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1. 发明授权

US08551908B2 Exhaust gas purification catalyst 有权
标题翻译：废气净化催化剂
公开(公告)号：US08551908B2
公开(公告)日：2013-10-08
申请号：US13001683
申请日：2009-06-26
申请人： Akemi Satou , Masahiko Takeuchi , Keizo Hiraku , Yusuke Kawamura , Takahiro Fujiwara , Tadashi Suzuki , Naoki Takahashi
发明人： Akemi Satou , Masahiko Takeuchi , Keizo Hiraku , Yusuke Kawamura , Takahiro Fujiwara , Tadashi Suzuki , Naoki Takahashi
IPC分类号： B01J23/00 , B01J21/00
CPC分类号： B01J23/002 , B01D53/945 , B01D2255/1021 , B01D2255/1023 , B01D2255/1025 , B01D2255/206 , B01D2255/20715 , B01D2255/9022 , B01D2255/908 , B01D2257/304 , B01J23/63 , B01J23/83 , B01J23/894 , B01J35/04 , B01J37/0244 , B01J2523/00 , Y02T10/22 , B01J2523/3712 , B01J2523/3718 , B01J2523/48 , B01J2523/828 , B01J2523/824 , B01J2523/822
摘要： An exhaust gas purification catalyst includes: a lower catalyst layer that contains a ceria-zirconia mixed oxide having 50 to 70 mass % of CeO2 and 5 mass % or more of Pr2O3 and carries at least one of Pt and Pd; and an upper catalyst layer that contains at least zirconia and carries at least Rh, wherein the total amount of CeO2 per liter of the carrier base is 15 to 30 g. Because the amount of CeO2 is small, formation of H2S is suppressed and a high capability of adsorbing and releasing oxygen is brought out in spite of the small amount of CeO2.
摘要翻译：废气净化催化剂包括：含有氧化铈 - 氧化锆混合氧化物的下部催化剂层，其具有50〜70质量％的CeO 2和5质量％以上的Pr 2 O 3，并携带Pt和Pd中的至少一种; 和至少含有氧化锆并至少含有Rh的上部催化剂层，其中每升载体碱的CeO 2的总量为15〜30g。由于CeO 2的量少，因此抑制了H 2 S的形成，并且尽管CeO 2的量少，但是吸附和释放氧的能力也很高。

2. 发明申请

US20110099987A1 EXHAUST GAS PURIFICATION CATALYST 有权
标题翻译：排气净化催化剂
公开(公告)号：US20110099987A1
公开(公告)日：2011-05-05
申请号：US13001683
申请日：2009-06-26
申请人： Akemi Satou , Masahiko Takeuchi , Keizo Hiraku , Yusuki Kawamura , Takahiro Fujiwara , Tadashi Suzuki , Naoki Takahashi
发明人： Akemi Satou , Masahiko Takeuchi , Keizo Hiraku , Yusuki Kawamura , Takahiro Fujiwara , Tadashi Suzuki , Naoki Takahashi
IPC分类号： F01N3/10
CPC分类号： B01J23/002 , B01D53/945 , B01D2255/1021 , B01D2255/1023 , B01D2255/1025 , B01D2255/206 , B01D2255/20715 , B01D2255/9022 , B01D2255/908 , B01D2257/304 , B01J23/63 , B01J23/83 , B01J23/894 , B01J35/04 , B01J37/0244 , B01J2523/00 , Y02T10/22 , B01J2523/3712 , B01J2523/3718 , B01J2523/48 , B01J2523/828 , B01J2523/824 , B01J2523/822
摘要： An exhaust gas purification catalyst includes: a lower catalyst layer that contains a ceria-zirconia mixed oxide having 50 to 70 mass % of CeO2 and 5 mass % or more of Pr2O3 and carries at least one of Pt and Pd; and an upper catalyst layer that contains at least zirconia and carries at least Rh, wherein the total amount of CeO2 per liter of the carrier base is 15 to 30 g. Because the amount of CeO2 is small, formation of H2S is suppressed and a high capability of adsorbing and releasing oxygen is brought out in spite of the small amount of CeO2.
摘要翻译：废气净化催化剂包括：含有氧化铈 - 氧化锆混合氧化物的下部催化剂层，其具有50〜70质量％的CeO 2和5质量％以上的Pr 2 O 3，并携带Pt和Pd中的至少一种; 和至少含有氧化锆并至少含有Rh的上部催化剂层，其中每升载体碱的CeO 2的总量为15〜30g。由于CeO 2的量少，因此抑制了H 2 S的形成，并且尽管CeO 2的量少，但是吸附和释放氧的能力也很高。

3. 发明授权

US08809495B2 Peptides imparting cell permeability to lipid membrane structure and/or enhancing cell permeability of lipid membrane structure, and lipid membrane structure comprising lipid bound to such peptide as constituent lipid and having cell permeability or showing enhanced cell permeability 有权
标题翻译：赋予细胞对脂质膜结构的渗透性和/或增强脂质膜结构的细胞渗透性的肽，以及脂质膜结构，其包含结合到诸如构成脂质的肽和具有细胞渗透性或显示增强的细胞渗透性
公开(公告)号：US08809495B2
公开(公告)日：2014-08-19
申请号：US13515970
申请日：2010-12-14
申请人： Hideyoshi Harashima , Takahiro Fujiwara , Hidetaka Akita
发明人： Hideyoshi Harashima , Takahiro Fujiwara , Hidetaka Akita
IPC分类号： C07K7/06 , A61K47/42 , A61K9/127 , C07K14/47 , A61K38/00 , A61K39/00
CPC分类号： C07K7/06 , A61K9/1271 , A61K38/00 , A61K47/60 , A61K47/62 , A61K47/6911
摘要： Provided are peptides imparting cell permeability to a lipid membrane structure and/or enhancing the cell permeability of a lipid membrane structure, and a lipid membrane structure which comprises, as a constituent lipid, a lipid bound to such a peptide and has cell permeability or shows enhanced cell permeability. The amino acid sequences of the peptides imparting cell permeability to a lipid membrane structure and/or enhancing the cell permeability of a lipid membrane structure are represented by: LX1X2X1X1X1L, LLX2X1X1X1L and LX1X2X1X1L (wherein L represents a leucine residue; X1 represents a polar amino acid residue; and X2 represents a polar, non-charged and branched chain amino acid residue).
摘要翻译：提供赋予脂质膜结构的细胞渗透性和/或增强脂质膜结构的细胞渗透性的肽，以及脂质膜结构，其包含作为构成脂质的与这种肽结合的脂质并具有细胞渗透性或显示增强细胞渗透性。赋予细胞对脂质膜结构的渗透性和/或增强脂质膜结构的细胞渗透性的肽的氨基酸序列由以下表示：LX1X2X1X1X1L，LLX2X1X1X1L和LX1X2X1X1L（其中L表示亮氨酸残基; X1表示极性氨基酸残基; X2表示极性，非带电荷和支链氨基酸残基）。

4. 发明申请

US20070208143A1 Water-soluble polymer and additive for paper manufacture 有权
标题翻译：用于造纸的水溶性聚合物和添加剂
公开(公告)号：US20070208143A1
公开(公告)日：2007-09-06
申请号：US11367487
申请日：2006-03-06
申请人： Yoshiharu Kimura , Takahiro Fujiwara
发明人： Yoshiharu Kimura , Takahiro Fujiwara
IPC分类号： C08F20/56
CPC分类号： C08F20/56 , C08F2/001 , C08F2/10 , C08F220/06 , C08F220/34 , C08F220/56 , C08F222/02 , C08F230/08
摘要： The present invention provides a method for preparing a water soluble polymer, which comprises: a first step of polymerizing: (a) 60 to 99.5 mol % of at least one selected from acrylamide and methacrylamide, (b) 0.5 to 20 mol % of at least one selected from α,β-unsaturated monocarboxylic acid, α,β-unsaturated dicarboxylic acid and salts thereof, and (c) 1 to 20 mol % of at least one selected from a water soluble cationic monomer and a salt thereof, (d) 0.01 to 1 mol % of a chain transfer agent, and (e) 0.005 to 5 mol % of a crosslinkable monomer, in the presence of a persulfate-based catalyst to obtain a prepolymer; and a second step of further adding the persulfate-based catalyst to the prepolymer obtained in the first step and the residual monomer, followed by the polymerization and termination of the polymerization. Consequently, it is made possible to suppress a rapid increase in viscosity during the polymerization thereby to obtain a water soluble branched polymer having high molecular weight and low viscosity.
摘要翻译：本发明提供一种制备水溶性聚合物的方法，其包括：聚合的第一步骤：（a）60至99.5mol％的选自丙烯酰胺和甲基丙烯酰胺的至少一种，（b）0.5至20mol％的选自α，β-不饱和一元羧酸，α，β-不饱和二羧酸及其盐中的至少一种，和（c）1〜20摩尔％的选自水溶性阳离子单体及其盐中的至少一种，（d ）0.01〜1摩尔％的链转移剂，（e）0.005〜5摩尔％的交联性单体，在过硫酸盐系催化剂存在下，得到预聚物; 以及将第一步骤中得到的预聚物和残留单体进一步添加过硫酸盐系催化剂，然后聚合并终止聚合的第二工序。因此，可以抑制聚合期间的粘度的快速增加，从而得到具有高分子量和低粘度的水溶性支链聚合物。

5. 发明申请

US20150128572A1 EXHAUST GAS CONTROL APPARATUS FOR INTERNAL COMBUSTION ENGINE 有权
标题翻译：用于内燃机的排气控制装置
公开(公告)号：US20150128572A1
公开(公告)日：2015-05-14
申请号：US14368832
申请日：2011-12-27
申请人： Takahiro Fujiwara , Norihisa Nakagawa , Kouichi Kimura , Shuntaro Okazaki , Keisuke Nagasaka , Ichiro Kitamura , Satoshi Kamitani , Koji Morita
发明人： Takahiro Fujiwara , Norihisa Nakagawa , Kouichi Kimura , Shuntaro Okazaki , Keisuke Nagasaka , Ichiro Kitamura , Satoshi Kamitani , Koji Morita
IPC分类号： F01N3/20 , F02D41/02
CPC分类号： F01N3/2006 , F01N3/101 , F01N3/20 , F01N3/22 , F01N9/00 , F01N11/00 , F01N2240/02 , F01N2260/04 , F01N2430/08 , F01N2560/025 , F01N2560/14 , F01N2590/11 , F01N2900/10 , F02D41/0255 , Y02T10/22 , Y02T10/47
摘要： An exhaust gas control apparatus for an internal combustion engine, controls an exhaust operation of the internal combustion engine (200) provided with an exhaust gas purification catalyst (216) in an exhaust passage (215). The exhaust gas control apparatus for the internal combustion engine is provided with a warming-up device configured to warm up the exhaust gas purification catalyst; and an oxygen supplying device (220, 221) configured to supply oxygen to the exhaust gas purification catalyst after the end of the warm-up. This makes it possible to preferably desorb sulfur adsorbed to the exhaust gas purification catalyst during warm-up. It is therefore possible to suppress a reduction in purification ability of the exhaust gas purification catalyst due to sulfur coating.
摘要翻译：一种用于内燃机的排气控制装置，控制在排气通道（215）中设置有排气净化催化剂（216）的内燃机（200）的排气操作。用于内燃机的排气控制装置设置有预热装置，其被配置为预热排气净化催化剂; 以及氧气供给装置（220,221），其构造成在所述预热结束后向所述排气净化催化剂供给氧。这使得可以优选在预热期间解吸吸附到废气净化催化剂上的硫。因此，能够抑制由于硫化而导致的排气净化催化剂的净化能力的降低。

6. 发明授权

US08552204B2 Zinc cluster 有权
标题翻译：锌簇
公开(公告)号：US08552204B2
公开(公告)日：2013-10-08
申请号：US13395312
申请日：2010-05-31
申请人： Yoshimasa Matsushima , Hideki Nara , Takahiro Fujiwara
发明人： Yoshimasa Matsushima , Hideki Nara , Takahiro Fujiwara
IPC分类号： C07D263/12 , C07D309/12 , C07F3/06 , C07C229/08 , C07C67/03
CPC分类号： C07D211/46 , B01J31/2239 , B01J2231/349 , B01J2531/0219 , B01J2531/26 , C07B41/12 , C07C53/18 , C07C67/03 , C07C67/08 , C07C269/06 , C07C2601/14 , C07D263/12 , C07D309/12 , C07F3/003 , C07C69/612 , C07C271/22
摘要： Disclosed is a novel zinc cluster compound represented by general formula (1): Zn4O (OCOR)6 (RCOOH)n, wherein R represents an alkyl group which has 1 to 4 carbon atoms and may be substituted with a halogen atom, and n represents 0.1 to 1, and also disclosed are a method for producing the compound and a reaction using the compound.
摘要翻译：公开了由通式（1）表示的新型锌簇化合物：Zn 4 O（OCOR）6（RCOOH）n，其中R表示具有1至4个碳原子并可被卤素原子取代的烷基，n表示 0.1〜1，也公开了使用该化合物的化合物的制造方法和反应。

7. 发明申请

US20120016148A1 METHOD FOR PRODUCING RUTHENIUM COMPLEX 有权
标题翻译：生产金属复合材料的方法
公开(公告)号：US20120016148A1
公开(公告)日：2012-01-19
申请号：US13138709
申请日：2010-03-18
申请人： Takahiro Fujiwara , Hideki Nara
发明人： Takahiro Fujiwara , Hideki Nara
IPC分类号： C07F15/00
CPC分类号： C07F15/0046 , C07F17/02
摘要： The present invention provides a method for inexpensively producing di-μ-chloro-bis[chloro(η6-1-isopropyl-4-methylbenzene)ruthenium (II)] complex used as a catalyst raw material for a hydrogenation or metathesis polymerization reaction at a high yield. In the present invention, the above-described problem can be solved by reacting ruthenium chloride or a hydrate thereof with γ-terpinene in a solvent. In particular, by using an alcohol having a boiling point of 100° C. or higher as a solvent, the yield of the above-described complex can be increased.
摘要翻译：本发明提供了一种廉价生产用作氢化或易位聚合反应的催化剂原料的二 - 氯 - 双[氯（＆eegr; 6-1-异丙基-4-甲苯）钌（II）]络合物的方法以高产量。在本发明中，上述问题可以通过使氯化钌或其水合物与γ-萜品烯在溶剂中反应来解决。特别是通过使用沸点为100℃以上的醇作为溶剂，可以提高上述络合物的收率。

8. 发明授权

US07038087B2 Process for the production of optically active amino alcohols 失效
标题翻译：用于制备光学活性氨基醇的方法
公开(公告)号：US07038087B2
公开(公告)日：2006-05-02
申请号：US10656617
申请日：2003-09-04
申请人： Takahiro Fujiwara , Hideki Nara , Tsukasa Sotoguchi
发明人： Takahiro Fujiwara , Hideki Nara , Tsukasa Sotoguchi
IPC分类号： C07C209/16 , C07C209/46 , C07C209/56
CPC分类号： C07C269/00 , C07B2200/07 , C07C213/02 , C07C2601/08 , C07C2601/14 , Y02P20/55 , C07C215/44 , C07C271/24
摘要： An object of the present invention is to provide a process for the production of an optically active amino alcohol, particularly an optically active amino alcohol of a trans-form, being excellent in economy and efficiency, and suitable for industry using easily available and less expensive materials.The present invention relates to a process for the production of an optically active amino alcohol comprising the steps that an optically active hydroxy ester in a trans-form obtained by an asymmetric hydrogenation of an easily available β-keto ester is reacted with hydrazine, the resulting optically active hydrazinocarbonyl alcohol is subjected to a Curtius rearrangement in the presence of alcohol and protective group of amino group of the resulting optically active alkoxycarbonylamino alcohol is deprotected. As a result of the process for the production in accordance with the present invention, the objected substance is able to be prepared in a high optical purity and in a high yield.
摘要翻译：本发明的目的是提供一种制备光学活性氨基醇，特别是反式形式的光学活性氨基醇的方法，其经济性和效率优异，并且适用于易于获得和较便宜的工业应用材料本发明涉及一种制备光学活性氨基醇的方法，该方法包括以下步骤：通过易于获得的β-酮酯的不对称氢化获得的反式的光学活性羟基酯与肼反应，得到光学活性肼基羰基醇在醇的存在下进行Curtius重排，并将得到的光学活性烷氧基羰基氨基醇的保护基的氨基脱保护。作为根据本发明的生产方法的结果，可以以高光学纯度和高产率制备被
反应物质。

9. 发明申请

US20120309937A1 PEPTIDES IMPARTING CELL PERMEABILITY TO LIPID MEMBRANE STRUCTURE AND/OR ENHANCING CELL PERMEABILITY OF LIPID MEMBRANE STRUCTURE, AND LIPID MEMBRANE STRUCTURE COMPRISING LIPID BOUND TO SUCH PEPTIDE AS CONSTITUENT LIPID AND HAVING CELL PERMEABILITY OR SHOWING ENHANCED CELL PERMEABILITY 有权
标题翻译： PEPTIDES将脂质膜结构和/或增强脂质膜结构的细胞渗透性和/或增强脂质膜结构的细胞渗透性的脂质渗透性，以及将包含脂质的脂质膜结合到这些肽作为组织脂质并具有细胞渗透性或显示增强的细胞渗透性
公开(公告)号：US20120309937A1
公开(公告)日：2012-12-06
申请号：US13515970
申请日：2010-12-14
申请人： Hideyoshi Harashima , Takahiro Fujiwara , Hidetaka Akita
发明人： Hideyoshi Harashima , Takahiro Fujiwara , Hidetaka Akita
IPC分类号： C07K1/113 , C07K1/107
CPC分类号： C07K7/06 , A61K9/1271 , A61K38/00 , A61K47/60 , A61K47/62 , A61K47/6911
摘要： Provided are peptides imparting cell permeability to a lipid membrane structure and/or enhancing the cell permeability of a lipid membrane structure, and a lipid membrane structure which comprises, as a constituent lipid, a lipid bound to such a peptide and has cell permeability or shows enhanced cell permeability. The amino acid sequences of the peptides imparting cell permeability to a lipid membrane structure and/or enhancing the cell permeability of a lipid membrane structure are represented by: LX1X2X1X1X1L, LLX2X1X1X1L and LX1X2X1X1L (wherein L represents a leucine residue; X1 represents a polar amino acid residue; and X2 represents a polar, non-charged and branched chain amino acid residue).
摘要翻译：提供赋予脂质膜结构的细胞渗透性和/或增强脂质膜结构的细胞渗透性的肽，以及脂质膜结构，其包含作为构成脂质的与这种肽结合的脂质并具有细胞渗透性或显示增强细胞渗透性。赋予细胞对脂质膜结构的渗透性和/或增强脂质膜结构的细胞渗透性的肽的氨基酸序列由以下表示：LX1X2X1X1X1L，LLX2X1X1X1L和LX1X2X1X1L（其中L表示亮氨酸残基; X1表示极性氨基酸残基; X2表示极性，非带电荷和支链氨基酸残基）。

10. 发明授权

US08241462B2 Papermaking internal sizing agent and use thereof 有权
标题翻译：造纸内部施胶剂及其用途
公开(公告)号：US08241462B2
公开(公告)日：2012-08-14
申请号：US12670186
申请日：2008-03-06
申请人： Kazunari Sakai , Takahiro Fujiwara , Kazushige Inaoka , Takashi Yamaguchi , Masaki Ito , Yasunobu Ooka
发明人： Kazunari Sakai , Takahiro Fujiwara , Kazushige Inaoka , Takashi Yamaguchi , Masaki Ito , Yasunobu Ooka
IPC分类号： D21H17/37 , D21H17/41 , D21H17/42 , D21H17/43 , D21H17/44 , D21H17/45
CPC分类号： D21H21/16 , D21H17/41 , D21H17/455 , D21H17/675
摘要： To provide a papermaking internal sizing agent capable of efficiently imparting sizing performance even in neutral papermaking which uses calcium carbonate as filler, and uses no aluminum sulfate or uses a small amount of aluminum sulfate, and also provide a paper or a paperboard obtained by using the papermaking internal sizing agent. The papermaking internal sizing agent comprises as an effective ingredient an amphoteric copolymer having hydrophobic groups and cationic groups, at least a part of the cationic groups being quaternized. Preferably, the amphoteric copolymer is obtained by polymerizing monomer ingredients that it essentially contain a hydrophobic monomer (A), a cationic monomer (B), and an anionic monomer (C) and that an anion equivalent of the monomer (C) is 0.1 to 90% of a cation equivalent of the monomer (B), in which a rate of quaternizing of the cationic groups is not less than 40% by mole. The paper or the paperboard contains the above papermaking internal sizing agent.
摘要翻译：提供即使在使用碳酸钙作为填料的中性造纸中也能有效赋予施胶性能，不使用硫酸铝或使用少量硫酸铝的造纸内施胶剂，并且还提供通过使用碳酸钙作为填料获得的纸或纸板造纸内部施胶剂。造纸内部施胶剂包括具有疏水基团和阳离子基团的两性共聚物作为有效成分，至少一部分阳离子基团被季铵化。优选地，两性共聚物通过使其基本上含有疏水单体（A），阳离子单体（B）和阴离子单体（C）的单体成分聚合而获得，并且单体（C）的阴离子当量为0.1〜单体（B）的阳离子当量的90％，其中阳离子基团的季铵化率不低于40摩尔％。纸或纸板包含上述造纸内部施胶剂。

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