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1. 发明授权

US08741046B2 Ink composition, inkjet recording method and colored body 有权
标题翻译：墨水组成，喷墨记录方法和彩色体
公开(公告)号：US08741046B2
公开(公告)日：2014-06-03
申请号：US13806981
申请日：2011-06-27
申请人： Akira Kawaguchi , Takahiko Matsui , Takashi Yoshimoto , Kenji Ooshima
发明人： Akira Kawaguchi , Takahiko Matsui , Takashi Yoshimoto , Kenji Ooshima
IPC分类号： C09D11/02
CPC分类号： C09D7/63 , B41M5/5218 , C09B67/0046 , C09B67/0055 , C09D11/17 , C09D11/328 , Y10T428/24802
摘要： A water-based black ink composition which exhibits a low intensity, colorless and neutral black color and provides a black recorded image the printed image of which has high density. The ink composition includes at least one compound represented by formula (1) or a salt thereof and an azo compound having λmax within the range of 550-660 nm. In the formula (1), R1 to R8 independently represent a hydrogen atom; a halogen atom; a sulfo group; a carboxy group; a sulfamoyl group; a carbamoyl group; a C1-C4 alkyl group; a C1-C4 alkoxy group; and a C1-C4 alkoxy group substituted with at least one group selected from a group consisting of a hydroxy group, a C1-C4 alkoxy group, a hydroxy C1-C4 alkoxy group, a sulfo group and a carboxy group. X represents a bivalent cross-linking group.
摘要翻译：一种水性黑色油墨组合物，其具有低强度，无色和中性黑色，并提供其印刷图像具有高密度的黑色记录图像。油墨组合物包含至少一种由式（1）表示的化合物或其盐和λmax在550-660nm范围内的偶氮化合物。式（1）中，R 1〜R 8分别独立地表示氢原子。卤素原子; 磺基; 羧基; 氨磺酰基; 氨基甲酰基; C1-C4烷基; C1-C4烷氧基; 被选自羟基，C1-C4烷氧基，羟基C1-C4烷氧基，磺基和羧基中的至少一个基团取代的C1-C4烷氧基。 X表示二价交联基团。

2. 发明授权

US08932393B2 Azo compound, ink composition, recording method and colored material 有权
标题翻译：偶氮化合物，油墨组合物，记录方法和着色材料
公开(公告)号：US08932393B2
公开(公告)日：2015-01-13
申请号：US13993599
申请日：2011-12-14
申请人： Takashi Yoshimoto , Akira Kawaguchi , Kenji Ooshima
发明人： Takashi Yoshimoto , Akira Kawaguchi , Kenji Ooshima
IPC分类号： C09D11/02 , C09B31/30 , C09D11/328 , C07D471/04
CPC分类号： C09D11/328 , C07D471/04 , C09B31/30
摘要： A coloring matter which exhibits excellent (ozone) gas resistance, high print density, low color rendering properties, low color saturation, and high-quality black hue when is recorded on a paper only for inkjet exclusive use, i.e., an azo compound represented by formula (1), a tautomer of the azo compound, or a salt of the azo compound or the tautomer; and an ink composition containing the coloring matter, particularly a black ink composition for inkjet recording applications.
摘要翻译：当仅用于喷墨专用的纸张上记录优异（臭氧）气体阻力，高印刷密度，低显色性能，低色饱和度和高质量黑色调的色素，即以式（1），偶氮化合物的互变异构体或偶氮化合物或互变异构体的盐; 以及含有色素的油墨组合物，特别是用于喷墨记录用途的黑色油墨组合物。

3. 发明授权

US08741045B2 Ink composition, inkjet recording method, and colored material 失效
标题翻译：油墨组合物，喷墨记录方法和着色材料
公开(公告)号：US08741045B2
公开(公告)日：2014-06-03
申请号：US13806956
申请日：2011-06-24
申请人： Akira Kawaguchi , Takahiko Matsui , Takashi Yoshimoto , Kenji Ooshima
发明人： Akira Kawaguchi , Takahiko Matsui , Takashi Yoshimoto , Kenji Ooshima
IPC分类号： C09D11/02
CPC分类号： C09D11/328 , B41M5/5218 , C09B31/28 , C09B31/30 , C09B35/56 , C09B43/16 , C09B67/0055
摘要： An aqueous black ink composition which enables the formation of an excellent black recorded image having extremely high ozone gas resistance and a neutral and achromatic color. The ink composition comprises: a dye which includes at least one compound represented by specific formula (1) or at least one tautomer or salt of the compound; a dye which includes at least one compound represented by specific formula (3) or at least one tautomer or salt of the compound; and a dye which includes at least one compound represented by specific formula (4) or at least one tautomer or salt of the compound.
摘要翻译：一种黑色油墨组合物，其能够形成具有极高的耐臭氧气体性和中性和无色性的优异的黑色记录图像。油墨组合物包含：包含至少一种由特定式（1）表示的化合物或至少一种该化合物的互变异构体或盐的染料; 包含至少一种由特定式（3）表示的化合物或至少一种该化合物的互变异构体或盐的染料; 和包含至少一种由特定式（4）表示的化合物或该化合物的至少一种互变异构体或盐的染料。

4. 发明申请

US20130321523A1 AZO COMPOUND, INK COMPOSITION, RECORDING METHOD AND COLORED MATERIAL 有权
标题翻译： AZO化合物，墨水组合物，记录方法和着色材料
公开(公告)号：US20130321523A1
公开(公告)日：2013-12-05
申请号：US13993599
申请日：2011-12-14
申请人： Takashi Yoshimoto , Akira Kawaguchi , Kenji Ooshima
发明人： Takashi Yoshimoto , Akira Kawaguchi , Kenji Ooshima
IPC分类号： C09D11/00
CPC分类号： C09D11/328 , C07D471/04 , C09B31/30
摘要： A coloring matter which exhibits excellent (ozone) gas resistance, high print density, low color rendering properties, low color saturation, and high-quality black hue when is recorded on a paper only for inkjet exclusive use, i.e., an azo compound represented by formula (1), a tautomer of the azo compound, or a salt of the azo compound or the tautomer; and an ink composition containing the coloring matter, particularly a black ink composition for inkjet recording applications.
摘要翻译：当仅用于喷墨专用的纸张上记录优异（臭氧）气体阻力，高印刷密度，低显色性能，低色饱和度和高质量黑色调的色素，即以式（1），偶氮化合物的互变异构体或偶氮化合物或互变异构体的盐; 以及含有色素的油墨组合物，特别是用于喷墨记录用途的黑色油墨组合物。

5. 发明申请

US20130288019A1 INK COMPOSITION, INKJET RECORDING METHOD, AND COLORED MATERIAL 失效
标题翻译：墨水组合物，喷墨记录方法和彩色材料
公开(公告)号：US20130288019A1
公开(公告)日：2013-10-31
申请号：US13806956
申请日：2011-06-24
申请人： Akira Kawaguchi , Takahiko Matsui , Takashi Yoshimoto , Kenji Ooshima
发明人： Akira Kawaguchi , Takahiko Matsui , Takashi Yoshimoto , Kenji Ooshima
IPC分类号： C09D11/00
CPC分类号： C09D11/328 , B41M5/5218 , C09B31/28 , C09B31/30 , C09B35/56 , C09B43/16 , C09B67/0055
摘要： An aqueous black ink composition which enables the formation of an excellent black recorded image having extremely high ozone gas resistance and a neutral and achromatic color. The ink composition comprises: a dye which includes at least one compound represented by specific formula (1) or at least one tautomer or salt of the compound; a dye which includes at least one compound represented by specific formula (3) or at least one tautomer or salt of the compound; and a dye which includes at least one compound represented by specific formula (4) or at least one tautomer or salt of the compound.
摘要翻译：一种黑色油墨组合物，其能够形成具有极高的耐臭氧气体性和中性和无色性的优异的黑色记录图像。油墨组合物包含：包含至少一种由特定式（1）表示的化合物或至少一种该化合物的互变异构体或盐的染料; 包含至少一种由特定式（3）表示的化合物或至少一种该化合物的互变异构体或盐的染料; 和包含至少一种由特定式（4）表示的化合物或该化合物的至少一种互变异构体或盐的染料。

6. 发明申请

US20130257974A1 INK COMPOSITION, INKJET RECORDING METHOD AND COLORED BODY 有权
标题翻译：墨水组合物，喷墨记录方法和彩色体
公开(公告)号：US20130257974A1
公开(公告)日：2013-10-03
申请号：US13994367
申请日：2011-12-14
申请人： Akira Kawaguchi , Takashi Yoshimoto , Kenji Ooshima
发明人： Akira Kawaguchi , Takashi Yoshimoto , Kenji Ooshima
IPC分类号： C09D11/00 , B42D15/00
CPC分类号： C09D11/328 , B42D15/00 , C09B31/30 , C09B33/28 , C09B43/16 , C09B67/0046 , C09B67/0055 , C09D11/324
摘要： An aqueous black ink composition that produces a black recorded image that is stable even when stored for a long time period, exhibits a neutral black to gray color with low color saturation and no tinge, has a high printed image density and exhibits excellent fastness properties of the recorded image, particularly ozone-gas resistance. The ink composition contain at least one kind of coloring matter (I), which a coloring matter represented by formula (1) below, a tautomer thereof, or a salt of the coloring matter or the tautomer; at least one kind of coloring matter (II), which is a coloring matter represented by formula (2) below or a salt thereof; and coloring matter (III), which is a coloring matter having an azo group other than coloring matters (I) and (II), or a salt thereof.
摘要翻译：黑色油墨组合物即使长时间保存也能稳定地生成黑色记录图像，呈现中性黑色至灰色，色彩饱和度低，无色调，印刷图像密度高，表现出优异的耐牢度记录的图像，特别是臭氧气体阻力。油墨组合物含有至少一种着色剂（I），其由下述式（1）表示的着色剂，其互变异构体或着色物质或互变异构体的盐; 至少一种色素（II），其为由下式（2）表示的着色剂或其盐; 和作为着色剂（I）和（II）以外的偶氮基的着色剂的色素（III）或其盐。

7. 发明申请

US20130101811A1 INK COMPOSITION, INKJET RECORDING METHOD AND COLORED BODY 有权
标题翻译：墨水组合物，喷墨记录方法和彩色体
公开(公告)号：US20130101811A1
公开(公告)日：2013-04-25
申请号：US13806981
申请日：2011-06-27
申请人： Akira Kawaguchi , Takahiko Matsui , Takashi Yoshimoto , Kenji Ooshima
发明人： Akira Kawaguchi , Takahiko Matsui , Takashi Yoshimoto , Kenji Ooshima
IPC分类号： C09D7/12
CPC分类号： C09D7/63 , B41M5/5218 , C09B67/0046 , C09B67/0055 , C09D11/17 , C09D11/328 , Y10T428/24802
摘要： A water-based black ink composition which exhibits a low intensity, colorless and neutral black color and provides a black recorded image the printed image of which has high density. The ink composition includes at least one compound represented by formula (1) or a salt thereof and an azo compound having λmax within the range of 550-660 nm. In the formula (1), R1 to R8 independently represent a hydrogen atom; a halogen atom; a sulfo group; a carboxy group; a sulfamoyl group; a carbamoyl group; a C1-C4 alykyl group; a C1-C4 alkoxy group; and a C1-C4 alkoxy group substituted with at least one group selected from a group consisting of a hydroxy group, a C1-C4 alkoxy group, a hydroxy C1-C4 alkoxy group, a sulfo group and a carboxy group. X represents a bivalent cross-linking group.
摘要翻译：一种水性黑色油墨组合物，其具有低强度，无色和中性黑色，并提供其印刷图像具有高密度的黑色记录图像。油墨组合物包含至少一种由式（1）表示的化合物或其盐和具有550-660nm范围内的兰姆巴的偶氮化合物。式（1）中，R 1〜R 8分别独立地表示氢原子。卤素原子; 磺基; 羧基; 氨磺酰基; 氨基甲酰基; C1-C4烷基; C1-C4烷氧基; 被选自羟基，C1-C4烷氧基，羟基C1-C4烷氧基，磺基和羧基中的至少一个基团取代的C1-C4烷氧基。 X表示二价交联基团。

8. 发明授权

US08864891B2 Ink composition, inkjet recording method and colored body 有权
标题翻译：墨水组成，喷墨记录方法和彩色体
公开(公告)号：US08864891B2
公开(公告)日：2014-10-21
申请号：US13994367
申请日：2011-12-14
申请人： Akira Kawaguchi , Takashi Yoshimoto , Kenji Ooshima
发明人： Akira Kawaguchi , Takashi Yoshimoto , Kenji Ooshima
IPC分类号： C09D11/02 , C09D11/328 , C09B33/28 , B42D15/00 , C09B43/16 , C09D11/324 , C09B31/30 , C09B67/22
CPC分类号： C09D11/328 , B42D15/00 , C09B31/30 , C09B33/28 , C09B43/16 , C09B67/0046 , C09B67/0055 , C09D11/324
摘要： An aqueous black ink composition that produces a black recorded image that is stable even when stored for a long time period, exhibits a neutral black to gray color with low color saturation and no tinge, has a high printed image density and exhibits excellent fastness properties of the recorded image, particularly ozone-gas resistance. The ink composition contain at least one kind of coloring matter (I), which a coloring matter represented by formula (1) below, a tautomer thereof, or a salt of the coloring matter or the tautomer; at least one kind of coloring matter (II), which is a coloring matter represented by formula (2) below or a salt thereof; and coloring matter (III), which is a coloring matter having an azo group other than coloring matters (I) and (II), or a salt thereof.
摘要翻译：黑色油墨组合物即使长时间保存也能稳定地生成黑色记录图像，呈现中性黑色至灰色，色彩饱和度低，无色调，印刷图像密度高，表现出优异的耐牢度记录的图像，特别是臭氧气体阻力。油墨组合物含有至少一种着色剂（I），其由下述式（1）表示的着色剂，其互变异构体或着色物质或互变异构体的盐; 至少一种色素（II），其为由下式（2）表示的着色剂或其盐; 和作为着色剂（I）和（II）以外的偶氮基的着色剂的色素（III）或其盐。

9. 发明授权

US08657433B2 Porphyrazine coloring matter, ink composition, recording method, and colored object 有权
标题翻译：紫菜色素，油墨组成，记录方法和彩色物品
公开(公告)号：US08657433B2
公开(公告)日：2014-02-25
申请号：US13377262
申请日：2010-06-08
申请人： Kenji Ooshima , Takashi Yoneda , Yasuo Kuroda , Akira Kawaguchi
发明人： Kenji Ooshima , Takashi Yoneda , Yasuo Kuroda , Akira Kawaguchi
IPC分类号： B41J2/01
CPC分类号： C09B67/0084 , C09B47/26 , C09D11/328
摘要： Provided is a porphyrazine dye suitable for use in ink-jet recording, the porphyrazine dye giving a cyan ink with a satisfactory hue, having various excellent fastness properties, in particular, ozone resistance, and attaining a high color density. Also provided is an ink composition containing the dye. The porphyrazine dye is a porphyrazine dye represented by formula (1) or a salt thereof. In formula (1), rings A to D each independently represents a benzene ring, a nitrogenous heteroaromatic ring, etc.; E represents an alkylene; X represents sulfoanilino, etc.; R represents a hydrogen atom, sulfo, carboxy, etc.; group F represents phenyl, a nitrogenous heteroaromatic ring, etc.; a is an integer of 1-6; b is 0.00-3.90, excluding 3.90, on average; c is 0.10-4.00, excluding 4.00, on average; and the sum of b and c is 1.00-4.00, excluding 4.00, on average.
摘要翻译：本发明提供一种适用于喷墨记录的四氮杂卟啉染料，该四氮杂卟啉染料具有令人满意的色调，具有各种优异的牢度特性，特别是耐臭氧性，并获得高色密度的青色墨。还提供含有该染料的油墨组合物。四氮杂卟啉染料是由式（1）表示的四氮杂卟啉染料或其盐。在式（1）中，环A至D各自独立地表示苯环，含氮杂芳环等; E表示亚烷基; X代表磺基苯胺基等。 R代表氢原子，磺基，羧基等; F组表示苯基，含氮杂芳环等; a为1-6的整数; b为0.00-3.90，平均不包括3.90; c为0.10-4.00，平均不包括4.00; b和c的总和平均为1.00-4.00，不包括4.00。

10. 发明申请

US20120013678A1 Porphyrazine Coloring Matter, Ink Composition Containing The Same And Colored Product 有权
标题翻译：紫菜色素，含有相同色泽的油墨组合物
公开(公告)号：US20120013678A1
公开(公告)日：2012-01-19
申请号：US13258124
申请日：2010-04-14
申请人： Takashi Yoneda , Kenji Ooshima , Akira Kawaguchi , Yuka Shishikura , Tomoki Fujita
发明人： Takashi Yoneda , Kenji Ooshima , Akira Kawaguchi , Yuka Shishikura , Tomoki Fujita
IPC分类号： B41J2/17 , C09B47/00 , B65D85/00 , C09D11/02
CPC分类号： C09B47/26 , B41M5/5218 , C09B47/064 , C09D11/328
摘要： The present invention relates to a porphyrazine coloring matter or a salt thereof represented by the following formula (1) [wherein, the rings of A to D are each independently a benzene ring or a 6-membered nitrogen-containing heteroaromatic ring, E is alkylene, X is a sulfo-substituted anilino group or the like which may further have a substituent, R1 is a C1-C6 alkyl group, b is 0.00 or more and less than 3.90 as an average value, c is 0.10 or more and less than 4.00 as an average value, and the sum of b and c is 1.00 or more and less than 4.00 as an average value]. The ink composition containing the porphyrazine coloring matter of the present invention has a good hue as a cyan ink, is excellent in various fastness properties, particularly in ozone fastness, allows a high print density, has properties hardly causing bronze phenomenon, and can provide a porphyrazine coloring matter suitable for inkjet recording and an ink composition containing this.
摘要翻译：本发明涉及由下式（1）表示的四氮杂卟啉色素或其盐[其中，A至D的环各自独立地为苯环或6元含氮杂芳环，E为亚烷基 X为可以进一步具有取代基的磺基取代的苯胺基等，R 1为C 1〜C 6烷基，b为0.00以上且小于3.90，作为平均值，c为0.10以上且小于 4.00作为平均值，b和c之和为1.00以上且小于4.00作为平均值]。含有本发明的四氮杂卟啉色素的油墨组合物作为青色油墨具有良好的色相，具有优异的各种牢度性能，特别是耐臭氧性，允许高印刷密度，具有几乎不引起青铜现象的性质，并且可以提供适用于喷墨记录的四氮杂卟啉色素和含有它的油墨组合物。

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