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    • 1. 发明申请
    • Method for improving the grip of a tyre on a snowy and/or icy road, and a winter tyre
    • 一种用于改善在雪和/或冰冷的道路上的轮胎和冬季轮胎的抓地力的方法
    • US20070062624A1
    • 2007-03-22
    • US11504096
    • 2006-08-15
    • Angela AmaddeoLuciano Garro
    • Angela AmaddeoLuciano Garro
    • B60C11/00
    • C08L9/00B60C1/0016C08K3/36C08K5/54C08L7/00C08L9/02C08L9/06C08L11/00C08L23/16C08L2666/08C08L2666/04
    • A method for improving tyre grip on snowy and/or icy roads includes forming a tread band with a base elastomeric material comprising at least 70 wt % of a polymer mixture including between 20 wt % and 60 wt % of at least one styrene/1,3-butadiene copolymer and between 40 wt % and 80 wt % of at least one 1,3-butadiene homopolymer. The at least one styrene/1,3-butadiene copolymer comprises styrene units and vinyl units. The at least one 1,3-butadiene homopolymer comprises vinyl units. The glass transition temperature of the at least one styrene/1,3-butadiene copolymer is at least 30° C. higher than that of the at least one 1,3-butadiene homopolymer. A mixture of the at least one styrene/1,3-butadiene copolymer with the at least one 1,3-butadiene homopolymer shows a single glass transition peak having a maximum value corresponding to a temperature greater than or equal to −70° C. and less than or equal to −45° C.
    • 一种用于改善雪和/或冰冷道路上的轮胎抓地力的方法包括:形成具有基础弹性体材料的胎面带,所述基础弹性体材料包含至少70重量%的包含20重量%至60重量%的至少一种苯乙烯/ 3-丁二烯共聚物和40重量%至80重量%的至少一种1,3-丁二烯均聚物。 所述至少一种苯乙烯/ 1,3-丁二烯共聚物包括苯乙烯单元和乙烯基单元。 所述至少一种1,3-丁二烯均聚物包括乙烯基单元。 所述至少一种苯乙烯/ 1,3-丁二烯共聚物的玻璃化转变温度比所述至少一种1,3-丁二烯均聚物的玻璃化转变温度高至少30℃。 所述至少一种苯乙烯/ 1,3-丁二烯共聚物与至少一种1,3-丁二烯均聚物的混合物显示具有对应于大于或等于-70℃的温度的最大值的单一玻璃化转变峰。 小于等于-45℃
    • 2. 发明授权
    • Elastomeric composition including at least one salt or oxide of a transition metal and tyre and tread band including the composition
    • 弹性组合物包括至少一种过渡金属的盐或氧化物,以及包括该组合物的轮胎和胎面带
    • US07934528B2
    • 2011-05-03
    • US10497240
    • 2001-12-21
    • Angela AmaddeoLuciano Garro
    • Angela AmaddeoLuciano Garro
    • B60C15/00
    • C08K3/24B60C1/0016C08K3/22C08K5/098C08L21/00Y10T152/10819C08L2666/08
    • An elastomeric composition includes at least one diene elastomeric polymer, at least one salt or oxide of a transition metal belonging to groups IIIA, IVA, VA, VIA, VIIA, or VIIIA of the Periodic Table, at least one vulcanization accelerator, sulphur or derivatives thereof, and at least one reinforcing filler. The elastomeric composition is substantially free of zinc or derivatives thereof. A tire for a vehicle wheel including at least one component including the elastomeric composition and a tread band for a tire including the elastomeric composition are also disclosed. The at least one diene elastomeric polymer may include a glass transition temperature lower than 20° C. The at least one salt of a transition metal may be an organic or inorganic metal salt. The at least one oxide of a transition metal may include one or more of: cobalt oxide; cerium oxide; molybdenum oxide; manganese oxide; and iron oxide.
    • 弹性体组合物包括至少一种二烯弹性体聚合物,属于元素周期表IIIA,IVA,VA,VIA,VIIA或VIIIA族的过渡金属的至少一种盐或氧化物,至少一种硫化促进剂,硫或衍生物 和至少一种增强填料。 弹性体组合物基本上不含锌或其衍生物。 还公开了一种用于车轮的轮胎,其包括至少一个包括弹性体组合物的组分和用于包括弹性体组合物的轮胎的胎面带。 至少一种二烯弹性体聚合物可以包括低于20℃的玻璃化转变温度。过渡金属的至少一种盐可以是有机或无机金属盐。 所述至少一种过渡金属的氧化物可包括以下中的一种或多种:氧化钴; 氧化铈; 氧化钼; 氧化锰 和氧化铁。
    • 3. 发明授权
    • Low rolling resistance tire for vehicles
    • 车辆低滚动阻力轮胎
    • US06624233B2
    • 2003-09-23
    • US09996589
    • 2001-11-30
    • Angela AmaddeoLuciano GarroFabrizia Sala
    • Angela AmaddeoLuciano GarroFabrizia Sala
    • C08K336
    • B60C1/0016C08K3/36C08K2201/014Y02T10/862Y10T152/10495C08L21/00
    • A low rolling resistance tire for vehicles includes a carcass structure, a belt structure coaxially extending around the carcass structure, and a tread coaxially extending around the belt structure and being externally provided with a rolling surface designed to contact the ground. The tread includes a vulcanized polymer base having at least a first silica-based reinforcing filler. The first silica-based reinforcing filler has an average projected area of aggregates, measured before incorporation into the polymer base, lower the 20,000 nm2, a dispersion index in the polymer base not lower than 97%, and an average projected area of the aggregates, measured after incorporation into the polymer base, between 8,500 nm2 and 18,000 nm2.
    • 用于车辆的低滚动阻力轮胎包括胎体结构,围绕胎体结构同轴延伸的带结构,以及围绕带结构同轴延伸的胎面,并且外部设置有设计成接触地面的滚动表面。 胎面包括具有至少第一二氧化硅基增强填料的硫化聚合物基材。 第一种二氧化硅基增强填料具有在结合到聚合物基质之前测量的聚集体的平均投影面积,降低20,000nm 2,聚合物基体中的分散指数不低于97%,平均投影面积 在结合到聚合物基质中后测量的聚集体在8,500nm 2和18,000nm 2之间。
    • 4. 发明授权
    • Vulcanizable rubber composition, in particular for low rolling resistance for vehicle tires
    • 可硫化橡胶组合物,特别是用于车辆轮胎的低滚动阻力
    • US06339122B1
    • 2002-01-15
    • US09393906
    • 1999-09-10
    • Luciano GarroAngela Amaddeo
    • Luciano GarroAngela Amaddeo
    • C08J340
    • C08L7/00B60C1/0016C08K3/04C08L9/00C08L9/06C08L19/006Y02T10/862Y10T152/10495C08L2666/08
    • A vulcanizable rubber composition is described comprising a cross-linkable unsaturated chain polymer base including natural rubber, at least a copolymer obtainable by polymerizing a conjugated diolefin with a vinyl aromatic hydrocarbon, and a main carbon black-based reinforcing filler, wherein: a) the copolymer is obtainable by polymerizing in 1,2 form with the vinyl aromatic hydrocarbon at least 50% by weight of the conjugated diolefin, so as to obtain in the copolymer a quantity of from 30% to 70% by weight to the total weight of the same of an olefin fraction having a 1,2 structure, and b) the carbon black has a DBP absorption value measured according to ISO 4656-1 equal to at least 110 ml/100 g, a reduction in the DBP absorption value measured after compression according to ISO 6894 equal to at least 25 ml/100 g and a surface area measured by means of CTAB absorption according to ISO 6810 not greater than 120 m2/g.
    • 描述了一种可硫化的橡胶组合物,其包含可交联的不饱和链聚合物基质,其包括天然橡胶,至少一种可通过使共轭二烯烃与乙烯基芳族烃聚合而获得的共聚物和主要的炭黑基增强填料,其中:a) 共聚物可通过1,2-乙烯基芳族烃以至少50重量%的共轭二烯烃聚合的形式获得,从而在共聚物中获得的量为30重量%至70重量% 相同的具有1,2结构的烯烃级分,和b)炭黑具有根据ISO 4656-1测量的等于至少110ml / 100g的DBP吸收值,压缩后测量的DBP吸收值降低 至ISO 6894等于至少25ml / 100g,并且通过根据ISO 6810的CTAB吸收测量的表面积不大于120m 2 / g。
    • 5. 发明授权
    • Vulcanizable rubber composition, in particular for low rolling
resistance treads for vehicle tires
    • 可硫化的橡胶组合物,特别是用于车辆轮胎的低滚动阻力胎面
    • US5996663A
    • 1999-12-07
    • US831978
    • 1997-04-02
    • Luciano GarroAngela Amaddeo
    • Luciano GarroAngela Amaddeo
    • B60C1/00C08K3/04C08K3/36C08K5/54C08L7/00C08L9/06C08L19/00C08L25/04
    • C08L7/00B60C1/0016C08L19/006C08L9/06C08K3/04C08L9/00Y10T152/10495
    • A vulcanizable rubber composition is described comprising a cross-linkable unsaturated chain polymer base including natural rubber, at least a copolymer obtainable by polymerizing a conjugated diolefin with a vinyl aromatic hydrocarbon, and a main carbon black-based reinforcing filler, wherein:a) the copolymer is obtainable by polymerizing in 1,2 form with the vinyl aromatic hydrocarbon at least 50% by weight of the conjugated diolefin, so as to obtain in the copolymer a quantity of from 30% to 70% by weight to the total weight of the same of an olefin fraction having a 1,2 structure, andb) the carbon black has a DBP absorption value measured according to ISO 4656-1 equal to at least 110 ml/100 g, a reduction in the DBP absorption value measured after compression according to ISO 6894 equal to at least 25 ml/100 g and a surface area measured by means of CTAB absorption according to ISO 6810 not greater than 120 m.sup.2 /g.
    • 描述了一种可硫化的橡胶组合物,其包含可交联的不饱和链聚合物基质,其包括天然橡胶,至少一种可通过使共轭二烯烃与乙烯基芳族烃聚合而获得的共聚物和主要的炭黑基增强填料,其中:a) 共聚物可通过1,2-乙烯基芳族烃以至少50重量%的共轭二烯烃聚合的形式获得,从而在共聚物中获得的量为30重量%至70重量% 相同的具有1,2结构的烯烃级分,以及b)炭黑具有根据ISO 4656-1测量的等于至少110ml / 100g的DBP吸收值,压缩后测量的DBP吸收值的降低 根据ISO 6894等于至少25ml / 100g,并且通过根据ISO 6810的CTAB吸收测量的表面积不大于120m 2 / g。
    • 8. 发明申请
    • Tyre for vehicle wheels, tread band and elastomeric composition used therein
    • 轮胎用于车轮,胎面带和弹性体组合物
    • US20050155687A1
    • 2005-07-21
    • US10497240
    • 2001-12-21
    • Angela AmaddeoLuciano Garro
    • Angela AmaddeoLuciano Garro
    • B60C1/00C08K3/00C08K3/22C08K3/24C08K5/00C08K5/098C08L9/00C08L21/00B60C15/00
    • C08K3/24B60C1/0016C08K3/22C08K5/098C08L21/00Y10T152/10819C08L2666/08
    • An elastomeric composition includes at least one diene elastomeric polymer, at least one salt or oxide of a transition metal belonging to groups IIIA, IVA, VA, VIA, VIIA, or VIIIA of the Periodic Table, at least one vulcanization accelerator, sulphur or derivatives thereof, and at least one reinforcing filler. The elastomeric composition is substantially free of zinc or derivatives thereof. A tyre for a vehicle wheel including at least one component including the elastomeric composition and a tread band for a tyre including the elastomeric composition are also disclosed. The at least one diene elastomeric polymer may include a glass transition temperature lower than 20° C. The at least one salt of a transition metal may be an organic or inorganic metal salt. The at least one oxide of a transition metal may include one or more of: cobalt oxide; cerium oxide; molybdenum oxide; manganese oxide; and iron oxide.
    • 弹性体组合物包括至少一种二烯弹性体聚合物,属于元素周期表IIIA,IVA,VA,VIA,VIIA或VIIIA族的过渡金属的至少一种盐或氧化物,至少一种硫化促进剂,硫或衍生物 和至少一种增强填料。 弹性体组合物基本上不含锌或其衍生物。 还公开了一种用于车轮的轮胎,其包括至少一个包括弹性体组合物的组分和用于包括弹性体组合物的轮胎的胎面带。 至少一种二烯弹性体聚合物可以包括低于20℃的玻璃化转变温度。过渡金属的至少一种盐可以是有机或无机金属盐。 所述至少一种过渡金属的氧化物可包括以下中的一种或多种:氧化钴; 氧化铈; 氧化钼; 氧化锰 和氧化铁。