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1. 发明授权

US4985412A Phosphoric acid ester, process for preparing the same, and detergent composition containing the same 失效
标题翻译：磷酸酯，其制备方法和含有它的洗涤剂组合物
公开(公告)号：US4985412A
公开(公告)日：1991-01-15
申请号：US260868
申请日：1988-10-21
申请人： Akira Matsunaga , Junya Wakatsuki , Nobutaka Horinishi , Takashi Imamura , Tomihiro Kurosaki
发明人： Akira Matsunaga , Junya Wakatsuki , Nobutaka Horinishi , Takashi Imamura , Tomihiro Kurosaki
IPC分类号： A61K8/06 , A61K8/00 , A61K8/55 , A61K8/58 , A61Q5/02 , A61Q19/10 , C07F9/09 , C08G65/32 , C11D1/78 , C11D1/88 , C11D3/36
CPC分类号： A61Q19/10 , A61K8/55 , A61K8/553 , A61Q5/02 , C07F9/091 , C11D1/886
摘要： Phosphoric acid esters represented by the following formulae (I) and (IX) as well as processes for preparing them are disclosed. ##STR1## wherein R.sub.1 represents a linear or branched, alkyl or alkenyl group having a C.sub.1-36 carbon atom content, with or without the hydrogen atom(s) being substituted with fluorine atom(s), or a phenyl group with substituted linear or branched alkyl group(s) having a C.sub.1-15 carbon atom content, R.sub.2 represents an alkylene group having a C.sub.2-3 carbon atom content, R.sub.3 and R.sub.4 independently denote a hydrogen atom or an alkyl group having a C.sub.1-3 carbon atom content, R.sub.5 and R.sub.6 independently denote a hydrogen atom, or an alkyl, alkenyl, or phenyl group with or without the hydrogen atom(s) being substituted with group(s) containing hetero atom(s), excepting for a mercapto group, R.sub.7 and R.sub.8 independently denote a hydrogen atom, or an alkyl, or alkenyl group, m is an integer of 0-30, n is an integer of 0-5, l is an integer of 0-3, M is a hydrogen atom, an alkali metal, an alkali earth metal, on ammonium group, an alkyl amine group, or an alkanol amine group. The phosphoric acid ester have outstanding surface activity and good foaming capability, and imparts only extremely low irritation to the skin. The detergent composition into which they are formulated is particularly useful as, shampoo, baby shampoo, body shampoo.

2. 发明授权

US5071585A Phosphoric acid ester, process for preparing the same, and detergent composition containing the same 失效
标题翻译：磷酸酯，其制备方法和含有它的洗涤剂组合物
公开(公告)号：US5071585A
公开(公告)日：1991-12-10
申请号：US604172
申请日：1990-10-29
申请人： Akira Matsunaga , Junya Wakatsuki , Nobutaka Horinishi , Takashi Imamura , Tomihiro Kurosaki
发明人： Akira Matsunaga , Junya Wakatsuki , Nobutaka Horinishi , Takashi Imamura , Tomihiro Kurosaki
IPC分类号： A61K8/06 , A61K8/00 , A61K8/55 , A61K8/58 , A61Q5/02 , A61Q19/10 , C07F9/09 , C08G65/32 , C11D1/78 , C11D1/88 , C11D3/36
CPC分类号： A61Q19/10 , A61K8/55 , A61K8/553 , A61Q5/02 , C07F9/091 , C11D1/886
摘要： Phosphoric acid esters represented by the following formulae (I) and (IX) as well as processes for preparing them are disclosed. ##STR1## wherein R.sub.1 represents a linear or branched, alkyl or alkenyl group having a C.sub.1-36 carbon atom content, with or without the hydrogen atom(s) being substituted with fluorine atom(s), or a phenyl group with substituted linear or branched alkyl group(s) having a C.sub.1-15 carbon atom content, R.sub.2 represents an alkylene group having a C.sub.2-3 carbon atom content, R.sub.3 and R.sub.4 independently denote a hydrogen atom or an alkyl group having a C.sub.1-3 carbon atom content, R.sub.5 and R.sub.6 independently denote a hydrogen atom, or an alkyl, alkenyl, or phenyl group with or without the hydrogen atom(s) being substituted with group(s) containing hetero atom(s), excepting for a mercapto group, R.sub.7 and R.sub.8 independently denote a hydrogen atom, or an alkyl, or alkenyl group, m is an integer of 0-30, n is an integer of 0-5, l is an integer of 0-3, M is a hydrogen atom, an alkali metal, an alkali earth metal, an ammonium group, an alkyl amine group, or an alkanol amine group. The phosphoric acid esters have outstanding surface activity and good foaming capability, and imparts only extremely low irritation to the skin. The detergent composition into which they are formulated is particularly useful as, shampoo, baby shampoo, body shampoo.

3. 发明授权

US5043424A Modification method for peptides and proteins by reacting with a phosphoric acid ester 失效
标题翻译：通过与磷酸酯反应来改变肽和蛋白质的方法
公开(公告)号：US5043424A
公开(公告)日：1991-08-27
申请号：US260709
申请日：1988-10-21
申请人： Akira Matsunaga , Nobutaka Horinishi , Junya Wakatsuki , Takashi Imamura , Tomihiro Kurosaki
发明人： Akira Matsunaga , Nobutaka Horinishi , Junya Wakatsuki , Takashi Imamura , Tomihiro Kurosaki
IPC分类号： C07K14/655 , C07K1/00 , C07K1/02 , C07K1/107 , C07K1/113 , C07K1/14 , C07K4/00 , C07K5/06 , C07K14/00 , C07K14/575 , C07K14/76 , C07K16/00 , C12N9/16 , C12N9/96
CPC分类号： C07K5/06191 , C07K1/1077
摘要： A peptide or protein is modified by reacting a phosphoric acid ester represented by the following general formula (I) with a peptide or protein: ##STR1## wherein R.sub.1 means a linear or branched, C.sub.1-36 alkyl or C.sub.2-36 alkenyl group whose hydrogen atom or atoms may be substituted by the corresponding number of fluorine atom(s) or a phenyl group substituted by at least one linear or branched C.sub.1-15 alkyl group, R.sub.2 denotes a C.sub.2-3 alkylene group, m stands for a number of 0-30, and M is a hydrogen atom, an alkali metal ion, an alkaline earth metal ion, an ammonium ion, an alkylamine residue or an alkanolamine residue.

4. 发明授权

US4845239A Phosphoric esters and process for preparing the same 失效
标题翻译：磷酸酯及其制备方法
公开(公告)号：US4845239A
公开(公告)日：1989-07-04
申请号：US32627
申请日：1987-04-01
申请人： Junya Wakatsuki , Tohru Katoh , Akira Matsunaga , Tomihiro Kurosaki
发明人： Junya Wakatsuki , Tohru Katoh , Akira Matsunaga , Tomihiro Kurosaki
IPC分类号： C07F9/09 , C07F9/655
CPC分类号： C07F9/65502
摘要： A novel phosphoric ester of the following formula (I) ##STR1## is prepared by reacting a phosphoric ester of the following formula (II) ##STR2## with a basic compound. By reacting the phosphoric ester (I) with various types of amine compounds or other acidic hydrogen-bearing compounds, various phospholipid analogue compounds or phosphoric esters can be derived.
摘要翻译：下式（I）的新型磷酸酯通过将下式（Ⅱ）的磷酸酯与碱性化合物反应来制备。通过使磷酸酯（I）与各种胺化合物或其它酸性含氢化合物反应，可以得到各种磷脂类似物或磷酸酯。

5. 发明授权

US4736051A Process for the preparation of an alkali metal salt of a diester phosphoric acid 失效
标题翻译：制备二酯磷酸的碱金属盐的方法
公开(公告)号：US4736051A
公开(公告)日：1988-04-05
申请号：US839200
申请日：1986-03-13
申请人： Junya Wakatsuki , Toru Kato , Tomihiro Kurosaki , Takashi Imamura
发明人： Junya Wakatsuki , Toru Kato , Tomihiro Kurosaki , Takashi Imamura
IPC分类号： A61K9/127 , C07F9/09 , C08F30/02 , C11D1/34 , C11D3/36 , C07F9/11
CPC分类号： C11D3/367 , A61K9/1272 , A61K9/1273 , C07F9/091 , C08F30/02 , C11D1/345
摘要： A process for preparing an alkali metal salt of a phosphoric ester represented by the following general formula (III): ##STR1## wherein R.sup.1 means an organic group, R.sup.2, R.sup.3, R.sup.4 and R.sup.5 denote individually a hydrogen atom or organic group, R.sup.2 and R.sup.4 may optionally be coupled together into a ring, and M stands for an alkali metal, which comprises reacting a monoalkali metal salt of an organophosphoric monoester, represented by the following general formula (I): ##STR2## wherein R.sup.1 and M have the same meaning as defined above, with an epoxy compound represented by the following general formula (II): ##STR3## wherein R.sup.2, R.sup.3, R.sup.4 and R.sup.5 have the same meaning as defined above.
摘要翻译：一种制备由以下通式（III）表示的磷酸酯的碱金属盐的方法：其中R1表示有机基团，R2，R3，R4和R5分别表示氢原子或有机基团 R 1和R 4可任意地连接在一起形成环，M代表碱金属，其包括使由以下通式（I）表示的有机磷单酯的单碱金属盐反应：其中 R1和M具有与上述相同的含义，与下列通式（II）表示的环氧化合物：其中R2，R3，R4和R5具有与上述相同的含义。

6. 发明授权

US4812254A Detergent composition 失效
标题翻译：洗涤剂组成
公开(公告)号：US4812254A
公开(公告)日：1989-03-14
申请号：US155291
申请日：1988-02-12
申请人： Junya Wakatsuki , Tomohiko Sano , Tomihiro Kurosaki
发明人： Junya Wakatsuki , Tomohiko Sano , Tomihiro Kurosaki
IPC分类号： A61K8/55 , A61Q5/02 , A61Q19/10 , C11D1/34 , C11D1/88 , C11D3/36
CPC分类号： A61Q5/02 , A61K8/55 , A61Q19/10 , C11D1/345 , C11D3/362
摘要： A detergent composition contains as an essential component a compound represented by the following general formula (I): ##STR1## wherein R means ##STR2## R.sup.1 denotes a straight-chain or branched alkyl or alkenyl group or a substituted phenyl group. R.sup.2 is an alkylene group having 2-3 carbon atoms, m is 0-30, and n stands for 0 or 1. M means a hydrogen atom or denotes an alkali metal, alkaline earth metal, zinc or aluminum atom, an ammonium ion, or an alkylamine or alkanolamine residuum thereby to indicate the formation of a salt of the compound of the general formula (I).

7. 发明授权

US4774350A Phosphoric ester 失效
标题翻译：磷酸酯
公开(公告)号：US4774350A
公开(公告)日：1988-09-27
申请号：US896100
申请日：1986-08-13
申请人： Junya Wakatsuki , Tohru Katoh , Tomihiro Kurosaki
发明人： Junya Wakatsuki , Tohru Katoh , Tomihiro Kurosaki
IPC分类号： A61K8/00 , A61K8/06 , A61K8/55 , A61Q19/00 , A61Q19/10 , B01F17/18 , B01F17/38 , B01F17/42 , C07F9/09 , C09K3/16 , C11D1/34 , C11D1/88
CPC分类号： A61Q19/10 , A61K8/06 , A61K8/55 , A61Q19/00 , C07F9/091 , C11D1/886
摘要： Novel phosphoric esters represented by the following general formula (I) ##STR1## wherein R.sub.1 represents a linear or branched alkyl or alkenyl group having 1 to 36 carbon atoms, or a phenyl group substituted with a linear or branched alkyl group having 1 to 15 carbon atoms, R.sub.2 represents an alkylene group having 2 to 3 carbon atoms, R.sub.3, R.sub.4 and R.sub.5 individually represent a hydrogen atom or a linear or branched alkyl group having 1 to 36 carbon atoms providing that any one of R.sub.3, R.sub.4 and R.sub.5 has 5 or more carbon atoms, and n is a number from 0 to 30 are obtained by reacting phosphoric esters of the following formula ##STR2## with amines at a high purity and in a high yield. The phosphoric esters (I) are excellent in the surface tension and foaming property, and give extremely low stimulus to the skin, so that they can be utilized in detergent compositions, cosmetic compositions, emulsifiers, dispersants, anti-static agents and the like.
摘要翻译：由下列通式（I）表示的新型磷酸酯其中R 1表示具有1至36个碳原子的直链或支链烷基或烯基，或被具有1个直链或支链烷基取代的苯基至15个碳原子，R 2表示具有2至3个碳原子的亚烷基，R 3，R 4和R 5各自表示氢原子或具有1至36个碳原子的直链或支链烷基，条件是R3，R4和R5中的任一个具有5个或更多个碳原子，并且n为0至30的数是通过以下方式使磷酸酯与胺以高纯度和高收率反应得到的。磷酸酯（I）的表面张力和起泡性优异，对皮肤的刺激性极低，可以用于洗涤剂组合物，化妆品组合物，乳化剂，分散剂，防静电剂等。

8. 发明授权

US4739092A Process for producing phosphoric ester salt of high purity 失效
标题翻译：制备高纯度磷酸酯盐的方法
公开(公告)号：US4739092A
公开(公告)日：1988-04-19
申请号：US932289
申请日：1986-11-19
申请人： Toshio Nozaki , Tomihiro Kurosaki , Junya Wakatsuki , Kiyoshi Aimono
发明人： Toshio Nozaki , Tomihiro Kurosaki , Junya Wakatsuki , Kiyoshi Aimono
IPC分类号： C07F9/11 , C07F9/02 , C07F9/09 , C07F9/113
CPC分类号： C07F9/025 , C07F9/09
摘要： A phosphoric ester salt of high purity is produced by converting a phosphoric ester in a mixture containing the phosphoric ester and one or more nonionic compounds into a phosphoric ester salt by using a basic compound, and extracting nonionic compounds from the above mixture by using a mixed solvent of aliphatic hydrocarbons or cycloaliphatic hydrocarbons, a lower alcohol and water.The above method is applicable to a non-crystalline phosphoric ester from which nonionic compounds cannot be removed by recystallization.The above obtained phosphoric ester salt of high purity can be used as it is or after condensation.
摘要翻译：通过使用碱性化合物将含有磷酸酯和一种或多种非离子化合物的混合物中的磷酸酯转化成磷酸酯盐，并通过使用混合物从上述混合物中提取非离子化合物来制备高纯度的磷酸酯盐脂族烃或脂环族烃的溶剂，低级醇和水。上述方法适用于通过再结晶不能除去非离子化合物的非结晶磷酸酯。上述得到的高纯度磷酸酯盐可以原样使用或冷凝后使用。

9. 发明授权

US4670575A Process for purification of phosphoric mono esters 失效
标题翻译：磷酸单酯的纯化方法
公开(公告)号：US4670575A
公开(公告)日：1987-06-02
申请号：US737490
申请日：1985-05-24
申请人： Tomihiro Kurosaki , Junya Wakatsuki , Hisakazu Furugaki , Katsutoshi Kojima
发明人： Tomihiro Kurosaki , Junya Wakatsuki , Hisakazu Furugaki , Katsutoshi Kojima
IPC分类号： C07F9/02 , C07F9/09
CPC分类号： C07F9/09 , C07F9/025
摘要： A novel process for producing a phosphoric monoester which comprises reacting per 1 mole of a linear or branched, saturated or non-saturated aliphatic alcohol having from 8 to 36 carbon atoms, from 2 to 10 moles of a polyphosphoric acid at 100 to 116% concetration converted as orthophosphoric acid in (a) one or more solvents selected from the group consisting of linear or branched saturated aliphatic hydrocarbons having from 4 to 8 carbon atoms and saturated cycloaliphatic hydrocarbons having from 5 to 7 carbon atoms, then adding (b) a lower alcohol having from 1 to 4 carbon atoms and water to the reaction mixture, transferring the orthophosphoric acid to the lower alcohol-aqueous phase to separate it from the phosphoric monoester, and concentrating the thus recovered orthophosphoric acid for reuse. The process reaction proceeds smoothly, separation and purification can be carried out readily and very effectively and the recovered phosphoric acid can be re-used.
摘要翻译：一种制备磷酸单酯的新方法，其包括每1摩尔具有8至36个碳原子的直链或支链饱和或不饱和脂族醇，2至10摩尔多磷酸，浓度为100至116％在（a）一种或多种选自具有4至8个碳原子的直链或支链饱和脂族烃和具有5至7个碳原子的饱和脂环族烃的溶剂中转化为正磷酸，然后加入（b）较低将具有1至4个碳原子的醇和水反应到反应混合物中，将正磷酸转移到低级醇水相以将其与磷酸单酯分离，并将由此回收的正磷酸浓缩以便重新使用。过程反应平稳进行，分离和纯化可以容易且非常有效地进行，回收的磷酸可以重复使用。

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