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1. 发明申请

US20170096582A1 RADIATION CURABLE AQUEOUS COMPOSITIONS WITH CONTROLLED POLYMER FLOW 审中-公开
公开(公告)号：US20170096582A1
公开(公告)日：2017-04-06
申请号：US15312259
申请日：2015-05-19
申请人： Allnex Belgium S.A.
发明人： Michel TIELEMANS , Jean-Yves SALVIATO , Jean-Noel BAURANT
IPC分类号： C09D175/16 , C08G18/81 , C08G18/22 , C08G18/73
CPC分类号： C09D175/16 , C08G18/0823 , C08G18/227 , C08G18/673 , C08G18/73 , C08G18/8175
摘要： Provided in the invention is an aqueous radiation curable composition (I) comprising: —at least one ethylenically unsaturated polyurethane (A) obtained from the reaction of at least one polyisocyanate compound (Ai); at least one ethylenically unsaturated compound (Aii) containing at least one reactive group capable to react with isocyanate groups; at least one hydrophilic compound (Aiii) containing at least one reactive group capable to react with isocyanate groups and at least one other group which is capable to render the polyurethane polymer dispersible in aqueous medium as such or after the formation of a salt; optionally, at least one polyol (Aiv); optionally, at least one further compound (Av) different from the polyol (Aiv) and comprising at least one reactive group capable to react with isocyanate groups; and optionally, at least one reactive electrophilic compound (Avi); said ethylenically unsaturated polyurethane (A) preferably being characterized by a molecular weight that is above 1,000 Daltons; —at least one ethylenically unsaturated polyurethane (B), different from the polyurethane (A), obtained from the reaction of at least one polyisocyanate compound (Bi); at least one ethylenically unsaturated compound (Bii) containing at least one reactive group capable to react with isocyanate groups; optionally, at least one polyol (Biv); optionally, at least one further compound (Bv) different from the polyol (Biv) and comprising at least one reactive group capable to react with isocyanate groups; and optionally, at least one reactive electrophilic compound (Bvi); said ethylenically unsaturated polyurethane (B) preferably being characterized by a molecular weight that is below 10,000 Daltons; and optionally, at least one ethylenically unsaturated compound (C) different from (A) and (B); wherein the radiation curable composition (I) in dry form has a steady-state creep viscosity η30, expressed as the apparent viscosity after a deformation time of 30 minutes with a load σ0=50 Pa at 23° C., that is above 1.103 Pa·s, more preferably above 1.104 Pa·s. Compositions (I) of the invention are characterized by a n improved creep viscosity r|3oand provide polymer materials with a good flow and mirror effect. In general these materials are less sensitive to dust pick-up and fingerprints. Further provided in the invention is a one-vessel solvent free process for preparing such materials.

2. 发明申请

US20220228027A1 BIOBASED URETHANE (METH)ACRYLATE FOR USE IN CLADDING 有权
公开(公告)号：US20220228027A1
公开(公告)日：2022-07-21
申请号：US17611757
申请日：2020-06-16
申请人： ALLNEX BELGIUM S.A.
发明人： Jurgen VAN HOLEN , Guido VANMEULDER , Michel TIELEMANS
IPC分类号： C09D175/14 , C08G18/73 , C08G18/67 , C08K5/17 , C09D7/48 , C09D7/63
摘要： A radiation curable and at least partially biobased urethane (meth)acrylate for use in a one-component coating composition for cladding an outdoor surface of a building, obtained from the reaction of at least the following compounds: a. A polyisocyanate compound having a biobased carbon content of at least 20%, preferably at least 50%, as determined by method A of the standard ASTM D6866-12: 2008, and b. A (meth)acrylate compound, different from compound a, and containing a reactive group capable to react with isocyanate groups.

3. 发明申请

US20160244631A1 WATERBORNE CURING COMPOSITIONS FOR ELECTRODEPOSITION AND RADIATION CURING 审中-公开
标题翻译：用于电沉积和辐射固化的水凝固组合物
公开(公告)号：US20160244631A1
公开(公告)日：2016-08-25
申请号：US15030929
申请日：2014-10-23
申请人： ALLNEX AUSTRIA GMBH , ALLNEX BELGIUM S.A.
发明人： Willibald PAAR , Michel TIELEMANS , Stephan PEETERS
IPC分类号： C09D163/00 , C09D5/44
CPC分类号： C09D163/00 , C08F283/10 , C08G18/672 , C08G18/792 , C08G59/1466 , C08G59/1477 , C08G59/1494 , C08G59/184 , C08L2205/05 , C09D5/4438 , C09D5/4492 , C09D163/10 , C09D175/16 , C25D13/22 , C08F220/18 , C08F220/28 , C08F220/34 , C08L33/06
摘要： The present invention relates to waterborne curing compositions for electrodeposition and radiation curing and processes to obtain such compositions. The compositions are characterized in that an ethylenically unsaturated compound (b), is dispersed in an aqueous solution by an at least partially neutralized (meth)acrylic modified amine epoxy adduct. The compositions of the invention are particularly suitable for coating metallic materials and temperature sensitive materials such as electrically conductive plastic materials.
摘要翻译：本发明涉及电沉积和辐射固化的水性固化组合物和获得这种组合物的方法。组合物的特征在于烯属不饱和化合物（b）通过至少部分中和的（甲基）丙烯酸改性胺环氧加成物分散在水溶液中。本发明的组合物特别适用于涂覆金属材料和感温材料如导电塑料材料。

4. 发明申请

US20150322291A1 RADIATION CURABLE AQUEOUS COMPOSITIONS WITH REVERSIBLE DRYING 审中-公开
标题翻译：具有可逆干燥的辐射可固化水性组合物
公开(公告)号：US20150322291A1
公开(公告)日：2015-11-12
申请号：US14648456
申请日：2014-01-13
申请人： ALLNEX BELGIUM S.A.
发明人： Jean-Yves SALVIATO , Michel TIELEMANS , Elodie SIBAND , Thierry RANDOUX
IPC分类号： C09D175/06
摘要： The present invention relates to an aqueous resin composition (I) comprising at least one polymerizable ethylenically unsaturated polyurethane polymer (A), optionally, at least one polymerizable ethylenically unsaturated compound (B) different from (A), and optionally, at least one neutralizing agent (C); wherein the polyurethane polymer (A) has a weight average molecular weight of less than 15.000 Daltons and is obtained from the reaction of: at least one polyisocyanate (i); at least one hydrophilic compound (ii) containing at least one reactive group capable to react with isocyanate groups and at least one group which is capable to render the polyurethane polymer dispersible or soluble in aqueous medium either directly or after reaction with a neutralizing agent (C) to provide a salt; at least one compound (iii) containing essentially one reactive group capable to react with isocyanate groups and at least one copolymerizable ethylenically unsaturated group; at least one compound (iv) containing at least two reactive groups capable to react with isocyanate groups; and, optionally, at least one chain extender (v) containing at least two reactive groups capable to react with isocyanate groups, which chain extender is different from compounds (iv); and wherein the non-volatile components of the resin composition (I) after drying are re-dispersible or re-soluble in water at 25° C. The present invention further relates to radiation curable compositions comprising a resin composition of the invention for use in coating applications or graphic art applications.
摘要翻译：本发明涉及包含至少一种可聚合的烯属不饱和聚氨酯聚合物（A），任选的至少一种不同于（A）的可聚合的烯键式不饱和化合物（B）和任选地至少一种中和代理人（C）; 其中所述聚氨酯聚合物（A）的重均分子量小于15.000道尔顿，并且由以下物质的反应获得：至少一种多异氰酸酯（i）; 含有至少一个能够与异氰酸酯基团反应的反应性基团的至少一种亲水性化合物（ⅱ）和至少一种能使聚氨酯聚合物直接或与中和剂反应（C ）提供盐; 至少一种含有基本上能够与异氰酸酯基团反应的一个反应性基团和至少一个可共聚的烯属不饱和基团的化合物（ⅲ）至少一种含有至少两个能够与异氰酸酯基反应的反应性基团的化合物（ⅳ）和任选的至少一种含有至少两个能够与异氰酸酯基团反应的反应性基团的扩链剂（v），该扩链剂与化合物（iv）不同; 并且其中干燥后的树脂组合物（I）的非挥发性组分在25℃下可再分散或再溶于水。本发明还涉及包含本发明的树脂组合物的可辐射固化组合物，其用于涂层应用或图形艺术应用。

5. 发明申请

US20150275041A1 AQUEOUS RADIATION CURABLE POLYURETHANE COMPOSITIONS 有权
标题翻译：水性可固化聚氨酯组合物
公开(公告)号：US20150275041A1
公开(公告)日：2015-10-01
申请号：US14737866
申请日：2015-06-12
申请人： Allnex Belgium S.A.
发明人： Michel TIELEMANS , Dirk BONTINCK , Jean-Claude VAN OVERVELT
IPC分类号： C09D175/16 , B29C67/00 , C08J3/28
CPC分类号： C09D175/16 , B29C64/124 , B29K2023/04 , B29K2023/10 , B29K2069/00 , B29K2075/00 , C08G18/0823 , C08G18/673 , C08G18/683 , C08J3/28 , C08J2375/16 , C08L75/16 , C09D175/14 , Y10T428/31551 , Y10T428/31554 , Y10T428/31591 , Y10T428/31598 , Y10T428/31601 , Y10T428/31605 , C08G18/6659 , C08L2666/20
摘要： The invention relates to radiation-curable aqueous composition comprising an (meth)acrylated polyurethane pre-polymer obtained from the reaction of a polyisocyanate, optionally a polyol, at least one hydrophilic compound containing at least one reactive group capable to react with isocyanate groups and which is capable to render the polyurethane pre-polymer dispersible in aqueous medium either directly or after the reaction with a neutralizing agent to provide a salt, an (meth)acrylated compound containing at least two reactive groups capable to react with isocyanate groups and an (meth)acrylated compound containing essentially one reactive group capable to react with isocyanate groups, said composition comprising an amount of (meth)acrylated and polymerizable ethylenically unsaturated groups of at least 3 meq per g.
摘要翻译：本发明涉及可辐射固化的水性组合物，其包含由多异氰酸酯，任选的多元醇反应获得的（甲基）丙烯酸酯化的聚氨酯预聚物，至少一种含至少一个能够与异氰酸酯基团反应的反应性基团的亲水性化合物，能够将聚氨酯预聚物直接或与中和剂反应后分散在水性介质中以提供盐，（甲基）丙烯酸酯化的化合物含有至少两个能够与异氰酸酯基团反应的反应性基团和（甲基））丙烯酸酯化的化合物，其基本上含有能够与异氰酸酯基团反应的一个反应性基团，所述组合物包含至少3meq / g的（甲基）丙烯酸酯化的和可聚合的烯键式不饱和基团。

6. 发明申请

US20140371387A1 AQUEOUS RADIATION CURABLE POLYURETHANE COMPOSITIONS 审中-公开
标题翻译：水性可固化聚氨酯组合物
公开(公告)号：US20140371387A1
公开(公告)日：2014-12-18
申请号：US14471058
申请日：2014-08-28
申请人： Allnex Belgium S.A.
发明人： Michel TIELEMANS
IPC分类号： C09D175/14 , C08G18/28 , C08G18/68 , C08G18/34 , C08K3/20 , C08G18/75
CPC分类号： C09D175/14 , C08G18/2825 , C08G18/348 , C08G18/675 , C08G18/683 , C08G18/758 , C08K3/20 , C08L75/14 , Y10S525/92 , C08G18/0823 , C08L2666/20
摘要： The invention relates to radiation-curable aqueous composition comprising a high molecular weight ethylenically unsaturated polyurethane obtained from the reaction of a polyisocyanate, at least one hydrophilic compound which is capable to render the polyurethane prepolymer dispersible in aqueous medium, an ethylenically unsaturated compound containing at least two reactive groups capable to react with isocyanate groups and an active hydrogen containing chain extender and a low molecular weight ethylenically unsaturated polyurethane end-capped with an ethylenically unsaturated compound containing essentially one reactive group capable to react with isocyanate groups.
摘要翻译：本发明涉及可辐射固化的水性组合物，其包含由多异氰酸酯反应获得的高分子量烯属不饱和聚氨酯，至少一种亲水性化合物，其能够使聚氨酯预聚物分散在水性介质中，至少含有至少含有两个能够与异氰酸酯基团反应的反应基团和含活性氢的扩链剂和低分子量烯键式不饱和聚氨酯封端，其中烯属不饱和化合物含有基本上可以与异氰酸酯基团反应的一个反应性基团。

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