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1. 发明申请

US20060128977A1 Conversion of 2,5-(hydroxymethyl)furaldehyde to industrial derivatives, purification of the derivatives, and industrial uses therefor 有权
公开(公告)号：US20060128977A1
公开(公告)日：2006-06-15
申请号：US11273947
申请日：2005-11-15
申请人： Alexandra Sanborn , Paul Bloom
发明人： Alexandra Sanborn , Paul Bloom
IPC分类号： C07D307/02
CPC分类号： C07D307/42 , C07C51/245 , C07D307/46 , C07C59/185
摘要： A method of preparing 2,5-bis(hydroxymethyl)tetrahydrofuran comprises heating a reaction mixture comprising 2,5-(hydroxymethyl)furaldehyde, an organic solvent, and a catalyst system comprising nickel and zirconium at a temperature, for a time, and at a pressure sufficient to promote reduction of the 2,5-(hydroxymethyl)furaldehyde to 2,5-bis(hydroxymethyl)tetrahydrofuran to produce a product mixture comprising 2,5-bis(hydroxymethyl)tetrahydrofuran.

2. 发明申请

US20060128843A1 Conversion of 2,5-(hydroxymethyl)furaldehyde to industrial derivatives, purification of the derivatives, and industrial uses therefor 有权
公开(公告)号：US20060128843A1
公开(公告)日：2006-06-15
申请号：US11070063
申请日：2005-03-02
申请人： Alexandra Sanborn , Paul Bloom
发明人： Alexandra Sanborn , Paul Bloom
IPC分类号： C08K5/15
CPC分类号： C07D307/42 , C07C51/245 , C07D307/46 , C07C59/185
摘要： A method of preparing 2,5-bis(hydroxymethyl)tetrahydrofuran comprises heating a reaction mixture comprising 2,5-(hydroxymethyl)furaldehyde, an organic solvent, and a catalyst system comprising nickel and zirconium at a temperature, for a time, and at a pressure sufficient to promote reduction of the 2,5-(hydroxymethyl)furaldehyde to 2,5-bis(hydroxymethyl)tetrahydrofuran to produce a product mixture comprising 2,5-bis(hydroxymethyl)tetrahydrofuran.

3. 发明申请

US20060128844A1 Conversion of 2,5-(hydroxymethyl)furaldehyde to industrial derivatives, purification of the derivatives, and industrial uses therefor 有权
公开(公告)号：US20060128844A1
公开(公告)日：2006-06-15
申请号：US11274554
申请日：2005-11-15
申请人： Alexandra Sanborn , Paul Bloom
发明人： Alexandra Sanborn , Paul Bloom
IPC分类号： C08K5/15 , C07D307/02
CPC分类号： C07D307/42 , C07C51/245 , C07D307/46 , C07C59/185
摘要： A method of preparing 2,5-bis(hydroxymethyl)tetrahydrofuran comprises heating a reaction mixture comprising 2,5-(hydroxymethyl)furaldehyde, an organic solvent, and a catalyst system comprising nickel and zirconium at a temperature, for a time, and at a pressure sufficient to promote reduction of the 2,5-(hydroxymethyl)furaldehyde to 2,5-bis(hydroxymethyl)tetrahydrofuran to produce a product mixture comprising 2,5-bis(hydroxymethyl)tetrahydrofuran.

4. 发明申请

US20120261618A1 REDUCTION OF HMF ETHERS WITH METAL CATALYST 有权
标题翻译：用金属催化剂还原HMF
公开(公告)号：US20120261618A1
公开(公告)日：2012-10-18
申请号：US13096348
申请日：2011-04-28
申请人： Paul D. Bloom , Alexandra Sanborn
发明人： Paul D. Bloom , Alexandra Sanborn
IPC分类号： C07D307/12 , C09K3/00 , C07C41/18 , C07C43/13 , C07D307/42 , C07D307/46
CPC分类号： C07D307/54 , C07C41/26 , C07C43/13 , C07D307/12 , C07D307/16 , C07D307/44 , C08K5/06 , C09K3/00
摘要： Methods of making reduced derivatives of hydroxymethyl furfural using metal catalysts are described. The derivatives may have tetrahydrofuran or furan nucleus with alkoxymethyl ether or ester moieties on the 5′ carbon and methanol on the 2′ carbon. Suitable metal catalyst include Raney nickel, a nickel catalyst with a zirconium promoter, a chromite catalyst with a barium, a palladium catalyst, such as palladium on carbon, or a ruthenium catalyst. Also provided are a new class of compounds, which are n-alkoxy hexane diols (i.e., 1,2 or 1,5 hexane diol ethers) and methods of making the same by reduction of furan or tetrahydrofuran deivatives.
摘要翻译：描述了使用金属催化剂制备羟甲基糠醛的还原衍生物的方法。衍生物可以在2'碳上的5'碳和甲醇上具有含有烷氧基甲基醚或酯部分的四氢呋喃或呋喃核。合适的金属催化剂包括阮内镍，具有锆促进剂的镍催化剂，具有钡的铬铁催化剂，钯催化剂如钯碳或钌催化剂。还提供了一类新的化合物，它们是正烷氧基己二醇（即1,2或1,5-己二醇醚）和通过还原呋喃或四氢呋喃衍生物制备该化合物的方法。

5. 发明授权

US08709286B2 Reduction of HMF ethers with metal catalyst 有权
标题翻译：用金属催化剂还原HMF醚
公开(公告)号：US08709286B2
公开(公告)日：2014-04-29
申请号：US13096348
申请日：2011-04-28
申请人： Paul D. Bloom , Alexandra Sanborn
发明人： Paul D. Bloom , Alexandra Sanborn
IPC分类号： C07D307/12
CPC分类号： C07D307/54 , C07C41/26 , C07C43/13 , C07D307/12 , C07D307/16 , C07D307/44 , C08K5/06 , C09K3/00
摘要： Methods of making reduced derivatives of hydroxymethyl furfural using metal catalysts are described. The derivatives may have tetrahydrofuran or furan nucleus with alkoxymethyl ether or ester moieties on the 5′ carbon and methanol on the 2′ carbon. Suitable metal catalyst include Raney nickel, a nickel catalyst with a zirconium promoter, a chromite catalyst with a barium, a palladium catalyst, such as palladium on carbon, or a ruthenium catalyst. Also provided are a new class of compounds, which are n-alkoxy hexane diols (i.e., 1,2 or 1,5 hexane diol ethers) and methods of making the same by reduction of furan or tetrahydrofuran derivatives.
摘要翻译：描述了使用金属催化剂制备羟甲基糠醛的还原衍生物的方法。衍生物可以在2'碳上的5'碳和甲醇上具有含有烷氧基甲基醚或酯部分的四氢呋喃或呋喃核。合适的金属催化剂包括阮内镍，具有锆促进剂的镍催化剂，具有钡的铬铁催化剂，钯催化剂如钯碳或钌催化剂。还提供了一类新的化合物，它们是正烷氧基己二醇（即1,2或1,5-己二醇醚）和通过还原呋喃或四氢呋喃衍生物制备该化合物的方法。

6. 发明授权

US08785666B1 Method for preparation of anhydrosugar ethers 有权
标题翻译：脱水糖醚的制备方法
公开(公告)号：US08785666B1
公开(公告)日：2014-07-22
申请号：US14262836
申请日：2014-04-28
申请人： Stephen Howard , Alexandra Sanborn
发明人： Stephen Howard , Alexandra Sanborn
IPC分类号： C07D493/04
CPC分类号： C07D493/04
摘要： A method for alkylation of an anhydrosugar compound in which a dialkyl carbonate is reacted with an anhydrosugar compound in the presence of a solid phase basic catalyst. Typical anhydrosugars are isosorbide.
摘要翻译：烷基化方法，其中在固相碱性催化剂存在下，碳酸二烷基酯与脱水糖化合物反应。典型的脱水糖是异山梨醇。

7. 发明授权

US08669383B2 Preparation of aminomethyl furans and alkoxymethyl furan derivatives from carbohydrates 有权
公开(公告)号：US08669383B2
公开(公告)日：2014-03-11
申请号：US13994170
申请日：2011-12-13
申请人： Stephen Howard , Alexandra Sanborn
发明人： Stephen Howard , Alexandra Sanborn
IPC分类号： C07D307/04 , C07D307/34
CPC分类号： C07D307/12 , C07D307/14 , C07D307/42 , C07D307/44 , C07D307/52
摘要： Described herein are single step methods of making various classes of alkylamine derivatives of furan and tetrahydrofuran by simultaneous contact of a sugar with H2, an acid catalyst and hydrogenation catalyst in the presence of an alkylamide solvent. The hydrogenation catalyst is a heterogeneous catalyst comprising a metal selected from the group consisting of Pt, Pd, and nickel. The acid catalysts may be homogeneous mineral acid or a heterogeneous acid catalyst on substrate. In a preferred practice the two catalysts are provided on a common heterogeneous bifunctional support. Using similar combinations of acid and hydrogenation catalysts, there is also described single step methods for making furandimethanol by simultaneously contacting a hexose with the two separate catalysts in the presence of H2 in an aprotic solvent, such as dimethylformamide. With the same catalyst system and similar reaction conditions, 2, 5 furan dialkylethers can also be made in a single step when the solvent includes an ROH alcohol.

8. 发明申请

US20130296584A1 Production of 5-Membered and 6-Membered Cyclic Esters of Polyols 有权
标题翻译： 5元和6元环多元醇的生产
公开(公告)号：US20130296584A1
公开(公告)日：2013-11-07
申请号：US13894724
申请日：2013-05-15
申请人： Stephen Howard , Alexandra Sanborn
发明人： Stephen Howard , Alexandra Sanborn
IPC分类号： C07D493/04
CPC分类号： C07D493/04 , C07D493/22 , Y02P20/582
摘要： Described herein are improved methods for the preparation of 5- and 6-membered cyclic mono and diesters of sugar alcohols and anhydrosugar alcohols by reaction with an organic acid RCOOH over a solid acidic substrate. The process is adaptable to a continuous process for simultaneously making and separating the cyclic esters from the sugar alcohols and anhydrosugar alcohols under mild conditions using the solid acid substrate as both the catalyst and a chromatographic bed for separation. The reactions are performed at mild temperatures of 70° C. to 100° C. and the formation of the cyclic esters is nearly quantitative. Also described is a method for making 5- and 6-membered cyclic mono and diesters of sugar alcohols and anhydrosugar alcohols using microwave irradiation in the presence of the organic acid.
摘要翻译：本文描述了通过在固体酸性底物上与有机酸RCOOH反应来制备糖醇和脱水糖醇的5-和6-元环状单酯和二酯的改进方法。该方法适用于在温和条件下使用固体酸底物作为催化剂和用于分离的色谱床同时制备和分离环状酯与糖醇和脱水葡萄糖醇的连续方法。反应在70℃至100℃的温和温度下进行，环酯的形成几乎是定量的。还描述了在有机酸存在下使用微波辐射制备糖醇和脱水糖醇的5-和6-元环状单酯和二酯的方法。

9. 发明授权

US08445705B2 Production of 5-membered and 6-membered cyclic esters of polyols 有权
公开(公告)号：US08445705B2
公开(公告)日：2013-05-21
申请号：US12993143
申请日：2009-05-28
申请人： Stephen Howard , Alexandra Sanborn
发明人： Stephen Howard , Alexandra Sanborn
IPC分类号： C07D493/04
CPC分类号： C07D493/04 , C07D493/22 , Y02P20/582
摘要： Described herein are improved methods for the preparation of 5- and 6-membered cyclic mono and diesters of sugar alcohols and anhydrosugar alcohols by reaction with an organic acid RCOOH over a solid acidic substrate. The process is adaptable to a continuous process for simultaneously making and separating the cyclic esters from the sugar alcohols and anhydrosugar alcohols under mild conditions using the solid acid substrate as both the catalyst and a chromatographic bed for separation. The reactions are performed at mild temperatures of 70° C. to 100° C. and the formation of the cyclic esters is nearly quantitative. Also described is a method for making 5- and 6-membered cyclic mono and diesters of sugar alcohols and anhydrosugar alcohols using microwave irradiation in the presence of the organic acid.

10. 发明申请

US20080027236A1 Processes for the preparation and purification of hydroxymethylfuraldehyde and derivatives 有权
公开(公告)号：US20080027236A1
公开(公告)日：2008-01-31
申请号：US11904812
申请日：2007-09-28
申请人： Alexandra Sanborn
发明人： Alexandra Sanborn
IPC分类号： C07D307/02 , C07C51/00
CPC分类号： C07D307/50 , C07C51/00 , C07C59/347
摘要： A method for utilizing an industrially convenient fructose source for a dehydration reaction converting a carbohydrate to a furan derivative is provided. Recovery methods also are provided. Embodiments of the methods improve upon the known methods of producing furan derivatives.

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