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    • 1. 发明授权
    • Process for forming overcoat
    • 成型外套的工艺
    • US5641574A
    • 1997-06-24
    • US553399
    • 1995-11-21
    • Akira KasariSatoshi IkushimaOsamu IsozakiNaoji MatsumotoJohn David Nordstrom
    • Akira KasariSatoshi IkushimaOsamu IsozakiNaoji MatsumotoJohn David Nordstrom
    • B05D1/36B05D7/00B05D7/24C08G59/42C09D157/00C09D163/00C09D167/00C09D167/02C09D175/00C09D175/04C09D201/00
    • B05D7/532C08G59/42Y10T428/31511
    • A process for forming an overcoat by the two-coat one-bake method wherein a base coat composition and a clear coat composition are applied to a substrate ##STR1## wet-on-wet and thereafter cured at the same time by heating, the process being characterized in that the base coat composition is an aqueous coating composition consisting primarily of: (I) an aqueous dispersion or solution of a polymer containing a crosslinkable functional group, (II) a crosslinking agent, (III) a coloring pigment, and (IV) water, the clear coat composition being a coating composition comprising: (A) at least one resin selected from the group consisting of (i) a resin having at least one epoxy group and at least one hydroxyl group in the molecule, (ii) a resin mixture of (ii-1) a resin having at least two epoxy groups in the molecule and (ii-2) a resin having at least two hydroxyl groups in the molecule, (iii) a resin having at least two epoxy groups in the molecule, and (iv) any mixture thereof, (B) a crosslinking agent comprising a compound having at least two noncyclic acid anhydride groups and represented by formula (1) wherein R is a monovalent hydrocarbon group having 2 to 50 carbon atoms, R' is a bivalent hydrocarbon group having 2 to 50 carbon atoms, the hydrocarbon groups R and R' containing or not containing an ether linkage, urethane linkage or ester linkage, and n is an integer of 1 to 500, and (C) a curing catalyst.
    • PCT No.PCT / JP93 / 00678 Sec。 371日期:1995年11月21日 102(e)1995年11月21日日期PCT提交1993年5月24日PCT公布。 第WO94 / 27741号公报 日期1994年12月8日一种通过双层单烘烤法形成外涂层的方法,其中将底涂层组合物和透明涂层组合物施加到基底上(1)湿润湿润,然后在 该方法的特征在于底涂层组合物是主要由以下组成的水性涂料组合物:(I)含有可交联官能团的聚合物的水性分散体或溶液,(II)交联剂,( III)着色颜料和(IV)水,所述透明涂料组合物为涂料组合物,其包含:(A)至少一种选自以下的树脂:(i)具有至少一个环氧基的树脂和至少一种 (ii)分子中具有至少两个环氧基的树脂(ii-1)和(ii-2)分子中具有至少两个羟基的树脂的树脂混合物,(iii)分子中具有至少两个羟基的树脂, 分子中具有至少两个环氧基的树脂,和(iv)任何混合物 (B)交联剂,其包含具有至少两个非环状酸酐基团并由式(1)表示的化合物,其中R是具有2至50个碳原子的一价烃基,R'是具有2至 50个碳原子,含有或不含醚键的烃基R和R',氨基甲酸酯键或酯键,n为1〜500的整数,(C)固化催化剂。
    • 2. 发明授权
    • Process for forming overcoat
    • 成型外套的工艺
    • US5609960A
    • 1997-03-11
    • US553398
    • 1995-11-21
    • Akira KasariSatoshi IkushimaOsamu IsozakiNaoji MatsumotoJohn D. Nordstrom
    • Akira KasariSatoshi IkushimaOsamu IsozakiNaoji MatsumotoJohn D. Nordstrom
    • B05D1/36B05D3/02B05D5/00B05D7/00B05D7/24B05D7/26C08G59/42C08L33/06C08L73/02C09D133/04C09D133/06C09D133/14C09D161/20C09D163/00C09D167/00C09D167/02C09D201/02C09D201/06
    • B05D7/532C08G59/42C09D133/068C09D163/00C08L33/066C08L73/02Y10T428/31511
    • A process for forming an overcoat by the two-coat one-bake method wherein a basecoat composition and a clear coat composition are applied to a substrate wet-on-wet and thereafter cured at the same time by heating, the process being characterized in that the base coat composition is a coating composition consisting primarily of a hydroxyl-containing resin, an amine resin, a pigment and an organic solvent, the clear coat composition being a coating composition comprising:(A) at least one resin selected from the group consisting of (i) a resin having at least one epoxy group and at least one hydroxyl group in the molecue, (ii) a resin mixture of (ii-1) a resin having at least two epoxy groups in the molecule and (ii-2) a resin having at least two hydroxyl groups in the molecule, (iii) a resin having at least two epoxy groups in the molecule, and (iv) any mixture thereof,(B) a crosslinking agent comprising a compound having at least two noncyclic acid anhydride groups and represented by the formula ##STR1## wherein R is a monovalent hydrocarbon group having 2 to 50 carbon atoms, R' is a bivalent hydrocarbon group having 2 to 50 carbon atoms, the hydrocarbon groups R and R' containing or not containing an ether linkage, urethane linkage or ester linkage, and n is an integer of 1 to 500 and (C) a curing catalyst.
    • PCT No.PCT / JP93 / 00669 Sec。 371日期:1995年11月21日 102(e)日期1995年11月21日PCT提交1993年5月21日PCT公布。 公开号WO94 / 27740 日期1994年12月8日一种通过双层单烘烤法形成外涂层的方法,其中将底涂层组合物和透明涂层组合物施加到湿润基板上,然后通过加热同时固化, 方法的特征在于,底涂层组合物是主要由含羟基树脂,胺树脂,颜料和有机溶剂组成的涂料组合物,透明涂料组合物是涂料组合物,其包含:(A)至少一种树脂 选自(i)在分子中具有至少一个环氧基和至少一个羟基的树脂,(ii)(ii-1)在分子中具有至少两个环氧基的树脂的树脂混合物 和(ii-2)在分子中具有至少两个羟基的树脂,(iii)分子中具有至少两个环氧基的树脂,和(iv)其任何混合物,(B)包含化合物 具有至少两个非环酸酐基团a d由下式表示:其中R是具有2至50个碳原子的一价烃基,R'是具有2至50个碳原子的二价烃基,烃基R和R'含有或不含有醚键 氨基甲酸酯键或酯键,n为1〜500的整数,(C)固化催化剂。
    • 5. 发明授权
    • Thermosetting compositions and methods of forming a finish coat
    • 热固性组合物和形成精整涂层的方法
    • US5821314A
    • 1998-10-13
    • US750468
    • 1996-12-13
    • Satoshi IkushimaYasumasa OkumuraOsamu IsozakiMinoru Tsunoda
    • Satoshi IkushimaYasumasa OkumuraOsamu IsozakiMinoru Tsunoda
    • C08G59/30C08G59/32C08G59/68C09D163/00C08G77/00
    • C09D163/00C08G59/306C08G59/3254C08G59/68
    • This invention provides a thermosetting composition comprising (A) a compound (A-1) containing an epoxy group or groups and a reactive silicon group or groups as essential functional group components in the same molecule, or a mixture (A-2) of an epoxy group-containing compound and a reactive silicon group-containing compound, and (B) an organotin catalyst, a thermosetting composition comprising (A) a compound (A-3) containing (i) an epoxy group or groups, (ii) a reactive silicon group or groups and (iii) a hydroxyl group or groups and/or a carboxyl group or groups as essential functional group components in the same molecule, or a mixture (A-4) of at least two types of compounds, each compound containing at least one member selected from the class consisting of functional group components (i) to (iii), and all of the functional group components (i) to (iii) being present in said mixture, and (B) an organotin catalyst; and methods of forming a finish coat using these thermosetting compositions. The thermosetting compositions of the invention is excellent in storage stability, curable at low temperatures, and capable of producing cured products free of discoloration. The coating methods of the invention can form coating films superior in low-temperature curability, finished appearance, acid resistance, scratch resistance, and weatherability.
    • PCT No.PCT / JP95 / 01198 Sec。 371日期1996年12月13日第 102(e)日期1996年12月13日PCT归档1995年6月15日PCT公布。 公开号WO95 / 35336 日期1995年12月28日本发明提供了一种热固性组合物,其包含(A)含有环氧基或反应性硅基团的化合物(A-1)和作为同一分子中的必需官能团成分的化合物(A-1)或混合物(A -2)含有环氧基的化合物和含有反应性硅基团的化合物,和(B)有机锡催化剂,包含(A)包含(i)环氧基或基团的化合物(A-3)的热固性组合物 ,(ii)反应性硅基团和(iii)羟基或基团和/或羧基或基团作为同一分子中的必需官能团组分,或至少两种类型的混合物(A-4) 的化合物,每种化合物含有选自官能团组分(i)至(iii)中的至少一种,和所有官能团组分(i)至(iii))存在于所述混合物中,(B )有机锡催化剂; 以及使用这些热固性组合物形成精整涂层的方法。 本发明的热固性组合物的储存稳定性优异,在低温下可固化,并且能够生产没有变色的固化产物。 本发明的涂布方法可以形成优异的低温固化性,成品外观,耐酸性,耐擦伤性和耐候性优异的涂膜。
    • 7. 发明授权
    • Liquid photocurable composition, water-based photocurable composition and resist pattern-forming method by use of the same
    • 液体光固化性组合物,水性光固化性组合物及其抗蚀剂图案形成方法
    • US06420090B1
    • 2002-07-16
    • US09453504
    • 1999-12-03
    • Daisuke KojimaGenji ImaiJun AkuiHideo KogureOsamu Isozaki
    • Daisuke KojimaGenji ImaiJun AkuiHideo KogureOsamu Isozaki
    • G03F7037
    • G03F7/164G03F7/027
    • A liquid photocurable composition containing a photopolymerizable polyurethane compound having a repeating unit represented by the following formula: B—[X]n[Y]m—B, where X is represented by the formula: and Y is represented by the formula: —OOCHN—A—NHCOO(R2)—, A is a structural unit derived from a polyisocyanate compound, B is same or different and a structural unit derived from a hydroxy compound having at least one photopolymerizable unsaturated group at molecular terminals respectively and optionally containing an ether linkage, R1 is a structural unit derived from a carboxyl group-containing polyol compound, R2 is a structural unit derived from a polyol compound, n is an integer of 1 to 10, m is an integer of 1 to 10, provided that one X and one Y are bonded to each other, or three or more of X and/or Y are bonded to each other, and optionally containing a photopolymerizable compound other than the photopolymerizable polyurethane compound.
    • 含有具有由下式表示的重复单元的光聚合性聚氨酯化合物的液体光固化性组合物:B- [X] n [Y] mB,其中X由下式表示:Y由下式表示:-OOCHN-A -NHCOO(R2) - ,A是衍生自多异氰酸酯化合物的结构单元,B相同或不同,并且衍生自在分子末端具有至少一个光聚合性不饱和基团且任选地含有醚键的羟基化合物的结构单元, R1是衍生自含羧基的多元醇化合物的结构单元,R2是来自多元醇化合物的结构单元,n是1〜10的整数,m是1〜10的整数,条件是一个X和一个 Y彼此键合,或者X和/或Y中的三个或更多个彼此键合,并且任选地含有除光聚合性聚氨酯化合物以外的光聚合性化合物。
    • 9. 发明授权
    • Resins with unsaturated carbonyl and hydroxyl groups
    • 具有不饱和羰基和羟基的树脂
    • US5216094A
    • 1993-06-01
    • US884881
    • 1992-05-18
    • Osamu IsozakiNaozumi Iwasawa
    • Osamu IsozakiNaozumi Iwasawa
    • C08F8/44
    • C08F8/44
    • The present invention provides a curable resin coating composition consisting essentially of:(i) a resin (A) containing .alpha.,.beta.-unsaturated carbonyl group and primary and/or secondary hydroxyl group, or(ii) a mixture of a resin (B) containing .alpha.,.beta.-unsaturated carbonyl group and a resin (C) containing primary and/or secondary hydroxyl group, and(iii) at least one curing catalyst selected from the group consisting of alkali metal alkoxides, metal hydroxides, organic acid salts of metals, quaternary ammonium hydroxides, quaternary phosphonium hydroxides, tertiary sulfonium hydroxides and organic acid salts of these onium hydroxides.
    • 本发明提供一种可固化树脂涂料组合物,其基本上由以下组成:(i)含有α,β-不饱和羰基和伯和/或仲羟基的树脂(A),或(ii)树脂(B) 含有α,β-不饱和羰基和含有伯和/或仲羟基的树脂(C),和(iii)至少一种选自碱金属醇盐,金属氢氧化物,金属有机酸盐的固化催化剂 ,季铵氢氧化物,季铵氢氧化物,叔锍氢氧化物和这些氢氧化镧的有机酸盐。