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    • 8. 发明申请
    • Coating material composition
    • 涂料组成
    • US20050182188A1
    • 2005-08-18
    • US11034137
    • 2005-01-12
    • Thorsten RischeTorsten PohlJurgen MeixnerUwe KlippertThomas Feller
    • Thorsten RischeTorsten PohlJurgen MeixnerUwe KlippertThomas Feller
    • C08G18/08C08G18/12C08G18/28C09D5/00C09D175/04C08K3/00
    • C08G18/0819C08G18/0828C08G18/12C08G18/283C09D5/00C09D175/04Y10T428/31551C08G18/3234C08G18/3231C08G18/3857C08L2666/20
    • Coating compositions that are stable to thermal yellowing that include coating materials containing I) one or more dispersions of hydroxyl-free polyurethanes and/or polyurethane-ureas, II) one or more aqueous solutions or dispersions of ionically modified, hydroxyl-containing polyurethanes and/or polyurethane-ureas, other than the constituents of component I), and III) at least one crosslinker. The dispersions are obtained by A) preparing an NCO-containing polyurethane prepolymer by reacting polyisocyanates with polymeric polyols and/or polyamines having number-average molecular weights of 400 to 8000 g/mol, isocyanate-reactive, ionically or potentially ionically hydrophilicizing compounds and/or isocyanate-reactive nonionically hydrophilicizing compounds; B) either dissolving the prepolymer obtained from step A) in aliphatic ketones or, diluting the prepolymer solution if the preparation has already been carried out in the presence of A6) by further addition of aliphatic ketones, and C) reacting the remaining free NCO groups of the prepolymer with a chain extender component.
    • 对于热黄变具有稳定性的涂料组合物,其包括含有I)一种或多种无羟基聚氨酯和/或聚氨酯 - 脲的分散体的涂料,II)一种或多种离子改性的含羟基聚氨酯的水溶液或分散体和/ 或聚氨酯 - 脲,除了组分I的组分之外)和III)至少一种交联剂。 分散体通过以下方式获得:A)通过使多异氰酸酯与数均分子量为400-8000g / mol,异氰酸酯反应性,离子或潜在离子亲水化的化合物和/或多异氰酸酯的聚合多元醇和/或多胺反应来制备含NCO的聚氨酯预聚物和/ 或异氰酸酯反应性非离子亲水化化合物; B)将通过步骤A)获得的预聚物溶解在脂族酮中,或者如果制备已经在A6的存在下进一步添加脂肪族酮,则稀释预聚物溶液),和C)使剩余的游离NCO基团 的预聚物与扩链剂组分。
    • 9. 发明授权
    • Aqueous PU dispersions with improved adhesion
    • 水性PU分散体具有改善的附着力
    • US08063138B2
    • 2011-11-22
    • US11827252
    • 2007-07-11
    • Thomas MünzmayTorsten PohlUwe Klippert
    • Thomas MünzmayTorsten PohlUwe Klippert
    • C08G18/08C09K3/00
    • C08G18/0828C08G18/10C08G18/12C08G18/3228C08G18/4208C08G18/73C08G18/755C08G18/3857C08G18/3872
    • A process for preparing polyester-polyurethane resin dispersions comprising: A) reacting i) one or more polyol components having a number average molecular weight of at least 300 daltons, at least 60% by weight of component i) being a polyester polyol with the fraction of aromatic carboxylic acid groups relative to all of the carboxylic acid groups used to prepared said polyester polyol being at least 60 mol %, ii) optionally one or more polyol components having a number average molecular weight of 62 to 299 daltons, and iii) optionally a compound which is monofunctional for the purposes of the isocyanate polyaddition reaction and has an ethylene oxide content of at least 50% by weight and a number average molecular weight of at least 400 daltons, with iv) a polyisocyanate to form a prepolymer, B) dissolving the prepolymer in an organic solvent, C) reacting the prepolymer with v) one or more aliphatic and/or alicyclic primary and/or secondary polyamines having a number average molecular weight of 60 to 300 daltons, said polyamine optionally being in combination with hydrazine or hydrazine hydrate, and vi) a hydrophilicized aliphatic diamine, D) precipitating the product from C) by adding water to form a dispersion, and E) removing the organic solvent.
    • 一种制备聚酯 - 聚氨酯树脂分散体的方法,包括:a)使i)一种或多种数均分子量为至少300道尔顿的多元醇组分,至少60重量%的组分i)作为聚酯多元醇, 芳族羧酸基团相对于用于制备所述聚酯多元醇的所有羧酸基团为至少60摩尔%,ii)任选的一种或多种数均分子量为62至299道尔顿的多元醇组分,和iii)任选地 为了异氰酸酯加聚反应的目的是单官能的化合物,其环氧乙烷含量至少为50重量%,数均分子量至少为400道尔顿,其中iv)多异氰酸酯以形成预聚物,B) 将预聚物溶解在有机溶剂中,C)使预聚物与v)一种或多种具有数均分子量的脂族和/或脂环族伯和/或仲多胺反应 r重量为60至300道尔顿,所述多胺任选与肼或水合肼组合,和vi)亲水化的脂族二胺,D)通过加入水使C)沉淀形成分散体,和E)除去有机物 溶剂。
    • 10. 发明授权
    • Coating material composition
    • 涂料组成
    • US07276554B2
    • 2007-10-02
    • US11034137
    • 2005-01-12
    • Thorsten RischeTorsten PohlJürgen MeixnerUwe KlippertThomas Feller
    • Thorsten RischeTorsten PohlJürgen MeixnerUwe KlippertThomas Feller
    • C08K3/00C08G18/08C08G18/28C08G18/12
    • C08G18/0819C08G18/0828C08G18/12C08G18/283C09D5/00C09D175/04Y10T428/31551C08G18/3234C08G18/3231C08G18/3857C08L2666/20
    • Coating compositions that are stable to thermal yellowing that include coating materials containing I) one or more dispersions of hydroxyl-free polyurethanes and/or polyurethane-ureas, II) one or more aqueous solutions or dispersions of ionically modified, hydroxyl-containing polyurethanes and/or polyurethane-ureas, other than the constituents of component I), and III) at least one crosslinker. The dispersions are obtained by A) preparing an NCO-containing polyurethane prepolymer by reacting polyisocyanates with polymeric polyols and/or polyamines having number-average molecular weights of 400 to 8000 g/mol, isocyanate-reactive, ionically or potentially ionically hydrophilicizing compounds and/or isocyanate-reactive nonionically hydrophilicizing compounds; B) either dissolving the prepolymer obtained from step A) in aliphatic ketones or, diluting the prepolymer solution if the preparation has already been carried out in the presence of A6) by further addition of aliphatic ketones, and C) reacting the remaining free NCO groups of the prepolymer with a chain extender component.
    • 对于热黄变具有稳定性的涂料组合物,其包括含有I)一种或多种无羟基聚氨酯和/或聚氨酯 - 脲的分散体的涂料,II)一种或多种离子改性的含羟基聚氨酯的水溶液或分散体和/ 或聚氨酯 - 脲,除了组分I的组分之外)和III)至少一种交联剂。 分散体通过以下方式获得:A)通过使多异氰酸酯与数均分子量为400-8000g / mol,异氰酸酯反应性,离子或潜在离子亲水化的化合物和/或多异氰酸酯的聚合多元醇和/或多胺反应来制备含NCO的聚氨酯预聚物和/ 或异氰酸酯反应性非离子亲水化化合物; B)将通过步骤A)获得的预聚物溶解在脂族酮中,或者如果制备已经在A6的存在下进一步添加脂肪族酮,则稀释预聚物溶液),和C)使剩余的游离NCO基团 的预聚物与扩链剂组分。