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1. 发明授权

US4588781A Fluorine-containing copolymer and composition containing the same 失效
标题翻译：含氟共聚物和含有该共聚物的组合物
公开(公告)号：US4588781A
公开(公告)日：1986-05-13
申请号：US722560
申请日：1985-04-12
申请人： Akira Ohmori , Nobuyuki Tomihashi , Yoshiki Shimizu
发明人： Akira Ohmori , Nobuyuki Tomihashi , Yoshiki Shimizu
IPC分类号： C08F214/24 , C08F216/14 , C08L27/12 , C08L33/12 , C09D127/12
CPC分类号： C08L33/12 , C08F214/242 , C08F216/1408 , C08L27/12 , C09D127/12
摘要： A fluorine-containing copolymer comprising chlorotrifluoroethylene, 2,2,3,3-tetrafluoropropyl vinyl ether and 0 to 25% by mole of a vinyl ether having a functional group selected from the group consisting of hydroxyl, glycidyl and amino. The fluorine-containing copolymer has a good compatibility with methyl methacrylate polymers and gives, in combination with methyl methacrylate polymers, products such as coating film, self-supporting film and molded article, which have good stain resistance and transparency.

2. 发明授权

US4564717A Fluorine-containing olefin 失效
标题翻译：含氟烯烃
公开(公告)号：US4564717A
公开(公告)日：1986-01-14
申请号：US653006
申请日：1984-09-21
申请人： Akira Ohmori , Nobuyuki Tomihashi , Hiroshi Inukai , Yoshiki Shimizu
发明人： Akira Ohmori , Nobuyuki Tomihashi , Hiroshi Inukai , Yoshiki Shimizu
IPC分类号： C08F16/00 , C07C27/00 , C07C29/124 , C07C33/42 , C07C67/00 , C08F16/02 , C08F16/04 , C08F12/20
CPC分类号： C07C33/423
摘要： A fluorine-containing olefin of the formula: CF.sub.2 .dbd.CF(CF.sub.2).sub.m (CH.sub.2).sub.n OH wherein m is 0 or an integer of 1 to 10 and n is an integer of 1 to 4, which is copolymerizable with various ethylenically unsaturated compounds and provide fluorine-containing copolymers useful as raw materials for room temperature curing paints, fluorine-containing rubbers and the like.
摘要翻译：下式的含氟烯烃：CF2 = CF（CF2）m（CH2）nOH其中m为0或1〜10的整数，n为1〜4的整数，可与各种烯键式不饱和化合物共聚，提供可用作室温固化涂料原料的含氟共聚物，含氟橡胶等。

3. 发明授权

US4544720A Fluorine-containing copolymer 失效
标题翻译：含氟共聚物
公开(公告)号：US4544720A
公开(公告)日：1985-10-01
申请号：US653005
申请日：1984-09-21
申请人： Akira Ohmori , Nobuyuki Tomihashi , Hiroshi Inukai , Yoshiki Shimizu
发明人： Akira Ohmori , Nobuyuki Tomihashi , Hiroshi Inukai , Yoshiki Shimizu
IPC分类号： C08L27/00 , C07C17/275 , C07C31/34 , C07C33/42 , C07C57/52 , C07C57/66 , C08F14/22 , C08F214/22 , C08L1/00 , C08L27/16 , C08L33/00 , C08L33/02 , C08L33/06 , C08L33/14 , C08L55/00 , C09D127/12 , C08F214/18 , C08F214/26
CPC分类号： C08F214/22 , C07C17/275 , C07C31/34 , C07C33/423 , C07C57/52 , C07C57/66 , C08L27/16 , C08L33/06 , C08L33/14
摘要： A novel fluorine-containing copolymer having functional groups comprising structural units of 1,1-difluoroethylene and structural units of a monomeric compound of the formula: ##STR1## wherein X is --OH, ##STR2## or --COOH group, m is 0 or an integer of 1 to 10 and n is an integer of 1 to 4, which may futher contain structural units of at least one monomer selected from the group consisting of tetrafluoroethylene, chlorotrifluoroethylene, monofluoroethylene 1,1,2-trifluoroethylene, hexafluoropropene and a fluoroalkyl vinyl ether. The copolymer is curable at room temperature, and is useful as a material for fluorine-containing rubbers, molded articles and paints.
摘要翻译：一种新型含氟共聚物，其具有包含1,1-二氟乙烯的结构单元和下式的单体化合物的结构单元的官能团：其中X为-OH，-COOH基团，m为0或 1〜10的整数，n为1〜4的整数，其还含有至少一种选自四氟乙烯，三氟氯乙烯，一氟乙烯，1,1,2-三氟乙烯，六氟丙烯和氟代烷基的单体的结构单元乙烯基醚。共聚物在室温下可固化，可用作含氟橡胶，模塑制品和涂料的材料。

4. 发明授权

US4634754A Fluorine-containing copolymer and composition containing the same for curing 失效
标题翻译：含氟共聚物和含有其的组合物用于固化
公开(公告)号：US4634754A
公开(公告)日：1987-01-06
申请号：US755765
申请日：1985-07-17
申请人： Akira Ohmori , Nobuyuki Tomihashi , Yoshiki Shimizu
发明人： Akira Ohmori , Nobuyuki Tomihashi , Yoshiki Shimizu
IPC分类号： C08F14/18 , C08F14/20 , C08F16/00 , C08F16/14 , C08F214/18 , C08F214/20 , C08F216/14 , C08L1/00 , C08L27/00 , C08L27/12 , C08L27/14 , C09D127/12
CPC分类号： C08F214/184 , C08L27/12
摘要： A fluorine-containing copolymer comprising structural units of the formula (a):--CH.sub.2 --CHF-- (a)structural units of the formula (b): ##STR1## and structural units of the formula (c): ##STR2## wherein X is --H or --F, Y is --OH, --COOH or ##STR3## l is 0 or an integar of 1, m is 0 or an integar of 1 to 6 and n is 0 or an integer of 1 to 4, provided that Y is --COOH when n is 0. The copolymer has a good solubility to solvent and is cross-linkable, and the composition containing the copolymer can be cured at room temperature, and provides a film having an excellent chemical resistance, weatherability, stain resistance, heat resistance and high frictional electrification property.
摘要翻译：包含式（a）的结构单元的含氟共聚物：-CH 2 -CHF-（a）式（b）的结构单元：图像（b）和式（c）的结构单元：（c）其中X为-H或-F，Y为-OH，-COOH或I为0或1为整数，m为0或1〜6的整数，n为0或整数为1〜4，条件是当n为0时，Y为-COOH。该共聚物对溶剂的溶解性良好且是可交联的，并且含有该共聚物的组合物可在室温下固化，并提供具有优异的膜耐化学性，耐候性，耐污性，耐热性和高摩擦带电特性。

5. 发明授权

US4622364A Fluorine-containing copolymer and composition containing the same 失效
标题翻译：含氟共聚物和含有该共聚物的组合物
公开(公告)号：US4622364A
公开(公告)日：1986-11-11
申请号：US817330
申请日：1986-01-09
申请人： Akira Ohmori , Nobuyuki Tomihashi , Yoshiki Shimizu
发明人： Akira Ohmori , Nobuyuki Tomihashi , Yoshiki Shimizu
IPC分类号： C08F214/24 , C08F216/14 , C08L27/12 , C08L33/12 , C09D127/12
CPC分类号： C08L33/12 , C08F214/242 , C08F216/1408 , C08L27/12 , C09D127/12
摘要： A fluorine-containing copolymer comprising chlorotrifluoroethylene, 2,2,3,3-tetrafluoropropyl vinyl ether and 0 to 25% by mole of a vinyl ether having a functional group selected from the group consisting of hydroxyl group, glycidyl group and amino group. The fluorine-containing copolymer has a good compatibility with methyl methacrylate polymers and gives, in combination use with methyl methacrylate polymers, products such as coating film, self-supporting film and molded article, which have good stain resistance and transparency.The fluorine-containing copolymer is preferably an alternating copolymer comprising chlorotrifluoroethylene and 2,2,3,3-tetrafluoropropyl vinyl ether.
摘要翻译：包含氯三氟乙烯，2,2,3,3-四氟丙基乙烯基醚和0-25％（摩尔）具有选自羟基，缩水甘油基和氨基的官能团的乙烯基醚的含氟共聚物。含氟共聚物与甲基丙烯酸甲酯聚合物具有良好的相容性，并与甲基丙烯酸甲酯聚合物组合使用，具有良好的耐污性和透明性的涂膜，自支撑膜和成型品等产品。含氟共聚物优选为包含氯三氟乙烯和2,2,3,3-四氟丙基乙烯基醚的交替共聚物。

6. 发明授权

US4581412A Coating composition of vinylidene fluoride copolymer and acrylic polymer 失效
标题翻译：偏氟乙烯共聚物和丙烯酸聚合物的涂料组合物
公开(公告)号：US4581412A
公开(公告)日：1986-04-08
申请号：US751409
申请日：1985-07-03
申请人： Akira Ohmori , Nobuyuki Tomihashi , Hiroshi Inukai , Yoshiki Shimizu
发明人： Akira Ohmori , Nobuyuki Tomihashi , Hiroshi Inukai , Yoshiki Shimizu
IPC分类号： C07C17/275 , C07C31/34 , C07C33/42 , C07C57/52 , C07C57/66 , C08L27/16 , C08L33/06 , C08L33/14 , C09D127/16 , C09D133/06 , C08L27/08 , C08L33/08 , C08L33/12
CPC分类号： C09D127/16 , C07C17/275 , C07C31/34 , C07C33/423 , C07C57/52 , C07C57/66 , C08L27/16 , C09D133/062 , C08L33/06 , C08L33/14
摘要： A fluoro-resin coating composition curable at room temperature and capable of providing coatings having an improved transparency or gloss which can be maintained for a long term, as well as excellent weatherability, chemical and solvent resistances, stain resistance and adhesion to substrates, which comprises a fluorine-containing copolymer comprising vinylidene fluoride and a minor amount of a vinyl monomer having a functional group capable of causing crosslinking at room temperature in the presence of a curing agent having at least difunctionality, and an acrylic resin.
摘要翻译：一种氟树脂涂料组合物，其在室温下可固化并且能够提供可长期保持改善的透明度或光泽的涂层，以及优异的耐候性，耐化学性和耐溶剂性，耐污染性和对基材的粘合性，其包括包含偏二氟乙烯和少量具有官能团的乙烯基单体的含氟共聚物在具有至少二官能度的固化剂的存在下在室温下能够引起交联的丙烯酸树脂。

7. 发明授权

US4557562A Copolymers for optical fibers 失效
标题翻译：光纤共聚物
公开(公告)号：US4557562A
公开(公告)日：1985-12-10
申请号：US651648
申请日：1984-09-17
申请人： Akira Ohmori , Nobuyuki Tomihashi , Takahiro Kitahara
发明人： Akira Ohmori , Nobuyuki Tomihashi , Takahiro Kitahara
IPC分类号： C08F20/00 , B29C47/00 , C08F20/22 , C08F220/00 , C08F220/04 , C08F220/06 , C08F220/22 , G02B1/04 , G02B6/00 , C08F214/18
CPC分类号： C08F220/22 , G02B1/048 , B29C47/00 , B29C47/0009
摘要： A copolymer for optical fibers of fluoroalkylmethacrylate and acrylic acid.
摘要翻译：氟代烷基甲基丙烯酸酯和丙烯酸的光纤的共聚物。

8. 发明授权

US4500694A Optical materials 失效
标题翻译：光学材料
公开(公告)号：US4500694A
公开(公告)日：1985-02-19
申请号：US491234
申请日：1983-05-03
申请人： Akira Ohmori , Nobuyuki Tomihashi , Takahiro Kitahara
发明人： Akira Ohmori , Nobuyuki Tomihashi , Takahiro Kitahara
IPC分类号： C08F20/00 , B29C47/00 , C08F20/22 , C08F220/22 , C08L33/00 , C08L33/02 , C08L33/04 , G02B1/04 , G02B6/00 , C08F214/18
CPC分类号： G02B1/043 , G02B1/04 , G02B1/048 , B29C47/00 , B29C47/0009 , B29C47/0014 , Y10T428/2964
摘要： An optical material comprising a thermal resisting fluoroalkylmethacrylate copolymer which essentially consists of(a) fluorine-containing methacrylate monomer unit of the formula ##STR1## wherein R.sub.f.sup.1 represents a fluoroalkyl group having 1 to 3 carbon atoms and(b) a fluorine-containing acrylate monomer unit of the formula ##STR2## wherein R.sub.1 and R.sub.2 are the same or different and represents a hydrogen atom or a lower alkyl group and R.sub.f.sup.2 represents a fluoroalkyl group having 1 to 3 carbon atoms.
摘要翻译：一种光学材料，包括耐热氟烷基甲基丙烯酸酯共聚物，其基本上由（a）式（IMAGE）的含氟甲基丙烯酸酯单体单元组成，其中Rf1表示具有1至3个碳原子的氟烷基和（b）含氟丙烯酸酯单体式中，R 1和R 2相同或不同，表示氢原子或低级烷基，Rf 2表示碳原子数1〜3的氟代烷基。

9. 发明授权

US4665144A Material for contact lenses 失效
标题翻译：隐形眼镜材料
公开(公告)号：US4665144A
公开(公告)日：1987-05-12
申请号：US808071
申请日：1985-12-12
申请人： Akira Ohmori , Nobuyuki Tomihashi
发明人： Akira Ohmori , Nobuyuki Tomihashi
IPC分类号： C08F20/22 , G02B1/04 , C08F20/24
CPC分类号： C08F20/22 , G02B1/043
摘要： This invention provides a material for contact lenses comprising a polymer having 10 to 100 5 by weight of a structural unit represented by the formula ##STR1## wherein R is (CH.sub.2).sub.l R.sup.1 or --CH.sub.2).sub.m (CF.sub.2).sub.n CFZ.sup.1 Z.sup.2 in which R.sup.1 is oxygen-containing fluoroalkyl, Z.sup.1 and Z.sup.2 are the same or different and each hydrogen, fluorine or fluoroalkyl, l is an integer of 1 to 5, m is an integer of 1 to 4 and n is 0 or an integer of 1 to 10, 0 to 60% by weight of a structural unit represented by the formula ##STR2## wherein R.sup.2 is lower alkyl, and 0 to 80% by weight of a structural unit represented by the formula ##STR3## wherein X is hydroxyl or carboxyl and p is an integer of 1 to 5.
摘要翻译：本发明提供了一种隐形眼镜材料，其包含具有10至100重量％的由式（IMAGE）表示的结构单元的聚合物，其中R是（CH 2）1 R 1或-CH 2）m（CF 2）n CFZ 1 Z 2，其中R 1是氧含氟氟烷基，Z 1和Z 2相同或不同，各氢，氟或氟烷基，l为1〜5的整数，m为1〜4的整数，n为0或1〜10的整数，至60重量％的由式“IMAGE”表示的结构单元，其中R 2是低级烷基，0至80重量％的由下式表示的结构单元：其中X是羟基或羧基，p是 1〜5的整数。

10. 发明授权

US4566755A Copolymers for optical fibers 失效
标题翻译：光纤共聚物
公开(公告)号：US4566755A
公开(公告)日：1986-01-28
申请号：US657479
申请日：1984-10-04
申请人： Akira Ohmori , Nobuyuki Tomihashi , Takahiro Kitahara
发明人： Akira Ohmori , Nobuyuki Tomihashi , Takahiro Kitahara
IPC分类号： C08F20/00 , B29C47/00 , C08F20/02 , C08F20/10 , C08F20/22 , C08F220/00 , C08F220/04 , C08F220/06 , C08F220/22 , G02B1/04 , G02B6/00 , C08F214/18
CPC分类号： C08F220/22 , G02B1/048 , B29C47/00 , B29C47/0014
摘要： A copolymer for optical fibers of fluoroalkylmethacrylate and methacrylic acid, the fluoroalkylmethacrylate having such properties that a homopolymer made of only the fluoroalkylmethacrylate has a glass transition temperature and a refractive index each in the range given by the following formulae (I) and (II), respectively:(1/Tg).ltoreq.9.47.times.10.sup.-3 -4.556.times.10.sup.-3 n.sup.20 (I)n.sup.20 .ltoreq.1.42 (II)wherein Tg represents the glass transition temperature (.degree.K.) of the homopolymer and n.sup.20 represents the refractive index thereof.
摘要翻译：甲基丙烯酸氟代烷基酯和甲基丙烯酸的光纤的共聚物，甲基丙烯酸氟代烷基酯具有这样的特性，使得仅由甲基丙烯酸氟烷基酯制成的均聚物的玻璃化转变温度和折射率各自在下式（I）和（II）给出的范围内，分别为：（1 / Tg）

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