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1. 发明授权

US10100402B2 Substrate holder for graphene film synthesis 有权
公开(公告)号：US10100402B2
公开(公告)日：2018-10-16
申请号：US13269037
申请日：2011-10-07
申请人： Ageeth A. Bol , Xuesong Li
发明人： Ageeth A. Bol , Xuesong Li
IPC分类号： C23C16/26 , C01B32/186 , C23C16/458 , B82Y30/00 , B82Y40/00
摘要： An apparatus and method for graphene film synthesis. The apparatus includes a quasi enclosed substrate holder which includes one open side, a cap disposed over the one open side of the quasi enclosed substrate holder, and a substrate for graphene film synthesis located inside the quasi enclosed substrate holder. The method includes placing a substrate for graphene film synthesis inside of a quasi enclosed substrate holder and generating a graphene film on the substrate via chemical vapor deposition, wherein the quasi enclosed substrate holder includes one open side and a cap disposed over the open side of the quasi enclosed substrate holder.

2. 发明授权

US08647978B1 Use of graphene to limit copper surface oxidation, diffusion and electromigration in interconnect structures 有权
标题翻译：使用石墨烯来限制互连结构中的铜表面氧化，扩散和电迁移
公开(公告)号：US08647978B1
公开(公告)日：2014-02-11
申请号：US13551962
申请日：2012-07-18
申请人： John A. Ott , Ageeth A. Bol
发明人： John A. Ott , Ageeth A. Bol
IPC分类号： H01L21/4763
CPC分类号： H01L23/52 , H01L21/7682 , H01L21/76852 , H01L21/76885 , H01L23/5222 , H01L23/53238 , H01L23/53276 , H01L23/5329 , H01L23/53295 , H01L2924/0002 , H01L2924/0001 , H01L2924/00
摘要： A contiguous layer of graphene is formed on exposed sidewall surfaces and a topmost surface of a copper-containing structure that is present on a surface of a substrate. The presence of the contiguous layer of graphene on the copper-containing structure reduces copper oxidation and surface diffusion of copper ions and thus improves the electromigration resistance of the structure. These benefits can be obtained using graphene without increasing the resistance of copper-containing structure.
摘要翻译：邻近的石墨烯层形成在暴露的侧壁表面和存在于基底表面上的含铜结构的最上表面。在含铜结构上存在连续的石墨烯层可以减少铜离子的铜氧化和表面扩散，从而提高结构的电迁移能力。这些益处可以使用石墨烯获得，而不增加含铜结构的电阻。

3. 发明申请

US20120000516A1 Graphene Solar Cell 审中-公开
标题翻译：石墨烯太阳能电池
公开(公告)号：US20120000516A1
公开(公告)日：2012-01-05
申请号：US12828446
申请日：2010-07-01
申请人： Ageeth A. Bol , Amal Kasry , Ahmed Maarouf , Glenn J. Martyna , Dennis M. Newns , Razvan A. Nistor , George S. Tulevski
发明人： Ageeth A. Bol , Amal Kasry , Ahmed Maarouf , Glenn J. Martyna , Dennis M. Newns , Razvan A. Nistor , George S. Tulevski
IPC分类号： H01L31/0288 , H01L31/18 , H01L31/0256
CPC分类号： H01L31/022433 , H01L31/022491 , H01L31/075 , Y02E10/548
摘要： A solar cell includes a semiconductor portion, a graphene layer disposed on a first surface of the semiconductor portion, and a first conductive layer patterned on the graphene layer, the first conductive layer including at least one bus bar portion and a plurality of fingers extending from the at least one bus bar portion.
摘要翻译：太阳能电池包括半导体部分，设置在半导体部分的第一表面上的石墨烯层和在石墨烯层上图案化的第一导电层，第一导电层包括至少一个汇流条部分和从所述至少一个汇流条部分。

4. 发明申请

US20110206934A1 GRAPHENE FORMATION UTILIZING SOLID PHASE CARBON SOURCES 有权
标题翻译：利用固相碳源的石墨形成
公开(公告)号：US20110206934A1
公开(公告)日：2011-08-25
申请号：US12710333
申请日：2010-02-22
申请人： Ageeth A. Bol , Roy A. Carruthers , Jack O. Chu , Alfred Grill , Christian Lavoie , Katherine L. Saenger , James C. Tsang
发明人： Ageeth A. Bol , Roy A. Carruthers , Jack O. Chu , Alfred Grill , Christian Lavoie , Katherine L. Saenger , James C. Tsang
IPC分类号： B32B9/00 , B32B15/04 , B05D3/02
CPC分类号： C01B31/0446 , B82Y30/00 , B82Y40/00 , C01B32/184 , Y10T428/30
摘要： A method for forming a single, few-layer, or multi-layer graphene and structure is described incorporating selecting a substrate having a buried layer of carbon underneath a metal layer, providing an ambient and providing a heat treatment to pass carbon through the metal layer to form a graphene layer on the metal layer surface or incorporating a metal-carbon layer which is heated to segregate carbon in the form of graphene to the surface or chemically reacting the metal in the metal-carbon layer with a substrate containing Si driving the carbon to the surface whereby graphene is formed.
摘要翻译：描述了形成单层，几层或多层石墨烯和结构的方法，其包括选择在金属层下方具有埋藏层的衬底的基底，提供环境并提供热处理以使碳通过金属层以在金属层表面上形成石墨烯层或掺入金属碳层，该金属碳层被加热以将石墨烯形式的碳分离到表面或使金属 - 碳层中的金属与含有驱动碳的Si的基板化学反应到形成石墨烯的表面。

5. 发明申请

US20120069338A1 Graphene Optical Sensor 有权
标题翻译：石墨烯光学传感器
公开(公告)号：US20120069338A1
公开(公告)日：2012-03-22
申请号：US12886908
申请日：2010-09-21
申请人： Ali Afzali , Ageeth A. Bol , Amal Kasry , George S. Tulevski
发明人： Ali Afzali , Ageeth A. Bol , Amal Kasry , George S. Tulevski
IPC分类号： G01N21/00
CPC分类号： G01N21/553 , G01N21/77 , G01N2021/7773 , G01N2021/7783
摘要： A method of using an optical sensor, the optical sensor comprising a sensing surface comprising graphene layer, the sensing surface located on a substrate, includes determining a first optical absorption spectrum for the graphene layer by a spectrophotometer; adding an analyte, the analyte selected to cause a shift in the first optical absorption spectrum, to the graphene layer; determining a second optical absorption spectrum for the modified graphene layer by a spectrophotometer; determining a shift between the first optical absorption spectrum and the second optical absorption spectrum; and determining a makeup of the analyte based on the determined shift.
摘要翻译：一种使用光学传感器的方法，所述光学传感器包括感测表面，所述感测表面包括石墨烯层，所述感测表面位于基底上，包括通过分光光度计确定所述石墨烯层的第一光吸收光谱; 添加分析物，所述分析物被选择以引起第一光吸收光谱的偏移到石墨烯层; 通过分光光度计测定改性石墨烯层的第二光吸收光谱; 确定第一光吸收光谱和第二光吸收光谱之间的偏移; 以及基于所确定的移位来确定分析物的组成。

6. 发明申请

US20120000521A1 Graphene Solar Cell And Waveguide 审中-公开
标题翻译：石墨烯太阳能电池和波导
公开(公告)号：US20120000521A1
公开(公告)日：2012-01-05
申请号：US12828449
申请日：2010-07-01
申请人： Ageeth A. Bol , Amal Kasry , Marcelo Kuroda , Ahmed Maarouf , Glenn J. Martyna , Dennis M. Newns , Razvan A. Nistor , George S. Tulevski
发明人： Ageeth A. Bol , Amal Kasry , Marcelo Kuroda , Ahmed Maarouf , Glenn J. Martyna , Dennis M. Newns , Razvan A. Nistor , George S. Tulevski
IPC分类号： H01L31/0232
CPC分类号： H01L31/022425 , H01L31/02168 , H01L31/022466 , H01L31/075 , H01L31/1884 , Y02E10/548
摘要： A solar cell includes a semiconductor portion, a graphene layer disposed on a first surface of the semiconductor portion, and a first conductive layer patterned on the graphene layer, the first conductive layer including at least one bus bar portion, a plurality of fingers extending from the at least one bus bar portion, and a refractive layer disposed on the first conductive layer.
摘要翻译：太阳能电池包括半导体部分，设置在半导体部分的第一表面上的石墨烯层和在石墨烯层上图案化的第一导电层，第一导电层包括至少一个汇流条部分，多个指状物从所述至少一个汇流条部分和设置在所述第一导电层上的折射层。

7. 发明授权

US08465647B2 Isolation of single-walled carbon nanotubes from double and multi-walled carbon nanotubes 有权
标题翻译：从双层和多壁碳纳米管分离单壁碳纳米管
公开(公告)号：US08465647B2
公开(公告)日：2013-06-18
申请号：US12636426
申请日：2009-12-11
申请人： Ageeth A. Bol , George S. Tulevski
发明人： Ageeth A. Bol , George S. Tulevski
IPC分类号： B01D11/00 , B01D17/038 , C01B31/02
CPC分类号： B01D21/262 , B01D17/0217 , B82Y30/00 , B82Y40/00 , C01B32/17 , C01B32/172 , C01B2202/02 , Y10S977/845
摘要： A method and system are disclosed for separating single-walled carbon nanotubes from double and multi-walled carbon nanotubes by using the difference in the buoyant density of Single-Walled versus Multi-Walled carbon nanotubes. In one embodiment, the method comprises providing a vessel with first and second solutions. The first solution comprises a quantity of carbon nanotubes, including single-walled carbon nanotubes and double and multi-walled carbon nanotubes. The single walled nanotubes have a first density, the double and multi-walled nanotubes having a second density. The second solution in the vessel has a third density between said first and second densities. The vessel is centrifuged to form first and second layers in the vessel, with the second solution between said first and second layers. The single-walled carbon nanotubes are predominantly in the first layer, and the second and multi-walled carbon nanotubes are predominantly in the second layer.
摘要翻译：公开了通过使用单壁碳纳米管与多壁碳纳米管的浮力密度的差异来从双层和多壁碳纳米管分离单壁碳纳米管的方法和系统。在一个实施例中，该方法包括向船舶提供第一和第二解决方案。第一种解决方案包括一定量的碳纳米管，包括单壁碳纳米管和双层和多壁碳纳米管。单壁纳米管具有第一密度，双壁和多壁纳米管具有第二密度。容器中的第二溶液在所述第一和第二密度之间具有第三密度。将容器离心以在容器中形成第一和第二层，第二溶液在所述第一和第二层之间。单壁碳纳米管主要位于第一层中，第二层和多壁碳纳米管主要位于第二层。

8. 发明授权

US08395774B2 Graphene optical sensor 有权
标题翻译：石墨烯光学传感器
公开(公告)号：US08395774B2
公开(公告)日：2013-03-12
申请号：US12886908
申请日：2010-09-21
申请人： Ali Afzali , Ageeth A. Bol , Amal Kasry , George S. Tulevski
发明人： Ali Afzali , Ageeth A. Bol , Amal Kasry , George S. Tulevski
IPC分类号： G01N21/00 , G01J3/42
CPC分类号： G01N21/553 , G01N21/77 , G01N2021/7773 , G01N2021/7783
摘要： A method of using an optical sensor, the optical sensor comprising a sensing surface comprising graphene layer, the sensing surface located on a substrate, includes determining a first optical absorption spectrum for the graphene layer by a spectrophotometer; adding an analyte, the analyte selected to cause a shift in the first optical absorption spectrum, to the graphene layer; determining a second optical absorption spectrum for the modified graphene layer by a spectrophotometer; determining a shift between the first optical absorption spectrum and the second optical absorption spectrum; and determining a makeup of the analyte based on the determined shift.
摘要翻译：一种使用光学传感器的方法，所述光学传感器包括感测表面，所述感测表面包括石墨烯层，所述感测表面位于基底上，包括通过分光光度计确定所述石墨烯层的第一光吸收光谱; 添加分析物，所述分析物被选择以引起第一光吸收光谱的偏移到石墨烯层; 通过分光光度计测定改性石墨烯层的第二光吸收光谱; 确定第一光吸收光谱和第二光吸收光谱之间的偏移; 以及基于所确定的移位来确定分析物的组成。

9. 发明授权

US08927057B2 Graphene formation utilizing solid phase carbon sources 有权
标题翻译：使用固相碳源的石墨烯形成
公开(公告)号：US08927057B2
公开(公告)日：2015-01-06
申请号：US12710333
申请日：2010-02-22
申请人： Ageeth A. Bol , Roy A. Carruthers , Jack O. Chu , Alfred Grill , Christian Lavoie , Katherine L. Saenger , James C. Tsang
发明人： Ageeth A. Bol , Roy A. Carruthers , Jack O. Chu , Alfred Grill , Christian Lavoie , Katherine L. Saenger , James C. Tsang
IPC分类号： B05D7/00 , C01B31/04 , B82Y30/00 , B82Y40/00
CPC分类号： C01B31/0446 , B82Y30/00 , B82Y40/00 , C01B32/184 , Y10T428/30
摘要： A method for forming a single, few-layer, or multi-layer graphene and structure is described incorporating selecting a substrate having a buried layer of carbon underneath a metal layer, providing an ambient and providing a heat treatment to pass carbon through the metal layer to form a graphene layer on the metal layer surface or incorporating a metal-carbon layer which is heated to segregate carbon in the form of graphene to the surface or chemically reacting the metal in the metal-carbon layer with a substrate containing Si driving the carbon to the surface whereby graphene is formed.
摘要翻译：描述了形成单层，几层或多层石墨烯和结构的方法，其包括选择在金属层下方具有埋藏层的衬底的基底，提供环境并提供热处理以使碳通过金属层以在金属层表面上形成石墨烯层或掺入金属碳层，该金属碳层被加热以将石墨烯形式的碳分离到表面或使金属 - 碳层中的金属与含有驱动碳的Si的基板化学反应到形成石墨烯的表面。

10. 发明申请

US20130164882A1 TRANSPARENT CONDUCTING LAYER FOR SOLAR CELL APPLICATIONS 审中-公开
标题翻译：用于太阳能电池应用的透明导电层
公开(公告)号：US20130164882A1
公开(公告)日：2013-06-27
申请号：US13337002
申请日：2011-12-23
申请人： Ali Afzali-Ardakani , Ageeth A. Bol , Mostafa M. EI-Ashry , Amal Kasry , Ahmed Maarouf , Glenn J. Martyna , Dennis M. Newns , Razvan Nistor , George S. Tulevski
发明人： Ali Afzali-Ardakani , Ageeth A. Bol , Mostafa M. EI-Ashry , Amal Kasry , Ahmed Maarouf , Glenn J. Martyna , Dennis M. Newns , Razvan Nistor , George S. Tulevski
IPC分类号： H01L31/0352 , H01L31/0224
CPC分类号： H01L31/075 , H01L31/022466 , H01L51/444 , Y02E10/548 , Y02E10/549 , Y02P70/521
摘要： Disclosed is a method which includes forming a bottom metallic electrode on an insulating substrate; forming a semiconductor junction on the metallic electrode; forming a transparent conducting overlayer in contact with the semiconductor junction; and forming a metallic layer in contact with the transparent conducting overlayer, wherein the metallic layer is formed by a plating process. The plating process may be an electroplating process or an electroless plating process. The transparent conducting overlayer may be carbon nanotubes or graphene. The semiconductor junction may be a p-i-n semiconductor junction, a p-n semiconductor junction, an n-p semiconductor junction or an n-i-p semiconductor junction.
摘要翻译：公开了一种在绝缘基板上形成底部金属电极的方法，在所述金属电极上形成半导体结; 形成与半导体结接触的透明导电覆层; 以及形成与所述透明导电覆盖层接触的金属层，其中所述金属层通过电镀工艺形成。电镀工艺可以是电镀工艺或无电镀工艺。透明导电覆层可以是碳纳米管或石墨烯。半导体结可以是p-i-n半导体结，p-n半导体结，n-p半导体结或n-i-p半导体结。

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