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    • 1. 发明授权
    • Method of manufacturing structure for connecting interconnect lines including metal layer with thickness larger than thickness of metallic compound layer
    • 制造包括厚度大于金属化合物层厚度的金属层的互连线的结构的制造方法
    • US06780769B2
    • 2004-08-24
    • US10464502
    • 2003-06-19
    • Masahiko FujisawaAkihiko OhsakiNoboru Morimoto
    • Masahiko FujisawaAkihiko OhsakiNoboru Morimoto
    • H01L2144
    • H01L21/76846H01L23/53238H01L2924/0002H01L2924/00
    • A metal layer (7), a metallic compound layer (8) and a metal layer (9) are stacked in this order when viewed from the side of a first copper interconnect line (2) and an interlayer insulating film (5) to constitute a second conductive barrier layer (20). As the material for the metal layers (7) and (9), an element having an atomic weight higher than that of copper such as tungsten (W) or tantalum (Ta) is applicable. A second copper interconnect line (6) is conductively connected to the first copper interconnect line (2) at a contact hole (12) through the second conductive barrier layer (20). As the ratio of the volume of the second copper interconnect line (6) at the region for filling a trench (11) to the volume of the second copper interconnect line (6) at the region for filling the contact hole (12) increases, tensile stress to be concentrated at the contact hole (12) becomes greater. As a result, a void is likely to be generated in the contact hole (12). In view of this, in order to improve the adhesion especially between the second copper interconnect line (6) at the region for filling the contact hole (12) and the second conductive barrier layer (20), the metal layer (9) is provided.
    • 从第一铜互连线(2)和层间绝缘膜(5)的侧面观察时,依次层叠金属层(7),金属化合物层(8)和金属层(9),构成 第二导电阻挡层(20)。 作为金属层(7)和(9)的材料,可以使用原子量高于诸如钨(W)或钽(Ta)的铜的元素。 第二铜互连线(6)通过第二导电阻挡层(20)在接触孔(12)处导电地连接到第一铜互连线(2)。 由于在填充接触孔(12)的区域处,用于填充沟槽(11)的区域处的第二铜互连线(6)的体积与第二铜互连线(6)的体积的比率增加, 要集中在接触孔(12)处的拉伸应力变大。 结果,在接触孔(12)中容易产生空隙。 鉴于此,为了改善在用于填充接触孔(12)的区域和第二导电阻挡层(20)之间的第二铜互连线(6)之间的粘合性,提供了金属层(9) 。
    • 2. 发明授权
    • Structure for connecting interconnect lines with interposed layer including metal layers and metallic compound layer
    • 用于连接具有包括金属层和金属化合物层的插入层的互连线的结构
    • US06624516B2
    • 2003-09-23
    • US09978005
    • 2001-10-17
    • Masahiko FujisawaAkihiko OhsakiNoboru Morimoto
    • Masahiko FujisawaAkihiko OhsakiNoboru Morimoto
    • H01L2348
    • H01L21/76846H01L23/53238H01L2924/0002H01L2924/00
    • A metal layer (7), a metallic compound layer (8) and a metal layer (9) are stacked in this order when viewed from the side of a first copper interconnect line (2) and an interlayer insulating film (5) to constitute a second conductive barrier layer (20). As the material for the metal layers (7) and (9), an element having an atomic weight higher than that of copper such as tungsten (W) or tantalum (Ta) is applicable. A second copper interconnect line (6) is conductively connected to the first copper interconnect line (2) at a contact hole (12) through the second conductive barrier layer (20). As the ratio of the volume of the second copper interconnect line (6) at the region for filling a trench (11) to the volume of the second copper interconnect line (6) at the region for filling the contact hole (12) increases, tensile stress to be concentrated at the contact hole (12) becomes greater. As a result, a void is likely to be generated in the contact hole (12). In view of this, in order to improve the adhesion especially between the second copper interconnect line (6) at the region for filling the contact hole (12) and the second conductive barrier layer (20), the metal layer (9) is provided.
    • 从第一铜互连线(2)和层间绝缘膜(5)的侧面观察时,依次层叠金属层(7),金属化合物层(8)和金属层(9),构成 第二导电阻挡层(20)。 作为金属层(7)和(9)的材料,可以使用原子量高于诸如钨(W)或钽(Ta)的铜的元素。 第二铜互连线(6)通过第二导电阻挡层(20)在接触孔(12)处导电地连接到第一铜互连线(2)。 由于在填充接触孔(12)的区域处,用于填充沟槽(11)的区域处的第二铜互连线(6)的体积与第二铜互连线(6)的体积的比率增加, 要集中在接触孔(12)处的拉伸应力变大。 结果,在接触孔(12)中容易产生空隙。 鉴于此,为了改善在用于填充接触孔(12)的区域和第二导电阻挡层(20)之间的第二铜互连线(6)之间的粘合性,提供了金属层(9) 。
    • 9. 发明授权
    • Method of manufacturing contact structure
    • 制造接触结构的方法
    • US06399424B1
    • 2002-06-04
    • US09663201
    • 2000-09-18
    • Masazumi MatsuuraKinya GotoNoboru Morimoto
    • Masazumi MatsuuraKinya GotoNoboru Morimoto
    • H01L2144
    • H01L21/76811H01L21/76801H01L21/76813H01L23/5329H01L2924/0002H01L2924/00
    • Implemented is a method of manufacturing a contact structure having a combination of formation of a buried wiring and that of a low dielectric constant interlayer insulating film in which a connecting hole to be formed in a low dielectric constant interlayer insulating film does not turn into an abnormal shape. A fourth interlayer insulating film 11 is formed on an upper surface of a third interlayer insulating film 10. Next, patterning for a wiring trench and a connecting hole is carried out into the fourth interlayer insulating film 11 and the third interlayer insulating film 10, respectively. Then, a pattern of the connecting hole is first formed in a third low dielectric constant interlayer insulating film 9. Thereafter, a second interlayer insulating film 8 exposed in the pattern is removed and a pattern of the wiring trench is formed in the third interlayer insulating film 10. Subsequently, second and third low dielectric constant interlayer insulating films 7 and 9 are etched, and the wiring trench and the connecting hole are formed at the same time. Thus, a photoresist can be formed again without the second and third low dielectric constant interlayer insulating films 7 and 9 exposed, and an abnormal shape is generated in the connecting hole with difficulty.
    • 具体实施方式是制造具有掩埋布线的形成和低介电常数层间绝缘膜的组合的接触结构的方法,其中形成在低介电常数层间绝缘膜中的连接孔不会变成异常 形状。 第四层间绝缘膜11形成在第三层间绝缘膜10的上表面上。接下来,分别对第四层间绝缘膜11和第三层间绝缘膜10进行布线沟槽和连接孔的图案化 。 然后,首先在第三低介电常数层间绝缘膜9中形成连接孔的图案。然后,去除以图案露出的第二层间绝缘膜8,并且在第三层间绝缘层中形成布线沟槽的图案 随后,蚀刻第二和第三低介电常数层间绝缘膜7和9,并且同时形成布线沟槽和连接孔。 因此,可以再次形成光致抗蚀剂,而不会使第二和第三低介电常数层间绝缘膜7和9暴露,并且难以在连接孔中产生异常形状。
    • 10. 发明授权
    • Method of manufacturing semiconductor device and semiconductor device
    • 制造半导体器件和半导体器件的方法
    • US06737319B2
    • 2004-05-18
    • US10300579
    • 2002-11-21
    • Noboru MorimotoMasazumi MatsuuraKinya Goto
    • Noboru MorimotoMasazumi MatsuuraKinya Goto
    • H01L218242
    • H01L21/76819
    • A method of manufacturing a semiconductor device is obtained which is capable of evading generation of a short circuit between wirings in an upper wiring layer even if a part of an upper surface of an FSG film is exposed by variations in a production step. After a USG film (4) is deposited to a thickness of 1 &mgr;m over an entire surface of an FSG film (3), the USG film (4) is polished and removed by a thickness of 900 nm from an upper surface thereof by the CMP method. At this time, a part of an upper surface of the FSG film (3) is exposed by variations in a production step. Next, the surface of the interlayer dielectric film (50) is cleaned with a cleaning liquid whose etching rate to the FSG film (3) and etching rate to the USG film (5) are substantially the same. Such a cleaning liquid may be, for example, an ammonia hydrogen peroxide mixture of NH4OH:H2O2:H2O=1:1:20. The structure shown in FIG. 5 is dipped in the above-mentioned ammonia hydrogen peroxide mixture for 60 seconds to clean the surface of the interlayer dielectric film (50).
    • 获得制造半导体器件的方法,即使通过制造步骤的变化使FSG膜的上表面的一部分露出,也能够避免在上布线层中的布线之间的短路的产生。 在USG膜(4)在FSG膜(3)的整个表面上沉积1μm的厚度之后,USG膜(4)从上表面抛光并去除900nm的厚度, CMP方法。 此时,FSG膜(3)的上表面的一部分通过制造工序的变形而露出。 接下来,用对FSG膜(3)的蚀刻速率和对USG膜(5)的蚀刻速率基本相同的清洗液清洁层间绝缘膜(50)的表面。 这样的清洗液可以是例如NH 4 OH:H 2 O 2 :H 2 O = 1:1:20的氨过氧化氢混合物。 图1所示的结构 5浸渍在上述氨过氧化氢混合物中60秒以清洁层间电介质膜(50)的表面。