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    • 6. 发明申请
    • Apparatus and Process for Preparing Silanes
    • 硅烷制备装置及方法
    • US20080095691A1
    • 2008-04-24
    • US11575226
    • 2005-07-21
    • Raymund SonnenscheinPeter AdlerTim PopkenJohn Kahsnitz
    • Raymund SonnenscheinPeter AdlerTim PopkenJohn Kahsnitz
    • B01D3/00B01J8/02C01B33/107
    • C01B33/107B01D3/009B01J8/025C01B33/1071C01B33/10773Y02P20/127Y10S203/06
    • The invention relates to an apparatus, for preparing silanes of the general formula HnSiCl4-n where n=1, 2, 3 and/or 4 by dismutation of at least one relatively highly chlorinated silane in the presence of a catalyst, which is based on at least one distillation column (1) having a column bottom (1.1) and a column top (1.2), at least one side reactor (2) with catalyst bed (3), at least one feed inlet (1.3), a product offtake (1.4) and at least one further product offtake (1.5 or 1.8), where the distillation column (1) is provided with at least one chimney tray (4) and at least one side reactor (2) is connected to the distillation column (1) via at least three pipes (5, 6, 7) in such a way that the connection point of the line (5) to the distillation column (1) for the discharge of the condensate from the chimney tray (4, 4.1) is at a higher level than the upper edge of the catalyst bed (3, 3.1 or 3.2), the line (6) for the discharge of the liquid phase from the side reactor (2) opens (6.1) into the distillation column (1) below the chimney tray (4) and this opening (6, 6.1) is at a lower level than the upper edge of the catalyst bed (3, 3.1 or 3.2) and the line (7) for the discharge of the gas phase from the associated side reactor (2) opens (7.1) into the distillation column (1) above the level (4.1) of the chimney tray (4). Furthermore, the present invention provides a process for preparing said silanes in the apparatus of the invention.
    • 本发明涉及一种用于制备通式为其中n = 1,2,3和/或4的硅烷的硅烷的装置,其中n = 1,2,3和/或4通过 在基于具有塔底(1.1)和塔顶(1.2)的至少一个蒸馏塔(1),至少一个具有催化剂的侧反应器(2)的催化剂存在下,至少一种相对高度氯化的硅烷 床(3),至少一个进料入口(1.3),产品出口(1.4)和至少一个另外的出料产品(1.5或1.8),其中蒸馏塔(1)设置有至少一个烟囱托盘(4) ),并且至少一个侧反应器(2)经由至少三个管(5,6,7)连接到蒸馏塔(1),使得管线(5)到蒸馏塔( 用于排出来自烟囱式塔盘(4,4.1)的冷凝物的排放比催化剂床(3,3.1或3.2)的上边缘高的水平,排出管线(6) 来自侧反应器(2)的液相的边界向烟囱盘(4)下方的蒸馏塔(1)打开(6.1),该开口(6,6.1)处于比催化剂的上边缘低的水平 床(3,3.1或3.2)和用于从相关联的反应器(2)排出气相的管线(7)打开(7.1)进入烟囱式塔板(4.1)上方的蒸馏塔(1) (4)。 此外,本发明提供了在本发明的装置中制备所述硅烷的方法。
    • 7. 发明授权
    • Processes for the purification of waters containing organic constituents
    • 净化含有机成分的水的方法
    • US6117331A
    • 2000-09-12
    • US820905
    • 1997-03-19
    • Peter FastGerda GrundJohn Kahsnitz
    • Peter FastGerda GrundJohn Kahsnitz
    • B01J20/26B01J20/34C02F1/28C02F1/58
    • B01J20/34C02F1/285
    • Conventional regenerative adsorptive methods for the purification of waters of organic constituents are limited in their application, when owing to a low content of organic water constituents the loading of the adsorbers is so low that the condensed water vapor desorbate no longer has a tendency to form two phases, or when the organic components are readily water-soluble and thus, following desorption with water vapor, can be separated only with difficulty out of the condensed desorbate. The process of the invention improves the tendency toward phase separation by cycling back the aqueous phase of the desorbate onto a loaded adsorber prior to its desorption in order to increase the loading and reduce, through additional supply of external heat, the required amount of water vapor for desorption. The present process is particularly useful for purification of industrial process waters or ground water.
    • 用于纯化有机成分的水的常规再生吸附方法在其应用中受到限制,当由于有机水成分含量低时,吸附器的负载非常低,使得冷凝的水蒸气解吸不再具有形成二 或者当有机成分容易溶于水时,因此在用水蒸汽解吸后,只能在冷凝的脱硫物中难以分离。 本发明的方法通过在其解吸附近循环将脱硫剂的水相循环回负载的吸附剂来改善相分离的趋势,以增加负载并通过额外供应外部热量减少所需量的水蒸气 用于解吸。 本方法对于工业过程水或地下水的净化特别有用。