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1. 发明授权

US4224435A Method for mixing raw materials for producing oxymethylene copolymers 失效
标题翻译：用于混合生产甲醛共聚物的原料的方法
公开(公告)号：US4224435A
公开(公告)日：1980-09-23
申请号：US48178
申请日：1979-06-13
申请人： Akitoshi Sugio , Akira Amamiya , Tadashi Kunii , Tomotaka Furusawa , Mutsuhiko Takeda , Katsumasa Tanaka , Toshikazu Umenura , Kiyokazu Kawaguchi
发明人： Akitoshi Sugio , Akira Amamiya , Tadashi Kunii , Tomotaka Furusawa , Mutsuhiko Takeda , Katsumasa Tanaka , Toshikazu Umenura , Kiyokazu Kawaguchi
IPC分类号： B01J4/00 , C08G2/00 , C08G2/10 , C08G2/18
CPC分类号： C08G2/18 , B01J4/001 , C08G2/00
摘要： In a method for mixing a trioxane, a polymerization catalyst and a comonomer for producing of oxymethylene copolymers by continuously copolymerizing trioxane with a cyclic ether or a cyclic acetal as a comonomer, the improved method comprises following steps:spouting a comonomer and a polymerization catalyst from nozzle openings which are set adjacent to each other,while washing both openings at the tip end of the nozzles with a flow of trioxane,whereby mixing said comonomer, said polymerization catalyst and said trioxane,and then feeding the mixture to a polymerization reactor to effect copolymerization.The raw materials are mixed together before they are fed to the polymerization reactor, and no clogging trouble at the tip end of the nozzle for feeding a polymerization catalyst occurs. Further the resulting copolymer has a much superior heat stability. In addition, since each of the reaction raw materials is quantititively fed, the molecular weight and conversion of the copolymer extended from the polymerization reactor is so constant that a stabilized operation of the polymerization reactor can be secured.
摘要翻译：在通过将三恶烷与环醚或环状缩醛连续共聚作为共聚单体的三恶烷，聚合催化剂和用于制备甲醛共聚物的共聚单体的方法中，改进的方法包括以下步骤：将共聚单体和聚合催化剂从喷嘴开口彼此相邻设置，同时用三恶烷流洗涤喷嘴前端的两个开口，由此混合所述共聚单体，所述聚合催化剂和所述三恶烷，然后将混合物进料到聚合反应器中以实现共聚。在将原料进料到聚合反应器中之前将原料混合在一起，并且不会在用于进料聚合催化剂的喷嘴的前端发生堵塞问题。此外，所得共聚物具有非常优异的热稳定性。此外，由于每个反应原料都是定量供料的，从聚合反应器中延伸的共聚物的分子量和转化率是恒定的，从而可以确保聚合反应器的稳定运行。

2. 发明授权

US4189565A Process for polymerizing trioxane 失效
标题翻译：三恶烷聚合方法
公开(公告)号：US4189565A
公开(公告)日：1980-02-19
申请号：US971565
申请日：1978-12-20
申请人： Akitoshi Sugio , Akira Amemiya , Tetsuya Abe , Tomotaka Furusawa , Takeo Suzumori , Mutsuhiko Takeda , Masaharu Kimura , Yoshiharu Ohtsuki , Katsumasa Tanaka , Toshikazu Umemura , Kiyokazu Kawaguchi , Michio Ohba
发明人： Akitoshi Sugio , Akira Amemiya , Tetsuya Abe , Tomotaka Furusawa , Takeo Suzumori , Mutsuhiko Takeda , Masaharu Kimura , Yoshiharu Ohtsuki , Katsumasa Tanaka , Toshikazu Umemura , Kiyokazu Kawaguchi , Michio Ohba
IPC分类号： C07D323/06 , C08F2/10 , C08G2/00 , C08G2/10 , C08G2/18
CPC分类号： C08G2/10 , C08G2/18
摘要： A process for polymerizing trioxane made from an aqueous solution of methanol-containing formaldehyde by a conventional method or copolymerizing the trioxane with another monomer, characterized bycooling the trioxane to crystallize it,allowing the trioxane in a crystalline state to stand in an open system in an atmosphere of air or an inert gas to remove polyoxymethylene dimethoxide from the trioxane,melting the trioxane, andpolymerizing the trioxane or copolymerizing the trioxane and the another monomer.
摘要翻译：聚合由甲醇含甲醛的水溶液通过常规方法或将三恶烷与另一种单体共聚的三恶烷的方法，其特征在于冷却三恶烷以使其结晶，使得结晶状态的三恶烷以开放体系空气或惰性气体气氛，从三恶烷中除去聚甲醛二甲氧基化物，熔融三恶烷，聚合三恶烷或共聚三恶烷和另一种单体。

3. 发明授权

US4301273A Process for stabilizing oxymethylene copolymers 失效
标题翻译：稳定甲醛共聚物的方法
公开(公告)号：US4301273A
公开(公告)日：1981-11-17
申请号：US153674
申请日：1980-05-27
申请人： Akitoshi Sugio , Akira Amemiya , Tadashi Kunii , Tomotaka Furusawa , Mutsuhiko Takeda , Katsumasa Tanaka , Toshikazu Umemura
发明人： Akitoshi Sugio , Akira Amemiya , Tadashi Kunii , Tomotaka Furusawa , Mutsuhiko Takeda , Katsumasa Tanaka , Toshikazu Umemura
IPC分类号： B01F7/04 , B01F15/06 , B01J3/00 , B01J19/20 , C08G2/00 , C08G2/18 , C08G2/30 , C08G2/36 , C08G2/28
CPC分类号： B01J3/006 , B01F15/065 , B01F7/042 , B01J19/20 , C08G2/00 , C08G2/36
摘要： In a process for producing a stabilized oxymethylene copolymer which comprises heat-melting an oxymethylene copolymer having unstable, unblocked terminals obtained by the copolymerization of trioxane with a cyclic acetal and/or a cyclic ether to heat decompose it in the presence of available heat stabilizers; the improvement which comprises heating said oxymethylene copolymer having unblocked terminals in a mixer at a temperature between the melting point of said oxymethylene copolymer and a point 100.degree. C. higher than said melting point under a pressure of 0.1 mmHg to a atmospheric pressure for a mean residence time of 5 to 60 minutes, said mixer comprising a casing, a jacket for heating medium fitted over its external wall, and at least two stirring shafts equipped with a plurality of scraping blades disposed in said casing, said stirring shafts being capable of rotating in the same or different directions, and in the meantime, rotating said stirring shafts of said mixer to heat decompose said oxymethylene copolymer while renewing the surface of the molten oxymethylene copolymer.
摘要翻译：在制备稳定化的甲醛共聚物的方法中，该方法包括将具有不稳定的未封端末端的甲醛共聚物进行加热熔融，其通过三恶烷与环状缩醛和/或环醚的共聚得到，以在可用的热稳定剂存在下将其分解; 改进之处在于，在混合器中将所述具有未封端末端的甲醛共聚物在所述甲醛共聚物的熔点和高于所述熔点的高于所述熔点的100℃的温度下在0.1mmHg的压力下加热至平均气压停留时间为5至60分钟，所述混合器包括壳体，装配在其外壁上的加热介质的护套，以及至少两个配备有设置在所述壳体中的刮刀的搅拌轴，所述搅拌轴能够旋转在相同或不同的方向上，并且同时旋转所述混合器的所述搅拌轴以使所述甲醛共聚物分解，同时更新熔融的甲醛共聚物的表面。

4. 发明授权

US4339569A Process for continuous production of oxymethylene polymer or copolymer 失效
标题翻译：连续生产甲醛聚合物或共聚物的方法
公开(公告)号：US4339569A
公开(公告)日：1982-07-13
申请号：US150986
申请日：1980-05-19
申请人： Akitoshi Sugio , Akira Amemiya , Tadashi Kunii , Tomotaka Furusawa , Mutsuhiko Takeda , Katsumasa Tanaka , Toshikazu Umemura
发明人： Akitoshi Sugio , Akira Amemiya , Tadashi Kunii , Tomotaka Furusawa , Mutsuhiko Takeda , Katsumasa Tanaka , Toshikazu Umemura
IPC分类号： B01J19/20 , C08G2/00 , C08G2/06 , C08G2/10 , C08G2/18 , C08G2/28 , C08K5/00 , C08K5/50
CPC分类号： B01J19/20 , C08G2/00 , C08G2/10 , C08G2/18
摘要： In a process for producing an oxymethylene homopolymer or copolymer having improved stability which comprises polymerizing trioxane or a mixture of trioxane and a cyclic ether and/or a cyclic acetal in bulk in the presence of a catalyst which is at least one compound selected from the group consisting of boron trifluoride, boron trifluoride hydrate and coordination compounds of boron trifluoride with organic compounds containing an oxygen or sulfur atom, the improvement which comprises performing the bulk polymerization without destroying the bulk polymerization system, or which comprises adding a tertiary phosphine compound to the polymerization system to deactivate the catalyst, before the polymerization system formed by the bulk polymerization is destroyed.
摘要翻译：在制备具有改进的稳定性的甲醛均聚物或共聚物的方法中，该方法包括在催化剂存在下，本体上聚合三恶烷或三恶烷和环醚和/或环状缩醛的混合物，所述催化剂是至少一种选自由三氟化硼，三氟化硼水合物和三氟化硼与含有氧或硫原子的有机化合物的配位化合物组成，其改进包括进行本体聚合而不破坏本体聚合体系，或包括向聚合物中加入叔膦化合物在通过本体聚合形成的聚合体系被破坏之前使催化剂失活的系统。

5. 发明授权

US4343929A Process for continuously polymerizing trioxane 失效
标题翻译：连续聚合三恶烷的方法
公开(公告)号：US4343929A
公开(公告)日：1982-08-10
申请号：US200065
申请日：1980-10-23
申请人： Akitoshi Sugio , Kazuyoshi Taka , Akira Amemiya , Tomotaka Furusawa , Mutsuhiko Takeda , Katsumasa Tanaka , Toshikazu Umemura , Yoshihiro Ono
发明人： Akitoshi Sugio , Kazuyoshi Taka , Akira Amemiya , Tomotaka Furusawa , Mutsuhiko Takeda , Katsumasa Tanaka , Toshikazu Umemura , Yoshihiro Ono
IPC分类号： B01J19/20 , C08G2/00 , C08G2/10 , C08G2/18
CPC分类号： C08G2/00 , B01J19/20 , C08G2/10 , C08G2/18 , B01J2219/00779 , B01J2219/182
摘要： A process for producing a polyacetal homopolymer or copolymer which comprises continuously feeding a liquid starting mixture containing molten trioxane and a catalyst and optionally a comonomer through a feed opening of a reactor, said reactor being a continuously stirring-type mixer having two stirring shafts having a plurality of plate-like paddles fixed thereto the cross-section of each of said paddles taken perpendicularly of the axial direction of the stirring shaft having a shape of a convex lens, an ellipse or a quasipolygon inscribing a phantom circle at each vertex, one of said paddles facing another paddle fixed to the other stirring shaft and said one paddle being positioned such that it rotates while the edges thereof keep a slight clearance from the inner surface of the barrel and the other paddle; polymerizing the starting mixture while moving it toward the discharge opening by the rotation of the paddles, the improvement wherein the profiles of the paddles are changed, or the arrangement of the paddles is changed continuously or stepwise, so that the transportability of the reaction mixture becomes progressively smaller from the feed opening toward the discharge opening of the reactor.
摘要翻译：一种制备聚缩醛均聚物或共聚物的方法，其包括通过反应器的进料口连续地供给含有熔融三恶烷和催化剂和任选的共聚单体的液体起始混合物，所述反应器是具有两个搅拌轴的连续搅拌型混合器，多个板状的叶片固定在其上，垂直于搅拌轴的轴向垂直于每个顶点形成凸透镜，椭圆形或准圆体的形状的每个顶板上的假体圆的横截面，所述桨叶面向固定到另一个搅拌轴的另一个桨叶，并且所述一个桨叶定位成使得其旋转，同时其边缘保持与筒体和另一个桨叶的内表面的微小间隙; 使起始混合物通过桨叶的旋转而朝向排出口移动而聚合起始混合物，改进了桨叶的轮廓改变，或者桨叶的排列被连续或逐步地改变，使得反应混合物的输送性变为从进料口向反应器的排出口逐渐变小。

6. 发明授权

US4366305A Process for heat stabilizing oxymethylene copolymers 失效
标题翻译：热稳定甲醛共聚物的方法
公开(公告)号：US4366305A
公开(公告)日：1982-12-28
申请号：US322249
申请日：1981-11-17
申请人： Akira Amemiya , Tadashi Kunii , Tomotaka Furusawa , Mutsuhiko Takeda , Katsumasa Tanaka , Toshikazu Umemura , Yoshihiro Ono , Isamu Masumoto , Noriyasu Nakao , Masanori Furukawa
发明人： Akira Amemiya , Tadashi Kunii , Tomotaka Furusawa , Mutsuhiko Takeda , Katsumasa Tanaka , Toshikazu Umemura , Yoshihiro Ono , Isamu Masumoto , Noriyasu Nakao , Masanori Furukawa
IPC分类号： C08G2/00 , C08G2/18 , C08G2/30 , C08G2/36 , C08G2/28
CPC分类号： C08G2/36 , C08G2/00 , C08G2/18 , B29C2947/92019 , B29C2947/92066 , B29C2947/92314 , B29C2947/924
摘要： In a process for producing a stabilized oxymethylene copolymer by heat-melting, at a temperature ranging between the melting point of the copolymer and a temperature 100.degree. C. higher than the melting point in a degassing apparatus in the presence of a heat stabilizer, a crude oxymethylene copolymer of trioxane with a cyclic acetal or cyclic ether, to decompose and eliminate the instable portions of the copolymer, the improvement which comprises using as the degassing apparatus in heat stabilizing the crude oxymethylene copolymer a combination of (A) an extruder and (B) a surface renewing-type mixer, and carrying out the operation by first feeding a crude oxymethylene copolymer to said extruder (A) to heat-melt and decompose 30-90% by weight of the instable portions of the crude copolymer, removing the decomposed gas via a vent provided in said extruder, and thereafter introducing the molten resin continuously to said surface renewing-type mixer (B) where substantially all of the remaining instable portions of the oxymethylene copolymer are heat-decomposed until the content of the instable portions falls below about 2 wt. %, thereby heat stabilizing the copolymer; said extruder (A) having a single or a plurality of shafts, said surface renewing-type mixer functioning to mix and knead the resin thereby constantly renewing the surface of the resin to volatize the volatiles contained therein.
摘要翻译：在通过热熔制备稳定化的甲醛共聚物的方法中，在热稳定剂存在下，在共聚物的熔点和高于脱气装置中的熔点的温度范围内的温度范围内，三恶烷与环缩醛或环醚的粗甲醛共聚物分解和消除共聚物的不稳定部分，其改进包括使用（A）挤出机和（A）挤出机的组合来将粗甲醛共聚物热稳定化作为脱气装置， B）表面更新型混合机，通过首先将粗甲醛共聚物进料到所述挤出机（A）进行加热熔融分解30-90重量％的粗共聚物的不稳定部分，除去通过设置在所述挤出机中的排气口分解气体，然后将熔融树脂连续地引入到所述表面更新型混合器（B），其中基本上所有的再生甲醛共聚物的不稳定部分被热分解直到不稳定部分的含量低于约2重量％。％，从而使共聚物热稳定化; 所述挤出机（A）具有单个或多个轴，所述表面更新型混合器用于混合和捏合树脂，从而不断地更新树脂的表面以挥发其中所含的挥发物。

7. 发明授权

US4115369A Process for continuous production of oxymethylene polymers 失效
标题翻译：连续生产甲醛聚合物的方法
公开(公告)号：US4115369A
公开(公告)日：1978-09-19
申请号：US855905
申请日：1977-11-29
申请人： Akitoshi Sugio , Tomotaka Furusawa , Katsumasa Tanaka , Toshikazu Umemura , Hiroyuki Urabe
发明人： Akitoshi Sugio , Tomotaka Furusawa , Katsumasa Tanaka , Toshikazu Umemura , Hiroyuki Urabe
IPC分类号： C08G2/00 , B01J19/20 , C08G2/10 , C08G2/18
CPC分类号： C08G2/18 , B01J19/20 , C08G2/10
摘要： A process for continuously producing an oxymethylene polymer by continuously polymerizing a starting monomer containing at least 50 mole% of trioxane in bulk in the presence of a catalyst, which comprises feeding the starting monomer into a first-stage polymerization reactor having a self-cleaning action to perform a first-stage polymerization reaction until the conversion reaches 40 to 70%, withdrawing the reaction mixture as a powder from the outlet of the first-stage polymerization reactor, feeding the reaction mixture into a second-stage polymerization reactor having a stirring action to perform a second-stage polymerization reaction until the conversion reaches 95 to 100%, and then withdrawing the polymerization product as a powder from the outlet of the second-stage polymerization reactor.
摘要翻译：在催化剂存在下，通过连续聚合含有至少50摩尔％的三恶烷的起始单体的方法连续生产甲醛聚合物的方法，其包括将起始单体进料到具有自清洁作用的第一阶段聚合反应器中进行第一阶段聚合反应，直到转化率达到40〜70％，从第一阶段聚合反应器的出口取出粉末状的反应混合物，将反应混合物进料到具有搅拌作用的第二阶段聚合反应器进行第二阶段聚合反应，直至转化率达到95〜100％，然后从第二阶段聚合反应器的出口取出作为粉末的聚合产物。

8. 发明授权

US08854498B2 Image pick-up apparatus and control method thereof 有权
标题翻译：摄像装置及其控制方法
公开(公告)号：US08854498B2
公开(公告)日：2014-10-07
申请号：US13285070
申请日：2011-10-31
申请人： Katsumasa Tanaka
发明人： Katsumasa Tanaka
IPC分类号： H04N5/76 , H04N5/232 , H04N9/82 , H04N5/77
CPC分类号： H04N5/23245 , H04N5/772 , H04N9/8205
摘要： The image pick-up apparatus has an image pick-up unit that picks up an image and outputs RAW still image data; a creation unit that creates, when the RAW still image data is picked up, a development parameter that is a parameter used in development processing of the RAW still image data; and a saving unit that saves, in a storage unit, the development parameter created when the RAW still image data is picked up as a first development parameter which can be used in development processing of the RAW still image data, and further saves, in the storage unit, a development parameter created at other time as a second development parameter which can be used in development processing of the RAW still image data, when saving the RAW still image data outputted from the image pick-up unit in the storage unit.
摘要翻译：图像拾取装置具有拾取图像并输出RAW静止图像数据的图像拾取单元; 创建单元，其在拾取RAW静止图像数据时创建作为RAW静止图像数据的显影处理中使用的参数的显影参数; 以及保存单元，其在存储单元中保存当RAW静止图像数据被拾取时创建的开发参数作为可用于RAW静止图像数据的显影处理的第一显影参数，并且还保存在存储单元，当将从图像拾取单元输出的RAW静止图像数据保存在存储单元中时，作为可以用于RAW静止图像数据的显影处理的第二显影参数在其他时间创建的显影参数。

9. 发明授权

US07933778B2 Serial transmission system, transmission device, and serial transmission method 失效
标题翻译：串行传输系统，传输设备和串行传输方式
公开(公告)号：US07933778B2
公开(公告)日：2011-04-26
申请号：US11763205
申请日：2007-06-14
申请人： Katsumasa Tanaka
发明人： Katsumasa Tanaka
IPC分类号： G10L21/00
CPC分类号： G10L19/167 , H04L7/0008
摘要： A serial transmission system has a transmission signal generator and a transmission signal receiver. The transmission signal generator generates a digital audio signal of multi-channel based on information of a sampling frequency, and serially transmits the information of the sampling frequency together with the digital audio signal. The transmission signal receiver serially receives the information of the sampling frequency and the digital audio signal from the transmission signal generator, and detects change in a transmission clock based on the information of the sampling frequency.
摘要翻译：串行传输系统具有发送信号发生器和发送信号接收器。发送信号发生器基于采样频率的信息生成多声道的数字音频信号，并且与数字音频信号一起串行发送采样频率的信息。发送信号接收器从发送信号发生器串行地接收采样频率和数字音频信号的信息，并且基于采样频率的信息检测发送时钟的变化。

10. 发明授权

US06962926B2 Antagonist of MCP-1 function, and compositions and methods of use thereof 失效
标题翻译： MCP-1功能的拮抗剂及其组合物及其使用方法
公开(公告)号：US06962926B2
公开(公告)日：2005-11-08
申请号：US10637746
申请日：2003-08-08
申请人： Edgardo Laborde , Louise Robinson , Fanying Meng , Brian T. Peterson , Hugo O. Villar , Steven E. Anuskiewicz , Wenli Ma , Yukiharu Matsumoto , Kunihisa Baba , Hideaki Inagaki , Katsumasa Tanaka , Yoshiro Ishiwata , Shoji Yokochi , Masayuki Okamoto , Takashi Nakamura , Atsushi Miyachi , Mitsuaki Takeuchi , Kouji Matsushima
发明人： Edgardo Laborde , Louise Robinson , Fanying Meng , Brian T. Peterson , Hugo O. Villar , Steven E. Anuskiewicz , Wenli Ma , Yukiharu Matsumoto , Kunihisa Baba , Hideaki Inagaki , Katsumasa Tanaka , Yoshiro Ishiwata , Shoji Yokochi , Masayuki Okamoto , Takashi Nakamura , Atsushi Miyachi , Mitsuaki Takeuchi , Kouji Matsushima
IPC分类号： A61K31/437 , A61K31/496 , A61K31/5377 , A61K31/5513 , A61K45/06 , A61P29/00 , C07D471/04 , C07D498/04 , C07D519/00 , C61K31/5377
CPC分类号： A61K31/437 , A61K9/0019 , A61K9/2054 , A61K9/4866 , A61K31/496 , A61K31/5377 , A61K31/5513 , A61K45/06 , C07D231/56 , C07D471/04 , A61K2300/00
摘要： Compounds of formula A and formula B: and their pharmaceutically acceptable salts, compositions comprising them, methods for their use, and their use in the preparation of medicaments. The compounds are antagonists of MCP-1 function, and are useful in the prevention and treatment of chronic or acute inflammatory or autoimmune diseases, such as multiple sclerosis, and in the prevention and treatment of allergic hypersensitivity disorders.
摘要翻译：式A和式B化合物及其药学上可接受的盐，包含它们的组合物，其使用方法及其在制备药物中的用途。该化合物是MCP-1功能的拮抗剂，可用于预防和治疗慢性或急性炎性或自身免疫性疾病如多发性硬化，以及预防和治疗过敏性超敏反应性疾病。

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