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    • 3. 发明授权
    • Method for recovering energy in-situ from underground resources and upgrading such energy resources above ground
    • 从地下资源原位回收能源和升级地面以上能源的方法
    • US08002033B2
    • 2011-08-23
    • US12380669
    • 2009-03-03
    • Albert CalderonTerry James Laubis
    • Albert CalderonTerry James Laubis
    • E21B43/24E21B43/243
    • E21B43/164E21B43/24E21B43/295
    • This method deals in recovering energy in-situ from an underground resource and upgrading such resource above ground. It consists of injecting a hot gas to pyrolyze it to produce gases and liquids with high hydrogen content and a residual hot char. The gases and liquids together with the injected hot gas form a mixture of gases and liquids that is brought above ground and treated into a clean mixture of gases and liquids rich in hydrogen and then used as a chemical feedstock and/or transportation fuel. Following the pyrolyzation of the resource, carbon dioxide and air are injected into the residual hot char to convert the CO2 into 2CO+N2, which is brought above ground and treated into a clean lean gas. This lean gas is used to generate efficient electric power, heat the injected gas for pyrolysis, and convert the 2CO+N2 as a feedstock into fertilizer.
    • 这种方法涉及从地下资源原位回收能源,并将这些资源升级到地面以上。 它包括注入热气体来热解它以产生具有高氢含量的气体和液体以及残留的热焦炭。 气体和液体与注入的热气体一起形成气体和液体的混合物,该混合气体和液体被置于地面之上,并被处理成清洁的富含氢气的气体和液体的混合物,然后用作化学原料和/或运输燃料。 在资源热解之后,将二氧化碳和空气注入剩余的热焦炭中以将CO 2转化为2CO + N 2,将其置于地上并处理成干净的贫气。 这种贫气用于产生有效的电力,加热注入的气体进行热解,并将作为原料的2CO + N2转化为肥料。
    • 4. 发明申请
    • Method and apparatus for continuously carbonizing materials
    • 连续碳化材料的方法和装置
    • US20120047975A1
    • 2012-03-01
    • US12807265
    • 2010-09-01
    • Albert CalderonTerry James Laubis
    • Albert CalderonTerry James Laubis
    • C10B7/00C05F11/02C09K3/00C10B57/04C10J3/00
    • C10B49/02C05D7/00C05F11/02C10B7/00C10B57/04
    • A method and apparatus for continuously carbonizing materials while co-producing gases in a coking chamber closed to the atmosphere, having a charger at one end comprising a pushing ram surrounding a mandrel that surrounds an air or oxygen injection lance. The other end of the coking chamber collects and separates coke from gases, with coke directed to a closed quenching chamber and gases directed to a cleanup. Thermal energy for converting coal into coke derives from combusting some metallurgical coal by said lance. In the case of producing coke from metallurgical coal, which is expensive because of limited supply, the herein method and apparatus are configured to separately charge a low-cost, abundant, carbonizing material and expensive metallurgical coal so that metallurgical coal surrounds the low-cost carbonizing material, and a lance combusts the low-cost carbonizing material, releasing thermal energy that heats metallurgical coal under reducing conditions, producing specification coke and gases more economically. After cleanup, gases are used as chemical feedstock or fuel. The word “coke” herein used may also be referred to as “charcoal” or “char.”
    • 一种用于连续碳化材料的方法和装置,同时在大气中的焦化室中共同生产气体,其一端具有充电器,包括围绕围绕空气或氧气注入喷枪的心轴的推动压头。 焦化室的另一端收集和分离焦炭与气体,焦炭被引导到封闭的淬火室,并将气体导向清洁。 将煤炭转化为焦炭的热能源是由所述喷枪燃烧一些冶金煤。 在由于供应有限而昂贵的冶金煤生产焦炭的情况下,本发明的方法和装置构造成分别对低成本,丰富的碳化材料和昂贵的冶金煤进行充电,使得冶金煤围绕低成本 碳化材料和喷枪燃烧低成本碳化材料,释放在还原条件下加热冶金煤的热能,更经济地制造规格的焦炭和气体。 清理后,使用气体作为化学原料或燃料。 这里使用的“焦炭”一词也可以称为“炭”或“炭”。
    • 6. 发明申请
    • Method for recovering energy in-situ from underground resources and upgrading such energy resources above ground
    • 从地下资源原位回收能源和升级地面以上能源的方法
    • US20100224369A1
    • 2010-09-09
    • US12380669
    • 2009-03-03
    • Albert CalderonTerry James Laubis
    • Albert CalderonTerry James Laubis
    • E21B43/24E21B36/00
    • E21B43/164E21B43/24E21B43/295
    • A method for recovering energy in-situ from underground resources such as coal and upgrading such energy above ground, comprising a first step consisting of injecting a hot recycling gas through said resource to devolatilize it to produce a raw hydrogen rich gas and an in-situ residual hot char wherein said hydrogen rich gas is brought above ground and is treated to become a cleaned, upgraded hydrogen rich gas serving as a feedstock to make a chemical and/or transportation fuel, and a second step consisting of injecting a waste greenhouse gas like carbon dioxide (CO2) plus an oxidant such as air into said hot char to convert said CO2 into CO+N2 which is brought above ground and treated to form a clean lean gas which can be beneficially used to: (i) generate efficient electric power, (ii) heat the hydrogen rich recycle gas, and (iii) make a needed by-product such as fertilizer.
    • 一种从诸如煤等地下资源中原位回收能源的方法,其特征在于包括将热回收气体通过所述资源注入脱挥发分以产生富含原氢的气体和原位的第一步骤 残余热焦炭,其中所述富氢气体被置于地面以上并被处理成为清洁的,升级的富氢气体,用作原料以制备化学和/或运输燃料,以及第二步骤,其包括将诸如 二氧化碳(CO 2)和氧化剂如空气进入所述热焦炭以将所述CO 2转化成CO + N 2,所述CO + N 2被置于地面并进行处理以形成干净的贫气,其可有利地用于:(i)产生有效的电力 ,(ii)加热富氢循环气体,和(iii)制备所需的副产物如肥料。
    • 10. 发明授权
    • Method and apparatus for upgrading bituminous material
    • 用于升级沥青材料的方法和装置
    • US07413647B2
    • 2008-08-19
    • US11078949
    • 2005-03-07
    • Albert CalderonTerry James LaubisRichard Owen McCarthy
    • Albert CalderonTerry James LaubisRichard Owen McCarthy
    • C10G47/02C10G47/24B01J8/08B01J8/12
    • C10G11/14B01J4/002B01J8/125B01J19/26B01J2208/00495B01J2208/00504B01J2208/00557B01J2219/0004B01J2219/185B01J2219/187B01J2219/1943B01J2219/1946C10G11/18
    • The present invention consists of an improved method and apparatus to upgrade bitumen in various forms which comprises four main components; namely, a fractionator equipped with a condenser, a heavy gas oil catalytic treater, a catalyst regenerator/gasifier and a gas cleanup assembly. In operation, the bitumen in liquid form is fed to the fractionator for initial separation of fractions with the bulk of the bitumen leaving the bottom of the fractionator in the form of a heavy gas oil which is pumped to the catalytic treater and sprayed on a hot catalyst to crack the heavy gas oil (an endothermic reaction) to release lighter hydrocarbons in the form of H2 rich volatile matter while depositing carbon on the catalyst. The volatile matter from the treater is directed to the fractionator where the condensable fractions are separated from the non-condensable H2 rich gas, a valuable primary gas. The carbon containing catalyst from the treater is recycled to the regenerator/gasifier, and the catalyst after being regenerated (an exothermic reaction) is fed hot to the treater. Various fractions are removed from the fractionator as intermediates in the form of light napthas and light oils. The off-gas from the regenerator/gasifier is directed to a gas cleanup system to produce a valuable secondary gas. Both the primary gas and the secondary gas may be further utilized in the processing of the intermediates produced by the method, the primary gas being a source of H2 and the secondary gas being a source of thermal energy.
    • 本发明包括一种以各种形式升级沥青的改进方法和装置,其包括四个主要组分; 即配备有冷凝器,重质瓦斯油催化处理器,催化剂再生器/气化器和气体净化组件的分馏器。 在操作中,将液体形式的沥青进料到分馏器中,用于初始分离馏分,其中大部分沥青离开分馏器的底部,形式为重质瓦斯油,其被泵送到催化处理器并喷涂在热的 催化剂裂解重质瓦斯油(吸热反应)以释放富含H 2 O 3挥发物质的较轻质烃,同时在催化剂上沉积碳。 来自处理器的挥发性物质被引导至分馏器,其中可冷凝馏分与不可冷凝的H 2富含气体(有价值的一次气体)分离。 来自处理器的含碳催化剂被再循环到再生器/气化器中,再生后的催化剂(放热反应)被热加热到处理器。 从分馏器中除去各种馏分,作为浅萘和轻油形式的中间体。 来自再生器/气化器的废气被引导到气体净化系统以产生有价值的二次气体。 初级气体和次级气体都可以进一步用于通过该方法生产的中间体的处理,主气体是H 2 2源,二次气体是热能源。