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    • 10. 发明授权
    • Process for manufacturing alkylamines
    • 制备烷基胺的方法
    • US4398041A
    • 1983-08-09
    • US344246
    • 1982-01-29
    • Robert N. CochranMichel Deeba
    • Robert N. CochranMichel Deeba
    • C07C85/06
    • C07C209/16
    • A process for converting a C.sub.1 -C.sub.4 alcohol to a non-equilibrium controlled distribution of mono-, di- and trialkylamines is disclosed. A mixture of the alcohol and ammonia is reacted in a first conversion reactor containing a shape selective catalyst to yield a first product stream comprising the mono- and disubstituted alkylamines and substantially no trisubstituted alkylamine. A predetermined fraction of the first product stream is removed and the remainder of the stream is reacted in a second conversion reactor containing a catalyst which yields a second product stream comprising an equilibrium controlled distribution of the mono-, di- and trisubstituted alkylamine. The fraction of the first product stream and the second product stream are combined to yield an alkylamines stream comprising a non-equilibrium controlled alkylamines distribution.
    • 公开了将C1-C4醇转化为单 - ,二 - 和三烷基胺的非平衡受控分布的方法。 醇和氨的混合物在含有形状选择性催化剂的第一转化反应器中反应,得到包含单取代烷基胺和二取代烷基胺并基本上不含三取代烷基胺的第一产物流。 除去预定部分的第一产物流,并将剩余的物流在包含催化剂的第二转化反应器中反应,该催化剂产生包含单取代,二取代和三取代的烷基胺的平衡受控分布的第二产物流。 将第一产物流和第二产物流的级分组合以产生包含非平衡控制的烷基胺分布的烷基胺流。