的极性热塑性嵌段。增强填料包括增强无机填料。极性TPE的存在使得可以改善胎面的湿抓地力和干抓地性能的折衷。

9. 发明申请

US20130005894A1 RUBBER COMPOSITION INCLUDING A POLAR THERMOPLASTIC ELASTOMER INCLUDING AN ALKYLACRYLATE UNIT 有权
标题翻译：橡胶组合物，包括包含丙烯酸酯单体的极性热塑性弹性体
公开(公告)号：US20130005894A1
公开(公告)日：2013-01-03
申请号：US13520401
申请日：2011-01-13
申请人： Garance Lopitaux , Didier Vasseur , Franck Varagniat
发明人： Garance Lopitaux , Didier Vasseur , Franck Varagniat
IPC分类号： B60C1/00 , C08K3/22 , C08L53/02
CPC分类号： C08L7/00 , B60C1/0016 , C08F212/08 , C08L9/06 , C08L21/00 , C08L53/02 , C08L2666/24 , C08F220/18 , C08F236/04 , C08L53/00
摘要： The present invention relates to a rubber composition that can advantageously be used for forming the tread of a tyre, which comprises: (a) an elastomer matrix comprising: from 60 to 95 phr of at least one diene elastomer and from 5 to 40 phr of a polar thermoplastic elastomer TPE comprising at least one elastomer block and one polar thermoplastic block selected from the homopolymer and copolymers of an alkylacrylic acid ester, the alkyl radical containing 1 to 4 carbon atoms, and (b) a reinforcing filler comprising a reinforcing inorganic filler, (c) a coupling agent. The presence of the polar thermoplastic elastomer makes it possible to improve the compromise of wet grip and dry grip performances of the tread.
摘要翻译：本发明涉及可有利地用于形成轮胎胎面的橡胶组合物，其包括：（a）弹性体基质，其包含：60至95phr的至少一种二烯弹性体和5至40phr的极性热塑性弹性体TPE，其包含至少一种弹性体嵌段和一种极性热塑性嵌段，其选自烷基丙烯酸酯，含有1至4个碳原子的烷基的均聚物和共聚物，和（b）包含增强无机填料的增强填料，（c）偶联剂。极性热塑性弹性体的存在使得可以改善胎面的湿抓地力和干抓地性能的折衷。

10. 发明申请

US20120259043A1 RUBBER COMPOSITION CONTAINING AN EPOXIDIZED SYNTHETIC RUBBER, AND TIRE TREAD CONTAINING SAME 审中-公开
标题翻译：含有环氧化合成橡胶的橡胶组合物和含有其的轮胎组合物
公开(公告)号：US20120259043A1
公开(公告)日：2012-10-11
申请号：US13501273
申请日：2010-10-12
申请人： Garance Lopitaux , Didier Vasseur , Franck Varagniat
发明人： Garance Lopitaux , Didier Vasseur , Franck Varagniat
IPC分类号： C08L63/08 , C08K5/09
CPC分类号： B60C1/0016 , C08C19/06 , C08K3/013 , C08K5/0016 , C08K5/103 , Y02T10/862 , C08L15/00
摘要： The present invention relates to a rubber composition based on at least one elastomeric matrix comprising an epoxidized synthetic rubber (ESR) having an epoxy function content ranging from 7% to 25%, a reinforcing filler, of which at least 50% by weight of the reinforcing filler is constituted of an inorganic filler, and a plasticizing agent comprising a polar liquid plasticizer for the manufacture of a tyre tread having an improved compromise of properties: grip on wet ground/rolling resistance.
摘要翻译：本发明涉及一种基于至少一种弹性体基体的橡胶组合物，其包含环氧官能含量为7％至25％的环氧化合成橡胶（ESR），增强填料，其中至少50重量％增强填料由无机填料和包含用于制造轮胎胎面的极性液体增塑剂的增塑剂构成，具有改进的性能损失：对湿地/滚动阻力的控制。

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