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    • 6. 发明授权
    • Method and apparatus for upgrading bituminous material
    • 用于升级沥青材料的方法和装置
    • US07413647B2
    • 2008-08-19
    • US11078949
    • 2005-03-07
    • Albert CalderonTerry James LaubisRichard Owen McCarthy
    • Albert CalderonTerry James LaubisRichard Owen McCarthy
    • C10G47/02C10G47/24B01J8/08B01J8/12
    • C10G11/14B01J4/002B01J8/125B01J19/26B01J2208/00495B01J2208/00504B01J2208/00557B01J2219/0004B01J2219/185B01J2219/187B01J2219/1943B01J2219/1946C10G11/18
    • The present invention consists of an improved method and apparatus to upgrade bitumen in various forms which comprises four main components; namely, a fractionator equipped with a condenser, a heavy gas oil catalytic treater, a catalyst regenerator/gasifier and a gas cleanup assembly. In operation, the bitumen in liquid form is fed to the fractionator for initial separation of fractions with the bulk of the bitumen leaving the bottom of the fractionator in the form of a heavy gas oil which is pumped to the catalytic treater and sprayed on a hot catalyst to crack the heavy gas oil (an endothermic reaction) to release lighter hydrocarbons in the form of H2 rich volatile matter while depositing carbon on the catalyst. The volatile matter from the treater is directed to the fractionator where the condensable fractions are separated from the non-condensable H2 rich gas, a valuable primary gas. The carbon containing catalyst from the treater is recycled to the regenerator/gasifier, and the catalyst after being regenerated (an exothermic reaction) is fed hot to the treater. Various fractions are removed from the fractionator as intermediates in the form of light napthas and light oils. The off-gas from the regenerator/gasifier is directed to a gas cleanup system to produce a valuable secondary gas. Both the primary gas and the secondary gas may be further utilized in the processing of the intermediates produced by the method, the primary gas being a source of H2 and the secondary gas being a source of thermal energy.
    • 本发明包括一种以各种形式升级沥青的改进方法和装置,其包括四个主要组分; 即配备有冷凝器,重质瓦斯油催化处理器,催化剂再生器/气化器和气体净化组件的分馏器。 在操作中,将液体形式的沥青进料到分馏器中,用于初始分离馏分,其中大部分沥青离开分馏器的底部,形式为重质瓦斯油,其被泵送到催化处理器并喷涂在热的 催化剂裂解重质瓦斯油(吸热反应)以释放富含H 2 O 3挥发物质的较轻质烃,同时在催化剂上沉积碳。 来自处理器的挥发性物质被引导至分馏器,其中可冷凝馏分与不可冷凝的H 2富含气体(有价值的一次气体)分离。 来自处理器的含碳催化剂被再循环到再生器/气化器中,再生后的催化剂(放热反应)被热加热到处理器。 从分馏器中除去各种馏分,作为浅萘和轻油形式的中间体。 来自再生器/气化器的废气被引导到气体净化系统以产生有价值的二次气体。 初级气体和次级气体都可以进一步用于通过该方法生产的中间体的处理,主气体是H 2 2源,二次气体是热能源。
    • 7. 发明授权
    • Advanced method for processing fuels
    • 加工燃料的先进方法
    • US07998236B2
    • 2011-08-16
    • US12228841
    • 2008-08-18
    • Albert CalderonTerry James LaubisRichard Owen McCarthy
    • Albert CalderonTerry James LaubisRichard Owen McCarthy
    • C01C3/00C05C11/00
    • C05C11/00C05C9/00Y02E50/343Y02W30/47
    • An advanced method for processing a solid feedstock such as coal and a liquid feedstock such as bitumen wherein gases produced from such fossil fuel feedstocks are divided in a way as to polygenerate various by-products which includes the conversion of a waste gas (flue gas) containing nitrogen (N2) and carbon dioxide (CO2) generated from the combustion of said gases to produce an intermediate made of carbon (C) and nitrogen (N2) in the form of cyanogen which in turn is converted to a fertilizer such as oxamide. This approach obviates the necessity of CO2 capture and storage in a geologic formation. Besides the making of a fertilizer from a waste gas containing N2 and CO2, the other by-products can be power in the form of electricity and/or steam from a lean gas and liquid transportation fuel like methanol/gasoline, or chemicals from a hydrogen rich gas. The method is applicable to utility as well as to industry. This approach provides a comprehensive solution with respect to the use of energy from fossil fuels in an efficient and environmentally acceptable manner.
    • 用于处理固体原料如煤和液体原料如沥青的先进方法,其中由这种化石燃料原料产生的气体以多种生成各种副产物的方式分开,其包括废气(烟道气) 含有由所述气体的燃烧产生的氮(N 2)和二氧化碳(CO 2),以产生氰化物形式的碳(C)和氮(N 2)制成的中间体,其又转化为肥料如草酰胺。 这种方法避免了二氧​​化碳捕获和储存在地质层中的必要性。 除了从含有N2和CO2的废气中制造肥料外,其他副产物可以是来自贫气和液体运输燃料如甲醇/汽油或来自氢的化学物质的电力和/或蒸汽的形式的动力 富气。 该方法适用于公用事业和工业。 这种方法以有效和环境可接受的方式提供了关于从化石燃料中使用能源的综合解决方案。
    • 9. 发明授权
    • Sustainable method inclusive of facilities to grow and process crops for food and biomass for energy in an environmentally acceptable manner
    • 可持续的方法,包括以环境可接受的方式种植和处理粮食和生物质能源的能源的设施
    • US09301452B2
    • 2016-04-05
    • US13573297
    • 2012-09-10
    • Albert CalderonRichard Owen McCarthyTerry James Laubis
    • Albert CalderonRichard Owen McCarthyTerry James Laubis
    • A01G1/00A01B79/02
    • A01G22/00A01B79/02Y02E50/12
    • An advanced method and facility for growing abundant crops for food together with a sustainable growth of biomass for energy within a farm setting measuring (by way of example) 600 acres and yielding some 180 bushels of corn per acre, amounting to a total farm yield of 108,000 bushels. By increasing the yield of 180 to 270 bushels per acre with drainage, irrigation, and a pond that accepts water in wet weather and dispenses water for irrigation in dry weather, and supplementing with fertilizer, the 108,000 bushels can be produced with only 400 acres, this freeing 200 acres for growing biomass to be harvested and delivered to a centralized processor (preferably in pellet form) and efficiently converts the biomass into a biofuel rich in H2 for transportation such as gasoline and a low-Btu biofuel to generate biopower while co-producing fertilizer to enhance growth of both crops and biomass.
    • 一个先进的方法和设施,用于种植丰富的粮食作物,以及在农场环境中可持续增长生物质能的能力(例如),以英亩计算(例如)600英亩,每英亩产生大约180蒲式耳的玉米,总产量为 108,000蒲式耳。 通过排水,灌溉和在天气中接受水分的池塘,在干旱天气下分配灌溉水,补充肥料,每英亩产量增加180至270蒲式耳,可生产108,000蒲式耳,只有400英亩, 这种200英亩的生长用于生长的生物量被收获并运送到集中处理器(优选以颗粒形式),并有效地将生物质转化为富含H2的生物燃料用于诸如汽油和低Btu生物燃料的运输,以产生生物能量, 生产肥料以增加作物和生物量的增长。