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1. 发明授权

US07432319B2 Process for making exfoliated polyolefin/clay nanocomposites 有权
标题翻译：制造剥离的聚烯烃/粘土纳米复合材料的方法
公开(公告)号：US07432319B2
公开(公告)日：2008-10-07
申请号：US11288623
申请日：2005-11-29
申请人： Honglan Lu , Zhongyang Liu , Chih-Jian Chen Chen , Youliang Hu , Yingying Lu , Yucai Ke , Cunyue Guo
发明人： Honglan Lu , Zhongyang Liu , Chih-Jian Chen Chen , Youliang Hu , Yingying Lu , Yucai Ke , Cunyue Guo
IPC分类号： C08K3/34
CPC分类号： D21H17/68 , C01B33/44 , D21H21/52
摘要： Processes are disclosed relating to modifying clays with an olefinic functionalized surfactant containing a chain end polymerizable double bond, and to treating the thus modified organoclay with an olefin polymerization catalyst precursor, and polymerizing an olefin in the presence of the thus treated organoclay and an organoaluminum cocatalyst.
摘要翻译：公开了涉及用含有链端可聚合双键的烯属官能化表面活性剂改性粘土的方法，并用烯烃聚合催化剂前体处理如此改性的有机粘土，并在如此处理的有机粘土和有机铝助催化剂存在下聚合烯烃。

2. 发明申请

US20070197381A1 Preparation of a magnesium halide support for olefin polymerization and a catalyst composition using the same 审中-公开
公开(公告)号：US20070197381A1
公开(公告)日：2007-08-23
申请号：US11786185
申请日：2007-04-11
申请人： Honglan Lu , Gapgoung Kong , Zhongyang Liu , Chih-Jian Chen
发明人： Honglan Lu , Gapgoung Kong , Zhongyang Liu , Chih-Jian Chen
IPC分类号： B01J21/04
CPC分类号： C08F10/00 , B01J27/138 , C08F10/02 , C08F210/16 , C08F4/6548 , C08F4/6557 , C08F4/6543 , C08F4/6546 , C08F4/651 , C08F4/6555 , C08F210/14 , C08F2500/12
摘要： A magnesium halide support material for a polyolefin catalysts is disclosed. The magnesium halide of present invention is prepared by reacting magnesium with an alkylhalide in a non-polar hydrocarbon solvent. Preparation of the support does not require the use electron donating solvents and therefore does not require extensive washing to remove the solvent from the support.

3. 发明申请

US20070123630A1 Process for making exfoliated polyolefin/clay nanocomposites 有权
标题翻译：制造剥离的聚烯烃/粘土纳米复合材料的方法
公开(公告)号：US20070123630A1
公开(公告)日：2007-05-31
申请号：US11288623
申请日：2005-11-29
申请人： Honglan Lu , Zhongyang Liu , Chih-Jian Chen , Youliang Hu , Yingying Lu , Yucai Ke , Cunyue Guo
发明人： Honglan Lu , Zhongyang Liu , Chih-Jian Chen , Youliang Hu , Yingying Lu , Yucai Ke , Cunyue Guo
IPC分类号： D21H19/18
CPC分类号： D21H17/68 , C01B33/44 , D21H21/52
摘要： Processes are disclosed relating to modifying clays with an olefinic functionalized surfactant containing a chain end polymerizable double bond, and to treating the thus modified organoclay with an olefin polymerization catalyst precursor, and polymerizing an olefin in the presence of the thus treated organoclay and an organoaluminum cocatalyst.
摘要翻译：公开了涉及用含有链端可聚合双键的烯属官能化表面活性剂改性粘土的方法，并用烯烃聚合催化剂前体处理如此改性的有机粘土，并在如此处理的有机粘土和有机铝助催化剂存在下聚合烯烃。

4. 发明申请

US20080132406A1 Catalyst system for producing ethylene (co) polymer with improved branch distribution 有权
标题翻译：用于生产具有改进的分支分布的乙烯（共）聚合物的催化剂体系
公开(公告)号：US20080132406A1
公开(公告)日：2008-06-05
申请号：US11634325
申请日：2006-12-05
申请人： Gapgoung Kong , Zhongyang Liu , Honglan Lu
发明人： Gapgoung Kong , Zhongyang Liu , Honglan Lu
IPC分类号： B01J31/14 , C07F7/02
CPC分类号： C08F10/00 , C08F210/16 , C08F4/6567 , C08F210/14 , C08F2500/08 , C08F2500/12 , C08F2500/20
摘要： A process for synthesizing a catalyst component for manufacturing ethylene polymer and co-polymer. The present invention provides a process for synthesizing catalyst component (A), comprising forming a complex by contacting the solid intermediate (B) with an aluminum compound represented by formula X3-nAl(OY)n, and alkyl metal (C), wherein X is halide, Y is a hydrocarbon group or chelating carbonyl group, and wherein 1 is less than or equal to n which is less than or equal to 3, and then contacting the complex with titanium halide having formula TiX4 wherein X is halide. Solid intermediate (B) is formed by reacting magnesium metal with alkyl halide in the presence of alkoxy aluminum represented by formula Al(ORa)3, silicon halide represented by formula SiX4 and alkoxy silane represented by formula Si(ORb)4, wherein Ra and Rb are an aromatic or aliphatic alkyl group and wherein X is halide. Alkyl metal (C) is synthesized by reacting alkyl aluminum compounds represented by formula AlRc3 with a secondary amine having formula HNRd2 and then by reacting with alkyl magnesium compounds represented by formula ReMgRf, wherein Rc, Rd, Re and Rf are an aromatic or aliphatic alkyl group. The catalyst component is suitable for producing ethylene polymer and co-polymer with narrow molecular weight distribution as well as improved branching compositional distribution.
摘要翻译：一种合成乙烯聚合物和共聚物制备催化剂组分的方法。本发明提供了一种合成催化剂组分（A）的方法，包括通过使固体中间体（B）与由式X 3-n Al（OY）表示的铝化合物接触而形成络合物 >烷基金属（C），其中X是卤化物，Y是烃基或螯合羰基，其中1小于或等于n小于或等于3，然后使络合物与具有式TiX 4的钛卤化物接触，其中X是卤化物。固体中间体（B）是通过使镁金属与烷基卤化物在由式Al（OR 3）3表示的烷氧基铝的存在下反应形成的，由式SiX 和由式Si（OR b）4 S表示的烷氧基硅烷，其中R a， b为芳族或脂族烷基，其中X为卤化物。烷基金属（C）通过使由式AlR 3 C 3表示的烷基铝化合物与具有式HNR的叔胺反应合成，然后通过与由式R 0表示的烷基镁化合物反应，其中R 0，R 2， d，R f和R f是芳族或脂族烷基。催化剂组分适用于生产具有窄分子量分布的乙烯聚合物和共聚物以及改进的支链组成分布。

5. 发明授权

US07307036B2 Highly active alpha-olefin polymerization catalyst 有权
标题翻译：高活性α-烯烃聚合催化剂
公开(公告)号：US07307036B2
公开(公告)日：2007-12-11
申请号：US10896723
申请日：2004-07-22
申请人： Guangxue Xu , Honglan Lu , Zhongyang Liu , Chih-Jian Chen
发明人： Guangxue Xu , Honglan Lu , Zhongyang Liu , Chih-Jian Chen
IPC分类号： B01J31/38
CPC分类号： C08F10/00 , C08F210/16 , Y02P20/52 , C08F4/6548 , C08F4/6565 , C08F210/06 , C08F2500/12 , C08F2500/24
摘要： A highly active alpha-olefin polymerization catalyst component is disclosed. In the presence of a co-catalyst, the catalyst component is useful for the production of LLDPE resins. The catalyst component is produced by a method whereby organic silicon compounds are reacted with a transition metal complex and active transition metal species is deposited on a silicon-containing MgCl2 that is prepared in situ in the presence of the organic silicon compounds.
摘要翻译：公开了一种高活性α-烯烃聚合催化剂组分。在助催化剂存在下，催化剂组分可用于生产LLDPE树脂。催化剂组分通过使有机硅化合物与过渡金属络合物反应的方法制备，并且活性过渡金属物质沉积在含硅MgCl 2上，所述MgCl 2 2原位在有机硅化合物。

6. 发明授权

US06841498B2 Catalyst system for ethylene (co)polymerization 有权
标题翻译：用于乙烯（共）聚合的催化剂体系
公开(公告)号：US06841498B2
公开(公告)日：2005-01-11
申请号：US10365556
申请日：2003-02-12
申请人： Gapgoung Kong , Zhongyang Liu , Honglan Lu
发明人： Gapgoung Kong , Zhongyang Liu , Honglan Lu
IPC分类号： C08F4/02 , C08F4/60 , C08F10/02 , C08F110/02 , C08F210/16 , B01J31/00 , B01J37/00
CPC分类号： C08F10/02 , C08F110/02 , C08F210/16 , C08F4/6555 , C08F4/651 , C08F2500/12 , C08F210/14
摘要： Disclosed is a new titanium based catalyst system for (co)-polymerizing ethylene or ethylene with alpha-olefin having 3 to 10 carbons. The catalyst is obtained by contacting a magnesium halide support with an aluminum compound and with a titanium halide compound and then treating the resulting solid with a magnesium-amide complex. The catalyst system is suitable for producing ethylene polymer and co-polymer with narrow molecular weight distribution as well as improved branching compositional distribution.
摘要翻译：公开了一种用于（共）聚合乙烯或乙烯与具有3至10个碳的α-烯烃的新的钛基催化剂体系。催化剂通过使卤化镁载体与铝化合物和卤化钛化合物接触，然后用镁 - 酰胺络合物处理所得固体而获得。催化剂体系适用于生产具有窄分子量分布的乙烯聚合物和共聚物以及改进的支链组成分布。

7. 发明授权

US07651969B2 Catalyst system for producing ethylene (co) polymer with improved branch distribution 有权
标题翻译：用于生产具有改进的分支分布的乙烯（共）聚合物的催化剂体系
公开(公告)号：US07651969B2
公开(公告)日：2010-01-26
申请号：US11634325
申请日：2006-12-05
申请人： Gapgoung Kong , Zhongyang Liu , Honglan Lu
发明人： Gapgoung Kong , Zhongyang Liu , Honglan Lu
IPC分类号： B01J21/00 , B01J37/00
CPC分类号： C08F10/00 , C08F210/16 , C08F4/6567 , C08F210/14 , C08F2500/08 , C08F2500/12 , C08F2500/20
摘要： A process for synthesizing a catalyst component for manufacturing ethylene polymer and co-polymer. The present invention provides a process for synthesizing catalyst component (A), comprising forming a complex by contacting the solid intermediate (B) with an aluminum compound represented by formula X3-nAl(OY)n, and alkyl metal (C), wherein X is halide, Y is a hydrocarbon group or chelating carbonyl group, and wherein 1 is less than or equal to n which is less than or equal to 3, and then contacting the complex with titanium halide having formula TiX4 wherein X is halide. Solid intermediate (B) is formed by reacting magnesium metal with alkyl halide in the presence of alkoxy aluminum represented by formula Al(ORa)3, silicon halide represented by formula SiX4 and alkoxy silane represented by formula Si(ORb)4, wherein Ra and Rb are an aromatic or aliphatic alkyl group and wherein X is halide. Alkyl metal (C) is synthesized by reacting alkyl aluminum compounds represented by formula AlRc3 with a secondary amine having formula HNRd2 and then by reacting with alkyl magnesium compounds represented by formula ReMgRf, wherein Rc, Rd, Re and Rf are an aromatic or aliphatic alkyl group. The catalyst component is suitable for producing ethylene polymer and co-polymer with narrow molecular weight distribution as well as improved branching compositional distribution.
摘要翻译：一种合成乙烯聚合物和共聚物制备催化剂组分的方法。本发明提供了一种合成催化剂组分（A）的方法，包括通过使固体中间体（B）与式X3-nAl（OY）n表示的铝化合物和烷基金属（C）接触来形成络合物，其中X 是卤化物，Y是烃基或螯合羰基，其中1小于或等于n小于或等于3，然后使配合物与式TiX 4的卤化钛接触，其中X是卤化物。由式Al（ORa）3表示的烷氧基铝，由式SiX4表示的卤化硅和由式Si（ORb）4表示的烷氧基硅烷）存在下，使镁金属与烷基卤反应形成固体中间体（B），其中R a和 Rb是芳族或脂族烷基，其中X是卤素。烷基金属（C）通过使由式AlRc3表示的烷基铝化合物与具有式HNRd2的仲胺反应，然后与由式ReMgRf表示的烷基镁化合物反应，其中Rc，Rd，Re和Rf是芳族或脂族烷基组。催化剂组分适用于生产具有窄分子量分布的乙烯聚合物和共聚物以及改进的支链组成分布。

8. 发明授权

US07211534B2 Preparation of a magnesium halide support for olefin polymerization and a catalyst composition using the same 有权
标题翻译：制备用于烯烃聚合的卤化镁载体和使用其的催化剂组合物
公开(公告)号：US07211534B2
公开(公告)日：2007-05-01
申请号：US10365558
申请日：2003-02-12
申请人： Honglan Lu , Gapgoung Kong , Zhongyang Liu , Chih-Jian Chen
发明人： Honglan Lu , Gapgoung Kong , Zhongyang Liu , Chih-Jian Chen
IPC分类号： B01J31/00
CPC分类号： C08F10/00 , B01J27/138 , C08F10/02 , C08F210/16 , C08F4/6548 , C08F4/6557 , C08F4/6543 , C08F4/6546 , C08F4/651 , C08F4/6555 , C08F210/14 , C08F2500/12
摘要： A magnesium halide support material for a polyolefin catalysts is disclosed. The magnesium halide of present invention is prepared by reacting magnesium with an alkylhalide in a non-polar hydrocarbon solvent. Preparation of the support does not require the use electron donating solvents and therefore does not require extensive washing to remove the solvent from the support.
摘要翻译：公开了一种用于聚烯烃催化剂的卤化镁载体材料。本发明的卤化镁是通过使镁与烷基卤在非极性烃溶剂中反应来制备的。载体的制备不需要使用电子给体溶剂，因此不需要大量洗涤以从载体中除去溶剂。

9. 发明申请

US20060019821A1 Highly active alpha-olefin polymerization catalyst 有权
标题翻译：高活性α-烯烃聚合催化剂
公开(公告)号：US20060019821A1
公开(公告)日：2006-01-26
申请号：US10896723
申请日：2004-07-22
申请人： Guangxue Xu , Honglan Lu , Zhongyang Liu , Chih-Jian Chen
发明人： Guangxue Xu , Honglan Lu , Zhongyang Liu , Chih-Jian Chen
IPC分类号： B01J31/00
CPC分类号： C08F10/00 , C08F210/16 , Y02P20/52 , C08F4/6548 , C08F4/6565 , C08F210/06 , C08F2500/12 , C08F2500/24
摘要： A highly active alpha-olefin polymerization catalyst component is disclosed. In the presence of a co-catalyst, the catalyst component is useful for the production of LLDPE resins. The catalyst component is produced by a method whereby organic silicon compounds are reacted with a transition metal complex and active transition metal species is deposited on a silicon-containing MgCl2 that is prepared in situ in the presence of the organic silicon compounds.
摘要翻译：公开了一种高活性α-烯烃聚合催化剂组分。在助催化剂存在下，催化剂组分可用于生产LLDPE树脂。催化剂组分通过使有机硅化合物与过渡金属络合物反应的方法制备，并且活性过渡金属物质沉积在含硅MgCl 2上，所述MgCl 2 2原位在有机硅化合物。

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