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1. 发明授权

US06248837B1 Process for preparing polyolefin diblock copolymers involving borane chain transfer reaction in transition metal-mediated olefin polymerization 失效
标题翻译：在过渡金属介导的烯烃聚合中涉及硼烷链转移反应的聚烯烃二嵌段共聚物的制备方法
公开(公告)号：US06248837B1
公开(公告)日：2001-06-19
申请号：US09359329
申请日：1999-07-21
申请人： Tze-Chiang Chung , Guangxue Xu
发明人： Tze-Chiang Chung , Guangxue Xu
IPC分类号： C08F29300
CPC分类号： C08F293/00 , C08G63/00
摘要： Polyolefin diblock copolymers are prepared via a chain transfer reaction with a borane dimer compound during a transition metal-catalyzed olefin polymerization in a process that resembles a transformation from transition metal coordination polymerization to free radical polymerization via a borane end group. The polyolefin diblock copolymers may be represented by the following formula: (Transition Metal Prepared Polyolefin)-b-(Free Radical Prepared Polymer), wherein the polyolefin segment is a homo-, co- and ter-polymer prepared by transition metal (especially metallocene catalyst) coordination polymerization of at least one olefin, and the free radical prepared polymer segment is prepared by free radical polymerization of at least one vinyl monomer, such as styrene, maleic anhydride, acrylates, methacrylates and their mixtures. The resulting diblock copolymers are useful as the interfacial materials to improve the interaction between polyolefins and other materials.
摘要翻译：在过渡金属催化的烯烃聚合期间，通过与硼烷二聚体化合物的链转移反应，在类似于从过渡金属配位聚合转变成通过硼烷端基进行自由基聚合的方法中制备聚烯烃二嵌段共聚物。聚烯烃二嵌段共聚物可以由下式表示：（过渡金属制备的聚烯烃）-b-（自由基制备的聚合物），其中聚烯烃链段是由过渡金属（特别是茂金属）制备的均聚物，共聚物和三聚物催化剂）配位聚合，并且通过至少一种乙烯基单体如苯乙烯，马来酸酐，丙烯酸酯，甲基丙烯酸酯及其混合物的自由基聚合制备自由基制备的聚合物链段。所得的二嵌段共聚物可用作界面材料以改善聚烯烃和其它材料之间的相互作用。

2. 发明申请

US20130253150A1 Ethylene CoPolymers With A Novel Composition Distribution And Processes For Making The Same 有权
标题翻译：具有新型组成分布的乙烯共聚物及其制备方法
公开(公告)号：US20130253150A1
公开(公告)日：2013-09-26
申请号：US13429013
申请日：2012-03-23
申请人： Honglan Lu , Guangxue Xu
发明人： Honglan Lu , Guangxue Xu
IPC分类号： C08F210/16
CPC分类号： C08F210/16 , C08F4/6055 , C08F10/00 , C08F4/6565 , C08F210/14 , C08F2500/12 , C08F2500/26 , C08F2500/21 , C08F2500/06
摘要： A Ziegler-Natta catalyzed ethylene copolymer having a novel composition distribution in which comonomers are incorporated into the high molecular weight polymer molecules and distributed evenly among the entire polyethylene chains, and a method for making the same are provided. The resins having a novel composition distribution have controlled molecular weight distribution which is narrower than conventional ZN-ethylene copolymers but broader than single-site catalyzed ethylene copolymers. The resins having a novel composition distribution exhibit a superior tear strength and impact strength.
摘要翻译：具有新的组成分布的齐格勒 - 纳塔催化的乙烯共聚物，其中将共聚单体并入高分子量聚合物分子并均匀分布在整个聚乙烯链中，并提供其制备方法。具有新型组成分布的树脂具有受控的分子量分布，其比常规ZN-乙烯共聚物窄，但比单位点催化的乙烯共聚物更宽。具有新组成分布的树脂具有优异的撕裂强度和冲击强度。

3. 发明授权

US07307036B2 Highly active alpha-olefin polymerization catalyst 有权
标题翻译：高活性α-烯烃聚合催化剂
公开(公告)号：US07307036B2
公开(公告)日：2007-12-11
申请号：US10896723
申请日：2004-07-22
申请人： Guangxue Xu , Honglan Lu , Zhongyang Liu , Chih-Jian Chen
发明人： Guangxue Xu , Honglan Lu , Zhongyang Liu , Chih-Jian Chen
IPC分类号： B01J31/38
CPC分类号： C08F10/00 , C08F210/16 , Y02P20/52 , C08F4/6548 , C08F4/6565 , C08F210/06 , C08F2500/12 , C08F2500/24
摘要： A highly active alpha-olefin polymerization catalyst component is disclosed. In the presence of a co-catalyst, the catalyst component is useful for the production of LLDPE resins. The catalyst component is produced by a method whereby organic silicon compounds are reacted with a transition metal complex and active transition metal species is deposited on a silicon-containing MgCl2 that is prepared in situ in the presence of the organic silicon compounds.
摘要翻译：公开了一种高活性α-烯烃聚合催化剂组分。在助催化剂存在下，催化剂组分可用于生产LLDPE树脂。催化剂组分通过使有机硅化合物与过渡金属络合物反应的方法制备，并且活性过渡金属物质沉积在含硅MgCl 2上，所述MgCl 2 2原位在有机硅化合物。

4. 发明申请

US20060019821A1 Highly active alpha-olefin polymerization catalyst 有权
标题翻译：高活性α-烯烃聚合催化剂
公开(公告)号：US20060019821A1
公开(公告)日：2006-01-26
申请号：US10896723
申请日：2004-07-22
申请人： Guangxue Xu , Honglan Lu , Zhongyang Liu , Chih-Jian Chen
发明人： Guangxue Xu , Honglan Lu , Zhongyang Liu , Chih-Jian Chen
IPC分类号： B01J31/00
CPC分类号： C08F10/00 , C08F210/16 , Y02P20/52 , C08F4/6548 , C08F4/6565 , C08F210/06 , C08F2500/12 , C08F2500/24
摘要： A highly active alpha-olefin polymerization catalyst component is disclosed. In the presence of a co-catalyst, the catalyst component is useful for the production of LLDPE resins. The catalyst component is produced by a method whereby organic silicon compounds are reacted with a transition metal complex and active transition metal species is deposited on a silicon-containing MgCl2 that is prepared in situ in the presence of the organic silicon compounds.
摘要翻译：公开了一种高活性α-烯烃聚合催化剂组分。在助催化剂存在下，催化剂组分可用于生产LLDPE树脂。催化剂组分通过使有机硅化合物与过渡金属络合物反应的方法制备，并且活性过渡金属物质沉积在含硅MgCl 2上，所述MgCl 2 2原位在有机硅化合物。

5. 发明授权

US07618913B2 Highly active alpha-olefin copolymerization catalyst system 有权
标题翻译：高活性α-烯烃共聚催化剂体系
公开(公告)号：US07618913B2
公开(公告)日：2009-11-17
申请号：US11513803
申请日：2006-08-31
申请人： Guangxue Xu , Honglan Lu , Chih-Jian Chen
发明人： Guangxue Xu , Honglan Lu , Chih-Jian Chen
IPC分类号： C08F4/64 , C08F4/649 , C08F4/642
CPC分类号： C08F10/00 , C08F210/16 , C08F4/6565 , C08F4/651 , C08F210/14 , C08F2500/12 , C08F210/08
摘要： A high activity magnesium-based supported catalyst component useful in a catalyst system for the compolymerization of ethylene and alpha-olefin and a process for preparing the catalyst component is described. In the process, alkoxysilane ester is contacted with a halogen-substituted silane to form an organic silicon complex. Optionally, the organic silicon complex is contacted with an aminosilane compound to form an organic silicon complex containing nitrogen. The organic silicon complex containing nitrogen or the organic silicon complex is contacted with a transition metal compound to form an organic silicon complex containing transition metal. The organic silicon complex containing transition metal is then contacted with a substituted aromatic ring nitrogen compound to form a fourth reaction complex, which is then contacted with a magnesium-based composite support that has been prepared in situ by reacting metallic magnesium with an alkyl or aromatic halide to form the catalyst component.
摘要翻译：描述了用于乙烯和α-烯烃的聚合的催化剂体系中的高活性镁基负载催化剂组分和制备催化剂组分的方法。在此过程中，烷氧基硅烷酯与卤素取代的硅烷接触以形成有机硅络合物。任选地，有机硅络合物与氨基硅烷化合物接触以形成含氮的有机硅络合物。含有氮或有机硅络合物的有机硅配合物与过渡金属化合物接触以形成含有过渡金属的有机硅络合物。然后将含有过渡金属的有机硅络合物与取代的芳环氮化合物接触，形成第四反应络合物，然后与镁基复合载体接触，镁基复合载体原位通过使金属镁与烷基或芳族卤化物以形成催化剂组分。

6. 发明申请

US20080058198A1 Highly active alpha-olefin copolymerization catalyst system 有权
标题翻译：高活性α-烯烃共聚催化剂体系
公开(公告)号：US20080058198A1
公开(公告)日：2008-03-06
申请号：US11513803
申请日：2006-08-31
申请人： Guangxue Xu , Honglan Lu , Chih-Jian Chen
发明人： Guangxue Xu , Honglan Lu , Chih-Jian Chen
IPC分类号： C08F4/02
CPC分类号： C08F10/00 , C08F210/16 , C08F4/6565 , C08F4/651 , C08F210/14 , C08F2500/12 , C08F210/08
摘要： A high activity magnesium-based supported catalyst component useful in a catalyst system for the compolymerization of ethylene and alpha-olefin and a process for preparing the catalyst component is described. In the process, alkoxysilane ester is contacted with a halogen-substituted silane to form an organic silicon complex. Optionally, the organic silicon complex is contacted with an aminosilane compound to form an organic silicon complex containing nitrogen. The organic silicon complex containing nitrogen or the organic silicon complex is contacted with a transition metal compound to form an organic silicon complex containing transition metal. The organic silicon complex containing transition metal is then contacted with a substituted aromatic ring nitrogen compound to form a fourth reaction complex, which is then contacted with a magnesium-based composite support that has been prepared in situ by reacting metallic magnesium with an alkyl or aromatic halide to form the catalyst component.
摘要翻译：描述了用于乙烯和α-烯烃的聚合的催化剂体系中的高活性镁基负载催化剂组分和制备催化剂组分的方法。在此过程中，烷氧基硅烷酯与卤素取代的硅烷接触以形成有机硅络合物。任选地，有机硅络合物与氨基硅烷化合物接触以形成含氮的有机硅络合物。含有氮或有机硅络合物的有机硅配合物与过渡金属化合物接触以形成含有过渡金属的有机硅络合物。然后将含有过渡金属的有机硅络合物与取代的芳环氮化合物接触，形成第四反应络合物，然后与镁基复合载体接触，镁基复合载体原位通过使金属镁与烷基或芳族卤化物以形成催化剂组分。

7. 发明申请

US20050009690A1 Catalyst component for olefin polymerization 有权
标题翻译：用于烯烃聚合的催化剂组分
公开(公告)号：US20050009690A1
公开(公告)日：2005-01-13
申请号：US10617238
申请日：2003-07-10
申请人： Guangxue Xu , Honglan Lu , Chih-Jian Chen
发明人： Guangxue Xu , Honglan Lu , Chih-Jian Chen
IPC分类号： B01J31/00 , C08F10/00 , C08F110/02 , C08F210/16
CPC分类号： C08F10/00 , C08F110/02 , C08F210/16 , Y02P20/52 , C08F4/651 , C08F4/6548 , C08F4/6565 , C08F2500/12 , C08F2500/20 , C08F210/14
摘要： A solid catalyst component useful for the (co)-polymerization of olefins is disclosed. The catalyst component is prepared by reacting an activated magnesium halide composite support with a halogenized transition metal compound and a chelating diamide compound in the presence of organo-magnesium as a promoting agent and halogenized silicon or boron compounds as an activator. The catalyst component can be used with an organo-aluminum compound to provide a solid catalyst system that is compatible with slurry and gas phase polymerization processes. Linear low density polyethylene (LLDPE) produced using the catalyst component of the present invention displays a low molecular weight distribution, improved co-monomer incorporation, low content of the low molecular weight component, and excellent morphological properties such as spherical shape and high bulk density.
摘要翻译：公开了一种用于烯烃（共）聚合的固体催化剂组分。催化剂组分通过在有机镁作为促进剂和卤化硅或硼化合物作为活化剂的存在下使活化的卤化镁复合载体与卤化过渡金属化合物和螯合二酰胺化合物反应来制备。催化剂组分可以与有机铝化合物一起使用以提供与淤浆和气相聚合方法相容的固体催化剂体系。使用本发明的催化剂组分制备的线性低密度聚乙烯（LLDPE）显示低分子量分布，改进的共聚单体掺入，低分子量组分含量，以及优异的形态特性如球形和高体积密度。

8. 发明授权

US08993693B2 Ethylene copolymers with a novel composition distribution and processes for making the same 有权
标题翻译：具有新型组成分布的乙烯共聚物及其制备方法
公开(公告)号：US08993693B2
公开(公告)日：2015-03-31
申请号：US13429013
申请日：2012-03-23
申请人： Honglan Lu , Guangxue Xu
发明人： Honglan Lu , Guangxue Xu
IPC分类号： C08F210/16 , C08F2/34 , C08F4/605
CPC分类号： C08F210/16 , C08F4/6055 , C08F10/00 , C08F4/6565 , C08F210/14 , C08F2500/12 , C08F2500/26 , C08F2500/21 , C08F2500/06
摘要： A Ziegler-Natta catalyzed ethylene copolymer having a novel composition distribution in which comonomers are incorporated into the high molecular weight polymer molecules and distributed evenly among the entire polyethylene chains, and a method for making the same are provided. The resins having a novel composition distribution have controlled molecular weight distribution which is narrower than conventional ZN-ethylene copolymers but broader than single-site catalyzed ethylene copolymers. The resins having a novel composition distribution exhibit a superior tear strength and impact strength.
摘要翻译：具有新的组成分布的齐格勒 - 纳塔催化的乙烯共聚物，其中将共聚单体并入高分子量聚合物分子并均匀分布在整个聚乙烯链中，并提供其制备方法。具有新型组成分布的树脂具有受控的分子量分布，其比常规ZN-乙烯共聚物窄，但比单位点催化的乙烯共聚物更宽。具有新组成分布的树脂具有优异的撕裂强度和冲击强度。

9. 发明授权

US07582712B1 Alpha-olefins polymerization catalyst 有权
标题翻译： α-烯烃聚合催化剂
公开(公告)号：US07582712B1
公开(公告)日：2009-09-01
申请号：US12151898
申请日：2008-05-09
申请人： Guangxue Xu , Honglan Lu
发明人： Guangxue Xu , Honglan Lu
IPC分类号： C08F4/42
CPC分类号： C08F10/00 , C08F210/16 , C08F4/6565 , C08F210/14 , C08F2500/12
摘要： Methods and apparatus to form a catalyst precursor, comprising combining in a reactor magnesium, an alkoxysilane compound, a halogenized silicon compound, a halogenized transition metal compound, a substituted aromatic furan compound having a structural formula, and an alkyl halide or aromatic halide compound to obtain a solid catalyst precursor, wherein the alkoxysilane compound and halogenized silicon compound are combined prior to either being exposed to the halogenized transition metal compound, and wherein the alkyl halide or aromatic halide compound is introduced to the reactor as the final step.
摘要翻译：形成催化剂前体的方法和装置，包括在反应器中将镁，烷氧基硅烷化合物，卤化硅化合物，卤化过渡金属化合物，具有结构式的取代的芳族呋喃化合物和烷基卤化物或芳族卤化物化合物获得固体催化剂前体，其中烷氧基硅烷化合物和卤化硅化合物在暴露于卤化过渡金属化合物之前合并，其中烷基卤化物或芳族卤化物化合物作为最终步骤引入反应器。

10. 发明授权

US06992034B2 Catalyst component for olefin polymerization 有权
标题翻译：用于烯烃聚合的催化剂组分
公开(公告)号：US06992034B2
公开(公告)日：2006-01-31
申请号：US10617238
申请日：2003-07-10
申请人： Guangxue Xu , Honglan Lu , Chih-Jian Chen
发明人： Guangxue Xu , Honglan Lu , Chih-Jian Chen
IPC分类号： C08F4/609 , C08F4/602 , C08F4/603 , C08F4/606
CPC分类号： C08F10/00 , C08F110/02 , C08F210/16 , Y02P20/52 , C08F4/651 , C08F4/6548 , C08F4/6565 , C08F2500/12 , C08F2500/20 , C08F210/14
摘要： A solid catalyst component useful for the (co)-polymerization of olefins is disclosed. The catalyst component is prepared by reacting an activated magnesium halide composite support with a halogenized transition metal compound and a chelating diamide compound in the presence of organo-magnesium as a promoting agent and halogenized silicon or boron compounds as an activator. The catalyst component can be used with an organo-aluminum compound to provide a solid catalyst system that is compatible with slurry and gas phase polymerization processes. Linear low density polyethylene (LLDPE) produced using the catalyst component of the present invention displays a low molecular weight distribution, improved co-monomer incorporation, low content of the low molecular weight component, and excellent morphological properties such as spherical shape and high bulk density.
摘要翻译：公开了一种用于烯烃（共）聚合的固体催化剂组分。催化剂组分通过在有机镁作为促进剂和卤化硅或硼化合物作为活化剂的存在下使活化的卤化镁复合载体与卤化过渡金属化合物和螯合二酰胺化合物反应来制备。催化剂组分可以与有机铝化合物一起使用以提供与淤浆和气相聚合方法相容的固体催化剂体系。使用本发明的催化剂组分制备的线性低密度聚乙烯（LLDPE）显示低分子量分布，改进的共聚单体掺入，低分子量组分含量，以及优异的形态特性如球形和高体积密度。

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