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1. 发明授权

US06964695B2 Method and equipment for removing volatile compounds from air 失效
标题翻译：从空气中除去挥发性化合物的方法和设备
公开(公告)号：US06964695B2
公开(公告)日：2005-11-15
申请号：US10660221
申请日：2003-09-11
申请人： Roger Nicholas Place , Andrew John Blackburn , Stephen Robert Tennison , Anthony Paul Rawlinson , Barry David Crittenden
发明人： Roger Nicholas Place , Andrew John Blackburn , Stephen Robert Tennison , Anthony Paul Rawlinson , Barry David Crittenden
IPC分类号： B01D53/04 , B01J20/20 , B01J20/34
CPC分类号： B01D53/0438 , B01D53/02 , B01D53/0423 , B01D53/0462 , B01D2253/102 , B01D2253/304 , B01D2253/306 , B01D2253/342 , B01D2257/708 , B01D2259/40081 , B01D2259/40086 , B01D2259/4009 , B01J20/20 , B01J20/28042 , B01J20/28057 , B01J20/3416 , B01J20/3441 , Y02A50/235 , Y10S95/901
摘要： A regenerable adsorber for removing VOCs from gas streams consists of a porous monolithic carbon which can be regenerated by heating by passing an electric current through it.
摘要翻译：用于从气流中除去VOC的可再生吸附器由多孔整体碳组成，其可以通过使电流通过其加热而再生。

2. 发明授权

US07160366B2 Filter element 失效
标题翻译：过滤元件
公开(公告)号：US07160366B2
公开(公告)日：2007-01-09
申请号：US10760083
申请日：2004-01-16
申请人： Andrew John Blackburn , Stephen Robert Tennison , Anthony Paul Rawlinson
发明人： Andrew John Blackburn , Stephen Robert Tennison , Anthony Paul Rawlinson
IPC分类号： B01D53/02
CPC分类号： B01D39/2055 , A62B23/02 , B01D53/02 , B01D53/0415 , B01D2253/102 , B01D2253/306 , B01D2253/342 , B01D2257/702 , B01D2257/93 , B01D2258/02 , B01D2259/4508 , B01D2259/4516 , B01D2259/4541 , B01D2259/4575 , B01J20/20 , B01J20/28004 , B01J20/28042 , B01J20/28045 , B01J20/28057 , B01J20/28095
摘要： An improved filter element which can be used in gas masks is formed of short lengths of porous monolithic carbon formed by partially curing a phenolic resin to a solid, comminuting the partially cured resin, extruding the comminuted resin, sintering the extruded resin so as to produce a form-stable sintered product and carbonising and activating the form-stable sintered product.
摘要翻译：可用于防毒面具的改进的过滤元件由通过将酚醛树脂部分固化成固体，粉碎部分固化的树脂，挤出粉碎的树脂，烧结挤出的树脂形成的短长度的多孔整体碳形成，从而产生一种形式稳定的烧结产品，并且对形成稳定的烧结产品进行碳化和活化。

3. 发明授权

US07317871B2 Heater for fluids comprising an electrically conductive porous monolith 失效
标题翻译：包括导电多孔整料的流体加热器
公开(公告)号：US07317871B2
公开(公告)日：2008-01-08
申请号：US10557919
申请日：2004-05-19
申请人： Stephen Robert Tennison , Andrew John Blackburn , Tho Truong Huynh , Piers Catton , Vladimir Strelko, Jr. , Jonathan Robert Tunbridge
发明人： Stephen Robert Tennison , Andrew John Blackburn , Tho Truong Huynh , Piers Catton , Vladimir Strelko, Jr. , Jonathan Robert Tunbridge
IPC分类号： A47J31/00
CPC分类号： H05B3/145
摘要： An electrical heater element of controlled resistivity which can be used for a wide range of applications is formed from an electrically conductive synthetic porous carbon monolith.
摘要翻译：可用于广泛应用的受控电阻率的电加热器元件由导电合成多孔碳整料形成。

4. 发明授权

US07655210B2 Porous carbons 有权
公开(公告)号：US07655210B2
公开(公告)日：2010-02-02
申请号：US11800805
申请日：2007-05-07
申请人： Stephen Robert Tennison , Oleksundr Prokopovych Kozynchenko , Volodymyr Vasyljovych Strelko , Andrew John Blackburn
发明人： Stephen Robert Tennison , Oleksundr Prokopovych Kozynchenko , Volodymyr Vasyljovych Strelko , Andrew John Blackburn
IPC分类号： C09C1/44
摘要： A method of making mesoporous carbon beads comprises steps of providing a nucleophilic component such as phenolic compound or phenol condensation prepolymer, dissolving the nucleophilic component in a pore former, together with at least one electrophilic cross-linking agent such as formaldehyde, paraformaldehyde, furfural and hexamethylene tetramine, dispersing the resulting solution into a mineral oil to form beads, condensing both the component and the agent in the presence of the pore former to form beads of porous resin, removing the beads from the mineral oil and carbonizing the beads to form mesoporous carbon beads.

5. 发明授权

US08227518B2 Porous carbons 有权
标题翻译：多孔碳
公开(公告)号：US08227518B2
公开(公告)日：2012-07-24
申请号：US13097819
申请日：2011-04-29
申请人： Stephen Robert Tennison , Oleksundr Prokopovych Kozynchenko , Volodymyr Vasyljovych Strelko , Andrew John Blackburn
发明人： Stephen Robert Tennison , Oleksundr Prokopovych Kozynchenko , Volodymyr Vasyljovych Strelko , Andrew John Blackburn
IPC分类号： C08J9/00 , C08G14/12
CPC分类号： C04B35/524 , C01B32/00 , C01B32/30 , C04B38/0064 , C04B38/009 , C04B2235/77 , Y10T428/24273 , Y10T428/2982 , C04B35/52 , C04B38/0022 , C04B38/0054 , C04B38/062
摘要： A cured porous phenolic resin is provided that can be made by cross-linking a phenol-formaldehyde pre-polymer in the presence of a pore former, preferably ethylene glycol. The resin may be formed in situ by condensing a phenol with or without modifying agents and with cross-linking agent by pouring partially cross-linked resin into hot oil, in which case mesoporous resin beads are obtained. The resulting resin has mesopores observable in carbon derived from said resin by a pore structure of said derived carbon that comprises mesopores of diameter of 20-500 Å, as estimated by nitrogen adsorption porosimentry, the value for the differential of pore volume V with respect to the logarithm of pore radius R (dV/d log R) for the mesopores being greater than 0.2 for at least some values of pore size in the range 20-500 Å. Microporous beads of the resin may be carbonized into mesoporous carbon beads.
摘要翻译：提供了一种固化的多孔酚醛树脂，其可以通过在成孔剂，优选乙二醇的存在下交联苯酚 - 甲醛预聚物来制备。树脂可以通过将苯酚与或不与改性剂和交联剂通过将部分交联的树脂倒入热油中而原位形成，在这种情况下获得介孔树脂珠。所得树脂具有通过所述衍生碳的孔结构可观察到的中孔，所述碳源包括直径为20-500的介孔，如通过氮吸附孔隙度估计的，孔体积V的差异值相对于对于孔径在20-500埃的至少一些值，中孔的孔半径R（dV / d log R）的对数大于0.2。树脂的微孔可以碳化成中孔碳珠。

6. 发明申请

US20100098615A1 Carbonising and/or Activating Carbonaceous Material 有权
公开(公告)号：US20100098615A1
公开(公告)日：2010-04-22
申请号：US12444840
申请日：2007-10-04
申请人： Stephen Robert Tennison , Jonathan Robert Tunbridge , Roger Nicholas Place , Andrew John Blackburn , Alan Mark Giles
发明人： Stephen Robert Tennison , Jonathan Robert Tunbridge , Roger Nicholas Place , Andrew John Blackburn , Alan Mark Giles
IPC分类号： C01B31/10 , F27B7/14
CPC分类号： F27B7/167 , C01B32/30 , C01B32/336 , C01B32/342 , C01B32/39 , C08F2/18 , C10B47/30 , C10B53/07 , C10B57/12 , F27B7/162 , Y02P20/143
摘要： A method is provided for carbonizing and activating carbonaceous material, which comprises supplying the material to an externally fired rotary kiln maintained at carbonizing and activating temperatures, the kiln having a downward slope to progress the material as it rotates, the kiln having an atmosphere substantially free of oxygen provided by a counter-current of steam or carbon dioxide, and annular weirs being provided at intervals along the kiln to control progress of the material. There may further be provided an externally fired rotary kiln for carbonizing and activating carbonaceous material having a hollow rotary body that has a downward slope towards a discharge end thereof, and which is provided at intervals along its length with annular weirs for controlling progress of the carbonaceous material. In embodiments, there is also provided a process is for producing discrete solid beads of polymeric material e.g. phenolic resin beads having a mesoporous structure, which may be useful as feedstock for the above mentioned carbonization/activation process or which may have other utility e.g. as ion exchange resins. The process may produce resin beads on an industrial scale without aggregates of resin building up speedily and interrupting production. The process comprises the steps of: (a) combining a stream of a polymerizable liquid precursor e.g. a novolac and hexamine as cross-linking agent dissolved in a first polar organic liquid e.g. ethylene glycol with a stream of a liquid suspension medium which is a second non-polar organic liquid with which the liquid precursor is substantially or completely immiscible e.g. transformer oil containing a drying oil; (b) mixing the combined stream to disperse the polymerizable liquid precursor as droplets in the suspension medium e.g. using an in-line static mixer; (c) allowing the droplets to polymerise in a laminar flow of the suspension medium so as to form discrete solid beads that cannot agglomerate; and (d) recovering the beads from the suspension medium. There is also provided apparatus for forming discrete solid beads of polymeric material, said apparatus comprising: a first line for conveying s stream of a polymerizable liquid precursor; a second line for conveying a stream of a dispersion medium with which the polymerizable liquid precursor is substantially or completely immiscible; an in-line mixer configured to receive a combined flow from the first and second lines and to disperse the polymerizable liquid precursor as droplets in the dispersion medium; a vertical polymerization column configured to receive the dispersion medium with the droplets dispersed therein and to permit the polymerizable liquid precursor polymerize while descending the column in a descending flow of polymerization medium; and a vessel at the base of the column for receiving the descending flow of dispersion medium and collecting polymerized solid beads.

7. 发明申请

US20100029795A1 Porous carbons 有权
公开(公告)号：US20100029795A1
公开(公告)日：2010-02-04
申请号：US11786072
申请日：2007-04-10
申请人： Stephen Robert Tennison , Oleksundr Prokopovych Kozynchenko , Volodymyr Vasyljovych Strelko , Andrew John Blackburn
发明人： Stephen Robert Tennison , Oleksundr Prokopovych Kozynchenko , Volodymyr Vasyljovych Strelko , Andrew John Blackburn
IPC分类号： C08J9/12
CPC分类号： C04B35/524 , C01B32/00 , C01B32/30 , C04B38/0064 , C04B38/009 , C04B2235/77 , Y10T428/24273 , Y10T428/2982 , C04B35/52 , C04B38/0022 , C04B38/0054 , C04B38/062
摘要： A method is provided for making mesoporous resin. It comprises: (a) providing a nucleophilic component which comprises a phenolic compound or a phenol condensation prepolymer optionally with one or more modifying reagents selected from hydroquinone, resorcinol, urea, aromatic amines and heteroaromatic amines; (b) dissolving the nucleophilic component in a pore former selected from the group consisting of a diol, a diol ether, a cyclic ester, a substituted cyclic ester, a substituted linear amide, a substituted cyclic amide, an amino alcohol and a mixture of any of the above with water, together with at least one electrophilic cross-linking agent selected from the group consisting of formaldehyde, paraformaldehyde, furfural and hexamethylene tetramine; and (c) condensing the nucleophilic component and the electrophilic cross-linking agent in the presence of the pore former to form a porous resin. The resin may be formed in situ by pouring the partially cross-linked resin into hot oil. Mesoporous resin beads are obtained which can be carbonised into mesoporous carbon beads.

8. 发明授权

US08501142B2 Carbonising and/or activating carbonaceous material 有权
标题翻译：碳化和/或活化碳质材料
公开(公告)号：US08501142B2
公开(公告)日：2013-08-06
申请号：US12444840
申请日：2007-10-04
申请人： Stephen Robert Tennison , Jonathan Robert Tunbridge , Roger Nicholas Place , Andrew John Blackburn , Alan Mark Giles
发明人： Stephen Robert Tennison , Jonathan Robert Tunbridge , Roger Nicholas Place , Andrew John Blackburn , Alan Mark Giles
IPC分类号： C01B31/00 , C01B33/26 , C01B31/08 , C01B3/24 , F27B7/02 , F27B7/06 , F27B7/32 , F27B7/14 , B01J19/00
CPC分类号： F27B7/167 , C01B32/30 , C01B32/336 , C01B32/342 , C01B32/39 , C08F2/18 , C10B47/30 , C10B53/07 , C10B57/12 , F27B7/162 , Y02P20/143
摘要： This disclosure relates to carbonizing and activating carbonaceous material. In some embodiments, the material is selected from coconut-derived material and like material of vegetable origin and resin materials to produce activated carbon, the production comprising supplying the material to the inlet end of a kiln, supplying to the kiln an atmosphere comprising steam or carbon dioxide substantially free of oxygen, maintaining a first region of the kiln having an independently controllable supply of heat at a temperature sufficient for drying or removing solvent from the material without carbonization, maintaining a second region of the kiln having an independently controllable supply of heat downstream from the first region at a temperature sufficient for carbonization of the material without activation; maintaining a third region of the kiln having an independently controllable supply of heat downstream from the second region at a temperature sufficient for activation of the carbonized material, and collecting activated carbon from the discharge end of the kiln.
摘要翻译：本公开涉及碳化和活化碳质材料。在一些实施方案中，材料选自椰子衍生的材料和植物来源的类似材料和树脂材料以产生活性炭，所述生产包括将材料供应到窑的入口端，向窑供应包含蒸汽或基本上不含氧的二氧化碳，保持窑的第一区域具有独立可控的供热温度，该温度足以在没有碳化的情况下从所述材料干燥或除去溶剂，保持窑的第二区域具有独立可控的供热在足以使材料碳化而不激活的温度下游从第一区域下游; 保持窑的第三区域具有在足以活化碳化材料的温度下从第二区域下游独立控制的热供应，以及从窑的排放端收集活性炭。

9. 发明授权

US07850942B2 Porous carbons 有权
标题翻译：多孔碳
公开(公告)号：US07850942B2
公开(公告)日：2010-12-14
申请号：US11800805
申请日：2007-05-07
申请人： Stephen Robert Tennison , Oleksundr Prokopovych Kozynchenko , Volodymyr Vasyljovych Strelko , Andrew John Blackburn
发明人： Stephen Robert Tennison , Oleksundr Prokopovych Kozynchenko , Volodymyr Vasyljovych Strelko , Andrew John Blackburn
IPC分类号： C09C1/44
CPC分类号： C04B35/524 , C01B32/00 , C01B32/30 , C04B38/0064 , C04B38/009 , C04B2235/77 , Y10T428/24273 , Y10T428/2982 , C04B35/52 , C04B38/0022 , C04B38/0054 , C04B38/062
摘要： A method of making mesoporous carbon beads comprises steps of providing a nucleophilic component such as phenolic compound or phenol condensation prepolymer, dissolving the nucleophilic component in a pore former, together with at least one electrophilic cross-linking agent such as formaldehyde, paraformaldehyde, furfural and hexamethylene tetramine, dispersing the resulting solution into a mineral oil to form beads, condensing both the component and the agent in the presence of the pore former to form beads of porous resin, removing the beads from the mineral oil and carbonizing the beads to form mesoporous carbon beads.
摘要翻译：制备介孔碳珠的方法包括以下步骤：提供亲核成分如酚类化合物或苯酚缩合预聚物，将亲核成分溶解在成孔剂中，以及至少一种亲电性交联剂如甲醛，多聚甲醛，糠醛和六亚甲基四胺，将所得溶液分散到矿物油中以形成珠粒，在成孔剂存在下将组分和试剂两者冷凝以形成多孔树脂珠，从矿物油中除去珠粒并使珠粒碳化以形成中孔碳珠。

10. 发明授权

US07842736B2 Porous carbons 有权
标题翻译：多孔碳
公开(公告)号：US07842736B2
公开(公告)日：2010-11-30
申请号：US11786072
申请日：2007-04-10
申请人： Stephen Robert Tennison , Oleksundr Prokopovych Kozynchenko , Volodymyr Vasyljovych Strelko , Andrew John Blackburn
发明人： Stephen Robert Tennison , Oleksundr Prokopovych Kozynchenko , Volodymyr Vasyljovych Strelko , Andrew John Blackburn
IPC分类号： C08G8/04 , C08J9/12 , C01B31/02
CPC分类号： C04B35/524 , C01B32/00 , C01B32/30 , C04B38/0064 , C04B38/009 , C04B2235/77 , Y10T428/24273 , Y10T428/2982 , C04B35/52 , C04B38/0022 , C04B38/0054 , C04B38/062
摘要： A method is provided for making mesoporous resin. It comprises: (a) providing a nucleophilic component which comprises a phenolic compound or a phenol condensation prepolymer optionally with one or more modifying reagents selected from hydroquinone, resorcinol, urea, aromatic amines and heteroaromatic amines; (b) dissolving the nucleophilic component in a pore former selected from the group consisting of a diol, a diol ether, a cyclic ester, a substituted cyclic ester, a substituted linear amide, a substituted cyclic amide, an amino alcohol and a mixture of any of the above with water, together with at least one electrophilic cross-linking agent selected from the group consisting of formaldehyde, paraformaldehyde, furfural and hexamethylene tetramine; and (c) condensing the nucleophilic component and the electrophilic cross-linking agent in the presence of the pore former to form a porous resin. The resin may be formed in situ by pouring the partially cross-linked resin into hot oil. Mesoporous resin beads are obtained which can be carbonized into mesoporous carbon beads.
摘要翻译：提供了制备介孔树脂的方法。其包括：（a）提供亲核组分，其包含酚类化合物或酚缩合预聚物，任选地含有一种或多种选自氢醌，间苯二酚，脲，芳族胺和杂芳族胺的改性剂; （b）将亲核组分溶解在选自二醇，二醇醚，环酯，取代的环酯，取代的直链酰胺，取代的环状酰胺，氨基醇和上述任何一种与水一起连同至少一种选自甲醛，多聚甲醛，糠醛和六亚甲基四胺的亲电子交联剂; 和（c）在成孔剂存在下将亲核成分和亲电子交联剂缩合形成多孔树脂。可以通过将部分交联的树脂倒入热油中来原位形成树脂。获得可以碳化成介孔碳珠的介孔树脂珠。

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